CN102251390A - Halogen-free moisture permeable flame-retardant coating adhesive for heavy fabrics and preparation method - Google Patents
Halogen-free moisture permeable flame-retardant coating adhesive for heavy fabrics and preparation method Download PDFInfo
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 50
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000004744 fabric Substances 0.000 title claims abstract description 34
- 238000000576 coating method Methods 0.000 title claims abstract description 33
- 239000011248 coating agent Substances 0.000 title claims abstract description 31
- 239000000853 adhesive Substances 0.000 title claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920000388 Polyphosphate Polymers 0.000 claims abstract description 21
- 239000001205 polyphosphate Substances 0.000 claims abstract description 21
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 21
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 238000005187 foaming Methods 0.000 claims abstract description 14
- 239000004088 foaming agent Substances 0.000 claims abstract description 14
- 239000004014 plasticizer Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 239000004902 Softening Agent Substances 0.000 claims abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 10
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 9
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 9
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical group COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- -1 softener Substances 0.000 claims description 3
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 claims description 2
- 229960001826 dimethylphthalate Drugs 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000012265 solid product Substances 0.000 claims description 2
- XCXGMRBXICPEKF-UHFFFAOYSA-L disodium;dodecane;sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCC XCXGMRBXICPEKF-UHFFFAOYSA-L 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 238000010008 shearing Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Chemical class 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical class [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006255 coating slurry Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000012796 inorganic flame retardant Substances 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提供一种厚重织物用无卤透湿阻燃涂层胶其特征在于组分配合比例按重量份计是：水性乳液0～25，聚磷酸酯聚合物62～85，增塑剂1.5～4，柔顺剂2～6.5，发泡剂2～7。其制备方法是首先在聚磷酸酯乳液中加入其重量10～15倍的水，再加热至93～100℃溶解，冷却后备用；用高速剪切机在搅拌下向釜内依次加入各组分，搅拌30min，然后放入发泡机中发泡得本发明产品。成本低，阻燃效果好，稳定性好。主要用于帐蓬及装备防护面料的阻燃。The invention provides a halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics, which is characterized in that the proportion of components is: 0-25 parts by weight of water-based emulsion, 62-85 parts of polyphosphate polymer, and 1.5-5 parts of plasticizer. 4. Softening agent 2-6.5, foaming agent 2-7. The preparation method is to firstly add water 10-15 times its weight into the polyphosphate emulsion, then heat to 93-100°C to dissolve, cool down and set aside; use a high-speed shearing machine to add each component into the kettle in turn under stirring , stirred for 30min, and then put into a foaming machine to foam to obtain the product of the present invention. Low cost, good flame retardant effect and good stability. It is mainly used for flame retardant of tents and equipment protective fabrics.
Description
技术领域 technical field
本发明涉及一种阻燃涂层胶及制备方法，特别是涉及一种厚重织物用无卤透湿阻燃涂层胶及制备方法。 The invention relates to a flame-retardant coating adhesive and a preparation method, in particular to a halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics and a preparation method.
背景技术 Background technique
对织物的阻燃处理目前多采用阻燃整理（浸轧）和阻燃涂层方法。阻燃涂层方法因为能赋予织物特殊性能，如舒知性、安全性等而被接受。但对于厚重紧密织物，由于其厚重密织阻隔了阻燃胶的渗透，造成非涂层面达不到阻燃要求。所以，对于厚重织物多采用先阻燃整理，后阻燃涂层的方法，但工艺复杂，且仍存在阻燃效果不佳的问题。近年来，对于厚重织物多采用发泡阻燃涂层技术。发泡涂层除具有一定的防水性、透气透湿性及耐水压性能外，还具有使薄型织物增厚，手感柔软的作用。另外发泡涂层整理既可以进行单面发泡整理，也可以对织物两面进行不同功能的发泡整理．有力于开发功能各异的新产品，如发泡阻燃涂层、抗紫外线整理等。CN101498105A采用水性聚氨酯乳液或水性丙烯酸乳液与溴系阻燃剂等制成涂层胶，按机械发泡整理技术制得了发泡涂层。制得涂层具有较好的柔性与阻燃性，但是其所用卤素、锑系阻燃剂系列不利于环境保护，且成本较高。CN101886340A采用亲水性聚氨酯树脂、有机溶剂、阻燃剂混合而成的织物涂层浆，虽能排除卤素或锑系阻燃剂对环境的影响，但其采用有机溶剂丁酮，N，N-二甲基甲酰胺，甲苯或二甲苯在干燥过程中又会挥发致使环境受影响，且增加了干燥过程中的火灾危险性，成本也较采用水性体系高。尤其重要的是采用物理混合无卤磷系或氮系阻燃颗粒（小于50μm，最好小于20μm），会堵塞织物缝隙，影响织物的耐水性及水洗性。 Flame-retardant finishing (padding) and flame-retardant coating methods are mostly used for fabric flame-retardant treatment. The flame retardant coating method is accepted because it can impart special properties to the fabric, such as comfort and safety. However, for thick and dense fabrics, the non-coated surface cannot meet the flame-retardant requirements because of its thick and dense weave that blocks the penetration of flame-retardant glue. Therefore, for heavy fabrics, the method of flame-retardant finishing first and then flame-retardant coating is often used, but the process is complicated and there is still the problem of poor flame-retardant effect. In recent years, foaming flame retardant coating technology has been used for heavy fabrics. In addition to certain water resistance, air permeability and water pressure resistance, the foam coating also has the function of thickening thin fabrics and making them soft to the touch. In addition, the foaming coating finishing can not only carry out foaming finishing on one side, but also carry out foaming finishing with different functions on both sides of the fabric. It is capable of developing new products with different functions, such as foaming flame-retardant coating, anti-ultraviolet finishing, etc. CN101498105A adopts water-based polyurethane emulsion or water-based acrylic emulsion and brominated flame retardant to make coating glue, and obtains foamed coating according to mechanical foaming finishing technology. The prepared coating has better flexibility and flame retardancy, but the series of halogen and antimony flame retardants used in it are not conducive to environmental protection, and the cost is high. CN101886340A adopts the fabric coating slurry mixed with hydrophilic polyurethane resin, organic solvent and flame retardant. Although it can eliminate the impact of halogen or antimony flame retardant on the environment, it uses organic solvent butanone, N, N- Dimethylformamide, toluene or xylene will volatilize during the drying process, which will affect the environment, increase the fire risk during the drying process, and cost more than the water-based system. It is especially important to use physically mixed halogen-free phosphorus or nitrogen-based flame-retardant particles (less than 50 μm, preferably less than 20 μm), which will block the gaps in the fabric and affect the water resistance and washability of the fabric.
发明内容 Contents of the invention
本发明的目的是在于克服上述不足之处，提供一种无环境污染、工艺简单、阻燃效果好、耐水性及水洗性好的厚重织物用无卤透湿阻燃涂层胶及其制备方法。 The object of the present invention is to overcome the above disadvantages, to provide a non-environmental pollution, simple process, good flame retardant effect, good water resistance and water washability for heavy fabrics with a halogen-free moisture-permeable flame-retardant coating adhesive and its preparation method .
本发明厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The component distribution ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics of the present invention is as follows in parts by weight:
水性乳液 0～25 Water-based emulsion 0～25
聚磷酸酯聚合物 62～85 Polyphosphate polymer 62～85
增塑剂 1.5～4 Plasticizer 1.5～4
柔顺剂 2～6.5 Softener 2～6.5
发泡剂 2～7 Foaming agent 2～7
其中，水性乳液为聚氨酯乳液或水性丙烯酸酯乳液。聚氨酯乳液固含量26-32%，PH值8-10；水性丙烯酸酯乳液玻璃化温度为-30℃-40℃，固含量25-30%，PH值8-10；聚磷酸酯聚合物是聚磷酸铵和聚乙烯醇的聚合物，其配制方法是，按重量份计是聚磷酸铵:聚乙烯醇=3~6∶1，混合后于100℃加热搅拌溶解，保温反应1～2ｈ，除去多余水分，然后再升温至120℃，保温0.5ｈ，得白色固体产物，60℃温度下干燥，研磨，得到白色棉花状聚磷酸酯聚合物，酯化度25~40。它是集树脂与阻燃一体的阻燃高分子物，主要发挥阻燃剂与粘结剂的作用。可避免阻燃剂与树脂物理混合中的不相容、析出、不耐久或耐湿问题。提高整体的阻燃性、耐水性及透湿度；增塑剂邻苯甲酸二甲酯；柔顺剂为有机硅乳液；发泡剂为阴离子表面活性剂十二烷基硫酸钠。 Wherein, the aqueous emulsion is polyurethane emulsion or aqueous acrylate emulsion. The solid content of polyurethane emulsion is 26-32%, and the pH value is 8-10; The polymer of ammonium phosphate and polyvinyl alcohol, the preparation method is: ammonium polyphosphate: polyvinyl alcohol = 3~6: 1 by weight, after mixing, heat and stir at 100°C to dissolve, keep warm for 1~2h, remove Excessive water, then raise the temperature to 120°C and keep it warm for 0.5h to obtain a white solid product, dry it at 60°C, and grind to obtain a white cotton-like polyphosphate polymer with an esterification degree of 25-40. It is a flame retardant polymer that integrates resin and flame retardant, and mainly plays the role of flame retardant and binder. It can avoid the problems of incompatibility, precipitation, impermanence or moisture resistance in the physical mixing of flame retardants and resins. Improve the overall flame retardancy, water resistance and moisture permeability; plasticizer dimethyl phthalate; softener is silicone emulsion; foaming agent is anionic surfactant sodium lauryl sulfate.
本发明厚重织物用无卤透湿阻燃涂层胶的制备方法，其步骤如下： The preparation method of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics of the present invention, the steps are as follows:
1）在聚磷酸酯聚合物中加入其重量7～15倍的水，再加热至93～100℃溶解成乳液，冷却后备用。 1) Add 7 to 15 times the weight of water to the polyphosphate polymer, then heat to 93 to 100°C to dissolve into an emulsion, and cool it for later use.
2）向釜内依次加入水性乳液、增塑剂、柔顺剂、发泡剂，高速剪切机搅匀后，在搅拌下加入步骤1）产物，再搅拌30min，然后放入发泡机中，发泡比1：2，得本发明厚重织物用无卤透湿阻燃涂层胶。 2) Add water-based emulsion, plasticizer, softener, and foaming agent to the kettle in sequence. After stirring with a high-speed shearer, add the product of step 1) under stirring, and then stir for 30 minutes, then put it into a foaming machine. The foaming ratio is 1:2, and the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics of the present invention is obtained.
本发明厚重织物用无卤透湿阻燃涂层胶的优点在于：其一、不含卤素与有机溶剂，是环境友好型涂层；其二、阻燃性能优异、成本低，能保持织物舒适性；其三、阻燃剂为无机多聚物与有机高分子的合成物，它是集树脂与阻燃一体的阻燃高分子物,可避免阻燃剂与树脂物理混合中的不相容、析出、不耐久或耐湿问题。提高整体的阻燃性、耐水性及透湿度，耐水洗5次后，LOI仍高于26%；其四、不采用单一低温无机阻燃剂，因而避免了无机物与有机物在复配过程中的表面相容性不好的难题，且避免了在高温固化或机械发泡过程中的分解损失，材料稳定性好、耐久性好，正常使用2年，其LOI基本保持不变，尤其适合于室外厚重帐篷及装备防护面料的阻燃。 The advantages of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics of the present invention are: first, it does not contain halogens and organic solvents, and is an environmentally friendly coating; second, it has excellent flame retardancy and low cost, and can keep the fabric comfortable Third, the flame retardant is a composite of inorganic polymers and organic polymers. It is a flame retardant polymer that integrates resin and flame retardant, which can avoid the incompatibility of flame retardants and resins in physical mixing. , precipitation, impermanence or moisture resistance. Improve the overall flame retardancy, water resistance and moisture permeability. After washing for 5 times, the LOI is still higher than 26%. Fourth, a single low-temperature inorganic flame retardant is not used, thus avoiding the compounding process of inorganic and organic substances The problem of poor surface compatibility, and avoiding the decomposition loss during high temperature curing or mechanical foaming, the material has good stability and durability, and its LOI remains basically unchanged after 2 years of normal use, especially suitable for Flame retardant for outdoor heavy tents and protective fabrics for equipment.
具体实施方式 Detailed ways
实施例1： Example 1:
厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The composition ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics is as follows in parts by weight:
水性乳液 0 Water-based emulsion 0 0
聚磷酸酯聚合物（聚磷酸铵:聚乙烯醇=3∶1） 85 Polyphosphate polymer (ammonium polyphosphate: polyvinyl alcohol = 3:1) 85
增塑剂 1.5 Plasticizer 1.5
柔顺剂 6.5 Softener 6.5
发泡剂 7。 Foaming agent 7.
其制备方法是： Its preparation method is:
1）在聚磷酸酯中加入其重量15倍的水以制成乳液,再加热至93～100℃溶解，冷却后备用。 1) Add 15 times the weight of water to polyphosphate to make an emulsion, then heat to 93-100°C to dissolve, cool and set aside.
2）向釜内依次加入水性乳液、增塑剂、柔顺剂、发泡剂，高速剪切机搅匀后，在搅拌下加入步骤1）产物，再搅拌30min，然后放入发泡机中，发泡比1：2，得本发明厚重织物用无卤透湿阻燃涂层胶。其性能指标如表1所示。 2) Add water-based emulsion, plasticizer, softener, and foaming agent to the kettle in sequence. After stirring with a high-speed shearer, add the product of step 1) under stirring, and then stir for 30 minutes, then put it into a foaming machine. The foaming ratio is 1:2, and the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics of the present invention is obtained. Its performance indicators are shown in Table 1.
实施例2： Example 2:
厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The composition ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics is as follows in parts by weight:
水性乳液（聚氨酯乳液） 10 Water-based emulsion (polyurethane emulsion)
聚磷酸酯聚合物（聚磷酸铵:聚乙烯醇=4∶1） 80 Polyphosphate polymer (ammonium polyphosphate:polyvinyl alcohol=4:1) 80
增塑剂 2 Plasticizer 2
柔顺剂 5 Softener 5
发泡剂 3 Foaming agent 3
在聚磷酸酯中加入其重量13倍的水以制成乳液，再加热至93～100℃溶解，冷却后备用；其余制备方法同实施例1。其性能指标如表1所示。 Add 13 times the weight of water to the polyphosphate to make an emulsion, then heat to 93-100°C to dissolve, cool down and set aside; the rest of the preparation method is the same as in Example 1. Its performance indicators are shown in Table 1.
实施例3： Example 3:
厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The composition ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics is as follows in parts by weight:
水性乳液（聚氨酯乳液） 15 Water-based emulsion (polyurethane emulsion) 15
聚磷酸酯聚合物（聚磷酸铵:聚乙烯醇=5∶1） 75 Polyphosphate polymer (ammonium polyphosphate:polyvinyl alcohol=5:1) 75
增塑剂 4 Plasticizer 4
柔顺剂 3 Softener 3
发泡剂 3 Foaming agent 3
在聚磷酸酯中加入其重量12倍的水以制成乳液，再加热至93～100℃溶解，冷却后备用；其余制备方法同实施例1，其性能指标如表1所示。 Add 12 times the weight of water to the polyphosphate to make an emulsion, then heat to 93-100°C to dissolve, and cool it for later use; the rest of the preparation method is the same as in Example 1, and its performance indicators are shown in Table 1.
实施例4 Example 4
厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The composition ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics is as follows in parts by weight:
水性乳液（聚氨酯乳液） 20 Water-based emulsion (polyurethane emulsion) 20
聚磷酸酯聚合物（聚磷酸铵:聚乙烯醇=6∶1） 72 Polyphosphate polymer (ammonium polyphosphate:polyvinyl alcohol=6:1) 72
增塑剂 4 Plasticizer 4
柔顺剂 2 Softener 2
发泡剂 2 Foaming agent 2
在聚磷酸酯中加入其重量11倍的水以制成乳液，再加热至93～100℃溶解，冷却后备用；其余制备方法同实施例1，其性能指标如表1所示。 Add 11 times the weight of water to the polyphosphate to make an emulsion, then heat to 93-100°C to dissolve, and cool it for later use; the rest of the preparation method is the same as in Example 1, and its performance indicators are shown in Table 1.
实施例5： Example 5:
厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The composition ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics is as follows in parts by weight:
水性乳液（水性丙烯酸酯乳液） 25 Water-based emulsion (water-based acrylate emulsion) 25
聚磷酸酯聚合物（聚磷酸铵:聚乙烯醇=4∶1） 65 Polyphosphate polymer (ammonium polyphosphate: polyvinyl alcohol = 4:1) 65
增塑剂 3 Plasticizer 3
柔顺剂 3 Softener 3
发泡剂 4 Foaming agent 4
在聚磷酸酯中加入其重量9倍的水以制成乳液，再加热至93～100℃溶解，冷却后备用；其余制备方法同实施例1，其性能指标如表1所示。 Add 9 times its weight of water to the polyphosphate to make an emulsion, then heat to 93-100°C to dissolve, and cool it for later use; the rest of the preparation method is the same as in Example 1, and its performance indicators are shown in Table 1.
实施例6： Embodiment 6:
厚重织物用无卤透湿阻燃涂层胶其组分配比按重量份计是： The composition ratio of the halogen-free moisture-permeable flame-retardant coating adhesive for heavy fabrics is as follows in parts by weight:
水性乳液（水性丙烯酸酯乳液） 25 Water-based emulsion (water-based acrylate emulsion) 25
聚磷酸酯聚合物（聚磷酸铵:聚乙烯醇=4∶1） 62 Polyphosphate polymer (ammonium polyphosphate: polyvinyl alcohol = 4:1) 62
增塑剂 3 Plasticizer 3
柔顺剂 4 Softener 4
发泡剂 6 Foaming agent 6
在聚磷酸酯中加入其重量7倍的水以制成乳液，再加热至93～100℃溶解，冷却后备用；其余制备方法同实施例1，其性能指标如表1所示。 Add water 7 times its weight to polyphosphate to make an emulsion, then heat to 93-100°C to dissolve, and cool it for later use; the rest of the preparation method is the same as in Example 1, and its performance indicators are shown in Table 1.
表1：产品性能指标： Table 1: Product performance indicators:
注：其中阻燃性能按GA504测试。 Note: The flame retardant performance is tested according to GA504.
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| CN105239378A (en) * | 2015-10-20 | 2016-01-13 | 湖州申祥丝织有限责任公司 | Novel formaldehyde-free flame-retardant finishing agent for cotton and finishing method thereof |
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| CN103211336A (en) * | 2012-01-21 | 2013-07-24 | 昆山华阳复合材料科技有限公司 | Coated fabric with safety protection and long-term flame-retardant effect and manufacturing process of coated fabric |
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| CN107513317B (en) * | 2016-06-17 | 2020-02-21 | 清远市普塞呋磷化学有限公司 | Water-based two-component waterproof antifouling flame-retardant coating adhesive and preparation method thereof |
| CN107419535A (en) * | 2017-09-05 | 2017-12-01 | 绍兴思安阻燃科技有限公司 | A kind of blending sofa cloth fabric flame retardant |
| CN110409194A (en) * | 2019-07-19 | 2019-11-05 | 温多利遮阳材料（德州）股份有限公司 | A kind of Fire-retarded carpet and its preparation process based on expansion type coating tailing |
| CN116103930A (en) * | 2023-01-05 | 2023-05-12 | 北京化工大学 | A kind of flame-retardant polyester and preparation method thereof |
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