CH478715A - Verfahren zur Herstellung von synthetischem, kristallinem, zeolithischem Natriumaluminosilikat - Google Patents

Verfahren zur Herstellung von synthetischem, kristallinem, zeolithischem Natriumaluminosilikat

Info

Publication number: CH478715A
Authority: CH; Switzerland
Prior art keywords: sep; reaction mixture; crystallization; ratio; crystalline
Prior art date: 1962-10-02

Application number

CH1200263A

Other languages

German (de)

English (en)

Inventor

Edwin Robson Harry

Original Assignee

Exxon Research Engineering Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1962-10-02

Filing date

1963-09-30

Publication date

1969-09-30

1963-09-30 Application filed by Exxon Research Engineering Co filed Critical Exxon Research Engineering Co

1969-09-30 Publication of CH478715A publication Critical patent/CH478715A/de

Links

238000000034 method Methods 0.000 title claims description 20
238000004519 manufacturing process Methods 0.000 title claims description 11
229910000503 Na-aluminosilicate Inorganic materials 0.000 title claims description 8
235000012217 sodium aluminium silicate Nutrition 0.000 title claims description 8
239000000429 sodium aluminium silicate Substances 0.000 title claims description 7
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 103
239000010457 zeolite Substances 0.000 claims description 57
229910052681 coesite Inorganic materials 0.000 claims description 42
229910052906 cristobalite Inorganic materials 0.000 claims description 42
229910052682 stishovite Inorganic materials 0.000 claims description 42
229910052905 tridymite Inorganic materials 0.000 claims description 42
238000002425 crystallisation Methods 0.000 claims description 37
230000008025 crystallization Effects 0.000 claims description 37
239000011541 reaction mixture Substances 0.000 claims description 36
229910001868 water Inorganic materials 0.000 claims description 32
229910021536 Zeolite Inorganic materials 0.000 claims description 28
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 26
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 23
239000003463 adsorbent Substances 0.000 claims description 7
239000000470 constituent Substances 0.000 claims description 6
230000036571 hydration Effects 0.000 claims description 5
238000006703 hydration reaction Methods 0.000 claims description 5
239000000843 powder Substances 0.000 claims description 3
230000001419 dependent effect Effects 0.000 claims 3
241001460678 Napo <wasp> Species 0.000 claims 1
239000000377 silicon dioxide Substances 0.000 description 38
239000000047 product Substances 0.000 description 34
235000012239 silicon dioxide Nutrition 0.000 description 20
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
239000011734 sodium Substances 0.000 description 13
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
239000013078 crystal Substances 0.000 description 8
239000011148 porous material Substances 0.000 description 8
239000000203 mixture Substances 0.000 description 7
238000002441 X-ray diffraction Methods 0.000 description 6
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 6
229910001388 sodium aluminate Inorganic materials 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 5
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
229910004298 SiO 2 Inorganic materials 0.000 description 4
239000004927 clay Substances 0.000 description 4
239000002178 crystalline material Substances 0.000 description 4
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
239000000523 sample Substances 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000029087 digestion Effects 0.000 description 3
239000012452 mother liquor Substances 0.000 description 3
239000000376 reactant Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
239000008119 colloidal silica Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000006101 laboratory sample Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
239000000741 silica gel Substances 0.000 description 2
229910002027 silica gel Inorganic materials 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
230000004913 activation Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000011835 investigation Methods 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/46—Amorphous silicates, e.g. so-called "amorphous zeolites"
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
- C01B33/2853—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively) of type Y

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

CH1200263A 1962-10-02 1963-09-30 Verfahren zur Herstellung von synthetischem, kristallinem, zeolithischem Natriumaluminosilikat CH478715A (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US22772962A	1962-10-02	1962-10-02

Publications (1)

Publication Number	Publication Date
CH478715A true CH478715A (de)	1969-09-30

Family

ID=22854224

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH1200263A CH478715A (de)	1962-10-02	1963-09-30	Verfahren zur Herstellung von synthetischem, kristallinem, zeolithischem Natriumaluminosilikat

Country Status (4)

Country	Link
CH (1)	CH478715A (da)
DK (1)	DK108423C (da)
ES (1)	ES292073A1 (da)
NL (1)	NL141152B (da)

1963
- 1963-09-20 ES ES0292073A patent/ES292073A1/es not_active Expired
- 1963-09-30 CH CH1200263A patent/CH478715A/de not_active IP Right Cessation
- 1963-10-02 NL NL298716A patent/NL141152B/xx not_active IP Right Cessation
- 1963-10-02 DK DK462763A patent/DK108423C/da active

Also Published As

Publication number	Publication date
DK108423C (da)	1967-12-11
ES292073A1 (es)	1964-03-01
NL141152B (nl)	1974-02-15

Legal Events

Date	Code	Title	Description
1972-04-28	PL	Patent ceased

Publication	Publication Date	Title
DE1951907C3 (de)	1984-02-16	Verfahren zur Herstellung eines zeolithischen Alumosilikats mit Faujasitstruktur
DE2507426C2 (de)	1986-08-07	Verfahren zur Herstellung des Zeolithen Ferrierit
DE2140481C3 (de)	1984-11-08	Verfahren zur Herstellung kristalliner Alumosilikate mit Faujasitstruktur
DE1237992B (de)	1967-04-06	Verfahren zur Herstellung von in Kieselsaeuregel oder Kieselsaeure-Metalloxyd-Mischgel eingebetteten kristallinen Aluminosilicat-Zeolithen
DE1467045A1 (de)	1968-12-19	Verfahren zur Herstellung von synthetischen,kristallinen,zeolithischen Aluminosilicaten
DE2824342A1 (de)	1978-12-21	Kristallines natriumalumosilicat vom typ 4a, seine herstellung und verwendung
DE3003361A1 (de)	1980-08-07	Katalysator und dessen verwendung
DE1442834A1 (de)	1969-05-08	Katalysatorenzusammensetzung und Verfahren zu ihrer Herstellung
CH493426A (de)	1970-07-15	Verfahren zur Verbesserung der physikalischen Eigenschaften von Alumino-Silikat-Zeolithen und deren Verwendung
DE1792631C3 (de)	1982-12-02	Verfahren zur Herstellung von Mordenit durch Erhitzen amorpher Silicium-Aluminiumoxid-Gemische
DE1545270A1 (de)	1970-02-05	Katalysator zur Umwandlung von Kohlenwasserstoffen und Verfahren zur Herstellung derselben
DE1667475B2 (de)	1976-05-26	Verfahren zur herstellung von kristallinen aluminosilicaten von faujasit-typ
DE2325228C3 (de)	1981-12-03	Kristalline Beryllo-Alumino-Silikate und Verfahren zu deren Herstellung
CH478715A (de)	1969-09-30	Verfahren zur Herstellung von synthetischem, kristallinem, zeolithischem Natriumaluminosilikat
DE3880437T2 (de)	1993-08-05	Zeolith ecr-30 mit hohem gehalt an siliciumdioxid und verfahren zu seiner herstellung.
DE2002626A1 (de)	1971-08-26	Verfahren zur Herstellung von Zeolithen mit Faujasit-Struktur
DE2455319A1 (de)	1975-05-28	Verfahren zur herstellung einer anorganischen verbindung mit der chemischen zusammensetzung eines zeolithen
DE69701213T2 (de)	2000-09-07	Aktiviertes, mit kieselsäure angereichertes mazzit, herstellungsverfahren sowie dessen verwendung
DE2028163A1 (de)	1971-12-16	Verfahren zur Herstellung von Zeolithen mit Faujasit-Struktur
DE2051448A1 (de)	1971-04-29	Verfahren zur Herstellung eines zeohthischen Alumosilikats
DE2256450C3 (de)	1981-07-30	Kristalline Beryllo-Alumino-Silikate und Verfahren zu deren Herstellung
DE1467036C3 (de)	1974-02-14	Verfahren zur Herstellung von synthetischen Kristallinen zeolithischen Natriumaluminosilikaten vom Typ Y
DE2353921C2 (de)	1985-01-17	Kristalline Beryllo-Alumino-Silikate und Verfahren zu deren Herstellung
DE19841230B4 (de)	2007-10-04	Verfahren zur Synthese von auf Flugasche basierendem Zeolith-Y
DE69202562T2 (de)	1995-09-28	Kieselsaürehaltiger offretit.