CH634988A5 - Cosmetic light-stabilising agent for the UV-A region - Google Patents

Cosmetic light-stabilising agent for the UV-A region Download PDF

Info

Publication number: CH634988A5
Authority: CH; Switzerland
Prior art keywords: pyrone; hydroxy; methyl; cosmetic; light stabilizer
Prior art date: 1977-06-23

Application number

CH689178A

Other languages

German (de)

English (en)

Inventor

Guenther Dr Konrad

Original Assignee

Henkel Kgaa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-06-23

Filing date

1978-06-23

Publication date

1983-03-15

1978-06-23 Application filed by Henkel Kgaa filed Critical Henkel Kgaa

1983-03-15 Publication of CH634988A5 publication Critical patent/CH634988A5/de

Links

239000002537 cosmetic Substances 0.000 title claims description 18
239000004611 light stabiliser Substances 0.000 title claims description 15
-1 hydroxyalkyl pyrone derivative Chemical class 0.000 claims description 25
239000000126 substance Substances 0.000 claims description 7
230000000475 sunscreen effect Effects 0.000 claims description 4
239000000516 sunscreening agent Substances 0.000 claims description 4
150000005840 aryl radicals Chemical group 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
230000000694 effects Effects 0.000 claims description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 1
208000000453 Skin Neoplasms Diseases 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 claims 1
125000005843 halogen group Chemical group 0.000 claims 1
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims 1
201000000849 skin cancer Diseases 0.000 claims 1
239000000203 mixture Substances 0.000 description 10
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 8
PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol Substances OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
239000003921 oil Substances 0.000 description 7
235000019198 oils Nutrition 0.000 description 7
210000003491 skin Anatomy 0.000 description 7
239000000839 emulsion Substances 0.000 description 5
QQNOPUCVSSJIIN-UHFFFAOYSA-N 4-hydroxy-6-methyl-3-(3-phenylprop-2-enoyl)pyran-2-one Chemical compound O=C1OC(C)=CC(O)=C1C(=O)C=CC1=CC=CC=C1 QQNOPUCVSSJIIN-UHFFFAOYSA-N 0.000 description 4
235000013871 bee wax Nutrition 0.000 description 4
239000012166 beeswax Substances 0.000 description 4
HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
239000006071 cream Substances 0.000 description 4
YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 4
SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 4
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
239000006210 lotion Substances 0.000 description 4
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
239000003380 propellant Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
206010042496 Sunburn Diseases 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
239000000843 powder Substances 0.000 description 3
DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
239000004808 2-ethylhexylester Substances 0.000 description 2
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
DMTRKPKZQVCOIF-UHFFFAOYSA-N 4-hydroxy-3-[3-(4-hydroxyphenyl)prop-2-enoyl]-6-methylpyran-2-one Chemical compound O=C1OC(C)=CC(O)=C1C(=O)C=CC1=CC=C(O)C=C1 DMTRKPKZQVCOIF-UHFFFAOYSA-N 0.000 description 2
PRQJIOZRFLEGHG-UHFFFAOYSA-N 4-hydroxy-3-[3-(4-methoxyphenyl)prop-2-enoyl]-6-methylpyran-2-one Chemical compound COC1=CC=C(C=C1)C=CC(=O)C=1C(OC(=CC1O)C)=O PRQJIOZRFLEGHG-UHFFFAOYSA-N 0.000 description 2
HSHNITRMYYLLCV-UHFFFAOYSA-N 4-methylumbelliferone Chemical compound C1=C(O)C=CC2=C1OC(=O)C=C2C HSHNITRMYYLLCV-UHFFFAOYSA-N 0.000 description 2
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
239000005642 Oleic acid Substances 0.000 description 2
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
235000021355 Stearic acid Nutrition 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
239000000443 aerosol Substances 0.000 description 2
229910021538 borax Inorganic materials 0.000 description 2
229960000846 camphor Drugs 0.000 description 2
229960000541 cetyl alcohol Drugs 0.000 description 2
235000012000 cholesterol Nutrition 0.000 description 2
238000009472 formulation Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
239000000787 lecithin Substances 0.000 description 2
229940067606 lecithin Drugs 0.000 description 2
235000010445 lecithin Nutrition 0.000 description 2
LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
239000002480 mineral oil Substances 0.000 description 2
235000010446 mineral oil Nutrition 0.000 description 2
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
235000008390 olive oil Nutrition 0.000 description 2
239000004006 olive oil Substances 0.000 description 2
235000019271 petrolatum Nutrition 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
230000005855 radiation Effects 0.000 description 2
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
239000004328 sodium tetraborate Substances 0.000 description 2
235000010339 sodium tetraborate Nutrition 0.000 description 2
239000008117 stearic acid Substances 0.000 description 2
230000037072 sun protection Effects 0.000 description 2
235000015112 vegetable and seed oil Nutrition 0.000 description 2
239000008158 vegetable oil Substances 0.000 description 2
WWMFRKPUQJRNBY-UHFFFAOYSA-N (2,3-dimethoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1OC WWMFRKPUQJRNBY-UHFFFAOYSA-N 0.000 description 1
LDGQHAMESHYIFU-UHFFFAOYSA-N 3-[3-(4-aminophenyl)prop-2-enoyl]-4-hydroxy-6-methylpyran-2-one Chemical compound NC1=CC=C(C=C1)C=CC(=O)C=1C(OC(=CC=1O)C)=O LDGQHAMESHYIFU-UHFFFAOYSA-N 0.000 description 1
ZOEKYAYGHVINTN-UHFFFAOYSA-N 3-[3-[4-(diethylamino)phenyl]prop-2-enoyl]-4-hydroxy-6-methylpyran-2-one Chemical compound C(C)N(C1=CC=C(C=CC(=O)C=2C(OC(=CC=2O)C)=O)C=C1)CC ZOEKYAYGHVINTN-UHFFFAOYSA-N 0.000 description 1
ACCWCWKIASBEKV-UHFFFAOYSA-N 3-benzylideneheptan-2-one Chemical compound CCCCC(C(C)=O)=CC1=CC=CC=C1 ACCWCWKIASBEKV-UHFFFAOYSA-N 0.000 description 1
MJIACMMODTYUHG-UHFFFAOYSA-N 3-hydroxy-6-methylpyran-2-one Chemical compound CC1=CC=C(O)C(=O)O1 MJIACMMODTYUHG-UHFFFAOYSA-N 0.000 description 1
LRCLIDIMQAJTGZ-UHFFFAOYSA-N 4-hydroxy-3-[3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]-6-methylpyran-2-one Chemical compound COc1cc(C=CC(=O)c2c(O)cc(C)oc2=O)ccc1O LRCLIDIMQAJTGZ-UHFFFAOYSA-N 0.000 description 1
QJQGKFBKKILFFI-UHFFFAOYSA-N 4-hydroxy-6-propan-2-ylpyran-2-one Chemical compound CC(C)C1=CC(O)=CC(=O)O1 QJQGKFBKKILFFI-UHFFFAOYSA-N 0.000 description 1
ATEFPOUAMCWAQS-UHFFFAOYSA-N 7,8-dihydroxycoumarin Chemical compound C1=CC(=O)OC2=C(O)C(O)=CC=C21 ATEFPOUAMCWAQS-UHFFFAOYSA-N 0.000 description 1
OTNIKUTWXUODJZ-UHFFFAOYSA-N 7-(ethylamino)-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(NCC)=CC=C21 OTNIKUTWXUODJZ-UHFFFAOYSA-N 0.000 description 1
CJIJXIFQYOPWTF-UHFFFAOYSA-N 7-hydroxycoumarin Natural products O1C(=O)C=CC2=CC(O)=CC=C21 CJIJXIFQYOPWTF-UHFFFAOYSA-N 0.000 description 1
239000004287 Dehydroacetic acid Substances 0.000 description 1
206010015150 Erythema Diseases 0.000 description 1
206010020649 Hyperkeratosis Diseases 0.000 description 1
208000001126 Keratosis Diseases 0.000 description 1
241000195947 Lycopodium Species 0.000 description 1
206010028980 Neoplasm Diseases 0.000 description 1
YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 description 1
QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
QNHQEUFMIKRNTB-UHFFFAOYSA-N aesculetin Natural products C1CC(=O)OC2=C1C=C(O)C(O)=C2 QNHQEUFMIKRNTB-UHFFFAOYSA-N 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
150000003934 aromatic aldehydes Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
BLFLLBZGZJTVJG-UHFFFAOYSA-N benzocaine Chemical compound CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
LSPHULWDVZXLIL-QUBYGPBYSA-N camphoric acid Chemical compound CC1(C)[C@H](C(O)=O)CC[C@]1(C)C(O)=O LSPHULWDVZXLIL-QUBYGPBYSA-N 0.000 description 1
201000011510 cancer Diseases 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000001684 chronic effect Effects 0.000 description 1
231100000762 chronic effect Toxicity 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000004040 coloring Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000000254 damaging effect Effects 0.000 description 1
YBGKGTOOPNQOKH-UHFFFAOYSA-N daphnetin Natural products OC1=CC=CC2=C1OC(=O)C=C2O YBGKGTOOPNQOKH-UHFFFAOYSA-N 0.000 description 1
235000019258 dehydroacetic acid Nutrition 0.000 description 1
JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
229940061632 dehydroacetic acid Drugs 0.000 description 1
PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 description 1
210000002615 epidermis Anatomy 0.000 description 1
231100000321 erythema Toxicity 0.000 description 1
ILEDWLMCKZNDJK-UHFFFAOYSA-N esculetin Chemical compound C1=CC(=O)OC2=C1C=C(O)C(O)=C2 ILEDWLMCKZNDJK-UHFFFAOYSA-N 0.000 description 1
230000001815 facial effect Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000000034 method Methods 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
NQBKFULMFQMZBE-UHFFFAOYSA-N n-bz-3-benzanthronylpyrazolanthron Chemical compound C12=CC=CC(C(=O)C=3C4=CC=CC=3)=C2C4=NN1C1=CC=C2C3=C1C1=CC=CC=C1C(=O)C3=CC=C2 NQBKFULMFQMZBE-UHFFFAOYSA-N 0.000 description 1
239000002674 ointment Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
235000011837 pasties Nutrition 0.000 description 1
239000000049 pigment Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
VJXOEQBGNNPWMQ-UHFFFAOYSA-N propan-2-yl 3-(4-acetamidophenyl)prop-2-enoate Chemical compound CC(C)OC(=O)C=CC1=CC=C(NC(C)=O)C=C1 VJXOEQBGNNPWMQ-UHFFFAOYSA-N 0.000 description 1
239000003223 protective agent Substances 0.000 description 1
229940100486 rice starch Drugs 0.000 description 1
229960004889 salicylic acid Drugs 0.000 description 1
230000037380 skin damage Effects 0.000 description 1
BBHVQBQNEHFBIO-UHFFFAOYSA-M sodium;2-(3,4-dimethoxyphenyl)-2-oxoacetate Chemical compound [Na+].COC1=CC=C(C(=O)C([O-])=O)C=C1OC BBHVQBQNEHFBIO-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
235000012222 talc Nutrition 0.000 description 1
DQFBYFPFKXHELB-VAWYXSNFSA-N trans-chalcone Chemical compound C=1C=CC=CC=1C(=O)\C=C\C1=CC=CC=C1 DQFBYFPFKXHELB-VAWYXSNFSA-N 0.000 description 1
LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
NSYSSMYQPLSPOD-UHFFFAOYSA-N triacetate lactone Chemical class CC1=CC(O)=CC(=O)O1 NSYSSMYQPLSPOD-UHFFFAOYSA-N 0.000 description 1
125000005209 triethanolammonium group Chemical class 0.000 description 1
ORHBXUUXSCNDEV-UHFFFAOYSA-N umbelliferone Chemical compound C1=CC(=O)OC2=CC(O)=CC=C21 ORHBXUUXSCNDEV-UHFFFAOYSA-N 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Landscapes

Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Birds (AREA)
Epidemiology (AREA)
Dermatology (AREA)
Cosmetics (AREA)

CH689178A 1977-06-23 1978-06-23 Cosmetic light-stabilising agent for the UV-A region CH634988A5 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19772728243 DE2728243A1 (de)	1977-06-23	1977-06-23	Kosmetische lichtschutzmittel fuer den uv-a-bereich

Publications (1)

Publication Number	Publication Date
CH634988A5 true CH634988A5 (en)	1983-03-15

Family

ID=6012160

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH689178A CH634988A5 (en)	1977-06-23	1978-06-23	Cosmetic light-stabilising agent for the UV-A region

Country Status (7)

Country	Link
AT (1)	AT355220B (fr)
BE (1)	BE868399A (fr)
CH (1)	CH634988A5 (fr)
DE (1)	DE2728243A1 (fr)
FR (1)	FR2395025A1 (fr)
IT (1)	IT1096576B (fr)
NL (1)	NL7806035A (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS60109544A (ja) *	1983-11-17	1985-06-15	Kao Corp	新規カルコン誘導体及びこれを含有する紫外線吸収剤
WO2003080592A1 (fr) *	2002-03-27	2003-10-02	Sumitomo Chemical Company, Limited	Composés 2-pyrone et utilisation de ceux-ci
WO2005028463A1 (fr) *	2003-09-17	2005-03-31	Sumitomo Chemical Company, Limited	Compose cinnamoyle et utilisation associee
JP4797351B2 (ja) *	2003-09-17	2011-10-19	住友化学株式会社	シンナモイル化合物及びその用途

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2334348A (en) *	1941-06-23	1943-11-16	Nat Marking Mach Co	Sunburn preventive
US3463791A (en) *	1965-10-23	1969-08-26	Squibb & Sons Inc	7-chloro-4-dedimethylamino-12,12alpha-secotetracycline-12-oic acid-6,12-lactones
US3438999A (en) *	1966-01-27	1969-04-15	Squibb & Sons Inc	Secotetracycline derivatives and their method of preparation
US3625976A (en) *	1969-12-09	1971-12-07	Int Flavors & Fragrances Inc	Coumarin ether sun-screening compounds
CH545631A (fr) *	1971-12-03	1974-02-15	Int Flavors & Fragrances Inc	Utilisation de derives de la coumarine comme filtres antisolaires
FR2161845A1 (fr) *	1971-12-03	1973-07-13	Int Flavors & Fragrances Inc	Ethers de coumarine antisolaires et procede de leur preparation

1977
- 1977-06-23 DE DE19772728243 patent/DE2728243A1/de not_active Withdrawn
1978
- 1978-06-02 NL NL7806035A patent/NL7806035A/xx not_active Application Discontinuation
- 1978-06-20 IT IT24728/78A patent/IT1096576B/it active
- 1978-06-22 AT AT455178A patent/AT355220B/de not_active IP Right Cessation
- 1978-06-23 BE BE188798A patent/BE868399A/fr not_active IP Right Cessation
- 1978-06-23 FR FR7818890A patent/FR2395025A1/fr active Granted
- 1978-06-23 CH CH689178A patent/CH634988A5/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
ATA455178A (de)	1979-07-15
FR2395025B1 (fr)	1983-01-21
IT7824728A0 (it)	1978-06-20
IT1096576B (it)	1985-08-26
FR2395025A1 (fr)	1979-01-19
AT355220B (de)	1980-02-25
BE868399A (fr)	1978-12-27
NL7806035A (nl)	1978-12-28
DE2728243A1 (de)	1979-01-11

Legal Events

Date	Code	Title	Description
1985-02-28	PL	Patent ceased
2024-10-31	PL	Patent ceased

Publication	Publication Date	Title
DE2544180C2 (de)	1984-02-23	Lichtschutzmittel für kosmetische Zwecke
DE3218973C2 (fr)	1991-05-29
DE3441636C2 (de)	1994-10-20	Ultraviolett-Absorber, enthaltend neue Chalkon-Derivate
EP0005182B1 (fr)	1981-07-29	Composition de protection contre l'effet de la lumière
EP0694521B1 (fr)	1998-01-21	Dérivés de cétotricyclo(5.2.1.0)decane
DE69100593T2 (de)	1994-03-31	Lichtbeständige filternde kosmetische zusammensetzung enthaltend einen uva-filter und ein beta-beta-diphenylacrylat oder einen alpha-cyano-beta-beta-diphenylacrylsäure-alkylester.
DE69734499T2 (de)	2006-08-03	Sonnenschutzmittel aus langkettigen, verzweigten Alkylbenzoaten oder Alkylhydroxybenzoaten
CH634986A5 (en)	1983-03-15	Cosmetic light-stabilising agent for the UV-A region
EP0581955B1 (fr)	1996-10-16	Utilisation de derives de benzimidazol comme substances filtrantes protectrices pour l'exposition aux rayons lumineux
EP0693471A1 (fr)	1996-01-24	Dérivés du benzylidène norcamphre
DE3741420A1 (de)	1988-06-09	Lichtstabiles kosmetisches mittel zum schutz der humanepidermis
DE19933460A1 (de)	2000-01-13	Verwendung von Ectoinen und sulfonierten UV-Filtern
DE69010047T2 (de)	1994-10-06	Hydrophile Derivate von Benzylidenkampfer enthaltende kosmetische und pharmazeutische Zusammensetzungen und sulfonierte hydrophile Derivate von Benzylidenkampfer.
DE3731858A1 (de)	1988-03-31	Lichtbestaendiges kosmetisches mittel, welches trihydroxyethylrutin in kombination mit wasserloeslichen filtern, die von benzylidenkampfer abgeleitet sind, enthaelt, und dessen verwendung zum schutze der haut und der haare
CH626803A5 (fr)	1981-12-15
US3479428A (en)	1969-11-18	Sunscreen composition and method of using the same
DE19508608B4 (de)	2006-06-29	Lichtbeständiges kosmetisches Mittel enthaltend Tetraalkylquercetin sowie Tetraalkylquercetine als solche
EP0714880A1 (fr)	1996-06-05	Dérivés bis(méthylidène)-phénylène
DE2347928A1 (de)	1974-04-11	Schutzmittel gegen aktinische strahlen und dieses enthaltende mittel
DE1492274C (fr)	1973-03-29
CH634987A5 (en)	1983-03-15	Cosmetic light-stabilising agent for the UV-A region
DE3833706A1 (de)	1989-04-20	Neue t-butylderivate von benzylidenkampfer, verfahren zu ihrer herstellung und ihre verwendung als antioxidationsmittel sowie als pharmazeutische und kosmetische mittel
CH634988A5 (en)	1983-03-15	Cosmetic light-stabilising agent for the UV-A region
DE2032914A1 (fr)	1971-01-07
EP0207287A2 (fr)	1987-01-07	Dérivés de l'indole, procédé de préparation et composé cosmétique solaire les contenant