CN100384826C - 空间位阻的胺醚的制备 - Google Patents

空间位阻的胺醚的制备 Download PDF

Info

Publication number: CN100384826C
Authority: CN; China
Prior art keywords: group; alkyl; formula; phenyl; compound
Prior art date: 1998-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CNB2004100473618A

Other languages

English (en)

Chinese (zh)

Other versions

CN1552758A (zh

Inventor

A·泽达

G·菲里

M·萨拉

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Schweiz AG

Original Assignee

Ciba Spezialitaetenchemie Holding AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-02-25

Filing date

1999-02-24

Publication date

2008-04-30

1998-02-25 Priority claimed from IT98MI000366A external-priority patent/ITMI980366A1/it

1999-02-24 Application filed by Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG

2004-12-08 Publication of CN1552758A publication Critical patent/CN1552758A/zh

2008-04-30 Application granted granted Critical

2008-04-30 Publication of CN100384826C publication Critical patent/CN100384826C/zh

2019-02-24 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

-1 amine ethers Chemical class 0.000 title claims abstract description 244
238000002360 preparation method Methods 0.000 title abstract description 19
150000001875 compounds Chemical class 0.000 claims abstract description 159
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 102
229910052799 carbon Inorganic materials 0.000 claims abstract description 89
150000001721 carbon Chemical group 0.000 claims abstract description 49
238000000034 method Methods 0.000 claims abstract description 40
229910052760 oxygen Inorganic materials 0.000 claims abstract description 40
239000001301 oxygen Substances 0.000 claims abstract description 39
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 36
239000000126 substance Substances 0.000 claims abstract description 35
229910052736 halogen Inorganic materials 0.000 claims abstract description 31
150000002367 halogens Chemical class 0.000 claims abstract description 31
125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 15
125000005647 linker group Chemical group 0.000 claims abstract description 11
239000011368 organic material Substances 0.000 claims abstract description 11
239000003381 stabilizer Substances 0.000 claims abstract description 11
239000003063 flame retardant Substances 0.000 claims abstract description 9
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
239000000203 mixture Substances 0.000 claims description 92
229910052739 hydrogen Inorganic materials 0.000 claims description 87
239000001257 hydrogen Substances 0.000 claims description 70
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 53
125000001931 aliphatic group Chemical group 0.000 claims description 40
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 39
125000000217 alkyl group Chemical group 0.000 claims description 38
239000003795 chemical substances by application Substances 0.000 claims description 37
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 37
239000011248 coating agent Substances 0.000 claims description 33
238000000576 coating method Methods 0.000 claims description 33
150000002431 hydrogen Chemical class 0.000 claims description 31
229910052751 metal Inorganic materials 0.000 claims description 24
239000002184 metal Substances 0.000 claims description 24
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 22
239000002253 acid Substances 0.000 claims description 19
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
239000000463 material Substances 0.000 claims description 18
239000004215 Carbon black (E152) Substances 0.000 claims description 17
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 17
125000003545 alkoxy group Chemical group 0.000 claims description 17
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 16
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
239000002904 solvent Substances 0.000 claims description 15
229920000620 organic polymer Polymers 0.000 claims description 13
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
125000000962 organic group Chemical group 0.000 claims description 12
229910052698 phosphorus Inorganic materials 0.000 claims description 12
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 12
229920002554 vinyl polymer Polymers 0.000 claims description 12
239000005864 Sulphur Substances 0.000 claims description 11
125000001118 alkylidene group Chemical group 0.000 claims description 11
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 11
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 11
125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 11
239000011574 phosphorus Substances 0.000 claims description 11
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 11
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
239000000049 pigment Substances 0.000 claims description 10
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
125000003118 aryl group Chemical group 0.000 claims description 9
229910052710 silicon Inorganic materials 0.000 claims description 9
239000010703 silicon Substances 0.000 claims description 9
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 8
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 8
XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
125000004093 cyano group Chemical group *C#N 0.000 claims description 6
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
230000003647 oxidation Effects 0.000 claims description 6
238000007254 oxidation reaction Methods 0.000 claims description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
125000006839 xylylene group Chemical group 0.000 claims description 6
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 5
238000010521 absorption reaction Methods 0.000 claims description 5
HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 5
229920001169 thermoplastic Polymers 0.000 claims description 5
HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims description 4
125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 4
GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
239000004902 Softening Agent Substances 0.000 claims description 4
125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 4
239000003963 antioxidant agent Substances 0.000 claims description 4
239000000975 dye Substances 0.000 claims description 4
150000000000 tetracarboxylic acids Chemical class 0.000 claims description 4
125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 3
HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 claims description 3
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
125000004423 acyloxy group Chemical group 0.000 claims description 3
125000002947 alkylene group Chemical group 0.000 claims description 3
230000003078 antioxidant effect Effects 0.000 claims description 3
239000012752 auxiliary agent Substances 0.000 claims description 3
235000019253 formic acid Nutrition 0.000 claims description 3
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 3
229960005141 piperazine Drugs 0.000 claims description 3
239000004416 thermosoftening plastic Substances 0.000 claims description 3
239000013008 thixotropic agent Substances 0.000 claims description 3
125000004050 enoyl group Chemical group 0.000 claims description 2
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
238000001782 photodegradation Methods 0.000 claims description 2
230000035945 sensitivity Effects 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 claims 2
125000005037 alkyl phenyl group Chemical group 0.000 claims 1
125000006575 electron-withdrawing group Chemical group 0.000 abstract description 13
230000008569 process Effects 0.000 abstract description 9
125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract description 7
125000004648 C2-C8 alkenyl group Chemical group 0.000 abstract description 6
125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
230000015556 catabolic process Effects 0.000 abstract 1
125000004122 cyclic group Chemical group 0.000 abstract 1
238000006731 degradation reaction Methods 0.000 abstract 1
238000004383 yellowing Methods 0.000 abstract 1
239000000243 solution Substances 0.000 description 57
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 47
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 37
239000002585 base Substances 0.000 description 37
239000003973 paint Substances 0.000 description 36
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 35
239000000047 product Substances 0.000 description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 26
FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 25
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 25
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
238000006243 chemical reaction Methods 0.000 description 24
150000002148 esters Chemical class 0.000 description 24
150000001412 amines Chemical class 0.000 description 23
229920005989 resin Polymers 0.000 description 21
239000011347 resin Substances 0.000 description 21
238000003756 stirring Methods 0.000 description 21
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 19
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 18
239000008199 coating composition Substances 0.000 description 17
229920001577 copolymer Polymers 0.000 description 17
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 17
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
239000012044 organic layer Substances 0.000 description 16
239000000843 powder Substances 0.000 description 16
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 15
239000004925 Acrylic resin Substances 0.000 description 15
235000015320 potassium carbonate Nutrition 0.000 description 15
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 14
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 14
239000004743 Polypropylene Substances 0.000 description 14
150000001408 amides Chemical class 0.000 description 14
239000003054 catalyst Substances 0.000 description 14
229960003742 phenol Drugs 0.000 description 14
229920000642 polymer Polymers 0.000 description 14
229920001155 polypropylene Polymers 0.000 description 14
239000007787 solid Substances 0.000 description 13
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 12
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 11
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 11
238000001723 curing Methods 0.000 description 11
125000005843 halogen group Chemical group 0.000 description 11
229910052938 sodium sulfate Inorganic materials 0.000 description 11
235000011152 sodium sulphate Nutrition 0.000 description 11
238000005160 1H NMR spectroscopy Methods 0.000 description 10
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
239000000654 additive Substances 0.000 description 10
229910052794 bromium Inorganic materials 0.000 description 10
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 10
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 10
229910052697 platinum Inorganic materials 0.000 description 10
150000003254 radicals Chemical class 0.000 description 10
239000004593 Epoxy Substances 0.000 description 9
239000004594 Masterbatch (MB) Substances 0.000 description 9
239000004721 Polyphenylene oxide Substances 0.000 description 9
238000013019 agitation Methods 0.000 description 9
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 9
239000012964 benzotriazole Substances 0.000 description 9
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
239000012141 concentrate Substances 0.000 description 9
238000001816 cooling Methods 0.000 description 9
239000007788 liquid Substances 0.000 description 9
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 8
230000000996 additive effect Effects 0.000 description 8
BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 8
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 8
KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 8
230000000694 effects Effects 0.000 description 8
239000004700 high-density polyethylene Substances 0.000 description 8
238000005984 hydrogenation reaction Methods 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
239000004417 polycarbonate Substances 0.000 description 8
229920000515 polycarbonate Polymers 0.000 description 8
229920000728 polyester Polymers 0.000 description 8
230000006641 stabilisation Effects 0.000 description 8
238000011105 stabilization Methods 0.000 description 8
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 7
150000008065 acid anhydrides Chemical class 0.000 description 7
150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
238000001035 drying Methods 0.000 description 7
238000005227 gel permeation chromatography Methods 0.000 description 7
229920001903 high density polyethylene Polymers 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 7
229940059574 pentaerithrityl Drugs 0.000 description 7
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
229920000570 polyether Polymers 0.000 description 7
229920000098 polyolefin Polymers 0.000 description 7
229920006324 polyoxymethylene Polymers 0.000 description 7
239000004814 polyurethane Substances 0.000 description 7
229910001220 stainless steel Inorganic materials 0.000 description 7
239000010935 stainless steel Substances 0.000 description 7
125000001424 substituent group Chemical group 0.000 description 7
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 7
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 6
239000005977 Ethylene Substances 0.000 description 6
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 6
239000004698 Polyethylene Substances 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
125000002252 acyl group Chemical group 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
238000005286 illumination Methods 0.000 description 6
229920000092 linear low density polyethylene Polymers 0.000 description 6
239000004707 linear low-density polyethylene Substances 0.000 description 6
239000011159 matrix material Substances 0.000 description 6
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
229910052759 nickel Inorganic materials 0.000 description 6
229920000573 polyethylene Polymers 0.000 description 6
229920001228 polyisocyanate Polymers 0.000 description 6
239000005056 polyisocyanate Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 6
238000005406 washing Methods 0.000 description 6
HTSVYUUXJSMGQC-UHFFFAOYSA-N 2-chloro-1,3,5-triazine Chemical class ClC1=NC=NC=N1 HTSVYUUXJSMGQC-UHFFFAOYSA-N 0.000 description 5
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
150000001993 dienes Chemical class 0.000 description 5
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
239000010410 layer Substances 0.000 description 5
229910052748 manganese Inorganic materials 0.000 description 5
238000002156 mixing Methods 0.000 description 5
230000004048 modification Effects 0.000 description 5
238000012986 modification Methods 0.000 description 5
239000000178 monomer Substances 0.000 description 5
GXFQBBOZTNQHMW-UHFFFAOYSA-N n'-(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound CC1(C)CC(NCCCCCCN)CC(C)(C)N1 GXFQBBOZTNQHMW-UHFFFAOYSA-N 0.000 description 5
ODGYWRBCQWKSSH-UHFFFAOYSA-N n'-ethylpropane-1,3-diamine Chemical compound CCNCCCN ODGYWRBCQWKSSH-UHFFFAOYSA-N 0.000 description 5
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 5
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
229920006380 polyphenylene oxide Polymers 0.000 description 5
229920002635 polyurethane Polymers 0.000 description 5
239000004800 polyvinyl chloride Substances 0.000 description 5
229920000915 polyvinyl chloride Polymers 0.000 description 5
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
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229920001601 polyetherimide Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920001444 polymaleic acid Polymers 0.000 description 1
239000002861 polymer material Substances 0.000 description 1
229920000193 polymethacrylate Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920000306 polymethylpentene Polymers 0.000 description 1
239000011116 polymethylpentene Substances 0.000 description 1
229920000069 polyphenylene sulfide Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920002981 polyvinylidene fluoride Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000011181 potassium carbonates Nutrition 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000037452 priming Effects 0.000 description 1
KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
MVCPDOUDYOUTKS-UHFFFAOYSA-N propanedithioic acid Chemical compound CCC(S)=S MVCPDOUDYOUTKS-UHFFFAOYSA-N 0.000 description 1
YORCIIVHUBAYBQ-UHFFFAOYSA-N propargyl bromide Chemical compound BrCC#C YORCIIVHUBAYBQ-UHFFFAOYSA-N 0.000 description 1
QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
125000006233 propoxy propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])OC([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000005767 propoxymethyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])[#8]C([H])([H])* 0.000 description 1
125000003373 pyrazinyl group Chemical group 0.000 description 1
125000003226 pyrazolyl group Chemical group 0.000 description 1
125000002098 pyridazinyl group Chemical group 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
125000000714 pyrimidinyl group Chemical group 0.000 description 1
239000010453 quartz Substances 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
125000005493 quinolyl group Chemical group 0.000 description 1
238000010526 radical polymerization reaction Methods 0.000 description 1
239000002516 radical scavenger Substances 0.000 description 1
238000007634 remodeling Methods 0.000 description 1
229920003987 resole Polymers 0.000 description 1
238000000518 rheometry Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 1
ORIHZIZPTZTNCU-YVMONPNESA-N salicylaldoxime Chemical compound O\N=C/C1=CC=CC=C1O ORIHZIZPTZTNCU-YVMONPNESA-N 0.000 description 1
YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
239000004299 sodium benzoate Substances 0.000 description 1
235000010234 sodium benzoate Nutrition 0.000 description 1
ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 1
IJRHDFLHUATAOS-DPMBMXLASA-N sodium;(z,12r)-12-hydroxyoctadec-9-enoic acid Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O IJRHDFLHUATAOS-DPMBMXLASA-N 0.000 description 1
238000000935 solvent evaporation Methods 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
125000003003 spiro group Chemical group 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003351 stiffener Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
230000035882 stress Effects 0.000 description 1
229920000638 styrene acrylonitrile Polymers 0.000 description 1
229920006132 styrene block copolymer Polymers 0.000 description 1
239000000758 substrate Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000012747 synergistic agent Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
229960000984 tocofersolan Drugs 0.000 description 1
229930003799 tocopherol Natural products 0.000 description 1
239000011732 tocopherol Substances 0.000 description 1
235000010384 tocopherol Nutrition 0.000 description 1
229960001295 tocopherol Drugs 0.000 description 1
239000012745 toughening agent Substances 0.000 description 1
IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical compound N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
125000001425 triazolyl group Chemical group 0.000 description 1
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
229920006305 unsaturated polyester Polymers 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
239000002966 varnish Substances 0.000 description 1
229920001866 very low density polyethylene Polymers 0.000 description 1
235000019154 vitamin C Nutrition 0.000 description 1
239000011718 vitamin C Substances 0.000 description 1
235000019165 vitamin E Nutrition 0.000 description 1
239000011709 vitamin E Substances 0.000 description 1
229940046009 vitamin E Drugs 0.000 description 1
239000002023 wood Substances 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
239000002076 α-tocopherol Substances 0.000 description 1
235000004835 α-tocopherol Nutrition 0.000 description 1
WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 1
239000002478 γ-tocopherol Substances 0.000 description 1
QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
239000002446 δ-tocopherol Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/56—Nitrogen atoms
- C07D211/58—Nitrogen atoms attached in position 4
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Hydrogenated Pyridines (AREA)
Compositions Of Macromolecular Compounds (AREA)
Plural Heterocyclic Compounds (AREA)

CNB2004100473618A 1998-02-25 1999-02-24 空间位阻的胺醚的制备 Expired - Lifetime CN100384826C (zh)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
ITMI98A000366		1998-02-25
IT98MI000366A ITMI980366A1 (it)	1998-02-25	1998-02-25	Preparazione di eteri amminici stericamente impediti
US10471898A	1998-06-25	1998-06-25
US09/104718		1998-06-25

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CNB991033833A Division CN1202085C (zh)	1998-02-25	1999-02-24	空间位阻的胺醚的制备

Publications (2)

Publication Number	Publication Date
CN1552758A CN1552758A (zh)	2004-12-08
CN100384826C true CN100384826C (zh)	2008-04-30

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CNB2004100473618A Expired - Lifetime CN100384826C (zh)	1998-02-25	1999-02-24	空间位阻的胺醚的制备
CNB991033833A Expired - Lifetime CN1202085C (zh)	1998-02-25	1999-02-24	空间位阻的胺醚的制备

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JP (2)	JP4798815B2 (2)
KR (1)	KR100561146B1 (2)
CN (2)	CN100384826C (2)
AR (1)	AR015238A1 (2)
BE (1)	BE1014990A5 (2)
BR (1)	BR9900807B1 (2)
CA (2)	CA2262435C (2)
CZ (1)	CZ302752B6 (2)
DE (2)	DE19964603B4 (2)
ES (1)	ES2159462B1 (2)
FR (1)	FR2777004B1 (2)
GB (1)	GB2334717B (2)
ID (1)	ID23225A (2)
MY (1)	MY123467A (2)
NL (1)	NL1011394C2 (2)
RU (1)	RU2224758C2 (2)
SG (1)	SG74700A1 (2)

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JP2004083913A (ja) *	2000-04-06	2004-03-18	Mitsubishi Rayon Co Ltd	難燃性ポリプロピレンフィルム
TW572896B (en)	2000-05-26	2004-01-21	Ciba Sc Holding Ag	Process for the synthesis of amine ethers from secondary amino oxides
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TW200407307A (en) *	2001-11-26	2004-05-16	Ciba Sc Holding Ag	Process for the synthesis of amine ethers from secondary amino oxides
JP4324940B2 (ja) *	2002-04-17	2009-09-02	チバホールディングインコーポレーテッド	ヒドロキシルアミンエステル含有難燃性ポリマー組成物
JP4167522B2 (ja) *	2002-05-31	2008-10-15	サンテーラ株式会社	オレフィン系樹脂組成物およびそれからなる積層フィルム
CA2576816C (en) *	2004-08-31	2012-10-16	Ciba Specialty Chemicals Holding Inc.	Stabilization of organic materials
PL1807395T3 (pl) *	2004-11-02	2016-06-30	Basf Se	Sposób syntezy n-alkoksyamin
ES2388886T3 (es) *	2006-11-23	2012-10-19	Basf Se	Procedimiento para la preparación de N-alilaminas terciarias estéricamente impedidas
KR101608094B1 (ko) *	2007-12-21	2016-03-31	바스프 에스이	나노 구조 ｕｖ 흡수제
KR20120043090A (ko) *	2009-08-18	2012-05-03	바스프 에스이	안정화된 중합체 봉지재를 가진 광전 모듈
DK2475655T3 (en) *	2009-09-10	2018-01-15	Basf Se	STERICALLY HINDED AMIN STABILIZER
EP2630137B1 (en) *	2010-10-20	2015-04-01	Basf Se	Sterically hindered amine light stabilizers with mixed functionalization
EP2514800B2 (de)	2011-04-21	2018-03-07	Merck Patent GmbH	Verbindungen und flüssigkristallines Medium
EP3526288B1 (en)	2016-10-14	2021-08-04	Basf Se	Stabilizer composition
CA3055864A1 (en) *	2017-03-28	2018-10-04	Basf Se	Light stabilizer mixture
CN109503554B (zh) *	2018-12-13	2020-10-30	天津利安隆新材料股份有限公司	一种聚合型受阻胺类光稳定剂ha-88的制备方法
JP7515497B2 (ja) *	2019-03-08	2024-07-12	ビーエーエスエフソシエタス・ヨーロピア	立体障害アミン安定剤混合物
CN112126060B (zh)	2019-06-25	2022-05-31	北京天罡助剂有限责任公司	一种聚合型高分子空间位阻胺及其制备方法
CN113354813B (zh) *	2021-06-02	2023-07-04	宿迁联盛科技股份有限公司	一种低碱性受阻胺光稳定剂nor 371的制备方法
JP2025511683A (ja)	2022-04-04	2025-04-16	ジェネアスケム・アーゲー	立体障害ニトロキシルエーテルを調製するためのプロセス
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Also Published As

Publication number	Publication date
CZ302752B6 (cs)	2011-10-19
FR2777004A1 (fr)	1999-10-08
CA2262435C (en)	2009-12-22
KR19990072904A (ko)	1999-09-27
FR2777004B1 (fr)	2005-12-30
CN1235159A (zh)	1999-11-17
CA2262435A1 (en)	1999-08-25
RU2224758C2 (ru)	2004-02-27
BE1014990A5 (fr)	2004-08-03
ES2159462A1 (es)	2001-10-01
NL1011394C2 (nl)	1999-10-26
GB9903463D0 (en)	1999-04-07
GB2334717B (en)	2000-04-26
JP2011006443A (ja)	2011-01-13
CN1202085C (zh)	2005-05-18
CA2643170A1 (en)	1999-08-25
DE19907945A1 (de)	1999-08-26
JPH11315067A (ja)	1999-11-16
DE19964603B4 (de)	2013-02-28
AR015238A1 (es)	2001-04-18
SG74700A1 (en)	2000-08-22
BR9900807A (pt)	2000-03-28
NL1011394A1 (nl)	1999-08-26
MY123467A (en)	2006-05-31
CN1552758A (zh)	2004-12-08
KR100561146B1 (ko)	2006-03-15
ID23225A (id)	2000-03-30
JP4798815B2 (ja)	2011-10-19
BR9900807B1 (pt)	2013-06-11
DE19907945B4 (de)	2013-06-06
CA2643170C (en)	2013-04-16
GB2334717A (en)	1999-09-01
ES2159462B1 (es)	2002-05-01

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2008-04-30	C14	Grant of patent or utility model
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2019-03-19	CX01	Expiry of patent term
2019-03-19	CX01	Expiry of patent term	Granted publication date: 20080430

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