CH645392A5 - Verfahren zur herstellung von polyvinylchloridhomo- oder -copolymeren durch suspensionspolymerisation. - Google Patents

Verfahren zur herstellung von polyvinylchloridhomo- oder -copolymeren durch suspensionspolymerisation. Download PDF

Info

Publication number: CH645392A5
Authority: CH; Switzerland
Prior art keywords: acid; polymerization; water; organic; coating
Prior art date: 1979-10-22

Application number

CH788080A

Other languages

German (de)

English (en)

Inventor

Hajime Kitamura

Toshihide Shimizu

Ichiro Kaneko

Ken Itoh

Original Assignee

Shinetsu Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-10-22

Filing date

1980-10-22

Publication date

1984-09-28

1980-10-22 Application filed by Shinetsu Chemical Co filed Critical Shinetsu Chemical Co

1984-09-28 Publication of CH645392A5 publication Critical patent/CH645392A5/de

Links

229920000915 polyvinyl chloride Polymers 0.000 title claims 13
239000004800 polyvinyl chloride Substances 0.000 title claims 13
238000004519 manufacturing process Methods 0.000 title claims 10
239000000725 suspension Substances 0.000 title claims 6
229920001577 copolymer Polymers 0.000 title claims 4
238000004770 highest occupied molecular orbital Methods 0.000 title 1
238000006116 polymerization reaction Methods 0.000 claims description 57
238000000576 coating method Methods 0.000 claims description 53
239000011248 coating agent Substances 0.000 claims description 50
239000000178 monomer Substances 0.000 claims description 37
229920000642 polymer Polymers 0.000 claims description 33
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
238000000034 method Methods 0.000 claims description 29
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 25
239000000203 mixture Substances 0.000 claims description 23
229920005989 resin Polymers 0.000 claims description 23
239000011347 resin Substances 0.000 claims description 23
239000002253 acid Substances 0.000 claims description 22
150000001451 organic peroxides Chemical class 0.000 claims description 20
230000008569 process Effects 0.000 claims description 17
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 13
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 12
-1 dodecylbenzene sulfone Chemical class 0.000 claims description 12
230000008021 deposition Effects 0.000 claims description 11
SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 claims description 10
150000002978 peroxides Chemical class 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
238000012360 testing method Methods 0.000 claims description 6
241000251468 Actinopterygii Species 0.000 claims description 5
AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 claims description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
238000001035 drying Methods 0.000 claims description 4
229920002554 vinyl polymer Polymers 0.000 claims description 4
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
230000015572 biosynthetic process Effects 0.000 claims description 3
YCMOBGSVZYLYBZ-UHFFFAOYSA-L disodium 5-[[4-[4-[(2-amino-8-hydroxy-6-sulfonatonaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]-2-hydroxybenzoate Chemical compound NC1=CC=C2C=C(C=C(O)C2=C1N=NC1=CC=C(C=C1)C1=CC=C(C=C1)N=NC1=CC=C(O)C(=C1)C(=O)O[Na])S(=O)(=O)O[Na] YCMOBGSVZYLYBZ-UHFFFAOYSA-L 0.000 claims description 3
VSSMQLIMSVAUDK-UHFFFAOYSA-L disodium;5-[(4-ethoxyphenyl)diazenyl]-2-[4-[(4-ethoxyphenyl)diazenyl]-2-sulfonatophenyl]sulfanylbenzenesulfonate Chemical compound [Na+].[Na+].C1=CC(OCC)=CC=C1N=NC(C=C1S([O-])(=O)=O)=CC=C1SC1=CC=C(N=NC=2C=CC(OCC)=CC=2)C=C1S([O-])(=O)=O VSSMQLIMSVAUDK-UHFFFAOYSA-L 0.000 claims description 3
238000010438 heat treatment Methods 0.000 claims description 3
239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 claims description 3
229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
229910001220 stainless steel Inorganic materials 0.000 claims description 3
239000010935 stainless steel Substances 0.000 claims description 3
239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
238000011068 loading method Methods 0.000 claims description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 2
238000000926 separation method Methods 0.000 claims description 2
MPCYPRXRVWZKGF-UHFFFAOYSA-J tetrasodium 5-amino-3-[[4-[4-[(8-amino-1-hydroxy-3,6-disulfonatonaphthalen-2-yl)diazenyl]phenyl]phenyl]diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3)C3=CC=C(C=C3)N=NC3=C(C=C4C=C(C=C(C4=C3O)N)S([O-])(=O)=O)S([O-])(=O)=O)=C(O)C2=C1N MPCYPRXRVWZKGF-UHFFFAOYSA-J 0.000 claims description 2
239000000243 solution Substances 0.000 claims 26
239000000975 dye Substances 0.000 claims 14
239000003505 polymerization initiator Substances 0.000 claims 12
150000003839 salts Chemical class 0.000 claims 9
239000003999 initiator Substances 0.000 claims 8
229910052783 alkali metal Inorganic materials 0.000 claims 7
238000010557 suspension polymerization reaction Methods 0.000 claims 7
150000003567 thiocyanates Chemical class 0.000 claims 7
239000012736 aqueous medium Substances 0.000 claims 6
239000002904 solvent Substances 0.000 claims 6
150000003863 ammonium salts Chemical class 0.000 claims 5
150000001735 carboxylic acids Chemical class 0.000 claims 5
238000006243 chemical reaction Methods 0.000 claims 5
239000002609 medium Substances 0.000 claims 5
IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 claims 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 4
150000007513 acids Chemical class 0.000 claims 4
150000001340 alkali metals Chemical class 0.000 claims 4
239000007864 aqueous solution Substances 0.000 claims 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 4
TWBYWOBDOCUKOW-UHFFFAOYSA-N isonicotinic acid Chemical compound OC(=O)C1=CC=NC=C1 TWBYWOBDOCUKOW-UHFFFAOYSA-N 0.000 claims 4
239000000463 material Substances 0.000 claims 4
229910052751 metal Inorganic materials 0.000 claims 4
239000002184 metal Substances 0.000 claims 4
239000000126 substance Substances 0.000 claims 4
150000003460 sulfonic acids Chemical class 0.000 claims 4
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims 3
DXRWYIKGBIPGAG-UHFFFAOYSA-M chembl2028375 Chemical compound [Na+].[O-][N+](=O)C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=C(O)C=C(S([O-])(=O)=O)C2=C1 DXRWYIKGBIPGAG-UHFFFAOYSA-M 0.000 claims 3
238000002845 discoloration Methods 0.000 claims 3
230000000694 effects Effects 0.000 claims 3
238000000465 moulding Methods 0.000 claims 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 3
RTLULCVBFCRQKI-UHFFFAOYSA-N 1-amino-4-[3-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-sulfoanilino]-9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=1)=CC=C(S(O)(=O)=O)C=1NC1=NC(Cl)=NC(Cl)=N1 RTLULCVBFCRQKI-UHFFFAOYSA-N 0.000 claims 2
BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims 2
SEXWRZHFWPOWFA-VAWYXSNFSA-N 5-(phenylcarbamoylamino)-2-[(e)-2-[4-(phenylcarbamoylamino)-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC(=O)NC=3C=CC=CC=3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(=O)NC1=CC=CC=C1 SEXWRZHFWPOWFA-VAWYXSNFSA-N 0.000 claims 2
WRSWXNQFTKCPHT-UHFFFAOYSA-N 5-bromo-2-(9-chloro-3-hydroxybenzo[g][1]benzothiol-2-yl)indol-3-one Chemical compound [O-]c1c(sc2c1ccc1cccc(Cl)c21)C1=[NH+]c2ccc(Br)cc2C1=O WRSWXNQFTKCPHT-UHFFFAOYSA-N 0.000 claims 2
LMKBZNJJQISXRN-UHFFFAOYSA-N 8-hydroxy-7-[[4-[4-[(2-hydroxynaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]naphthalene-1,3,6-trisulfonic acid Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(C=C1)C1=CC=C(C=C1)N=NC1=C(C=C2C=C(C=C(C2=C1O)S(O)(=O)=O)S(O)(=O)=O)S(O)(=O)=O LMKBZNJJQISXRN-UHFFFAOYSA-N 0.000 claims 2
JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 claims 2
BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims 2
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
239000005711 Benzoic acid Substances 0.000 claims 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
ZGUNAGUHMKGQNY-ZETCQYMHSA-N L-alpha-phenylglycine zwitterion Chemical compound OC(=O)[C@@H](N)C1=CC=CC=C1 ZGUNAGUHMKGQNY-ZETCQYMHSA-N 0.000 claims 2
206010039509 Scab Diseases 0.000 claims 2
KXXFHLLUPUAVRY-UHFFFAOYSA-J [Na+].[Na+].[Na+].[Cu++].[O-]C(=O)C1=CC=C(C=C1N=N[C-](N=NC1=C([O-])C(NC2=NC(F)=NC(NCCOCCS(=O)(=O)C=C)=N2)=CC(=C1)S([O-])(=O)=O)C1=CC=CC=C1)S([O-])(=O)=O Chemical compound [Na+].[Na+].[Na+].[Cu++].[O-]C(=O)C1=CC=C(C=C1N=N[C-](N=NC1=C([O-])C(NC2=NC(F)=NC(NCCOCCS(=O)(=O)C=C)=N2)=CC(=C1)S([O-])(=O)=O)C1=CC=CC=C1)S([O-])(=O)=O KXXFHLLUPUAVRY-UHFFFAOYSA-J 0.000 claims 2
150000001342 alkaline earth metals Chemical class 0.000 claims 2
230000008901 benefit Effects 0.000 claims 2
235000010233 benzoic acid Nutrition 0.000 claims 2
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
ZBNARPCCDMHDDV-UHFFFAOYSA-N chembl1206040 Chemical compound C1=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=CC4=CC(=CC(N)=C4C=3O)S(O)(=O)=O)S(O)(=O)=O)C)=C(O)C2=C1N ZBNARPCCDMHDDV-UHFFFAOYSA-N 0.000 claims 2
BEQIIZJSZSVJJK-UHFFFAOYSA-M chembl2028372 Chemical compound [Na+].OC1=CC=C(S([O-])(=O)=O)C=C1N=NC1=C(O)C=CC2=CC=CC=C12 BEQIIZJSZSVJJK-UHFFFAOYSA-M 0.000 claims 2
239000003795 chemical substances by application Substances 0.000 claims 2
238000007334 copolymerization reaction Methods 0.000 claims 2
230000007423 decrease Effects 0.000 claims 2
KJPDHFPPVKRMMG-UHFFFAOYSA-L disodium 2,4-diamino-3-[[4-[4-[(2,6-diamino-3-methyl-5-sulfonatophenyl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]-5-methylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(S([O-])(=O)=O)=C(N)C(N=NC=2C(=CC(=CC=2)C=2C=C(C)C(N=NC=3C(=C(C=C(C)C=3N)S([O-])(=O)=O)N)=CC=2)C)=C1N KJPDHFPPVKRMMG-UHFFFAOYSA-L 0.000 claims 2
VDRKHPFIMDTBNX-UHFFFAOYSA-L disodium 7-amino-8-[[4-[4-[(2-amino-8-oxido-6-sulfonaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]-3-sulfonaphthalen-1-olate Chemical compound C1=CC(=CC=C1C2=CC=C(C=C2)N=NC3=C(C=CC4=CC(=CC(=C43)[O-])S(=O)(=O)O)N)N=NC5=C(C=CC6=CC(=CC(=C65)[O-])S(=O)(=O)O)N.[Na+].[Na+] VDRKHPFIMDTBNX-UHFFFAOYSA-L 0.000 claims 2
239000002270 dispersing agent Substances 0.000 claims 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 2
SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 claims 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims 2
238000002360 preparation method Methods 0.000 claims 2
239000001044 red dye Substances 0.000 claims 2
PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims 2
229910052708 sodium Inorganic materials 0.000 claims 2
239000011734 sodium Substances 0.000 claims 2
150000003457 sulfones Chemical class 0.000 claims 2
239000000375 suspending agent Substances 0.000 claims 2
QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 claims 2
150000004992 toluidines Chemical class 0.000 claims 2
SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 claims 2
PEAGNRWWSMMRPZ-UHFFFAOYSA-L woodstain scarlet Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 PEAGNRWWSMMRPZ-UHFFFAOYSA-L 0.000 claims 2
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims 1
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims 1
OESPFRYVCUTRKF-UHFFFAOYSA-N 2-(1,3-dioxo-2,3-dihydro-1h-inden-2-yl)quinoline-6,8-disulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S(O)(=O)=O)C=C(S(=O)(=O)O)C=C2C=C1 OESPFRYVCUTRKF-UHFFFAOYSA-N 0.000 claims 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
ZSPDYGICHBLYSD-UHFFFAOYSA-N 2-methylnaphthalene-1-carboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C)=CC=C21 ZSPDYGICHBLYSD-UHFFFAOYSA-N 0.000 claims 1
NXVGUNGPINUNQN-UHFFFAOYSA-N 2-phenylpropan-2-yl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C1=CC=CC=C1 NXVGUNGPINUNQN-UHFFFAOYSA-N 0.000 claims 1
ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 claims 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
229920008712 Copo Polymers 0.000 claims 1
108010010803 Gelatin Proteins 0.000 claims 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 claims 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
JQYMGXZJTCOARG-UHFFFAOYSA-N Reactive blue 2 Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=C1S(O)(=O)=O)=CC=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S(O)(=O)=O)=C1 JQYMGXZJTCOARG-UHFFFAOYSA-N 0.000 claims 1
239000004147 Sorbitan trioleate Substances 0.000 claims 1
PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims 1
229920002472 Starch Polymers 0.000 claims 1
229910000831 Steel Inorganic materials 0.000 claims 1
CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 claims 1
230000002730 additional effect Effects 0.000 claims 1
239000000654 additive Substances 0.000 claims 1
230000002411 adverse Effects 0.000 claims 1
230000001476 alcoholic effect Effects 0.000 claims 1
150000001339 alkali metal compounds Chemical class 0.000 claims 1
150000001336 alkenes Chemical class 0.000 claims 1
150000008064 anhydrides Chemical class 0.000 claims 1
229910052788 barium Inorganic materials 0.000 claims 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
239000001045 blue dye Substances 0.000 claims 1
238000005282 brightening Methods 0.000 claims 1
239000001049 brown dye Substances 0.000 claims 1
229910052792 caesium Inorganic materials 0.000 claims 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
229910052791 calcium Inorganic materials 0.000 claims 1
239000011575 calcium Substances 0.000 claims 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
239000001768 carboxy methyl cellulose Substances 0.000 claims 1
235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
125000002843 carboxylic acid group Chemical group 0.000 claims 1
239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
239000001913 cellulose Substances 0.000 claims 1
229920002678 cellulose Polymers 0.000 claims 1
229920003086 cellulose ether Polymers 0.000 claims 1
AZOPGDOIOXKJRA-UHFFFAOYSA-L chembl1817788 Chemical compound [Na+].[Na+].C1=C(C([O-])=O)C(O)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C=C(C(O)=CC=2)C([O-])=O)C=C1 AZOPGDOIOXKJRA-UHFFFAOYSA-L 0.000 claims 1
XRPLBRIHZGVJIC-UHFFFAOYSA-L chembl3182776 Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC3=CC(=C(N=NC=4C=CC=CC=4)C(O)=C3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 XRPLBRIHZGVJIC-UHFFFAOYSA-L 0.000 claims 1
230000001055 chewing effect Effects 0.000 claims 1
229920006026 co-polymeric resin Polymers 0.000 claims 1
238000012505 colouration Methods 0.000 claims 1
239000000470 constituent Substances 0.000 claims 1
238000000354 decomposition reaction Methods 0.000 claims 1
ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 claims 1
239000006185 dispersion Substances 0.000 claims 1
238000007720 emulsion polymerization reaction Methods 0.000 claims 1
150000002148 esters Chemical class 0.000 claims 1
235000019441 ethanol Nutrition 0.000 claims 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims 1
210000003608 fece Anatomy 0.000 claims 1
235000019253 formic acid Nutrition 0.000 claims 1
238000009472 formulation Methods 0.000 claims 1
229920000159 gelatin Polymers 0.000 claims 1
239000008273 gelatin Substances 0.000 claims 1
235000019322 gelatine Nutrition 0.000 claims 1
235000011852 gelatine desserts Nutrition 0.000 claims 1
JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 1
231100000206 health hazard Toxicity 0.000 claims 1
230000006872 improvement Effects 0.000 claims 1
238000009776 industrial production Methods 0.000 claims 1
239000004615 ingredient Substances 0.000 claims 1
230000000977 initiatory effect Effects 0.000 claims 1
229910021432 inorganic complex Inorganic materials 0.000 claims 1
239000005453 ketone based solvent Substances 0.000 claims 1
239000004310 lactic acid Substances 0.000 claims 1
235000014655 lactic acid Nutrition 0.000 claims 1
239000010871 livestock manure Substances 0.000 claims 1
229910052749 magnesium Inorganic materials 0.000 claims 1
239000011777 magnesium Substances 0.000 claims 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
239000011976 maleic acid Substances 0.000 claims 1
150000002689 maleic acids Chemical class 0.000 claims 1
229910017604 nitric acid Inorganic materials 0.000 claims 1
239000001048 orange dye Substances 0.000 claims 1
150000007524 organic acids Chemical class 0.000 claims 1
235000005985 organic acids Nutrition 0.000 claims 1
150000002894 organic compounds Chemical class 0.000 claims 1
239000003960 organic solvent Substances 0.000 claims 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Substances OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 1
UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 claims 1
125000000864 peroxy group Chemical group O(O*)* 0.000 claims 1
239000011574 phosphorus Substances 0.000 claims 1
229910052698 phosphorus Inorganic materials 0.000 claims 1
235000002949 phytic acid Nutrition 0.000 claims 1
239000000467 phytic acid Substances 0.000 claims 1
229940068041 phytic acid Drugs 0.000 claims 1
239000000049 pigment Substances 0.000 claims 1
239000002861 polymer material Substances 0.000 claims 1
230000000379 polymerizing effect Effects 0.000 claims 1
235000012731 ponceau 4R Nutrition 0.000 claims 1
159000000001 potassium salts Chemical class 0.000 claims 1
238000007781 pre-processing Methods 0.000 claims 1
239000001047 purple dye Substances 0.000 claims 1
235000012752 quinoline yellow Nutrition 0.000 claims 1
150000004053 quinones Chemical class 0.000 claims 1
230000009467 reduction Effects 0.000 claims 1
OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 claims 1
230000035945 sensitivity Effects 0.000 claims 1
238000004904 shortening Methods 0.000 claims 1
MTNKEJFOGYPHON-AAKIMCHBSA-N sodium;5-[(z)-(3-carboxy-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methylbenzoic acid Chemical compound [Na+].C1=C(C(O)=O)C(=O)C(C)=C\C1=C(C=1C(=CC=CC=1Cl)Cl)/C1=CC(C)=C(O)C(C(O)=O)=C1 MTNKEJFOGYPHON-AAKIMCHBSA-N 0.000 claims 1
239000007787 solid Substances 0.000 claims 1
239000011877 solvent mixture Substances 0.000 claims 1
235000019337 sorbitan trioleate Nutrition 0.000 claims 1
229960000391 sorbitan trioleate Drugs 0.000 claims 1
238000005507 spraying Methods 0.000 claims 1
235000019698 starch Nutrition 0.000 claims 1
239000008107 starch Substances 0.000 claims 1
239000010959 steel Substances 0.000 claims 1
125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims 1
125000000542 sulfonic acid group Chemical group 0.000 claims 1
239000004094 surface-active agent Substances 0.000 claims 1
238000004448 titration Methods 0.000 claims 1
230000001988 toxicity Effects 0.000 claims 1
231100000419 toxicity Toxicity 0.000 claims 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
ROXJKRREYRXPIT-UHFFFAOYSA-N trithiocyanatomethyl thiocyanate Chemical compound N#CSC(SC#N)(SC#N)SC#N ROXJKRREYRXPIT-UHFFFAOYSA-N 0.000 claims 1
CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 claims 1
229920001567 vinyl ester resin Polymers 0.000 claims 1
239000001043 yellow dye Substances 0.000 claims 1
238000002474 experimental method Methods 0.000 description 5
AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 5
ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 4
ALWXETURCOIGIZ-UHFFFAOYSA-N 1-nitropropylbenzene Chemical compound CCC([N+]([O-])=O)C1=CC=CC=C1 ALWXETURCOIGIZ-UHFFFAOYSA-N 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
238000013459 approach Methods 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000004898 kneading Methods 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
229940116357 potassium thiocyanate Drugs 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229940035339 tri-chlor Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CH788080A 1979-10-22 1980-10-22 Verfahren zur herstellung von polyvinylchloridhomo- oder -copolymeren durch suspensionspolymerisation. CH645392A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP54136262A JPS606361B2 (ja)	1979-10-22	1979-10-22	塩化ビニル系単量体の重合方法

Publications (1)

Publication Number	Publication Date
CH645392A5 true CH645392A5 (de)	1984-09-28

Family

ID=15171066

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH788080A CH645392A5 (de)	1979-10-22	1980-10-22	Verfahren zur herstellung von polyvinylchloridhomo- oder -copolymeren durch suspensionspolymerisation.

Country Status (21)

Country	Link
JP (1)	JPS606361B2 (da)
AT (1)	AT369755B (da)
BE (1)	BE885813A (da)
BR (1)	BR8006772A (da)
CA (1)	CA1193394A (da)
CH (1)	CH645392A5 (da)
CU (1)	CU21471A (da)
DE (1)	DE3039543A1 (da)
DK (1)	DK443880A (da)
ES (1)	ES8107254A1 (da)
FR (1)	FR2467860B1 (da)
GB (1)	GB2061980B (da)
HU (1)	HU191809B (da)
IN (1)	IN151895B (da)
IT (1)	IT1133972B (da)
MX (1)	MX155347A (da)
NL (1)	NL8005812A (da)
NO (1)	NO803099L (da)
PL (1)	PL227440A1 (da)
PT (1)	PT71944B (da)
SE (1)	SE8007331L (da)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62176245A (ja) *	1986-01-29	1987-08-03	Sekisui Chem Co Ltd	電話機
JPS62219736A (ja) *	1986-03-19	1987-09-28	Matsushita Electric Works Ltd	電話用切り分け器
JPS62219737A (ja) *	1986-03-19	1987-09-28	Matsushita Electric Works Ltd	電話用切り分け器

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4093788A (en) *	1974-06-24	1978-06-06	Stauffer Chemical Company	Method for the preparation of polyvinyl chloride by suspension or emulsion polymerization
JPS5212291A (en) *	1975-07-18	1977-01-29	Shin Etsu Chem Co Ltd	Process for polymerizing vinyl chloride
JPS5214688A (en) *	1975-07-24	1977-02-03	Shin Etsu Chem Co Ltd	A process for polymerizing vinyl chloride
JPS5224070A (en) *	1975-08-19	1977-02-23	Toshiba Corp	Productio method of magnetron anode
JPS5224953A (en) *	1975-08-22	1977-02-24	Osaka Transformer Co Ltd	Arc welding machine
JPS5228347A (en) *	1975-08-29	1977-03-03	Nippon Kogaku Kk <Nikon>	Position detector unit
LU76676A1 (da) *	1977-02-01	1978-09-13
JPS548690A (en) *	1977-06-20	1979-01-23	Goodrich Co B F	Method of preventing polymer from adhering on inner surface of polymerization reactor

1979
- 1979-10-22 JP JP54136262A patent/JPS606361B2/ja not_active Expired
1980
- 1980-10-14 IN IN1167/CAL/80A patent/IN151895B/en unknown
- 1980-10-17 CA CA000362647A patent/CA1193394A/en not_active Expired
- 1980-10-17 NO NO803099A patent/NO803099L/no unknown
- 1980-10-20 DK DK443880A patent/DK443880A/da not_active Application Discontinuation
- 1980-10-20 SE SE8007331A patent/SE8007331L/xx unknown
- 1980-10-20 DE DE19803039543 patent/DE3039543A1/de not_active Withdrawn
- 1980-10-20 GB GB8033747A patent/GB2061980B/en not_active Expired
- 1980-10-21 MX MX184414A patent/MX155347A/es unknown
- 1980-10-21 IT IT25487/80A patent/IT1133972B/it active
- 1980-10-21 PT PT71944A patent/PT71944B/pt unknown
- 1980-10-21 BR BR8006772A patent/BR8006772A/pt unknown
- 1980-10-21 BE BE0/202545A patent/BE885813A/fr not_active IP Right Cessation
- 1980-10-21 FR FR8022441A patent/FR2467860B1/fr not_active Expired
- 1980-10-21 CU CU35339A patent/CU21471A/es unknown
- 1980-10-21 ES ES496127A patent/ES8107254A1/es not_active Expired
- 1980-10-22 NL NL8005812A patent/NL8005812A/nl not_active Application Discontinuation
- 1980-10-22 CH CH788080A patent/CH645392A5/de not_active IP Right Cessation
- 1980-10-22 AT AT0521080A patent/AT369755B/de not_active IP Right Cessation
- 1980-10-22 PL PL22744080A patent/PL227440A1/xx unknown
- 1980-10-22 HU HU802567A patent/HU191809B/hu unknown

Also Published As

Publication number	Publication date
AT369755B (de)	1983-01-25
BR8006772A (pt)	1981-04-28
IN151895B (da)	1983-08-27
PT71944A (en)	1980-11-01
CU21471A (en)	1983-10-04
ES496127A0 (es)	1981-10-01
JPS606361B2 (ja)	1985-02-18
IT1133972B (it)	1986-07-24
FR2467860A1 (fr)	1981-04-30
JPS5659808A (en)	1981-05-23
SE8007331L (sv)	1981-04-23
DK443880A (da)	1981-04-23
ATA521080A (de)	1982-06-15
NO803099L (no)	1981-04-23
IT8025487A0 (it)	1980-10-21
MX155347A (es)	1988-02-22
ES8107254A1 (es)	1981-10-01
PT71944B (en)	1981-08-31
PL227440A1 (da)	1981-07-10
NL8005812A (nl)	1981-04-24
BE885813A (fr)	1981-02-16
HU191809B (en)	1987-04-28
GB2061980B (en)	1983-06-29
GB2061980A (en)	1981-05-20
CA1193394A (en)	1985-09-10
DE3039543A1 (de)	1981-09-10
FR2467860B1 (fr)	1985-11-15

Legal Events

Date	Code	Title	Description
1993-06-30	PL	Patent ceased
2024-10-31	PL	Patent ceased

Publication	Publication Date	Title
DE2840010C3 (de)	1982-05-13	Pfropfmischpolymerisate
DE2635780C2 (da)	1989-03-09
DE1795078B2 (de)	1974-02-21	Wäßrige Polytetraftuoräthylen-Dispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung
DE1064719B (de)	1959-09-03	Verfahren zur Herstellung vernetzbarer bzw. vernetzter Polymerer
DE1102407B (de)	1961-03-16	Verfahren zur Herstellung von fluoreszierenden Polymerisaten
DE2942657A1 (de)	1981-04-30	Verfahren zur herstellung von polyvinylpyrrolidon, dessen waessrige loesung eine hohe viskositaet aufweist, durch waermebehandlung von waessrigen loesungen von ueblichem polyvinylpyrrolidon
DE2560671C2 (da)	1989-12-14
DE3019390C2 (da)	1989-01-19
EP0590460A2 (de)	1994-04-06	Hochkonzentrierte wässrige Poly(acrylnitril)-Emulsionen und Verfahren zu ihrer Herstellung
CH631187A5 (en)	1982-07-30	Process for the polymerisation of vinyl chloride
DE2548424A1 (de)	1976-05-13	Verfahren zum polymerisieren von vinylchlorid
DE2433486B2 (de)	1977-08-25	Verfahren zur herstellung von emulsionen, konzentrierten dispersionen und pasten von hydrophilen polymeren fuellstoffen in weichmachern
DE2757065C2 (de)	1982-03-11	Verfahren zur Polymerisation von Vinylchlorid, allein oder zusammen mit anderen Vinylhalogeniden oder anderen mit Vinylchlorid copolymerisierbaren Comonomeren, in wäßriger Dispersion und Reaktionsgefäß zu dessen Durchführung
DE1174070B (de)	1964-07-16	Verfahren zur Herstellung von Polymerisaten und Mischpolymerisaten des Acrylnitrils
DE68919163T2 (de)	1995-03-09	Verfahren zur Unterdrückung der Bildung von Polymerkrusten.
CH645392A5 (de)	1984-09-28	Verfahren zur herstellung von polyvinylchloridhomo- oder -copolymeren durch suspensionspolymerisation.
DE19744845A1 (de)	1999-04-15	Verfahren zur Herstellung von Homo- und Mischpolymerisaten des Vinylchlorids
CH624687A5 (en)	1981-08-14	Process for the polymerisation of vinyl chloride
DE2632468C2 (da)	1989-04-20
DE2637582A1 (de)	1977-03-03	Verfahren zur herstellung von vinylchloridpolymeren
DE2539430C2 (de)	1985-05-23	Verfahren zum Abstoppen der Polymerisation von Vinylchlorid in wäßriger Emulsion oder Suspension
DE2415983A1 (de)	1974-10-10	Verfahren zum substanzhomo- oder -copolymerisieren von vinylchlorid
EP0850956A2 (de)	1998-07-01	Verfahren zur Herstellung wässriger Polymerisatdispersionen durch radikalische, wässrige Emulsions-polymerisation
DD232711A5 (de)	1986-02-05	Verfahren zur verhinderung der abscheidung von polymerkrusten bei der polymerisation von aethylenisch ungesaettigten monomeren und beschichtungszusammensetzung zur durchfuehrung dieses verfahrens
DE2807180C2 (da)	1991-12-05