CH455719A - Katalysatormischung, Verfahren zur Herstellung und Verwendung derselben - Google Patents

Katalysatormischung, Verfahren zur Herstellung und Verwendung derselben

Info

Publication number: CH455719A
Authority: CH; Switzerland
Prior art keywords: zone; catalyst; aromatic hydrocarbon; transalkylation; alkylation
Prior art date: 1962-12-21

Application number

CH1587763A

Other languages

German (de)

English (en)

Inventor

Leo Dr Pollitzer Ernest

Vladimir Dr Haensel

Samuel Dr Bloch Herman

Original Assignee

Universal Oil Prod Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1962-12-21

Filing date

1963-12-23

Publication date

1968-05-15

1962-12-21 Priority claimed from US246459A external-priority patent/US3205277A/en

1963-12-23 Application filed by Universal Oil Prod Co filed Critical Universal Oil Prod Co

1968-05-15 Publication of CH455719A publication Critical patent/CH455719A/de

Links

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239000000203 mixture Substances 0.000 title claims description 51
238000004519 manufacturing process Methods 0.000 title claims description 8
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 86
238000005804 alkylation reaction Methods 0.000 claims description 41
238000010555 transalkylation reaction Methods 0.000 claims description 41
230000029936 alkylation Effects 0.000 claims description 40
238000006243 chemical reaction Methods 0.000 claims description 38
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 28
229910052731 fluorine Inorganic materials 0.000 claims description 28
239000011737 fluorine Substances 0.000 claims description 28
229930195733 hydrocarbon Natural products 0.000 claims description 28
150000002430 hydrocarbons Chemical class 0.000 claims description 25
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 24
150000001336 alkenes Chemical class 0.000 claims description 23
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 23
239000002253 acid Substances 0.000 claims description 22
238000006116 polymerization reaction Methods 0.000 claims description 21
239000011261 inert gas Substances 0.000 claims description 20
229910052809 inorganic oxide Inorganic materials 0.000 claims description 19
239000004215 Carbon black (E152) Substances 0.000 claims description 16
-1 ethylene, propylene Chemical group 0.000 claims description 16
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230000002378 acidificating effect Effects 0.000 description 2
150000001350 alkyl halides Chemical class 0.000 description 2
239000002168 alkylating agent Substances 0.000 description 2
229940100198 alkylating agent Drugs 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
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PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
150000004056 anthraquinones Chemical class 0.000 description 2
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239000003795 chemical substances by application Substances 0.000 description 2
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238000004040 coloring Methods 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
150000001925 cycloalkenes Chemical class 0.000 description 2
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238000005470 impregnation Methods 0.000 description 2
239000013067 intermediate product Substances 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
150000005673 monoalkenes Chemical class 0.000 description 2
150000007530 organic bases Chemical class 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
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238000001556 precipitation Methods 0.000 description 2
JTXAHXNXKFGXIT-UHFFFAOYSA-N propane;prop-1-ene Chemical group CCC.CC=C JTXAHXNXKFGXIT-UHFFFAOYSA-N 0.000 description 2
238000007086 side reaction Methods 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
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229910052754 neon Inorganic materials 0.000 description 1
GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
PGSADBUBUOPOJS-UHFFFAOYSA-N neutral red Chemical compound Cl.C1=C(C)C(N)=CC2=NC3=CC(N(C)C)=CC=C3N=C21 PGSADBUBUOPOJS-UHFFFAOYSA-N 0.000 description 1
229910052755 nonmetal Inorganic materials 0.000 description 1
LIXVMPBOGDCSRM-UHFFFAOYSA-N nonylbenzene Chemical class CCCCCCCCCC1=CC=CC=C1 LIXVMPBOGDCSRM-UHFFFAOYSA-N 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
JIRNEODMTPGRGV-UHFFFAOYSA-N pentadecylbenzene Chemical class CCCCCCCCCCCCCCCC1=CC=CC=C1 JIRNEODMTPGRGV-UHFFFAOYSA-N 0.000 description 1
125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
239000006187 pill Substances 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
TYRGSDXYMNTMML-UHFFFAOYSA-N propyl hydrogen sulfate Chemical compound CCCOS(O)(=O)=O TYRGSDXYMNTMML-UHFFFAOYSA-N 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
YYMBJDOZVAITBP-UHFFFAOYSA-N rubrene Chemical compound C1=CC=CC=C1C(C1=C(C=2C=CC=CC=2)C2=CC=CC=C2C(C=2C=CC=CC=2)=C11)=C(C=CC=C2)C2=C1C1=CC=CC=C1 YYMBJDOZVAITBP-UHFFFAOYSA-N 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical class CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
239000002912 waste gas Substances 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

CH1587763A 1962-12-21 1963-12-23 Katalysatormischung, Verfahren zur Herstellung und Verwendung derselben CH455719A (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US24632062A	1962-12-21	1962-12-21
US24631962A	1962-12-21	1962-12-21
US246459A US3205277A (en)	1962-12-21	1962-12-21	Alkylation-transalkylation process

Publications (1)

Publication Number	Publication Date
CH455719A true CH455719A (de)	1968-05-15

Family

ID=27399916

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH1587763A CH455719A (de)	1962-12-21	1963-12-23	Katalysatormischung, Verfahren zur Herstellung und Verwendung derselben

Country Status (7)

Country	Link
BR (1)	BR6355568D0 (da)
CH (1)	CH455719A (da)
DE (1)	DE1442931A1 (da)
DK (1)	DK117554B (da)
ES (1)	ES294716A1 (da)
GB (1)	GB1063489A (da)
SE (1)	SE334600B (da)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2133032B (en) *	1983-01-07	1986-09-24	Coalite Group Plc	Preparation of dimethylnaphthalenes

1963
- 1963-12-19 DE DE19631442931 patent/DE1442931A1/de active Pending
- 1963-12-20 DK DK598763AA patent/DK117554B/da unknown
- 1963-12-20 ES ES0294716A patent/ES294716A1/es not_active Expired
- 1963-12-20 BR BR155568/63A patent/BR6355568D0/pt unknown
- 1963-12-23 GB GB50623/63A patent/GB1063489A/en not_active Expired
- 1963-12-23 CH CH1587763A patent/CH455719A/de unknown
1967
- 1967-09-01 SE SE12175/67A patent/SE334600B/xx unknown

Also Published As

Publication number	Publication date
GB1063489A (en)	1967-03-30
ES294716A1 (es)	1964-07-01
BR6355568D0 (pt)	1973-07-19
DK117554B (da)	1970-05-11
DE1442931A1 (de)	1969-05-29
SE334600B (da)	1971-05-03

Publication	Publication Date	Title
CH422739A (de)	1966-10-31	Verfahren zum Alkylieren aromatischer Kohlenwasserstoffe
EP2358469A1 (de)	2011-08-24	Oligomerisierung von olefinen
EP2238095A1 (de)	2010-10-13	Verfahren zur oligomerisierung von alkenen
DE69105965T2 (de)	1995-04-27	Gebundener verbrückter Ton zur Anwendung bei der Herstellung von alkylaromatischen Verbindungen.
US3205277A (en)	1965-09-07	Alkylation-transalkylation process
US3201486A (en)	1965-08-17	Alkylation of alkylatable organic compounds
CH455719A (de)	1968-05-15	Katalysatormischung, Verfahren zur Herstellung und Verwendung derselben
DE69525075T2 (de)	2002-07-18	Verfahren zur herstellung von ethylbenzol oder von cumol
DE2059979A1 (de)	1971-06-16	Verfahren zur Alkylierung von aromatischen Kohlenwasserstoffen
DE68924165T2 (de)	1996-02-29	Heterogenes isoparaffin/olefin-alkylierungsverfahren.
DE943645C (de)	1956-05-24	Verfahren zur AEthylierung von acyclischen Olefinen
DE69302928T2 (de)	1996-10-10	Verfahren zur Herstellung von monoalkenylierten aromatischen Kohlenwasserstoffen
DE1643110C (da)
AT214424B (de)	1961-04-10	Verfahren zur kontinuierlichen Alkylierung aromatischer Kohlenwasserstoffe
DE1493285A1 (de)	1969-04-03	Verfahren zur Alkylierung von aromatischen Verbindungen
AT215978B (de)	1961-07-10	Verfahren zur Alkylierung aromatischer Kohlenwasserstoffe
DE1907639A1 (de)	1970-08-20	Alkylierungs-Umalkylierungsverfahren zur Herstellung monoalkylierter aromatischer Verbindungen
AT220141B (de)	1962-03-12	Verfahren zur kontinuierlichen Monoalkylierung aromatischer Kohlenwasserstoffe
DE19513117A1 (de)	1996-10-10	Verfahren zur Alkylierung und Transalkylierung von Aromaten
DE1443451A1 (de)	1968-11-14	Verfahren zur Alkylierung von aromatischen Verbindungen
DE1793330C3 (de)	1974-07-25	Verfahren zur Herstellung Methylbutenen
DE2148874C3 (de)	1980-02-21	Katalysator für die Alkylierung von aromatischen Kohlenwasserstoffen
DE1418446C (de)	1971-01-28	Verfahren zur Alkylierung von aroma tischen Kohlenwasserstoffen mit Olefinen
CH410885A (de)	1966-04-15	Verfahren zur Alkylierung aromatischer Kohlenwasserstoffe
AT226734B (de)	1963-04-10	Verfahren zur Herstellung eines festen Phosphorsäurekatalysators