CN100424239C - Maize protein colored textile fiber and method for producing same - Google Patents
Maize protein colored textile fiber and method for producing same Download PDFInfo
- Publication number
- CN100424239C CN100424239C CNB2006101273425A CN200610127342A CN100424239C CN 100424239 C CN100424239 C CN 100424239C CN B2006101273425 A CNB2006101273425 A CN B2006101273425A CN 200610127342 A CN200610127342 A CN 200610127342A CN 100424239 C CN100424239 C CN 100424239C
- Authority
- CN
- China
- Prior art keywords
- fiber
- colored textile
- protein
- textile fiber
- maize protein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 27
- 108090000623 proteins and genes Proteins 0.000 title claims abstract description 16
- 102000004169 proteins and genes Human genes 0.000 title claims abstract description 16
- 235000002017 Zea mays subsp mays Nutrition 0.000 title claims abstract description 15
- 240000008042 Zea mays Species 0.000 title claims description 13
- 239000004753 textile Substances 0.000 title claims description 7
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 title claims description 6
- 235000009973 maize Nutrition 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 9
- 235000005822 corn Nutrition 0.000 claims abstract description 9
- 238000009987 spinning Methods 0.000 claims abstract description 7
- 239000000985 reactive dye Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000003213 activating effect Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 3
- 229910052708 sodium Inorganic materials 0.000 claims 3
- 239000011734 sodium Substances 0.000 claims 3
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 11
- 235000018102 proteins Nutrition 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 3
- 108010064851 Plant Proteins Proteins 0.000 abstract description 2
- 230000005484 gravity Effects 0.000 abstract description 2
- 235000021118 plant-derived protein Nutrition 0.000 abstract description 2
- 230000008719 thickening Effects 0.000 abstract description 2
- 238000002166 wet spinning Methods 0.000 abstract description 2
- 241000209149 Zea Species 0.000 abstract 2
- 238000001514 detection method Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 230000005070 ripening Effects 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 7
- 229920002494 Zein Polymers 0.000 description 3
- 239000005019 zein Substances 0.000 description 3
- 229940093612 zein Drugs 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010017389 Frotteurism Diseases 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 239000011546 protein dye Substances 0.000 description 1
- 230000003161 proteinsynthetic effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000009965 tatting Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
The invention provides a colored fiber of corn protein and manufacture method. There is activated dye in corn protein. The manufacture method is that activated dye is added in the process for confecting spinning solution and plant protein colored fiber with the density of 0.7-3.0dtex is slubbed by wet spinning technology after ripening and polymerizing in reaction vessel. Because of activated dye added in confecting process, strike and fixation rates are improved. In detection method the cooler fiber has good fastness with five degree and enough light. There are no pollution and public disaster in the activated dye. The fiber is provided with good moisture conduction, light gravity, dry heat resistance and so on. It is knitted and tatted to various ultrathin or thickening apparel fabrics with high grade.
Description
Technical field
The invention belongs to textile material, relating in particular to by corn protein and REACTIVE DYES is that the look of component spins fiber, also relates to the manufacture method of this colored fibre (spinning hereinafter to be referred as look) simultaneously.
Background technology
Zein fiber just had the zein fiber production of " Vicara " as far back as 1948, it is a Zein fibers, and to nineteen fifty-seven, corn Vicara fiber is formally manufactured by U.S. Wei Jiya-Ka Liluolaina chemical company.Soon afterwards, the U.S. well-known Cargill cereal company develops successfully " corn acid fiber by polylactic ", and drops into and produce in batches, and output was once reaching 6000 tons.Manufacture method by plant protein synthetic fiber and this fiber is disclosed among national patent CN99116636.1 and the CN02109966.9 in addition.More than the fiber of its production need to carry out bleaching and dyeing thereafter because the cellulose fibre strand is a polypeptide polymer, not anti-caustic soda, protein fibre all can be subjected to infringement in various degree in highly basic still is weak base, even cause decomposing.The fastness of acid dyeing is very poor, albumen is in separation, purifying and spinning process process, suffered obvious impairment, the amino negligible amounts during amino acid is formed, so the ability of combination dye reduces greatly, again because the protein of this fiber mainly is distributed in fibrous outer, negligible amounts, and swelling comes off easily, so even a large amount of ACID DYES are gone up in absorption, dyestuff also comes off under damp and hot and Frotteurism with protein easily, and color is not bright-coloured yet.In addition, our proof, quite a few dyestuff also is adsorbed in fiber internal layer fibrous, but fastness is very poor, low in glossiness.Easier fading under the ultraviolet ray irradiation.
Summary of the invention
Purpose of the present invention provides color fibre exactly, and the COLOR FASTNESS that overcomes former technology is poor, the shortcoming of low in glossiness.Saved the poststaining technology in the former fabrication processes, to spinning material, all very favourable to environmental protection.
The technical scheme that the present invention proposes to address the above problem is: adopted the first production technology that dyes and afterwards weave
In the process of preparation spinning solution, add REACTIVE DYES, fully maturation, polymerization in reactor, and use wet spinning technology, be spun into the phytoprotein colored fibre of fine density 0.8-2.4dtex.Owing in system liquid process, add REACTIVE DYES, improved dye uptake and fixation rate.This colored fibre after testing, COLOR FASTNESS is good, fat light foot.COLOR FASTNESS can reach the 4-5 level.This REACTIVE DYES is pollution-free, nuisanceless, have and good lead moist and wet putting.Light specific gravity, strength and elongation height, acid-proof alkaline are good.Soft, smooth, drapability is better than silk.Anti-boiling water shrinks and dry heat resistance.Can be knitting, tatting becomes the high-grade fabric of various ultra-thin or thickenings.
Description of drawings
Fig. 1 is the process chart of patent of the present invention
The specific embodiment
(1) corn protein preparation, polyvinyl alcohol soaks, the mill base preparation;
(2) corn protein and immersion back polyvinyl alcohol, mill base are joined reactor, heat 55 ℃-105 ℃, reacted 100-120 minute;
(3) add activating agent, be shaped on chromogen liquid;
(4) spinning;
(5) crosslinked;
(6) full gear; (being up to state standards)
(7) curl;
(8) cut off;
(9) Vacuum shaping;
(10) packing.
Use activating agent, percentage preparation by weight:
Sodium phosphate 0.1-0.3%
Sodium perborate 0.2-0.5%
Sodium tetraborate 0.4-0.6%
Acetamide 0.2-0.4%
Bio-ethanol 0.4-0.6%
Dibenzoyl peroxide 0.6-0.8%
REACTIVE DYES, preparation by weight percentage:
Rubine-ED 0.2-0.4%
Reactive yellow ED-2G 0.3-0.5%
Reactive red ED-3B 0.3-0.5%
The various active dyestuff has different proportionings, makes the stoste of different colours.
In our spun staple fibre detects, use above three kinds of REACTIVE DYES, can dye the mill base of tens kinds and tens kinds different colours.
In the final experiment of weaving face fabric.Water-fast washing with UV resistant shone.COLOR FASTNESS is fine, and bright in colour.This colored fibre, following market is very wide.
Claims (4)
1. maize protein colored textile fiber, it is characterized in that: this look spins fiber and contains activating agent and REACTIVE DYES composition, uses activating agent to be bio-ethanol----0.4%--0.6%, dibenzoyl peroxide----0.6%--0.8%, sodium phosphate----0.1%--0.3%, sodium perborate----0.2%--0.5%, sodium tetraborate----0.4%--0.6%, acetamide----0.2%--0.4%.
2. according to claims 1 described maize protein colored textile fiber, it is characterized in that REACTIVE DYES is active rubine-ED0.2%-0.4%, reactive yellow ED-2G 0.3%--0.5%, reactive red ED-3B 0.3%-0.5%.
3. according to claims 2 described maize protein colored textile fibers, it is characterized in that REACTIVE DYES has different proportionings, makes the stoste of different colours.
4. according to the preparation method of claims 1 described maize protein colored textile fiber, the steps include:
(1) corn protein preparation, polyvinyl alcohol soaks, the mill base preparation;
(2) corn protein and immersion back polyvinyl alcohol, mill base are joined in the reactor, heat 55 ℃-105 ℃, reacted 100-120 minute;
(3) add activating agent and be shaped on chromogen liquid;
(4) spinning;
(5) crosslinked;
(6) full gear, requirement is up to state standards;
(7) curl;
(8) cut off;
(9) Vacuum shaping;
(10) packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101273425A CN100424239C (en) | 2006-04-28 | 2006-09-15 | Maize protein colored textile fiber and method for producing same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610040010.3 | 2006-04-28 | ||
| CN200610040010 | 2006-04-28 | ||
| CNB2006101273425A CN100424239C (en) | 2006-04-28 | 2006-09-15 | Maize protein colored textile fiber and method for producing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1952225A CN1952225A (en) | 2007-04-25 |
| CN100424239C true CN100424239C (en) | 2008-10-08 |
Family
ID=38058778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101273425A Expired - Fee Related CN100424239C (en) | 2006-04-28 | 2006-09-15 | Maize protein colored textile fiber and method for producing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100424239C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102102268B (en) * | 2011-03-04 | 2013-07-10 | 嘉兴学院 | Method for preparing colored fabric containing polylactic acid fiber and silk components |
| EP2716798B1 (en) | 2011-06-01 | 2019-12-18 | Spiber Inc. | Artificial polypeptide fiber and method for producing same |
| CN103132170A (en) * | 2011-11-29 | 2013-06-05 | 唐雪 | Natural plant synthetic fiber |
| EP2868782B1 (en) * | 2012-06-28 | 2020-07-15 | Spiber Inc. | Spun-dyed protein fiber and method for producing same |
| CN103334177B (en) * | 2013-07-31 | 2015-06-24 | 韩晓根 | Flame-retardant corn protein fiber production method and product thereof |
| CN103343395B (en) * | 2013-07-31 | 2015-06-24 | 韩晓根 | Production method and product of antibacterial corn protein fibers |
| EP3281948B1 (en) | 2015-04-09 | 2020-06-10 | Spiber Inc. | Polar solvent solution and production method thereof |
| JP6856828B2 (en) | 2015-04-09 | 2021-04-14 | Ｓｐｉｂｅｒ株式会社 | Polar solvent solution and its manufacturing method |
| CN109295535A (en) * | 2018-09-26 | 2019-02-01 | 河南省绒山纺织品科技有限公司 | The preparation method and the colored activated organic functions fiber of five cereals of the colored activated organic functions fiber of five cereals and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2552079A (en) * | 1948-09-21 | 1951-05-08 | Corn Prod Refining Co | Production of zein fibers |
| US5750064A (en) * | 1996-01-19 | 1998-05-12 | E. I. Du Pont De Nemours And Company | Dry spinning process for producing zein fibers |
| CN1364948A (en) * | 2001-05-14 | 2002-08-21 | 胡宗善 | Protein synthetic fibre spinning solution and its producing method |
| CN1490444A (en) * | 2002-10-14 | 2004-04-21 | 王琳琳 | Producing process flow path for corn fibre |
| CN1515710A (en) * | 2003-01-09 | 2004-07-28 | 李官奇 | Protein synthetic fiber and its production method |
| CN1584154A (en) * | 2004-06-03 | 2005-02-23 | 丰纪述 | Natural high-polymer polymer modified fibre and filament preparing method |
-
2006
- 2006-09-15 CN CNB2006101273425A patent/CN100424239C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2552079A (en) * | 1948-09-21 | 1951-05-08 | Corn Prod Refining Co | Production of zein fibers |
| US5750064A (en) * | 1996-01-19 | 1998-05-12 | E. I. Du Pont De Nemours And Company | Dry spinning process for producing zein fibers |
| CN1364948A (en) * | 2001-05-14 | 2002-08-21 | 胡宗善 | Protein synthetic fibre spinning solution and its producing method |
| CN1490444A (en) * | 2002-10-14 | 2004-04-21 | 王琳琳 | Producing process flow path for corn fibre |
| CN1515710A (en) * | 2003-01-09 | 2004-07-28 | 李官奇 | Protein synthetic fiber and its production method |
| CN1584154A (en) * | 2004-06-03 | 2005-02-23 | 丰纪述 | Natural high-polymer polymer modified fibre and filament preparing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1952225A (en) | 2007-04-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11124900B2 (en) | Method for preparing flame-retardant cellulosic fibers | |
| CN103541213B (en) | Wash the dyeing and finishing technology of bright and beautiful snow pear suede cotton like fabric | |
| CN100424239C (en) | Maize protein colored textile fiber and method for producing same | |
| CN103469634B (en) | A kind of colouring method of super imitative cotton wool-blend fabric | |
| CN107475794A (en) | A kind of fire-retardant koplon of silicon nitrogen system and preparation method thereof | |
| CN107558267B (en) | Dyeing and finishing method for textile material and textile product | |
| CN101200831B (en) | Soybean fiber thermal underwear face fabric | |
| CN111058316A (en) | Alkaline pad dyeing method for chinlon 56 and cellulose fiber blended fabric | |
| CN109554939B (en) | A kind of indigo dyeing method of polyamide 56 fiber or polyamide 56/cotton blended fabric and product thereof | |
| CN107177926B (en) | A kind of preparation method of double-sided cloth | |
| CN114836971B (en) | Jean fabric washing method and jean fabric | |
| CN103541246A (en) | Dyeing technology for polyester brocade sydney down cotton-imitated fabric | |
| CN100445436C (en) | Soybean protein colored spinning fiber and its production method | |
| CN105002588A (en) | Preparation method for imitating cotton polyester-PET/PA6 copolymer fiber | |
| CN115679465B (en) | A kind of preparation method of light regenerated cellulose fiber | |
| CN113957731B (en) | Process for improving fastness of soaping solution of cellulose fiber and polyester blended dark fabric | |
| CN114250528A (en) | Environment-friendly coated yarn based on biological material and preparation method thereof | |
| CN110080010B (en) | Preparation method of colored cellulose fibers | |
| CN113862883A (en) | Ice silk cool fabric and processing method thereof | |
| CN118407174B (en) | A microporous moisture-wicking and quick-drying yarn, its preparation method, and fabric. | |
| CN107129633B (en) | A kind of high fading resistance polypropylene-graphene color masterbatch and preparation method thereof | |
| CN106337304A (en) | Jeans fabric and dying method thereof | |
| CN113123126A (en) | Moisture-absorbing quick-drying antibacterial mildew-proof modified regenerated fiber cotton yarn and preparation process thereof | |
| CN118127698B (en) | Ammonia fabric with good air permeability and moisture removal performance and preparation method thereof | |
| CN114737296B (en) | Bamboo fiber blended towel and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| DD01 | Delivery of document by public notice |
Addressee: Han Xiaogen Document name: Notification of Termination of Patent Right |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081008 Termination date: 20110915 |