CH638815A5 - N-((phosphinyl)-amino)-thio- und n-((phosphinothioyl)-amino)-thio-methylcarbamate, verfahren zu ihrer herstellung sowie ihre verwendung in pestiziden. - Google Patents

N-((phosphinyl)-amino)-thio- und n-((phosphinothioyl)-amino)-thio-methylcarbamate, verfahren zu ihrer herstellung sowie ihre verwendung in pestiziden. Download PDF

Info

Publication number: CH638815A5
Authority: CH; Switzerland
Prior art keywords: radical; methyl; thio; amino; carbon atoms
Prior art date: 1978-02-03

Application number

CH106979A

Other languages

German (de)

English (en)

Inventor

Stephen James Nelson

Original Assignee

Upjohn Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-02-03

Filing date

1979-02-02

Publication date

1983-10-14

1978-11-20 Priority claimed from US05/962,266 external-priority patent/US4208409A/en

1979-02-02 Application filed by Upjohn Co filed Critical Upjohn Co

1983-10-14 Publication of CH638815A5 publication Critical patent/CH638815A5/de

Links

-1 (PHOSPHINYL) -AMINO Chemical class 0.000 title claims description 60
238000000034 method Methods 0.000 title claims description 11
239000000575 pesticide Substances 0.000 title description 19
238000004519 manufacturing process Methods 0.000 title description 2
150000001875 compounds Chemical class 0.000 claims description 65
125000004432 carbon atom Chemical group C* 0.000 claims description 62
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 52
125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 52
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 51
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 36
125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 36
239000000203 mixture Substances 0.000 claims description 28
239000004480 active ingredient Substances 0.000 claims description 24
239000003795 chemical substances by application Substances 0.000 claims description 21
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 20
YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims description 18
125000000217 alkyl group Chemical group 0.000 claims description 13
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CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 11
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 11
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239000002283 diesel fuel Substances 0.000 description 1
RJBIAAZJODIFHR-UHFFFAOYSA-N dihydroxy-imino-sulfanyl-$l^{5}-phosphane Chemical class NP(O)(O)=S RJBIAAZJODIFHR-UHFFFAOYSA-N 0.000 description 1
238000007865 diluting Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
HPYNZHMRTTWQTB-UHFFFAOYSA-N dimethylpyridine Natural products CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000003480 eluent Substances 0.000 description 1
238000010828 elution Methods 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000003337 fertilizer Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
238000003306 harvesting Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
238000011031 large-scale manufacturing process Methods 0.000 description 1
231100001231 less toxic Toxicity 0.000 description 1
229920005610 lignin Polymers 0.000 description 1
239000007788 liquid Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
230000001069 nematicidal effect Effects 0.000 description 1
239000007764 o/w emulsion Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000002674 ointment Substances 0.000 description 1
231100000418 oral toxicity Toxicity 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
239000012430 organic reaction media Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052625 palygorskite Inorganic materials 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
150000003012 phosphoric acid amides Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000005080 plant death Effects 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
239000010453 quartz Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000009738 saturating Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
238000005549 size reduction Methods 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000000935 solvent evaporation Methods 0.000 description 1
239000004455 soybean meal Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
125000005270 trialkylamine group Chemical group 0.000 description 1
238000001363 water suppression through gradient tailored excitation Methods 0.000 description 1
239000004563 wettable powder Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2454—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2479—Compounds containing the structure P(=X)n-N-acyl, P(=X)n-N-heteroatom, P(=X)n-N-CN (X = O, S, Se; n = 0, 1)
- C07F9/2483—Compounds containing the structure P(=X)n-N-acyl, P(=X)n-N-heteroatom, P(=X)n-N-CN (X = O, S, Se; n = 0, 1) containing the structure P(=X)n-N-S (X = O, S, Se; n = 0, 1)
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus as a ring member
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657154—Cyclic esteramides of oxyacids of phosphorus

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Organic Chemistry (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Biochemistry (AREA)
Molecular Biology (AREA)
Dentistry (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Plant Pathology (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CH106979A 1978-02-03 1979-02-02 N-((phosphinyl)-amino)-thio- und n-((phosphinothioyl)-amino)-thio-methylcarbamate, verfahren zu ihrer herstellung sowie ihre verwendung in pestiziden. CH638815A5 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US87495978A	1978-02-03	1978-02-03
US05/962,266 US4208409A (en)	1977-02-04	1978-11-20	N-[(phosphinyl or phosphinothioyl)amino]thio-methylcarbamates and pesticidal methods

Publications (1)

Publication Number	Publication Date
CH638815A5 true CH638815A5 (de)	1983-10-14

Family

ID=27128362

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH106979A CH638815A5 (de)	1978-02-03	1979-02-02	N-((phosphinyl)-amino)-thio- und n-((phosphinothioyl)-amino)-thio-methylcarbamate, verfahren zu ihrer herstellung sowie ihre verwendung in pestiziden.

Country Status (19)

Country	Link
JP (1)	JPS5828879B2 (fr)
AU (1)	AU521661B2 (fr)
BR (1)	BR7900672A (fr)
CA (1)	CA1133918A (fr)
CH (1)	CH638815A5 (fr)
DD (1)	DD141779A5 (fr)
DE (1)	DE2902647A1 (fr)
DK (1)	DK45379A (fr)
EG (1)	EG14058A (fr)
ES (1)	ES477417A1 (fr)
FR (1)	FR2422673B1 (fr)
GB (1)	GB2015527B (fr)
HU (1)	HU184209B (fr)
IL (1)	IL56502A (fr)
IT (1)	IT1202876B (fr)
NL (1)	NL7900857A (fr)
OA (1)	OA06176A (fr)
PL (1)	PL115203B1 (fr)
YU (1)	YU24179A (fr)

1979
- 1979-01-24 DE DE19792902647 patent/DE2902647A1/de not_active Withdrawn
- 1979-01-24 AU AU43607/79A patent/AU521661B2/en not_active Ceased
- 1979-01-25 IL IL56502A patent/IL56502A/xx unknown
- 1979-02-02 ES ES477417A patent/ES477417A1/es not_active Expired
- 1979-02-02 DD DD79210794A patent/DD141779A5/de unknown
- 1979-02-02 DK DK45379A patent/DK45379A/da not_active Application Discontinuation
- 1979-02-02 YU YU00241/79A patent/YU24179A/xx unknown
- 1979-02-02 FR FR7902723A patent/FR2422673B1/fr not_active Expired
- 1979-02-02 CH CH106979A patent/CH638815A5/de not_active IP Right Cessation
- 1979-02-02 NL NL7900857A patent/NL7900857A/xx not_active Application Discontinuation
- 1979-02-02 GB GB7903755A patent/GB2015527B/en not_active Expired
- 1979-02-02 JP JP54011322A patent/JPS5828879B2/ja not_active Expired
- 1979-02-02 HU HU79UO153A patent/HU184209B/hu unknown
- 1979-02-02 IT IT19865/79A patent/IT1202876B/it active
- 1979-02-02 BR BR7900672A patent/BR7900672A/pt unknown
- 1979-02-02 CA CA320,756A patent/CA1133918A/fr not_active Expired
- 1979-02-03 PL PL1979213213A patent/PL115203B1/pl unknown
- 1979-02-03 OA OA56726A patent/OA06176A/fr unknown
- 1979-02-03 EG EG69/79A patent/EG14058A/xx active

Also Published As

Publication number	Publication date
JPS54115377A (en)	1979-09-07
GB2015527A (en)	1979-09-12
YU24179A (en)	1983-02-28
EG14058A (en)	1984-06-30
JPS5828879B2 (ja)	1983-06-18
FR2422673B1 (fr)	1985-06-28
IL56502A (en)	1983-11-30
HU184209B (en)	1984-07-30
NL7900857A (nl)	1979-08-07
BR7900672A (pt)	1979-09-04
DK45379A (da)	1979-08-04
AU4360779A (en)	1979-08-09
CA1133918A (fr)	1982-10-19
DE2902647A1 (de)	1979-08-09
AU521661B2 (en)	1982-04-22
FR2422673A1 (fr)	1979-11-09
OA06176A (fr)	1981-06-30
IT7919865A0 (it)	1979-02-02
DD141779A5 (de)	1980-05-21
PL213213A1 (fr)	1980-02-25
ES477417A1 (es)	1980-07-01
GB2015527B (en)	1982-04-21
PL115203B1 (en)	1981-03-31
IT1202876B (it)	1989-02-15

Legal Events

Date	Code	Title	Description
1986-10-31	PL	Patent ceased
2024-10-31	PL	Patent ceased

Publication	Publication Date	Title
US4081536A (en)	1978-03-28	N-[(phosphinyl) amino]thio- and N-[(phosphinothioyl)amino]-thio-methylcarbamates and methods for controlling insects
DE2619303A1 (de)	1976-11-18	Neue schwefelhaltige bisformamidine, verfahren zu ihrer herstellung und verwendung derselben sowie diese enthaltende land-, garten- und forstwirtschaftliche chemikalien
CH632767A5 (de)	1982-10-29	Phosphonsaeure- und thiophosphonsaeureester enthaltende schaedlingsbekaempfungsmittel.
EP0046928B1 (fr)	1983-06-08	Organophosphates, procédé pour leur préparation et leur utilisation dans des compositions pesticides
DE2732930C2 (de)	1985-08-14	Neue 0-Äthyl-S-n-propyl-O-2,2,2- trihalogenäthylphosphorthiolate (oder -thionothiolate), Verfahren zu ihrer Herstellung und ihre Verwendung als Insektizide, Akarizide und Nematizide
DE2015527B2 (de)	1979-07-05	Cyanoalkylaldoximcarbamate und ihre Verwendung als Insektizide
EP0007020B1 (fr)	1981-10-14	Esters organiques de l'acide phosphorique, procédé pour leur préparation, leur utilisation, pesticides et leur préparation
CH537147A (de)	1973-05-31	Schädlingsbekämpfungsmittel
DD215002A5 (de)	1984-10-31	Pestizide zusammensetzung
DE2119981A1 (de)	1971-11-11	Thiophosphatderivate von Acetylhydraziden und ihre Verwendung als Schädlingsbekämpfungsmittel
US4201733A (en)	1980-05-06	Process for preparing N-[(phosphinyl)amino]thio- and N-[(phosphinyl)amino]th
DE2655212A1 (de)	1977-07-14	Aminothiocarbamate, verfahren zu ihrer herstellung und diese enthaltende pestizide
CH638815A5 (de)	1983-10-14	N-((phosphinyl)-amino)-thio- und n-((phosphinothioyl)-amino)-thio-methylcarbamate, verfahren zu ihrer herstellung sowie ihre verwendung in pestiziden.
EP0001292B1 (fr)	1980-07-23	Halogenoalkyldithiophosphates, procédé pour leur préparation et leur utilisation comme pesticides
US4208409A (en)	1980-06-17	N-[(phosphinyl or phosphinothioyl)amino]thio-methylcarbamates and pesticidal methods
DE1806120A1 (de)	1969-05-14	Neue Carbamoyloxime,Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekaempfung von Schaedlingen
DE69428109T2 (de)	2002-01-24	Organophosphor-Verbindungen, Verfahren zu ihrer Herstellung und diese enthaltende Insektizide, Acarizide und Nematozide
EP0001975B1 (fr)	1981-04-15	Esters pyridazinonyliques d'acide-(di) (thio) phosphorique(phosphonique), leur procédé de préparation, pesticides les contenant et procédé pour lutter contre les insectes nuisibles
DD215001A5 (de)	1984-10-31	Pestizide zusammensetzung
DE2119211A1 (en)	1971-12-02	Organophosphates - active against insects and nematodes
DE2314948A1 (de)	1973-10-04	Dithiophosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide, akarizide und nematozide
EP0127049A2 (fr)	1984-12-05	Esters organiques d'acide phosphorique
DE2916937A1 (de)	1979-11-15	Phosphorsaeureester und ihre derivate
DD218829A5 (de)	1985-02-20	Pestizide zusammensetzung
DE2024151A1 (fr)	1970-11-26