CH200068A - Process for the production of an acidic wool dye. - Google Patents
Process for the production of an acidic wool dye.Info
- Publication number
- CH200068A CH200068A CH200068DA CH200068A CH 200068 A CH200068 A CH 200068A CH 200068D A CH200068D A CH 200068DA CH 200068 A CH200068 A CH 200068A
- Authority
- CH
- Switzerland
- Prior art keywords
- dye
- production
- acidic
- acidic wool
- wool dye
- Prior art date
Links
- 210000002268 wool Anatomy 0.000 title claims description 8
- 230000002378 acidificating effect Effects 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000000975 dye Substances 0.000 claims description 10
- XBLPHYSLHRGMNW-UHFFFAOYSA-N 4-chloro-3-nitrobenzonitrile Chemical compound [O-][N+](=O)C1=CC(C#N)=CC=C1Cl XBLPHYSLHRGMNW-UHFFFAOYSA-N 0.000 claims description 3
- HYLOSPCJTPLXSF-UHFFFAOYSA-N 5-amino-2-anilinobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1NC1=CC=CC=C1 HYLOSPCJTPLXSF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000609 carbazolyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000005266 diarylamine group Chemical group 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Coloring (AREA)
Description
Verfahren zur Herstellung eines sauren Wollfarbstoffes. Es wurde gefunden, dass man zu wert vollen sauren Wollfarbstoffen gelangt, wenn man Nitroverbindungen der allgemeinen For mel
EMI0001.0003
worin Y Halogen oder eine Alkoxygruppe bedeutet, mit Aminosulfonsäuren der Diaryl- amin-, Cycloalkyl-arylamin- oder Carbazol- reihe kondensiert.
Die Kondensation erfolgt in Gegenwart säurebindender Mittel wie Natriumacetat, Kalk, Kreide und ähnlicher Stoffe in Wasser oder in geeigneten organischen Lösungsmit teln oder in Gemischen beider durch Erwär men sowohl unter Rückflusskühlung, als auch unter Druck.
Die so erhaltenen sauren Wollfarbstoffe sind durch sehr gutes Egalisiervermögen, so wie gute Echtheitseigenschaften der damit erzielten Färbungen ausgezeichnet, insbeson dere durch hervorragende Lichtechtheit.
Vorliegendes Patent bezieht sich nun auf ein Verfahren zur Herstellung eines sauren Wollfarbstoffes, dadurch gekennzeichnet, dass man 1-Chlor-2-nitro-4-cyanbenzol mit 4- Aminodiphenylamin - 2 - sulfonsäure konden siert.
Der so erhaltene Farbstoff färbt Wolle aus saurem Bade in gelbbraunen Tönen von guter Egalität und hervorragender Lichtecht heit.
<I>Beispiel:</I> 26,4 Teile 4-Aminodiphenylamin-2-sul- fonsäure, 18,5 Teile 1-Chlor-2-nitro-4-cyan- benzol und 11 Teile Natriumkarbonat werden mit etwa 150 Teilen Wasser und 40 Teilen Alkohol mehrere Stunden unter Rückfluss zum Sieden erhitzt. Hierauf wird die Lö- sung filtriert und der gebildete Farbstoff durch Zusatz von Natriumchlorid abgeschie den.
Process for the production of an acidic wool dye. It has been found that valuable acidic wool dyes can be obtained if nitro compounds of the general formula
EMI0001.0003
where Y denotes halogen or an alkoxy group, condensed with aminosulfonic acids of the diarylamine, cycloalkyl-arylamine or carbazole series.
The condensation takes place in the presence of acid-binding agents such as sodium acetate, lime, chalk and similar substances in water or in suitable organic solvents or in mixtures of both by heating men both under reflux cooling and under pressure.
The acidic wool dyes obtained in this way are distinguished by very good leveling properties and good fastness properties of the dyeings achieved therewith, in particular by excellent lightfastness.
The present patent relates to a process for the preparation of an acidic wool dye, characterized in that 1-chloro-2-nitro-4-cyanobenzene is condensed with 4-aminodiphenylamine-2-sulfonic acid.
The dye thus obtained dyes wool from an acid bath in yellow-brown shades of good levelness and excellent lightfastness.
<I> Example: </I> 26.4 parts of 4-aminodiphenylamine-2-sulphonic acid, 18.5 parts of 1-chloro-2-nitro-4-cyanobenzene and 11 parts of sodium carbonate are mixed with about 150 parts of water and 40 parts of alcohol heated to boiling under reflux for several hours. The solution is then filtered and the dye formed is separated off by adding sodium chloride.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200068X | 1936-08-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH200068A true CH200068A (en) | 1938-09-30 |
Family
ID=5759223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH200068D CH200068A (en) | 1936-08-25 | 1937-08-11 | Process for the production of an acidic wool dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH200068A (en) |
-
1937
- 1937-08-11 CH CH200068D patent/CH200068A/en unknown
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