CN101498105A - Aqueous foaming flame-retardant coating glue for textile and preparation thereof - Google Patents
Aqueous foaming flame-retardant coating glue for textile and preparation thereof Download PDFInfo
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- CN101498105A CN101498105A CNA2008100631342A CN200810063134A CN101498105A CN 101498105 A CN101498105 A CN 101498105A CN A2008100631342 A CNA2008100631342 A CN A2008100631342A CN 200810063134 A CN200810063134 A CN 200810063134A CN 101498105 A CN101498105 A CN 101498105A
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- retardant
- flame
- aqueous
- agent
- foaming
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 79
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 238000000576 coating method Methods 0.000 title claims abstract description 47
- 238000005187 foaming Methods 0.000 title claims abstract description 40
- 239000011248 coating agent Substances 0.000 title claims abstract description 26
- 239000004753 textile Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000003292 glue Substances 0.000 title claims description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 57
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000004814 polyurethane Substances 0.000 claims abstract description 18
- 229920002635 polyurethane Polymers 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- -1 acrylic ester Chemical class 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 14
- 239000002243 precursor Substances 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 239000004604 Blowing Agent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000006260 foam Substances 0.000 claims description 8
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- 229920000058 polyacrylate Polymers 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229940088990 ammonium stearate Drugs 0.000 claims description 6
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 235000021317 phosphate Nutrition 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 claims description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000010290 biphenyl Nutrition 0.000 claims description 4
- 239000004305 biphenyl Substances 0.000 claims description 4
- 125000006267 biphenyl group Chemical group 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 239000004816 latex Substances 0.000 claims description 4
- 229920000126 latex Polymers 0.000 claims description 4
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 3
- 229930188012 Bromoether Natural products 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- HJCMMOODWZOXML-UHFFFAOYSA-N bromo hypobromite Chemical compound BrOBr HJCMMOODWZOXML-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229940106691 bisphenol a Drugs 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- WHJDTUHLRPOPSK-UHFFFAOYSA-N 4-amino-4-oxo-3-sulfobutanoic acid Chemical class NC(=O)C(S(O)(=O)=O)CC(O)=O WHJDTUHLRPOPSK-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 125000005526 alkyl sulfate group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 4
- 238000007730 finishing process Methods 0.000 abstract description 3
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000012747 synergistic agent Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000011159 matrix material Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 206010010219 Compulsions Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an aqueous foaming flame-retardant coating gum for textiles and a preparation method thereof. The existing flame-retardant coating gum can not meet requirements of a foaming finishing process. The aqueous foaming flame-retardant coating gum is prepared from the following components: aqueous substrate emulsion comprising aqueous polyurethane emulsion and aqueous acrylic ester emulsion, brominated flame retardant additive, phosphate based flame retardant additive, a flame retardant synergistic agent, a thickening agent, a foaming agent, a foaming stabilizer, an anti-settling agent and a feeling agent. The coating gum can meet the requirements of a foaming finishing technique, finishes coatings of fabrics after directly being physically foamed by a mechanical foaming machine and meets new requirements of textiles for coating finishing.
Description
Technical field
The present invention relates to the used for textiles finishing agent, specifically a kind of aqueous foaming flame-retardant coating glue for textile and preparation method thereof.
Technical background
Along with the continuous development of textile industry, industry and textiles for general use increase rapidly, and the fire that is caused by textiles also constantly increases, the safety that is constantly threatening human life and property.Therefore, the anti-flaming function of textiles delays fire spreading to eliminating disaster hidden-trouble, and the loss that reduces human life and property is very important.Industrially developed country has formulated corresponding textiles flame-retardant standard and method of testing at present, and some country also carries out textiles fire resistance standard in conjunction with relevant law compulsion.This has promoted various countries' industrial department and research department all competitively being engaged in the fire-retardant research of textiles over nearly 20 years, has therefore promoted the development of antiflaming finishing agent.
China is later to the exploitation of flame retardant textiles, just carries out the research and development to flame retardant textiles in recent years energetically, and has obtained suitable progress.Simultaneously, national correlation department has been formulated mandatory standard GB 20286-2006 " public place fire-retardant product and assembly fire resistance require and sign " in 2006,7 kinds of family expenses drapery fire resistance features all there is clearly regulation, and in formal enforcement on March 1st, 2007.Obviously, the domestic from now on market demand to flame retardant textiles is very wide, and potentiality to be exploited is huge, and the technical research of flame-proof treatment aspect of therefore accelerating textiles is very urgent.At present, adopting the waterborne flame retardant coating adhesive is the main developing direction of fabric fire-retardant finishing to fabric fire-retardant finishing, and this is attributed to this method can significantly reduce quantity of wastewater effluent, and energy savings has good environment-friendly advantage.
Chinese patent application 93115328.X discloses a kind of anti-flaming dope that can be used for the fabric primary coat, Chinese patent application CN200480025533.X discloses a kind of fire-retardant combination that is used for the general fabrics coating, but they can not satisfy the requirement of foaming finishing process.
Summary of the invention
Technical problem to be solved by this invention is to overcome the defective that above-mentioned prior art exists, a kind of aqueous foaming flame-retardant coating glue for textile is provided, it can satisfy the requirement of foaming finishing process, after can directly carrying out physical blowing by the mechanical foaming machine, can carry out top finish to the variety classes fabric to it.
For this reason, the present invention adopts following technical scheme: aqueous foaming flame-retardant coating glue for textile, it comprises following component: the aqueous base precursor emulsion of being made up of aqueous polyurethane emulsion, water-and acrylate emulsion, bromine is a flame-retardant additive, phosphorous flame-retardant additive, retardant synergist, thickener, blowing agent, foam stabilizer, anti-settling agent and hand feeling agent.
Above-mentioned aqueous foaming flame-retardant coatings glue, aqueous polyurethane emulsion are the anion cross-linked type latex emulsion, solid content 26-32%, and pH value 8-10 accounts for the 20-50% of aqueous base precursor emulsion weight; The water-and acrylate emulsion is pure third self-crossing emulsion that can foam, and vitrification point is-30 ℃-40 ℃, solid content 25-30%, and pH value 8-10 accounts for the 50-80% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, bromine is that flame-retardant additive is deca-BDE, TDE, eight bromo ether, hexabromo-Cyclododecane, tetrabromobisphenol A, three (2, the 3-dibromopropyl) combination of one or more in the fulminuric acid ester, its addition is the 30-50% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, the phosphorous flame-retardant additive is a halogenated organic phosphate series, select three-(chloro isopropyl) phosphates for use, three (β-chloroethyl) phosphate, three (2,3-two chloropropyls) phosphate, fire retardant V6, fire retardant V68, fire retardant FR-780, fire retardant FR-550, fire retardant FR-540, fire retardant FR-530, fire-retardant FR-2 02, fire retardant FR-118, fire retardant FR-8, bisphenol-A two (diphenyl phosphoester), one or more combinations in the resorcinol two (diphenyl phosphoester), its addition is the 0-40% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, retardant synergist is that (code name that the present invention adopts Shenzhen auspicious great chemical materials Co., Ltd to produce is the silicon-nitrogen compound of RH-01, RH-02, RH-03W for antimonous oxide, nano zine oxide, silicon-nitrogen compound, the silicon-nitrogen compound that also can adopt other companies to produce) one or more combinations in, its addition is the 5-15% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, thickener are acrylic polymer emulsions, and its addition is the 5-10% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, blowing agent are selected one or more combinations in the following surfactant for use:
1) anion surfactant: alkyl sulfate (salt) class, direct-connected pure sulfuric ester (salt) class, sulfosuccinate class, sulfosuccinic amide-type; 2) non-ionic surface active agent: alkyl alcoholamine, ethylene oxide/propylene oxide block copolymer (OS-25); Blowing agent is made into the aqueous solution that mass concentration is 20-30%, and its addition is the 1-10% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, foam stabilizer are that mass concentration is the ammonium stearate solution of 15-25%, and its addition is the 5-15% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, thickener are polyacrylate dispersion, and its addition is the 5-10% of aqueous base precursor emulsion weight.
Above-mentioned aqueous foaming flame-retardant coatings glue, anti-settling agent are the association type aqueous polyurethane emulsion or/and aerosil, and its addition is the 2-5% of aqueous base precursor emulsion.
Above-mentioned aqueous foaming flame-retardant coatings glue, hand feeling agent are organic silicon emulsion, and its addition is the 0.5-1.0% of aqueous base precursor emulsion.
Another object of the present invention provides the preparation method of above-mentioned aqueous foaming flame-retardant coatings glue, and its step is as follows:
At first, in having the reactor of agitating device, drop into two kinds of matrix emulsions (aqueous polyurethane emulsion and water-and acrylate emulsion), and fully mix;
Secondly, adding bromine successively in still is flame-retardant additive, phosphorous flame-retardant additive, retardant synergist, stirs;
Then, by the ultra fine device mixture is carried out ultra fine, realized that the matrix emulsion coats in powder particle Surface Physical/chemistry, the refinement degree of the latex particle size after compound reaches the 600-1000 order;
At last, in still, add blowing agent, foam stabilizer, thickener, anti-settling agent and hand feeling agent successively, fully stir, get product after the filtration.
The present invention compared with prior art has following beneficial effect:
1, the coating adhesive that makes can satisfy foaming finishing technique requirement, directly it is carried out physical blowing by the mechanical foaming machine after, fabric is carried out top finish, satisfied the new demand of fabric coating arrangement;
2, satisfy the coating adhesive of different fabrics by regulating its composition and ratio, can making, be applied to the top finish that kind fabric spins in families such as curtain, sofa performance requirements such as fire-retardant, pliabilitys;
Defectives such as 3, the shading that also is applicable to fabric is put in order, and the coating window shade before having overcome mainly adopts the direct cutter of multilayer aqueous coating to be coated with, and feel is stiffening, or adopts the solvent-borne type product that the sense of moulding is arranged, and appearance effect is undesirable;
4, according to the requirement of fabric, coating adhesive can be controlled at 0.33-0.67g/cm with its foaming density through the mechanical foaming machine
3Scope;
5, the treatment process that has adopted a kind of physical/chemical to combine carries out super-refinement and coats processing coating adhesive, has realized that the matrix emulsion coats at powder particle Surface Physical/chemistry, makes coating adhesive have good storage stability;
6, the production equipment of Cai Yonging is simple, can batch type, batch (-type) ground produces, and production cost is low, efficient is high, wide application.
The invention will be further described below in conjunction with the specific embodiment.
The specific embodiment
Embodiment 1
The coating adhesive prescription that the fire-retardant curtain fabric of shading is used is as follows:
The matrix emulsion
20 parts of aqueous polyurethane emulsions
80 parts of water-and acrylate emulsions
35 parts of deca-BDEs
9 parts of antimonous oxides
8 parts of polyacrylate dispersions
2 parts of 25% alkylsurfuric acid ester solutions
5 parts of ammonium stearate solution
Anti-settling agent
2 parts of aerosils
2 parts of associativity polyurethane solutions
1 part of organic silicon emulsion
Embodiment 2
Viscose glue or cotton composition are that the coating adhesive that main heavily fabric is used is filled a prescription as follows:
The matrix emulsion
30 parts of aqueous polyurethane emulsions
70 parts of water-and acrylate emulsions
30 parts of TDEs
Fire retardant FR-118 40 part
Retardant synergist
5 parts of antimonous oxides
5 parts of RH-03W
5 parts of polyacrylate dispersions
5 parts of 30% sulfosuccinic acid ester solutions
20 parts of ammonium stearate solution
Anti-settling agent
1 part of aerosil
3 parts of associativity polyurethane solutions
0.5 part of organic silicon emulsion
Embodiment 3
The terylene composition is that the coating adhesive that main heavily fabric is used is filled a prescription as follows:
The matrix emulsion
40 parts of aqueous polyurethane emulsions
60 parts of water-and acrylate emulsions
40 parts of hexabromo-Cyclododecane
The phosphorous flame-retardant additive
10 parts of FR-530
10 parts of V68
Retardant synergist
8 parts of antimonous oxides
2 parts of RH-02
9 parts of polyacrylate dispersions
8 parts of 25%OS-25 solution
12 parts of ammonium stearate solution
Anti-settling agent
3 parts of aerosils
2 parts of associativity polyurethane solutions
0.7 part of organic silicon emulsion
Embodiment 4
As follows at the coating adhesive prescription that suede nap is used:
The matrix emulsion
50 parts of aqueous polyurethane emulsions
50 parts of water-and acrylate emulsions
50 parts of eight bromo ethers
Fire retardant FR-780 10 part
Retardant synergist
10 parts of antimonous oxides
5 parts of nano zine oxides
10 parts of polyacrylate dispersions
10 parts of 25% alkyl sulphate solutions
15 parts of ammonium stearate solution
Anti-settling agent
1 part of aerosil
1 part of associativity polyurethane solutions
1 part of organic silicon emulsion.
The preparation method of the foregoing description is as follows:
At first, in having the reactor of agitating device, drop into two kinds of matrix emulsions (aqueous polyurethane emulsion and water-and acrylate emulsion) 100 parts, and fully mix;
Secondly, adding bromine successively in still according to prescription is flame-retardant additive, phosphorous flame-retardant additive, retardant synergist and aerosil, stirs;
Then, by the ultra fine device mixture is carried out ultra fine, realized that the matrix emulsion coats at powder particle Surface Physical/chemistry, the refinement degree of compound back latex particle size reaches 600-1000 order scope;
At last, in still, add blowing agent, foam stabilizer, thickener, association type aqueous polyurethane emulsion and hand feeling agent successively, fully stir, get product after the filtration.
The aqueous foaming flame-retardant coatings glue that the present invention makes has following physical index:
Outward appearance: oyster white thickness body,
Solid content: 50-58%,
PH value: 8.0-10.0,
Density: 0.8-1.0g/cm
3,
Viscosity: 200-600mPa.s,
Shelf-stability: 3 months.
The above only is preferred embodiment of the present invention.Every foundation technical spirit of the present invention all falls within the scope of protection of the present invention any simple modification, equivalent variations and modification that above embodiment did.
Claims (10)
1, aqueous foaming flame-retardant coating glue for textile, it comprises following components in part by weight: 100 parts of the aqueous base precursor emulsions of being made up of 20-50 part aqueous polyurethane emulsion, 50-80 part water-and acrylate emulsion, bromine is flame-retardant additive 30-50 part, phosphorous flame-retardant additive 0-40 part, retardant synergist 5-15 part, thickener 5-10 part, blowing agent 1-10 part, foam stabilizer 5-15 part, anti-settling agent 2-5 part, hand feeling agent 0.5-1.0 part.
2, aqueous foaming flame-retardant coatings glue according to claim 1, it is characterized in that: described bromine is that flame-retardant additive is deca-BDE, TDE, eight bromo ether, one or more combinations in hexabromo-Cyclododecane, tetrabromobisphenol A, three (2, the 3-dibromopropyl) the fulminuric acid ester.
3, aqueous foaming flame-retardant coatings glue according to claim 1, it is characterized in that: described phosphorous flame-retardant additive is one or more combinations in three-(chloro isopropyl) phosphates, three (β-chloroethyl) phosphate, three (2,3-two chloropropyls) phosphate, fire retardant V6, fire retardant V68, fire retardant FR-780, fire retardant FR-550, fire retardant FR-540, fire retardant FR-530, fire-retardant FR-2 02, fire retardant FR-118, fire retardant FR-8, bisphenol-A two (diphenyl phosphoester), the resorcinol two (diphenyl phosphoester).
4, aqueous foaming flame-retardant coatings glue according to claim 1 is characterized in that: described retardant synergist is one or more combinations in antimonous oxide, nano zine oxide, the silicon-nitrogen compound.
5, water foaming flame-retardant coating glue according to claim 1 is characterized in that: described thickener is a polyacrylate dispersion.
6, aqueous foaming flame-retardant coatings glue according to claim 1 is characterized in that: described blowing agent is an anion surfactant or/and non-ionic surface active agent, and described blowing agent is mixed with the aqueous solution that mass concentration is 20-30%.
7, aqueous foaming flame-retardant coatings glue according to claim 6 is characterized in that described anion surfactant is alkyl sulfate, alkyl sulfate, straight chain alcohol sulfuric ester, straight chain alcohol sulfate, sulfosuccinate, sulfosuccinic acid amides; Described non-ionic surface active agent is alkyl alcoholamine, ethylene oxide/propylene oxide block copolymer.
8, aqueous foaming flame-retardant coatings glue according to claim 1 is characterized in that: described foam stabilizer is that mass concentration is the ammonium stearate solution of 18-25%.
9, aqueous foaming flame-retardant coatings glue according to claim 1 is characterized in that: described anti-settling agent is that the association type aqueous polyurethane emulsion is or/and aerosil; Described hand feeling agent is an organic silicon emulsion.
10, the preparation method of aqueous foaming flame-retardant coatings glue according to claim 1, its step is as follows: 1) add aqueous polyurethane emulsion and water-and acrylate emulsion in reactor, fully mix; 2) adding bromine successively in reactor is flame-retardant additive, phosphorous flame-retardant additive, retardant synergist, stirs; 3) mixture is carried out ultra fine, the refinement degree that makes compound back latex particle size is at the 600-1000 order; 4) in reactor, add blowing agent, foam stabilizer, thickener, anti-settling agent and hand feeling agent successively, fully stir, get product after the filtration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100631342A CN101498105B (en) | 2008-07-11 | 2008-07-11 | Aqueous foaming flame-retardant coating glue for textile and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100631342A CN101498105B (en) | 2008-07-11 | 2008-07-11 | Aqueous foaming flame-retardant coating glue for textile and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101498105A true CN101498105A (en) | 2009-08-05 |
| CN101498105B CN101498105B (en) | 2011-10-05 |
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Cited By (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115983A (en) * | 2011-01-26 | 2011-07-06 | 烟台华大化学工业有限公司 | Aqueous polyurethane superfine fiber synthetic leather and preparation method thereof |
| CN102251390A (en) * | 2011-06-28 | 2011-11-23 | 公安部四川消防研究所 | Halogen-free moisture permeable flame-retardant coating adhesive for heavy fabrics and preparation method |
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4208485A (en) * | 1978-04-18 | 1980-06-17 | Gaf Corporation | Foaming composition for textile finishing and coatings |
| US4230746A (en) * | 1979-09-24 | 1980-10-28 | Gaf Corporation | Foaming composition for textile finishing and coatings |
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| CN100351289C (en) * | 2005-07-13 | 2007-11-28 | 安徽大学 | Radiation polymerization method for aqueous polyurethane-siliceous acrylic resin fabric coating |
-
2008
- 2008-07-11 CN CN2008100631342A patent/CN101498105B/en active Active
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Address after: 311215 Xiaoshan economic and Technological Development Zone, Hangzhou, Zhejiang Patentee after: The mass of Limited by Share Ltd Address before: 311215 Xiaoshan economic and Technological Development Zone, Hangzhou, Zhejiang Patentee before: Chuanhua Co., Ltd., Zhejiang |
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