CL2020002323A1 - Uso de compuestos de heteroaril-triazol y heteroaril-tetrazol como pesticidas en la protección de plantas - Google Patents

Uso de compuestos de heteroaril-triazol y heteroaril-tetrazol como pesticidas en la protección de plantas

Info

Publication number
CL2020002323A1
CL2020002323A1 CL2020002323A CL2020002323A CL2020002323A1 CL 2020002323 A1 CL2020002323 A1 CL 2020002323A1 CL 2020002323 A CL2020002323 A CL 2020002323A CL 2020002323 A CL2020002323 A CL 2020002323A CL 2020002323 A1 CL2020002323 A1 CL 2020002323A1
Authority
CL
Chile
Prior art keywords
heteroaryl
triazole
pesticides
plant protection
tetrazole compounds
Prior art date
Application number
CL2020002323A
Other languages
English (en)
Inventor
Hans-Georg Schwarz
Werner Hallenbach
Alexander Arlt
Kerstin Ilg
Marc Linka
Elke Hellwege
Ulrich Ebbinghaus-Kintscher
Sebastian Horstmann
Peter Jeschke
Martin Füsslein
Grande Yolanda Cancho
Arunas Jonas Damijonaitis
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of CL2020002323A1 publication Critical patent/CL2020002323A1/es

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/33Heterocyclic compounds
    • A61K31/395Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/435Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
    • A61K31/44Non condensed pyridines; Hydrogenated derivatives thereof
    • A61K31/4427Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems
    • A61K31/4439Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems containing a five-membered ring with nitrogen as a ring hetero atom, e.g. omeprazole
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00Antiparasitic agents
    • A61P33/10Anthelmintics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00Antiparasitic agents
    • A61P33/14Ectoparasiticides, e.g. scabicides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D403/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D403/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/14Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epidemiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

La presente invención se refiere al uso de compuestos de heteroaril–triazol y heteroaril–tetrazol, al uso de formulaciones y composiciones que comprenden dichos compuestos para controlar plagas animales, que incluyen artrópodos e insectos, en la protección de plantas.
CL2020002323A 2018-03-08 2020-09-08 Uso de compuestos de heteroaril-triazol y heteroaril-tetrazol como pesticidas en la protección de plantas CL2020002323A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP18160736 2018-03-08
EP18185778 2018-07-26

Publications (1)

Publication Number Publication Date
CL2020002323A1 true CL2020002323A1 (es) 2021-04-30

Family

ID=65529718

Family Applications (1)

Application Number Title Priority Date Filing Date
CL2020002323A CL2020002323A1 (es) 2018-03-08 2020-09-08 Uso de compuestos de heteroaril-triazol y heteroaril-tetrazol como pesticidas en la protección de plantas

Country Status (14)

Country Link
US (1) US20200404919A1 (es)
EP (1) EP3761791A1 (es)
JP (1) JP2021516238A (es)
KR (1) KR20200129128A (es)
CN (1) CN111818801A (es)
AU (1) AU2019229521A1 (es)
BR (1) BR112020016946A2 (es)
CL (1) CL2020002323A1 (es)
MX (1) MX2020009320A (es)
PH (1) PH12020551407A1 (es)
PY (1) PY1918202A (es)
TW (1) TW201940477A (es)
UY (1) UY38142A (es)
WO (1) WO2019170626A1 (es)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UY38184A (es) 2018-04-17 2019-10-31 Bayer Ag Compuestos heteroarilo-triazol y heteroarilo-tetrazol novedosos como plaguicidas
IL277978B2 (en) * 2018-04-25 2024-07-01 Bayer Ag Novel heteroaryl-triazole and heteroaryl-tetrazole compounds as pesticides
CN112087951A (zh) * 2018-05-08 2020-12-15 先正达农作物保护股份公司 施用某一种或多种杂芳基-1,2,4-三唑和杂芳基-四唑化合物来控制对植物、其繁殖材料和植物衍生产品的损害的方法
PY1974248A (es) * 2018-09-13 2020-08-21 Syngenta Participations Ag Compuestos de azol-amida pesticidamente activos
PY1974629A (es) * 2018-09-13 2021-01-11 Syngenta Participations Ag Compuestos de azol-amida pesticidamente activos
WO2020094363A1 (en) 2018-11-05 2020-05-14 Syngenta Participations Ag Pesticidally active azole-amide compounds
CN113597424B (zh) * 2019-03-20 2025-04-18 先正达农作物保护股份公司 杀有害生物活性的唑酰胺化合物
BR112021018822A2 (pt) * 2019-03-22 2021-11-23 Syngenta Crop Protection Ag Derivados de n-[1-(5-bromo-2-pirimidin-2-il-1,2,4-triazol-3-il)etil]-2-ciclopropil-6-(trifluorometil)piridina-4-carboxamida e compostos relacionados como inseticidas
TWI853009B (zh) * 2019-03-29 2024-08-21 瑞士商先正達農作物保護公司 殺有害生物活性之二-醯胺化合物
EP3725788A1 (en) 2019-04-15 2020-10-21 Bayer AG Novel heteroaryl-substituted aminoalkyl azole compounds as pesticides
EP4003973B1 (en) 2019-07-23 2024-11-20 Bayer Aktiengesellschaft Novel heteroaryl-triazole compounds as pesticides
PH12022550179A1 (en) 2019-07-23 2022-11-14 Bayer Ag Novel heteroaryl-triazole compounds as pesticides
MX2022004366A (es) * 2019-10-09 2022-05-06 Bayer Ag Nuevos compuestos de heteroarilo-triazol como pesticidas.
BR112022006791A2 (pt) 2019-10-09 2022-06-28 Bayer Ag Novos compostos heteroaril-triazol como pesticidas
TW202128650A (zh) * 2019-10-11 2021-08-01 德商拜耳動物保健有限公司 作為殺蟲劑之新穎的雜芳基取代之吡𠯤衍生物
WO2021068179A1 (en) * 2019-10-11 2021-04-15 Bayer Animal Health Gmbh Novel heteroaryl-substituted pyrazine derivatives as pesticides
TW202134226A (zh) 2019-11-18 2021-09-16 德商拜耳廠股份有限公司 作為殺蟲劑之新穎雜芳基-三唑化合物
TW202136248A (zh) 2019-11-25 2021-10-01 德商拜耳廠股份有限公司 作為殺蟲劑之新穎雜芳基-三唑化合物
WO2021122911A1 (en) 2019-12-18 2021-06-24 Intervet International B.V. Anthelmintic compounds comprising a quinoline structure
MX2022007671A (es) 2019-12-18 2022-07-19 Intervet Int Bv Compuestos antihelminticos que comprenden una estructura de azaindoles.
CN115551839B (zh) * 2020-02-18 2024-06-04 拜耳公司 作为农药的杂芳基-三唑化合物
TWI891782B (zh) 2020-05-06 2025-08-01 德商拜耳廠股份有限公司 作為殺蟲劑之新穎雜芳基三唑化合物
EP3929189A1 (en) 2020-06-25 2021-12-29 Bayer Animal Health GmbH Novel heteroaryl-substituted pyrazine derivatives as pesticides
AU2021395477A1 (en) 2020-12-11 2023-06-22 Intervet International B.V. Anthelmintic compounds comprising a thienopyridine structure
WO2022233777A1 (en) 2021-05-06 2022-11-10 Bayer Aktiengesellschaft Alkylamide substituted, annulated imidazoles and use thereof as insecticides
AU2022335669A1 (en) 2021-08-25 2024-02-01 Bayer Aktiengesellschaft Novel pyrazinyl-triazole compounds as pesticides
EP4414364A4 (en) * 2021-10-08 2025-09-24 Nihon Nohyaku Co Ltd PYRIMIDINYL TRIAZOLE COMPOUND OR SALT THEREOF, PEST CONTROL AGENT CONTAINING SAID COMPOUND AS ACTIVE INGREDIENT, AND PEST CONTROL METHOD
EP4198033A1 (en) 2021-12-14 2023-06-21 Basf Se Heterocyclic compounds for the control of invertebrate pests
CN114487166B (zh) * 2021-12-31 2024-05-28 山东京博生物科技有限公司 一种2,6-二羟基-3-氰基-4-三氟甲基吡啶含量的检测方法
TW202413341A (zh) * 2022-09-23 2024-04-01 美商富曼西公司 吡唑醯胺殺昆蟲劑
CN121039120A (zh) 2023-04-24 2025-11-28 巴斯夫欧洲公司 用于防治无脊椎有害生物的嘧啶化合物
EP4455137A1 (en) 2023-04-24 2024-10-30 Basf Se Pyrimidine compounds for the control of invertebrate pests
EP4712773A1 (en) * 2023-05-17 2026-03-25 Basf Se Pesticidal mixtures comprising a benzamide compound
WO2025186065A1 (en) 2024-03-05 2025-09-12 Bayer Aktiengesellschaft Heteroaryl-substituted (aza)quinoxaline derivatives as pesticides
WO2025224076A1 (de) 2024-04-23 2025-10-30 Bayer Aktiengesellschaft Substituierte arylpyrazine sowie deren salze und ihre verwendung als herbizide wirkstoffe
WO2025257242A1 (de) 2024-06-14 2025-12-18 Bayer Aktiengesellschaft Heterocyclyl-substituierte aryl- und heteroarylpyrazine sowie deren salze und ihre verwendung als herbizide wirkstoffe

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63135364A (ja) * 1986-11-28 1988-06-07 Nissan Chem Ind Ltd アミド置換アセトニトリル誘導体、その製法および農園芸用殺菌剤
JPH10204066A (ja) * 1997-01-28 1998-08-04 Nippon Bayer Agrochem Kk 1−フエニル−5−アニリノテトラゾール類及び農薬としてのその利用
EP1099695A1 (en) 1999-11-09 2001-05-16 Laboratoire Theramex S.A. 5-aryl-1H-1,2,4-triazole compounds as inhibitors of cyclooxygenase-2 and pharmaceutical compositions containing them
GB0213715D0 (en) 2002-06-14 2002-07-24 Syngenta Ltd Chemical compounds
TWI312272B (en) 2003-05-12 2009-07-21 Sumitomo Chemical Co Pyrimidine compound and pests controlling composition containing the same
GB0414438D0 (en) 2004-06-28 2004-07-28 Syngenta Participations Ag Chemical compounds
RU2394819C2 (ru) 2004-10-20 2010-07-20 Кумиай Кемикал Индастри Ко., Лтд. Инсектицид, акарицид и нематоцид, содержащие в качестве активного компонента производное 3-триазолилфенилсульфида
BRPI0616667B1 (pt) 2005-10-06 2017-07-18 Nippon Soda Co. , Ltd. Compounds of cyclical amine or salts thereof or non-oxides thereof, and agents for control of fever
JP5268461B2 (ja) 2008-07-14 2013-08-21 Meiji Seikaファルマ株式会社 Pf1364物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤
CN101337940B (zh) 2008-08-12 2012-05-02 国家农药创制工程技术研究中心 具杀虫活性的含氮杂环二氯烯丙醚类化合物
CN101337937B (zh) 2008-08-12 2010-12-22 国家农药创制工程技术研究中心 具有杀虫活性的n-苯基-5-取代氨基吡唑类化合物
CN101715774A (zh) 2008-10-09 2010-06-02 浙江化工科技集团有限公司 一个具有杀虫活性化合物制备及用途
EP2184273A1 (de) 2008-11-05 2010-05-12 Bayer CropScience AG Halogen-substituierte Verbindungen als Pestizide
GB0820344D0 (en) 2008-11-06 2008-12-17 Syngenta Ltd Herbicidal compositions
US9067892B2 (en) 2008-12-12 2015-06-30 Syngenta Crop Protection, Inc. Spiroheterocyclic N-oxypiperidines as pesticides
TWI487486B (zh) 2009-12-01 2015-06-11 Syngenta Participations Ag 以異唑啉衍生物為主之殺蟲化合物
WO2011085575A1 (zh) 2010-01-15 2011-07-21 江苏省农药研究所股份有限公司 邻杂环甲酰苯胺类化合物及其合成方法和应用
JP2013527208A (ja) 2010-05-31 2013-06-27 シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト 作物を増強する方法
CN101967139B (zh) 2010-09-14 2013-06-05 中化蓝天集团有限公司 一种含一氟甲氧基吡唑的邻甲酰氨基苯甲酰胺类化合物、其合成方法及应用
CN103261188A (zh) * 2010-12-17 2013-08-21 先正达参股股份有限公司 杀虫化合物
JP2014534182A (ja) 2011-10-03 2014-12-18 シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト 殺虫化合物としてのイソオキサゾリン誘導体
WO2013050317A1 (en) 2011-10-03 2013-04-11 Syngenta Limited Polymorphs of an isoxazoline derivative
CN102391261A (zh) 2011-10-14 2012-03-28 上海交通大学 一种n-取代噁二嗪类化合物及其制备方法和应用
TWI566701B (zh) 2012-02-01 2017-01-21 日本農藥股份有限公司 芳烷氧基嘧啶衍生物及包含該衍生物作為有效成分的農園藝用殺蟲劑及其使用方法
US9334238B2 (en) 2012-03-30 2016-05-10 Basf Se N-substituted pyridinylidenes for combating animal pests
EP2647626A1 (en) 2012-04-03 2013-10-09 Syngenta Participations AG. 1-Aza-spiro[4.5]dec-3-ene and 1,8-diaza-spiro[4.5]dec-3-ene derivatives as pesticides
NZ700595A (en) 2012-04-27 2016-04-29 Dow Agrosciences Llc Pesticidal compositions and processes related thereto
US9282739B2 (en) 2012-04-27 2016-03-15 Dow Agrosciences Llc Pesticidal compositions and processes related thereto
CN103232431B (zh) 2013-01-25 2014-11-05 青岛科技大学 一种二卤代吡唑酰胺类化合物及其应用
CN103109816B (zh) 2013-01-25 2014-09-10 青岛科技大学 硫代苯甲酰胺类化合物及其应用
US20140275503A1 (en) 2013-03-13 2014-09-18 Dow Agrosciences Llc Process for the preparation of certain triaryl rhamnose carbamates
WO2014187846A1 (en) 2013-05-23 2014-11-27 Syngenta Participations Ag Tank-mix formulations
CN103265527B (zh) 2013-06-07 2014-08-13 江苏省农用激素工程技术研究中心有限公司 邻氨基苯甲酰胺化合物及其制备方法和应用
CN103524422B (zh) 2013-10-11 2015-05-27 中国农业科学院植物保护研究所 苯并咪唑衍生物及其制备方法和用途
MX2016004942A (es) 2013-10-17 2016-06-28 Dow Agrosciences Llc Procesos para la preparacion de compuestos plaguicidas.
CA2925873A1 (en) 2013-10-17 2015-04-23 Dow Agrosciences Llc Processes for the preparation of pesticidal compounds
TWI679197B (zh) * 2016-05-05 2019-12-11 瑞士商伊蘭科動物健康公司 雜芳基-1,2,4-三唑及雜芳基-三唑化合物
JP2019534306A (ja) 2016-11-10 2019-11-28 羅欣薬業(上海)有限公司Luoxin Pharmaceutical(Shanghai) Co., Ltd. 窒素含有大員環系化合物、その製造方法、薬物組成物および使用

Also Published As

Publication number Publication date
WO2019170626A1 (en) 2019-09-12
TW201940477A (zh) 2019-10-16
PY1918202A (es) 2020-02-05
CN111818801A (zh) 2020-10-23
JP2021516238A (ja) 2021-07-01
MX2020009320A (es) 2020-10-07
UY38142A (es) 2019-10-01
BR112020016946A2 (pt) 2020-12-15
EP3761791A1 (en) 2021-01-13
US20200404919A1 (en) 2020-12-31
PH12020551407A1 (en) 2021-09-01
KR20200129128A (ko) 2020-11-17
AU2019229521A1 (en) 2020-09-03

Similar Documents

Publication Publication Date Title
CL2020002323A1 (es) Uso de compuestos de heteroaril-triazol y heteroaril-tetrazol como pesticidas en la protección de plantas
CL2020002741A1 (es) Nuevos compuestos de heteroaril-triazol y heteroaril-tetrazol como pesticidas
UY38970A (es) Nuevos compuestos de heteroaril–triazol como plaguicidas
CO2022000516A2 (es) Novedosos compuestos de heteroaril-triazol como plaguicidas
CL2020002706A1 (es) Compuestos heteroaril–triazol y heteroaril–tetrazol como pesticidas
CO2022000513A2 (es) Novedosos compuestos de heteroaril-triazol como plaguicidas
UY39087A (es) Nuevos compuestos de heteroaril–triazol como pesticidas
CL2020002665A1 (es) Compuestos heteroarilo-triazol y heteroarilo-tetrazol novedosos como plaguicidas
UY38962A (es) Nuevos compuestos de heteroaril–triazol como plaguicidas
PY1929303A (es) Compuestos heteroarilo-triazol y heteroarilo-tetrazol novedosos como plaguicidas
CO2022004289A2 (es) Nuevos compuestos de heteroarilo-triazol como pesticidas
UY38664A (es) Compuestos de aminoalquil azol sustituidos con heteroarilo novedosos como plaguicidas
CO2022004290A2 (es) Nuevos compuestos de heteroarilo-triazol como pesticidas
CL2020002313A1 (es) Compuestos herbicidas.
CO2024001738A2 (es) Nuevos compuestos de pirazinil–triazol como pesticidas
UY38784A (es) Compuestos de espiro ciclohexanodiona herbicida
BR112018068034A2 (pt) compostos espiro da fórmula i, composição, composição agrícola para combater pragas animais, método de combate ou controle de pragas invertebradas, método de proteção de plantas, semente e uso dos compostos
PY1930371A (es) Compuestos heteroarilo-triazol y heteroarilo-tetrazol novedosos como plaguicidas.-