CH420085A - Verfahren zur Herstellung von Zirkontetraazetat - Google Patents

Verfahren zur Herstellung von Zirkontetraazetat

Info

Publication number: CH420085A
Authority: CH; Switzerland
Prior art keywords: zirconium; acetic acid; tetraacetate; acetic; dissolved
Prior art date: 1960-01-29

Application number

CH1332860A

Other languages

German (de)

English (en)

Inventor

Brugger Wilhelm Dr Dipl-Chem

Original Assignee

Goldschmidt Ag Th

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1960-01-29

Filing date

1960-11-26

Publication date

1966-09-15

1960-11-26 Application filed by Goldschmidt Ag Th filed Critical Goldschmidt Ag Th

1966-09-15 Publication of CH420085A publication Critical patent/CH420085A/de

Links

MFFVROSEPLMJAP-UHFFFAOYSA-J zirconium(4+);tetraacetate Chemical compound [Zr+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O MFFVROSEPLMJAP-UHFFFAOYSA-J 0.000 title claims description 30
238000000034 method Methods 0.000 title claims description 28
238000004519 manufacturing process Methods 0.000 title claims description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 153
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 55
235000011054 acetic acid Nutrition 0.000 claims description 49
CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 claims description 16
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 16
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 12
229910052801 chlorine Inorganic materials 0.000 claims description 11
239000000460 chlorine Substances 0.000 claims description 8
238000004821 distillation Methods 0.000 claims description 8
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
239000007800 oxidant agent Substances 0.000 claims description 3
150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
230000001419 dependent effect Effects 0.000 claims 2
125000000218 acetic acid group Chemical class C(C)(=O)* 0.000 claims 1
238000009835 boiling Methods 0.000 claims 1
239000011541 reaction mixture Substances 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 13
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 12
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 12
229910000041 hydrogen chloride Inorganic materials 0.000 description 12
230000015572 biosynthetic process Effects 0.000 description 9
125000001309 chloro group Chemical group Cl* 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
229910052726 zirconium Inorganic materials 0.000 description 7
-1 zirconium alkoxides Chemical class 0.000 description 7
230000008030 elimination Effects 0.000 description 6
238000003379 elimination reaction Methods 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000000203 mixture Substances 0.000 description 5
238000003756 stirring Methods 0.000 description 5
150000003755 zirconium compounds Chemical class 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
GGROONUBGIWGGS-UHFFFAOYSA-N oxygen(2-);zirconium(4+);hydrate Chemical compound O.[O-2].[O-2].[Zr+4] GGROONUBGIWGGS-UHFFFAOYSA-N 0.000 description 4
239000007858 starting material Substances 0.000 description 4
XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical compound [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
238000001816 cooling Methods 0.000 description 3
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
150000003754 zirconium Chemical class 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
229910007926 ZrCl Inorganic materials 0.000 description 2
229910007928 ZrCl2 Inorganic materials 0.000 description 2
229910006213 ZrOCl2 Inorganic materials 0.000 description 2
MJOQJPYNENPSSS-XQHKEYJVSA-N [(3r,4s,5r,6s)-4,5,6-triacetyloxyoxan-3-yl] acetate Chemical compound CC(=O)O[C@@H]1CO[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O MJOQJPYNENPSSS-XQHKEYJVSA-N 0.000 description 2
BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
230000007717 exclusion Effects 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
150000007524 organic acids Chemical class 0.000 description 2
235000005985 organic acids Nutrition 0.000 description 2
235000011837 pasties Nutrition 0.000 description 2
239000012071 phase Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000000344 soap Substances 0.000 description 2
239000002689 soil Substances 0.000 description 2
239000004753 textile Substances 0.000 description 2
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
229910007932 ZrCl4 Inorganic materials 0.000 description 1
HIUQVNUSHJTZOG-UHFFFAOYSA-J [Zr+4].CC(O)=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O Chemical compound [Zr+4].CC(O)=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O HIUQVNUSHJTZOG-UHFFFAOYSA-J 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
230000000274 adsorptive effect Effects 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000013078 crystal Substances 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
150000002363 hafnium compounds Chemical class 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
VRQWWCJWSIOWHG-UHFFFAOYSA-J octadecanoate;zirconium(4+) Chemical compound [Zr+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O VRQWWCJWSIOWHG-UHFFFAOYSA-J 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
LYTNHSCLZRMKON-UHFFFAOYSA-L oxygen(2-);zirconium(4+);diacetate Chemical compound [O-2].[Zr+4].CC([O-])=O.CC([O-])=O LYTNHSCLZRMKON-UHFFFAOYSA-L 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
230000009466 transformation Effects 0.000 description 1
229910009112 xH2O Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Inorganic Compounds Of Heavy Metals (AREA)

CH1332860A 1960-01-29 1960-11-26 Verfahren zur Herstellung von Zirkontetraazetat CH420085A (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DEG28916A DE1148992B (de)	1960-01-29	1960-01-29	Verfahren zur Herstellung von kristallisiertem, lagerfaehigem Zirkontetraacetat

Publications (1)

Publication Number	Publication Date
CH420085A true CH420085A (de)	1966-09-15

Family

ID=7123604

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH1332860A CH420085A (de)	1960-01-29	1960-11-26	Verfahren zur Herstellung von Zirkontetraazetat

Country Status (4)

Country	Link
BE (1)	BE599270A (fr)
CH (1)	CH420085A (fr)
DE (1)	DE1148992B (fr)
GB (1)	GB946318A (fr)

1960
- 1960-01-29 DE DEG28916A patent/DE1148992B/de active Pending
- 1960-11-26 CH CH1332860A patent/CH420085A/de unknown
- 1960-12-14 GB GB43084/60A patent/GB946318A/en not_active Expired
1961
- 1961-01-19 BE BE599270A patent/BE599270A/fr unknown

Also Published As

Publication number	Publication date
GB946318A (en)	1964-01-08
DE1148992B (de)	1963-05-22
BE599270A (fr)	1961-05-16

Publication	Publication Date	Title
DE2418569C3 (de)	1978-08-17	Verfahren zur Herstellung von dl-Weinsäure
CH420085A (de)	1966-09-15	Verfahren zur Herstellung von Zirkontetraazetat
DE646109C (de)	1937-06-08	Herstellung von Kryolith
DE1227914B (de)	1966-11-03	Verfahren zur Herstellung von 3-(1, 2-Dithia-cyclopentyl)-5-pentansaeure
DE2159127A1 (de)	1972-06-15	Verfahren zur Herstellung von hochreinem Trimangantetroxyd
DE472870C (de)	1929-03-09	Verfahren zur Herstellung von Glyzerin durch Gaerung
US1235929A (en)	1917-08-07	Process for bleaching textile fibers.
DE887945C (de)	1953-08-27	Verfahren zur Herstellung von reinstem Aluminiumacetat mit niedrigem Essigsaeuregehalt
DE709668C (de)	1941-08-23	Verfahren zur Herstellung von ª‰-monohalogensubstituierten Homologen der Essigsaeure
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DE852731C (de)	1952-10-16	Verfahren zum Abbau ungesaettigter Fettsaeuren
DE165279C (fr)
US3076831A (en)	1963-02-05	Manufacture of crystalline zirconium tetraacetate
DE552833C (de)	1932-06-18	Verfahren zur Herstellung der Anhydride und Chloride von einwertigen gesaettigten Saeuren der Fettreihe
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DE1049846B (de)	1959-02-05	Verfahren zur Reinigung von Milchsäure
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DE818492C (de)	1951-10-25	Verfahren zur Herstellung von 6-Methyl-octa-3, 5, 7-trien-2-ol
DE2163711C3 (de)	1977-02-10	Verfahren zur Herstellung sulfathaltiger, basischer Aluminiumchloride
DE646406C (de)	1937-06-12	Verfahren zur Herstellung von Aralkylcellulose aus Cellulose, Alkalilauge und einem Aralkylhalogenid
AT28071B (de)	1907-04-10	Verfahren zur Darstellung von Weinstein.
AT110124B (de)	1928-07-10	Verfahren zur Herstellung von Natriumformiat.
DE878259C (de)	1953-06-01	Verfahren zur Herstellung eines penicillinhaltigen Produktes
DE2151565C3 (de)	1977-04-21	Verfahren zur gleichzeitigen Herstellung von aliphatischen Bromcarbonsäuren und Alkylbromlden
DE1935725C3 (de)	1974-06-27	Verfahren zur Herstellung von Chlorphenylestern