CA2328385C - Installation et procede de production d'hydrocarbures par synthese fischer-tropsch dans un reacteur comportant sur la boucle de recirculation des moyens de limitation de l'attrition du solide - Google Patents

Installation et procede de production d'hydrocarbures par synthese fischer-tropsch dans un reacteur comportant sur la boucle de recirculation des moyens de limitation de l'attrition du solide Download PDF

Info

Publication number: CA2328385C
Authority: CA; Canada
Prior art keywords: suspension; zone; reaction; solid particles; liquid
Prior art date: 1999-12-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002328385A

Other languages

English (en)

French (fr)

Other versions

CA2328385A1 (fr

Inventor

Eric Lenglet

Jean-Marc Schweitzer

Franck Gaviot-Blanc

Giuseppe Belmonte

Vincenzo Piccolo

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

IFP Energies Nouvelles IFPEN

Agip Petroli SpA

Eni SpA

Original Assignee

IFP Energies Nouvelles IFPEN

Agip Petroli SpA

Eni SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-12-22

Filing date

2000-12-19

Publication date

2009-11-24

2000-12-19 Application filed by IFP Energies Nouvelles IFPEN, Agip Petroli SpA, Eni SpA filed Critical IFP Energies Nouvelles IFPEN

2001-06-22 Publication of CA2328385A1 publication Critical patent/CA2328385A1/fr

2009-11-24 Application granted granted Critical

2009-11-24 Publication of CA2328385C publication Critical patent/CA2328385C/fr

2020-12-19 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000007787 solid Substances 0.000 title claims abstract description 62
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 49
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 38
230000015572 biosynthetic process Effects 0.000 title claims abstract description 33
238000003786 synthesis reaction Methods 0.000 title claims abstract description 33
238000000034 method Methods 0.000 title claims abstract description 18
238000009434 installation Methods 0.000 title claims abstract description 12
230000003134 recirculating effect Effects 0.000 title 1
239000002245 particle Substances 0.000 claims abstract description 71
238000006243 chemical reaction Methods 0.000 claims abstract description 60
239000000725 suspension Substances 0.000 claims abstract description 60
239000007788 liquid Substances 0.000 claims abstract description 43
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 22
238000000926 separation method Methods 0.000 claims abstract description 21
239000003054 catalyst Substances 0.000 claims description 28
239000007789 gas Substances 0.000 claims description 13
238000007872 degassing Methods 0.000 claims description 12
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 9
239000001257 hydrogen Substances 0.000 claims description 9
229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
239000000047 product Substances 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 7
239000011949 solid catalyst Substances 0.000 claims description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
238000013467 fragmentation Methods 0.000 claims description 5
238000006062 fragmentation reaction Methods 0.000 claims description 5
238000009826 distribution Methods 0.000 claims description 4
238000000605 extraction Methods 0.000 claims description 4
150000002431 hydrogen Chemical class 0.000 claims description 3
230000001133 acceleration Effects 0.000 claims description 2
239000012263 liquid product Substances 0.000 claims description 2
230000002194 synthesizing effect Effects 0.000 claims 1
239000002002 slurry Substances 0.000 description 19
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
238000005096 rolling process Methods 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
230000003628 erosive effect Effects 0.000 description 2
239000010419 fine particle Substances 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000011707 mineral Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000011882 ultra-fine particle Substances 0.000 description 2
238000011144 upstream manufacturing Methods 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000011324 bead Substances 0.000 description 1
239000007809 chemical reaction catalyst Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
-1 fractions naphtha Chemical class 0.000 description 1
238000001033 granulometry Methods 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000011148 porous material Substances 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/006—Separating solid material from the gas/liquid stream by filtration
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
- C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
- C07C1/066—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system used for dissolving, suspending or transporting the catalyst
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00654—Controlling the process by measures relating to the particulate material
- B01J2208/0069—Attrition
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Combustion & Propulsion (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA002328385A 1999-12-22 2000-12-19 Installation et procede de production d'hydrocarbures par synthese fischer-tropsch dans un reacteur comportant sur la boucle de recirculation des moyens de limitation de l'attrition du solide Expired - Fee Related CA2328385C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR9916316		1999-12-22
FR9916316A FR2802832B1 (fr)	1999-12-22	1999-12-22	Installation et procede de production d'hydrocarbures par synthese fischer-tropsch dans un reacteur comportant sur la boucle de recirculation des moyens de limitation de l'attrition du solide

Publications (2)

Publication Number	Publication Date
CA2328385A1 CA2328385A1 (fr)	2001-06-22
CA2328385C true CA2328385C (fr)	2009-11-24

Family

ID=9553690

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002328385A Expired - Fee Related CA2328385C (fr)	1999-12-22	2000-12-19	Installation et procede de production d'hydrocarbures par synthese fischer-tropsch dans un reacteur comportant sur la boucle de recirculation des moyens de limitation de l'attrition du solide

Country Status (5)

Country	Link
CA (1)	CA2328385C (it)
FR (1)	FR2802832B1 (it)
IT (1)	IT1320132B1 (it)
NO (1)	NO321115B1 (it)
ZA (1)	ZA200007692B (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2005068407A1 (en)	2004-01-07	2005-07-28	Conocophillips Company	Systems and methods for catalyst/hydrocarbon product separation

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2161974A (en) *	1937-01-21	1939-06-13	Standard Oil Dev Co	Method of controlling exothermic reactions
US2440109A (en) *	1945-02-06	1948-04-20	Texas Co	Method of effecting catalytic reactions
DE3245318C3 (de) *	1982-12-08	1996-06-20	Bayer Ag	Verfahren zur Durchführung von Druckreaktionen mit suspendierten Katalysatoren
US5900159A (en) *	1996-02-29	1999-05-04	Shell Oil Company	Method for separating liquid from a slurry
ITMI980865A1 (it) *	1998-04-23	1999-10-23	Eniricerche S P A Ora Enitecno	Procedimento per la preparazione di idrocarburi da gas di sintesi

1999
- 1999-12-22 FR FR9916316A patent/FR2802832B1/fr not_active Expired - Fee Related
2000
- 2000-12-19 CA CA002328385A patent/CA2328385C/fr not_active Expired - Fee Related
- 2000-12-20 ZA ZA200007692A patent/ZA200007692B/xx unknown
- 2000-12-20 NO NO20006516A patent/NO321115B1/no not_active IP Right Cessation
- 2000-12-21 IT IT2000MI002782A patent/IT1320132B1/it active

Also Published As

Publication number	Publication date
ITMI20002782A1 (it)	2002-06-21
FR2802832B1 (fr)	2002-01-18
NO20006516D0 (no)	2000-12-20
NO321115B1 (no)	2006-03-20
FR2802832A1 (fr)	2001-06-29
IT1320132B1 (it)	2003-11-18
ZA200007692B (en)	2002-06-20
NO20006516L (no)	2001-06-25
CA2328385A1 (fr)	2001-06-22

Legal Events

Date	Code	Title	Description
2005-11-03	EEER	Examination request
2020-01-30	MKLA	Lapsed	Effective date: 20191219

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EP2207608B1 (fr)	2019-01-23	Dispositif de separation d'un solide finement divise en suspension dans un liquide visqueux
CA2400742C (fr)	2010-05-25	Procede de production d'hydrocarbures a partir de gaz de synthese dans un reacteur triphasique
US20100184873A1 (en)	2010-07-22	Multi stage process for producing hydrocarbons from syngas
EP1448749B1 (fr)	2008-02-27	Procede de conversion de gaz de synthese dans des reacteurs en serie
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FR2832415A1 (fr)	2003-05-23	Procede de conversion de gaz de synthese dans des reacteurs en serie
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