ES2159462A1 - Preparacion de eteres aminicos estericamente impedidos. - Google Patents

Preparacion de eteres aminicos estericamente impedidos.

Info

Publication number
ES2159462A1
ES2159462A1 ES009900376A ES9900376A ES2159462A1 ES 2159462 A1 ES2159462 A1 ES 2159462A1 ES 009900376 A ES009900376 A ES 009900376A ES 9900376 A ES9900376 A ES 9900376A ES 2159462 A1 ES2159462 A1 ES 2159462A1
Authority
ES
Spain
Prior art keywords
formula
alkyl
compounds
cycloalkyl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009900376A
Other languages
English (en)
Other versions
ES2159462B1 (es
Inventor
Alessandro Zedda
Gianluca Ferri
Massimiliano Sala
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT98MI000366A external-priority patent/ITMI980366A1/it
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2159462A1 publication Critical patent/ES2159462A1/es
Application granted granted Critical
Publication of ES2159462B1 publication Critical patent/ES2159462B1/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56—Nitrogen atoms
    • C07D211/58—Nitrogen atoms attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Hydrogenated Pyridines (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Preparación de éteres amínicos estéricamente impedidos. Los compuestos de la invención corresponden a la fórmula I, en la que R es un grupo de enlace orgánico conteniendo 2-500 átomos de carbono que forma, junto con los átomos de carbono a los que está directamente conectado y el átomo de nitrógeno, una estructura de anillo acídica de 5, 6 ó 7 miembros sustituidos. R{sub,1}, R{sub,2}, R{sub,3}, R{sub,4}, R{sub,5}, R{sub,6}, R{sub,7} y R{sub,8} tienen el significado explicado en la memoria y en las reivindicaciones. El procedimiento se caracteriza porque se oxida un compuesto de fórmula II en presencia de un disolvente, eligiendo el oxidante entre oxígeno, peróxidos, nitratos, permanganatos o cloratos. Los compuestos de fórmula I, y sus correspondientes compuestos hidrogenados y/o halogenados, son apropiados como estabilizadores para materiales orgánicos frente a degradación por luz, oxígeno y/o calor o amarilleamiento; algunos son también activos como retardadores de llama.
ES009900376A 1998-02-25 1999-02-24 Preparacion de eteres aminicos estericamente impedidos. Expired - Lifetime ES2159462B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT98MI000366A ITMI980366A1 (it) 1998-02-25 1998-02-25 Preparazione di eteri amminici stericamente impediti
US10471898A 1998-06-25 1998-06-25

Publications (2)

Publication Number Publication Date
ES2159462A1 true ES2159462A1 (es) 2001-10-01
ES2159462B1 ES2159462B1 (es) 2002-05-01

Family

ID=26331570

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009900376A Expired - Lifetime ES2159462B1 (es) 1998-02-25 1999-02-24 Preparacion de eteres aminicos estericamente impedidos.

Country Status (17)

Country Link
JP (2) JP4798815B2 (es)
KR (1) KR100561146B1 (es)
CN (2) CN100384826C (es)
AR (1) AR015238A1 (es)
BE (1) BE1014990A5 (es)
BR (1) BR9900807B1 (es)
CA (2) CA2643170C (es)
CZ (1) CZ302752B6 (es)
DE (2) DE19907945B4 (es)
ES (1) ES2159462B1 (es)
FR (1) FR2777004B1 (es)
GB (1) GB2334717B (es)
ID (1) ID23225A (es)
MY (1) MY123467A (es)
NL (1) NL1011394C2 (es)
RU (1) RU2224758C2 (es)
SG (1) SG74700A1 (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
JP2004083913A (ja) * 2000-04-06 2004-03-18 Mitsubishi Rayon Co Ltd 難燃性ポリプロピレンフィルム
JP3540759B2 (ja) * 2000-04-06 2004-07-07 三菱レイヨン株式会社 難燃性ポリプロピレン繊維及びその製造方法
TW572896B (en) * 2000-05-26 2004-01-21 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
EP1038912A3 (en) * 2000-06-22 2000-12-27 Ciba SC Holding AG High molecular weight hindered hydrocarbyloxyamine stabilizers
TWI273115B (en) * 2000-12-12 2007-02-11 Ciba Sc Holding Ag Improved weatherability of flame retardant polyolefin
TW200407307A (en) * 2001-11-26 2004-05-16 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
JP4324940B2 (ja) * 2002-04-17 2009-09-02 チバ ホールディング インコーポレーテッド ヒドロキシルアミンエステル含有難燃性ポリマー組成物
JP4167522B2 (ja) * 2002-05-31 2008-10-15 サンテーラ株式会社 オレフィン系樹脂組成物およびそれからなる積層フィルム
US8105504B2 (en) * 2004-08-31 2012-01-31 Basf Se Stabilization of organic materials
EP1807395B1 (en) * 2004-11-02 2015-12-23 Basf Se Process for the synthesis of n-alkoxyamines
US8217170B2 (en) * 2006-11-23 2012-07-10 Basf Se Process for the preparation of tertiary N-allyl sterically hindered amines
JP5595279B2 (ja) * 2007-12-21 2014-09-24 ビーエーエスエフ ソシエタス・ヨーロピア 農業用のプラスチックフィルムもしくは包装フィルム、または、当該フィルムのためのナノ構造ｕｖ吸収剤の使用
JP5734293B2 (ja) * 2009-08-18 2015-06-17 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 安定化ポリマー封止材を有する光電モジュール
US8895647B2 (en) * 2009-09-10 2014-11-25 Basf Se Sterically hindered amine stabilizer
CN105693698B (zh) 2010-10-20 2019-11-22 巴斯夫欧洲公司 多功能位阻胺光稳定剂
EP2514800B2 (de) * 2011-04-21 2018-03-07 Merck Patent GmbH Verbindungen und flüssigkristallines Medium
CN110062790B (zh) * 2016-10-14 2021-09-24 巴斯夫欧洲公司 稳定剂组合物
JP7301747B2 (ja) * 2017-03-28 2023-07-03 ビーエーエスエフ ソシエタス・ヨーロピア 光安定剤混合物
CN109503554B (zh) * 2018-12-13 2020-10-30 天津利安隆新材料股份有限公司 一种聚合型受阻胺类光稳定剂ha-88的制备方法
IL286101B2 (en) * 2019-03-08 2025-10-01 Basf Se Spatially disordered amine stabilizer mixtures
CN112126060B (zh) * 2019-06-25 2022-05-31 北京天罡助剂有限责任公司 一种聚合型高分子空间位阻胺及其制备方法
CN113354813B (zh) * 2021-06-02 2023-07-04 宿迁联盛科技股份有限公司 一种低碱性受阻胺光稳定剂nor 371的制备方法
WO2023194065A1 (en) 2022-04-04 2023-10-12 Zedda Innovation Consulting Process for the preparation of sterically hindered nitroxyl ethers
WO2025067782A1 (en) 2023-09-27 2025-04-03 Geneuschem Ag Preparation of n-alkoxyamine hals from corresponding hydroxylamines

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309402A1 (en) * 1987-09-21 1989-03-29 Ciba-Geigy Ag N-substituted hindered amine stabilizers
ES2097081A1 (es) * 1993-04-05 1997-03-16 Ciba Geigy Ag Nuevos compuestos de piperidin-triazina adecuados para usarse como estabilizadores para materiales organicos.
ES2099024A1 (es) * 1993-07-16 1997-05-01 Ciba Geigy Ag Nuevos derivados de 2,2,6,6-tetrametil-4-piperidinol para su uso como estabilizantes a la luz, estabilizantes al calor, y estabilizantes a la oxidacion para materiales organicos.
EP0782994A1 (en) * 1995-12-04 1997-07-09 Ciba SC Holding AG Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
EP0792911A2 (en) * 1996-02-27 1997-09-03 Fmc Corporation Flame resistant polyolefin compositions

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IT1215462B (it) * 1987-05-07 1990-02-14 Ciba Geigy Spa Composti piperidinici utilizzabili come stabilizzanti alla luce, al calore e all'ossidazione per polimeri sintetici.
US4824884A (en) * 1987-08-12 1989-04-25 Pennwalt Corporation Cyclic anhydride derivatives of hydrazide functionalized hindered amine light stabilizers
US5124378A (en) * 1987-09-21 1992-06-23 Ciba-Geigy Corporation Stabilization of ambient cured coatings
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US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
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EP0389420B1 (en) * 1989-03-21 1994-09-21 Ciba-Geigy Ag Ethylenically unsaturated compounds containing 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine moieties, and polymers, copolymers and stabilized compositions
IT1246170B (it) * 1990-07-24 1994-11-16 Ciba Geigy Spa Composizione stabilizzante per polipropilene comprendente composti triazinici contenenti gruppi piperidinici e composti metallici
US5180830A (en) * 1991-04-24 1993-01-19 Himont Incorporated Process for preparing hindered amine light stabilizers
US5216156A (en) * 1992-05-05 1993-06-01 Ciba-Geigy Corporation Non-migrating 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine 1,3,5-triazine derivatives
TW270131B (es) * 1993-07-13 1996-02-11 Ciba Geigy
US5393812A (en) * 1993-08-31 1995-02-28 Hercules Incorporated Flame retardant, light stable composition
US5380828A (en) * 1993-10-05 1995-01-10 Ciba-Geigy Corporation Azodicarboxylic acid derivatives containing hindered amine moieties as polymer stabilizers
AU7216796A (en) * 1995-10-12 1997-04-30 Ciba-Geigy Ag Thermally stable hindered amines as stabilizers
US6046304A (en) * 1995-12-04 2000-04-04 Ciba Specialty Chemicals Corporation Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
JPH09292682A (ja) * 1996-04-23 1997-11-11 Fuji Photo Film Co Ltd ハロゲン化銀カラー写真感光材料
CN1222513C (zh) * 1997-02-03 2005-10-12 富士写真菲林株式会社 卤化银彩色照相感光材料和其中所用的菲尼酮化合物以及这类化合物的制备方法
ITMI980366A1 (it) * 1998-02-25 1999-08-25 Ciba Spec Chem Spa Preparazione di eteri amminici stericamente impediti

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309402A1 (en) * 1987-09-21 1989-03-29 Ciba-Geigy Ag N-substituted hindered amine stabilizers
ES2097081A1 (es) * 1993-04-05 1997-03-16 Ciba Geigy Ag Nuevos compuestos de piperidin-triazina adecuados para usarse como estabilizadores para materiales organicos.
ES2099024A1 (es) * 1993-07-16 1997-05-01 Ciba Geigy Ag Nuevos derivados de 2,2,6,6-tetrametil-4-piperidinol para su uso como estabilizantes a la luz, estabilizantes al calor, y estabilizantes a la oxidacion para materiales organicos.
EP0782994A1 (en) * 1995-12-04 1997-07-09 Ciba SC Holding AG Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
EP0792911A2 (en) * 1996-02-27 1997-09-03 Fmc Corporation Flame resistant polyolefin compositions

Also Published As

Publication number Publication date
CA2262435A1 (en) 1999-08-25
KR19990072904A (ko) 1999-09-27
DE19907945A1 (de) 1999-08-26
BE1014990A5 (fr) 2004-08-03
BR9900807A (pt) 2000-03-28
CZ302752B6 (cs) 2011-10-19
CA2643170A1 (en) 1999-08-25
KR100561146B1 (ko) 2006-03-15
FR2777004B1 (fr) 2005-12-30
DE19964603B4 (de) 2013-02-28
SG74700A1 (en) 2000-08-22
CN1235159A (zh) 1999-11-17
JP4798815B2 (ja) 2011-10-19
AR015238A1 (es) 2001-04-18
GB2334717A (en) 1999-09-01
FR2777004A1 (fr) 1999-10-08
MY123467A (en) 2006-05-31
NL1011394C2 (nl) 1999-10-26
ES2159462B1 (es) 2002-05-01
GB2334717B (en) 2000-04-26
NL1011394A1 (nl) 1999-08-26
CA2643170C (en) 2013-04-16
CN1202085C (zh) 2005-05-18
RU2224758C2 (ru) 2004-02-27
GB9903463D0 (en) 1999-04-07
ID23225A (id) 2000-03-30
CN100384826C (zh) 2008-04-30
JPH11315067A (ja) 1999-11-16
JP2011006443A (ja) 2011-01-13
DE19907945B4 (de) 2013-06-06
BR9900807B1 (pt) 2013-06-11
CN1552758A (zh) 2004-12-08
CA2262435C (en) 2009-12-22

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