CN1026981C - 胍衍生物的制备方法 - Google Patents

胍衍生物的制备方法 Download PDF

Info

Publication number
CN1026981C
CN1026981C CN89109577A CN89109577A CN1026981C CN 1026981 C CN1026981 C CN 1026981C CN 89109577 A CN89109577 A CN 89109577A CN 89109577 A CN89109577 A CN 89109577A CN 1026981 C CN1026981 C CN 1026981C
Authority
CN
China
Prior art keywords
compound
salt
methyl
formula
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN89109577A
Other languages
English (en)
Chinese (zh)
Other versions
CN1045261A (zh
Inventor
采女英树
岩永幸一
樋口典子
南田勲
岡内哲夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Takeda Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27284327&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1026981(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Takeda Pharmaceutical Co Ltd filed Critical Takeda Pharmaceutical Co Ltd
Publication of CN1045261A publication Critical patent/CN1045261A/zh
Priority to CN93101375A priority Critical patent/CN1060615C/zh
Application granted granted Critical
Publication of CN1026981C publication Critical patent/CN1026981C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/36—Radicals substituted by singly-bound nitrogen atoms
    • C07D213/40—Acylated substituent nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C279/30—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to nitro or nitroso groups
    • C07C279/32—N-nitroguanidines
    • C07C279/36—Substituted N-nitroguanidines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/12—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/22—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D277/28—Radicals substituted by nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/34—Oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
CN89109577A 1988-12-27 1989-12-26 胍衍生物的制备方法 Expired - Lifetime CN1026981C (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN93101375A CN1060615C (zh) 1988-12-27 1993-02-10 胍衍生物杀虫剂组合物

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP33219288 1988-12-27
JP332192/88 1988-12-27
JP23589/89 1989-01-31
JP2358989 1989-01-31
JP18778989 1989-07-19
JP187789/89 1989-07-19

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN93101375A Division CN1060615C (zh) 1988-12-27 1993-02-10 胍衍生物杀虫剂组合物

Publications (2)

Publication Number Publication Date
CN1045261A CN1045261A (zh) 1990-09-12
CN1026981C true CN1026981C (zh) 1994-12-14

Family

ID=27284327

Family Applications (1)

Application Number Title Priority Date Filing Date
CN89109577A Expired - Lifetime CN1026981C (zh) 1988-12-27 1989-12-26 胍衍生物的制备方法

Country Status (14)

Country Link
US (3) US5034404A (2)
EP (3) EP0493369B1 (2)
KR (2) KR0169469B1 (2)
CN (1) CN1026981C (2)
AT (2) ATE129998T1 (2)
BR (1) BR8906791A (2)
CA (2) CA2202305A1 (2)
DE (3) DE68924787T2 (2)
ES (2) ES2055003T3 (2)
HU (1) HU207291B (2)
IE (3) IE960441L (2)
IL (1) IL92724A (2)
IN (1) IN170288B (2)
NL (1) NL350044I2 (2)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101796962A (zh) * 2010-04-16 2010-08-11 陕西美邦农药有限公司 一种含噻虫胺与马拉硫磷的杀虫组合物
CN103098818A (zh) * 2013-01-04 2013-05-15 广西三晶化工科技有限公司 一种含噻虫胺和杀虫单的农药复配混合物和杀虫药肥及其生产方法

Families Citing this family (137)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2779403B2 (ja) * 1988-11-29 1998-07-23 日本バイエルアグロケム株式会社 殺虫性ニトロ化合物
IE960441L (en) * 1988-12-27 1990-06-27 Takeda Chemical Industries Ltd Guanidine derivatives, their production and insecticides
JP2605651B2 (ja) * 1988-12-27 1997-04-30 武田薬品工業株式会社 グアニジン誘導体、その製造法及び殺虫剤
EP0418199A3 (en) * 1989-09-13 1991-06-12 Ciba-Geigy Ag Guanidine derivatives
JPH03200768A (ja) * 1989-10-24 1991-09-02 Agro Kanesho Co Ltd ニトログアニジン化合物及び殺虫剤
US5180833A (en) * 1990-03-16 1993-01-19 Takeda Chemical Industries, Ltd. Process for the preparation of chlorothiazole derivatives
IE911168A1 (en) * 1990-04-13 1991-10-23 Takeda Chemical Industries Ltd Novel intermediates for preparing guanidine derivatives,¹their preparation and use
IL99161A (en) * 1990-08-17 1996-11-14 Takeda Chemical Industries Ltd History of guanidine A process for their preparation and preparations from pesticides that contain them
EP0483055A1 (de) * 1990-10-05 1992-04-29 Ciba-Geigy Ag Triazacyclohexanderivate
TW198724B (2) * 1990-10-24 1993-01-21 Ciba Geigy Ag
CH680827A5 (2) * 1991-03-14 1992-11-30 Ciba Geigy Ag
TW202434B (2) * 1991-04-04 1993-03-21 Ciba Geigy Ag
DE4204919A1 (de) * 1992-02-19 1993-08-26 Bayer Ag Verfahren zur herstellung von 2-chlor-5-alkylaminomethyl-pyridinen
US5531981A (en) * 1992-05-01 1996-07-02 Takeda Chemical Industries, Ltd. Method for treatment of termite
US6022871A (en) * 1992-07-22 2000-02-08 Novartis Corporation Oxadiazine derivatives
TW240163B (en) * 1992-07-22 1995-02-11 Syngenta Participations Ag Oxadiazine derivatives
DE4232561A1 (de) * 1992-09-29 1994-03-31 Bayer Ag Bekämpfung von Fischparasiten
DE4301110A1 (de) * 1993-01-18 1994-07-21 Bayer Ag Verfahren zur Herstellung von 2-Amino-5-aminomethyl-pyridin
DE4308152A1 (de) * 1993-03-15 1994-09-22 Bayer Ag Verfahren zur Herstellung von 2-Halogen-5-cyano-pyridinen
US5434181A (en) * 1993-10-26 1995-07-18 Mitsui Toatsu Chemicals, Inc. Furanyl insecticide
DE4414569A1 (de) * 1994-04-27 1995-11-02 Bayer Ag Verwendung von substituierten Aminen zur Behandlung von Hirnleistungsstörungen
DE4417742A1 (de) 1994-05-20 1995-11-23 Bayer Ag Nicht-systemische Bekämpfung von Parasiten
DE4423353A1 (de) 1994-07-04 1996-01-11 Bayer Ag Verfahren zur Herstellung N-acylierter 2-Chlor-5-aminomethylpyridine
DE4426753A1 (de) * 1994-07-28 1996-02-01 Bayer Ag Mittel zur Bekämpfung von Pflanzenschädlingen
TW328084B (en) * 1995-06-23 1998-03-11 Takeda Pharm Industry Co Ltd Process for producing guanidine derivatives, intermediates therefor and their production
WO1997009312A1 (en) * 1995-09-08 1997-03-13 Nippon Soda Co., Ltd. Process for producing 3-(aminomethyl)-6-chloropyridines
ZA9610046B (en) * 1995-12-01 1997-07-10 Ciba Geigy Process for preparing 2-chlorothiazole compounds
US5821261A (en) * 1995-12-08 1998-10-13 Merck & Co., Inc. Substituted saturated aza heterocycles as inhibitors of nitric oxide synthase
DE19548872A1 (de) 1995-12-27 1997-07-03 Bayer Ag Synergistische insektizide Mischungen
US6828275B2 (en) * 1998-06-23 2004-12-07 Bayer Aktiengesellschaft Synergistic insecticide mixtures
DE19622355A1 (de) 1996-06-04 1997-12-11 Bayer Ag Formkörper die agrochemische Mittel freisetzen
ATE308531T1 (de) 1996-12-19 2005-11-15 Syngenta Participations Ag Verfahren zur herstellung von thiazolederivaten
DE19654079A1 (de) * 1996-12-23 1998-06-25 Bayer Ag Endo-ekto-parasitizide Mittel
WO1998034484A1 (en) 1997-02-10 1998-08-13 Takeda Chemical Industries, Ltd. Aqueous suspension of agrochemical
DK0975222T3 (da) 1997-02-10 2007-03-26 Sumitomo Chem Takeda Agro Co Befugtelig eller vandoplöselig granulær agrokemisk sammensætning
DE19712411A1 (de) 1997-03-25 1998-10-01 Bayer Ag Verfahren zur Herstellung von 1,3-disubstituierten 2-Nitroguanidinen
DE19712885A1 (de) * 1997-03-27 1998-10-01 Bayer Ag Verfahren zur Herstellung von N-Alkyl-N'-nitroguanidinen
JP2001515066A (ja) * 1997-08-20 2001-09-18 ノバルティス アクチエンゲゼルシャフト 置換された２−ニトログアニジン誘導体の製造方法
JP2001515888A (ja) * 1997-09-08 2001-09-25 ノバルティス アクチエンゲゼルシャフト 農薬としてのヘテロ環式化合物
WO1999033809A1 (en) * 1997-12-24 1999-07-08 Takeda Chemical Industries, Ltd. Method for producing isoureas
US6844339B2 (en) * 1998-01-16 2005-01-18 Syngenta Crop Protection, Inc. Use of neonicotinoids in pest control
DE19807630A1 (de) 1998-02-23 1999-08-26 Bayer Ag Wasserhaltige Mittel zur Bekämpfung parasitierender Insekten und Milben an Menschen
ID26225A (id) 1998-03-19 2000-12-07 Novartis Ag Proses pembuatan senyawa turunan nitroguanidin
JP4196427B2 (ja) 1998-04-09 2008-12-17 住友化学株式会社 有害節足動物駆除組成物
DE19823396A1 (de) * 1998-05-26 1999-12-02 Bayer Ag Synergistische insektizide Mischungen
US6140350A (en) * 1998-06-08 2000-10-31 Sumitomo Chemical Company, Limited Method for controlling ectoparasites
CA2334618C (en) 1998-06-10 2010-01-12 Bayer Aktiengesellschaft Agents for combating plant pests
DE69900356T2 (de) * 1998-07-24 2002-07-11 Mitsui Chemicals, Inc. Nitro-Isoharnstoffderivate
US6201017B1 (en) 1998-07-27 2001-03-13 Sumitomo Chemical Co., Ltd. Ectoparasite controlling agent for animals
AU750504B2 (en) * 1998-07-30 2002-07-18 Sumitomo Chemical Company, Limited Tick controlling agent
JP4214594B2 (ja) 1998-09-28 2009-01-28 住友化学株式会社 シロアリ防除エアゾール剤
US6149913A (en) * 1998-11-16 2000-11-21 Rhone-Poulenc Ag Company, Inc. Compositions and methods for controlling insects
US6503904B2 (en) 1998-11-16 2003-01-07 Syngenta Crop Protection, Inc. Pesticidal composition for seed treatment
CO5210925A1 (es) 1998-11-17 2002-10-30 Novartis Ag Derivados de diamino nitroguanidina tetrasustituidos
DE19908447A1 (de) 1999-02-26 2000-08-31 Bayer Ag Verfahren zur Herstellung von 2-Chlor-5-chlormethylthiazol
DE19913174A1 (de) 1999-03-24 2000-09-28 Bayer Ag Synergistische insektizide Mischungen
US6156703A (en) * 1999-05-21 2000-12-05 Ijo Products, Llc Method of inhibiting fruit set on fruit producing plants using an aqueous emulsion of eicosenyl eicosenoate and docosenyl eicosenoate
DE19948129A1 (de) * 1999-10-07 2001-04-12 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
JP4288794B2 (ja) * 1999-10-26 2009-07-01 住友化学株式会社 殺虫・殺ダニ組成物
DE19953775A1 (de) 1999-11-09 2001-05-10 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE19961604A1 (de) 1999-12-21 2001-07-05 Bayer Ag Verfahren zur Herstellung von 1,3-disubstituierten 2-Nitroguanidinen
DE10103832A1 (de) * 2000-05-11 2001-11-15 Bayer Ag Fungizide Wirkstoffkombinationen
DE10024934A1 (de) 2000-05-19 2001-11-22 Bayer Ag Wirkstoffkombinationen mit insektiziden akariziden Eigenschaften
CN1501917A (zh) * 2000-08-30 2004-06-02 美国陶氏益农公司 杀虫剂用化合物、杀螨剂用化合物及其使用和制备方法
US6838473B2 (en) * 2000-10-06 2005-01-04 Monsanto Technology Llc Seed treatment with combinations of pyrethrins/pyrethroids and clothiandin
US20020103233A1 (en) 2000-11-30 2002-08-01 Arther Robert G. Compositions for enhanced acaricidal activity
DE10059606A1 (de) 2000-12-01 2002-06-06 Bayer Ag Wirkstoffkombinationen
US6407251B1 (en) 2000-12-28 2002-06-18 Takeda Chemical Industries, Ltd. Process for preparing 2-chloro-5-chloromethylthiazole
DE10117676A1 (de) * 2001-04-09 2002-10-10 Bayer Ag Dermal applizierbare flüssige Formulierungen zur Bekämpfung von parasitierenden Insekten an Tieren
DE10121652A1 (de) * 2001-05-03 2002-11-07 Bayer Ag Verfahren zur Herstellung von 1,3-disubstituierten 2-Nitroguanidinen
AR036872A1 (es) 2001-08-13 2004-10-13 Du Pont Compuesto de antranilamida, composicion que lo comprende y metodo para controlar una plaga de invertebrados
DE10140108A1 (de) * 2001-08-16 2003-03-06 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
WO2003059067A1 (de) * 2002-01-17 2003-07-24 Basf Aktiengesellschaft Fungizide mischungen auf der basis von oximetherderivaten_und guanidinderivaten
DE10203688A1 (de) * 2002-01-31 2003-08-07 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE10248257A1 (de) * 2002-10-16 2004-04-29 Bayer Cropscience Ag Wirkstoffkombinationen im insektiziden und akariziden Eigenschaften
US8232261B2 (en) * 2003-07-18 2012-07-31 Bayer Cropscience Lp Method of minimizing herbicidal injury
DE10333371A1 (de) * 2003-07-23 2005-02-10 Bayer Ag Fungizide Wirkstoffkombinationen
DE10347440A1 (de) 2003-10-13 2005-05-04 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE102004006075A1 (de) 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE10356820A1 (de) 2003-12-05 2005-07-07 Bayer Cropscience Ag Synergistische insektizide Mischungen
US20070155797A1 (en) 2003-12-12 2007-07-05 Bayer Cropscience Aktiengesellschaft Synergistic insecticidal mixtures
DE102004032418A1 (de) * 2004-04-07 2005-10-27 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102004033289A1 (de) * 2004-04-24 2005-11-10 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE102004038329A1 (de) * 2004-06-16 2005-12-29 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE102004037506A1 (de) * 2004-08-03 2006-02-23 Bayer Cropscience Ag Methode zur Verbesserung der Pflanzenverträglichkeit gegenüber Glyphosate
SG155230A1 (en) * 2004-08-25 2009-09-30 Bayer Cropscience Lp Method of controlling termites
DE102004056626A1 (de) 2004-11-24 2006-06-01 Bayer Cropscience Ag Substituierte Oxyguanidine
CN1328264C (zh) * 2004-12-13 2007-07-25 中国农业大学 含噁二嗪环的[反]－β－法尼烯类似物及其制备方法与应用
DE102004062513A1 (de) 2004-12-24 2006-07-06 Bayer Cropscience Ag Insektizide auf Basis von Neonicotinoiden und ausgewählten Strobilurinen
DE102004062512A1 (de) 2004-12-24 2006-07-06 Bayer Cropscience Ag Synergistische Mischungen mit insektizider und fungizider Wirkung
US9919979B2 (en) 2005-01-21 2018-03-20 Bayer Cropscience Lp Fertilizer-compatible composition
US9326509B2 (en) 2005-02-22 2016-05-03 Basf Se Composition and method for improving plant health
DE102005022994A1 (de) * 2005-05-19 2006-11-30 Bayer Cropscience Ag Methode zur Verbesserung des Pflanzenwachstums und der Steigerung der Widerstandsfähigkeit gegen bodenbürtige Schadpilze in Pflanzen
EP1731037A1 (en) 2005-06-04 2006-12-13 Bayer CropScience AG Increase of stress tolerance by application of neonicotinoids on plants engineered to be stress tolerant
CN104170838B (zh) 2005-06-09 2016-03-30 拜尔农作物科学股份公司 活性物质结合物
EP1893759B1 (en) 2005-06-15 2009-08-12 Bayer BioScience N.V. Methods for increasing the resistance of plants to hypoxic conditions
JP5066808B2 (ja) * 2006-01-13 2012-11-07 住友化学株式会社 チアゾール化合物の製造方法
DE102006014487A1 (de) 2006-03-29 2007-10-04 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102006030710A1 (de) * 2006-07-03 2008-01-10 Bayer Cropscience Ag Synergistische insektizide und fungizide Mischungen
WO2008003738A1 (en) * 2006-07-06 2008-01-10 Bayer Cropscience Ag Pesticidal composition comprising a pyridylethylbenzamide derivative and an insecticide compound
DE102006046688B3 (de) * 2006-09-29 2008-01-24 Siemens Ag Kälteanlage mit einem warmen und einem kalten Verbindungselement und einem mit den Verbindungselementen verbundenen Wärmerohr
MX2009003378A (es) * 2006-09-30 2009-04-09 Bayer Cropscience Ag Concentrados en suspension para la mejora de la absorcion por la raiz de principios activos agroquimicos.
EP1905302A1 (de) * 2006-09-30 2008-04-02 Bayer CropScience AG Suspensionskonzentrate
PT2124557E (pt) * 2007-02-02 2015-02-27 Plant Health Care Inc Composições fungicidas sinérgicas compreendendo formononetina
JP5066933B2 (ja) * 2007-02-21 2012-11-07 住友化学株式会社 有害生物防除剤組成物及び有害生物の防除方法
MX2009008798A (es) 2007-02-22 2009-08-24 Syngenta Participations Ag Derivados de iminipiridina y sus usos como microbicidas.
US20100196520A1 (en) * 2007-06-18 2010-08-05 Hanan Elraz Insect repellent formulations
EP2008519A1 (de) 2007-06-28 2008-12-31 Bayer CropScience AG Verwendung von Wirkstoffkombinationen mit insektiziden Eigenschaften zur Bekämpfung von tierischen Schädlingen aus der Familie der Stinkwanzen
DE102007045922A1 (de) 2007-09-26 2009-04-02 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102007045956A1 (de) 2007-09-26 2009-04-09 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden und akariziden Eigenschaften
EP2070416A1 (de) 2007-12-11 2009-06-17 Bayer CropScience AG Verwendung von Wirkstoffkombinationen zur Bekämpfung von tierischen Schädlingen
EP2127522A1 (de) 2008-05-29 2009-12-02 Bayer CropScience AG Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
US8110608B2 (en) 2008-06-05 2012-02-07 Ecolab Usa Inc. Solid form sodium lauryl sulfate (SLS) pesticide composition
JP5355053B2 (ja) * 2008-09-19 2013-11-27 住友化学株式会社 有害生物防除用組成物及び有害生物の防除方法
US20100197786A1 (en) * 2008-11-27 2010-08-05 Hanan Elraz Insect-repellent formulations
EP2227951A1 (de) 2009-01-23 2010-09-15 Bayer CropScience AG Verwendung von Enaminocarbonylverbindungen zur Bekämpfung von durch Insekten übertragenen Viren
WO2010096613A1 (en) 2009-02-19 2010-08-26 Pioneer Hi-Bred International, Inc. Blended refuge deployment via manipulation during hybrid seed production
EP2225940B1 (en) 2009-03-05 2014-03-12 GAT Microencapsulation GmbH Oil dispersions of nAChR binding neonicotinoids
MX336396B (es) 2009-05-03 2016-01-15 Monsanto Technology Llc Sistemas y procesos para combinar diferentes tipos de semillas.
RU2565081C2 (ru) * 2009-11-17 2015-10-20 Байер Кропсайенс Аг Комбинации активных соединений
US9034850B2 (en) 2009-11-20 2015-05-19 Sk Chemicals Co., Ltd. Gonadotropin releasing hormone receptor antagonist, preparation method thereof and pharmaceutical composition comprising the same
EP2382865A1 (de) 2010-04-28 2011-11-02 Bayer CropScience AG Synergistische Wirkstoffkombinationen
WO2011161040A1 (en) 2010-06-21 2011-12-29 Basf Se Pesticidal composition comprising a benzoylurea compound and chlorfenapyr and their uses.
US8968757B2 (en) 2010-10-12 2015-03-03 Ecolab Usa Inc. Highly wettable, water dispersible, granules including two pesticides
WO2012107585A1 (fr) 2011-02-11 2012-08-16 Ceva Sante Animale Sa Nouvelles compositions antiparasitaires topiques concentrees et stables
WO2012124795A1 (en) 2011-03-17 2012-09-20 Sumitomo Chemical Company, Limited Pest control composition and pest control method
JP5906723B2 (ja) 2011-03-17 2016-04-20 住友化学株式会社 有害生物防除組成物及び有害生物の防除方法
EP2707373A1 (de) 2011-05-10 2014-03-19 Bayer Intellectual Property GmbH Bicyclische (thio)carbonylamidine
JP5760781B2 (ja) 2011-07-13 2015-08-12 住友化学株式会社 有害節足動物防除組成物及び有害節足動物の防除方法
WO2013056730A1 (en) 2011-10-18 2013-04-25 In2Care B.V. Systemic use of compounds in humans that kill free-living blood-feeding ectoparasites
JP6048110B2 (ja) * 2012-02-17 2016-12-21 住友化学株式会社 イネ種子の発芽促進方法及びイネの栽培方法
CA2978081C (en) 2012-04-06 2021-11-23 Monsanto Technology Llc Proteins toxic to hemipteran insect species
CN103621552B (zh) * 2012-08-29 2016-01-20 南京华洲药业有限公司 一种含噻虫胺和丙溴磷的复合杀虫组合物及其用途
WO2014035469A1 (en) 2012-08-31 2014-03-06 Bayer Cropscience Lp Combinations and methods for controlling turfgrass pests
JP6261931B2 (ja) 2013-01-23 2018-01-17 住友化学株式会社 有害節足動物防除組成物
AU2017216079B9 (en) 2016-02-01 2021-11-04 Elanco Animal Health Gmbh Rhipicephalus nicotinic acetylcholine receptor and pest control acting thereon
RU2019144010A (ru) 2017-06-08 2021-07-13 Мерк Шарп И Доум Корп. Пиразолопиримидиновые ингибиторы pde9

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1397436A (en) * 1972-09-05 1975-06-11 Smith Kline French Lab Heterocyclic n-cyanoguinidines
JPS53108970A (en) * 1977-03-07 1978-09-22 Yamanouchi Pharmaceut Co Ltd Novel guanidine derivative and its preparation
US4108859A (en) * 1977-06-06 1978-08-22 The Dow Chemical Company Microbicidal (pyridinylamino) alkyl guanidines
US4220654A (en) * 1979-06-04 1980-09-02 Merck & Co., Inc. Cyclic imidazole cyanoguanidines
ZA839248B (en) * 1982-12-14 1984-10-31 Smith Kline French Lab Pyridine derivatives
AU2222083A (en) * 1982-12-14 1984-06-21 Smith Kline & French Laboratories Limited Pyridine derivatives
EP0113070B1 (en) * 1982-12-20 1988-01-13 American Cyanamid Company The use of substituted nitro and cyanoguanidines for increasing crop yield
GB8306666D0 (en) * 1983-03-10 1983-04-13 Pfizer Ltd Therapeutic agents
US4604393A (en) * 1984-01-30 1986-08-05 Cornu Pierre Jean Phenyloxoalkyl piperidines and the pharmaceutical compositions containing them
DE3681465D1 (2) * 1985-02-04 1991-10-24 Nihon Bayer Agrochem K.K., Tokio/Tokyo, Jp
JPH085859B2 (ja) * 1986-07-01 1996-01-24 日本バイエルアグロケム株式会社 新規アルキレンジアミン類
DE3639877A1 (de) * 1986-11-21 1988-05-26 Bayer Ag Hetarylalkyl substituierte 5- und 6-ringheterocyclen
EP0306696B1 (de) * 1987-08-04 1994-02-16 Ciba-Geigy Ag Substituierte Guanidine
JP2884412B2 (ja) * 1988-10-21 1999-04-19 日本バイエルアグロケム株式会社 殺虫性シアノ化合物
JP2779403B2 (ja) * 1988-11-29 1998-07-23 日本バイエルアグロケム株式会社 殺虫性ニトロ化合物
JPH03218354A (ja) * 1988-12-23 1991-09-25 Nippon Soda Co Ltd 置換ピリジルアルキル誘導体、その製造方法及び殺虫剤
IE960441L (en) * 1988-12-27 1990-06-27 Takeda Chemical Industries Ltd Guanidine derivatives, their production and insecticides

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101796962A (zh) * 2010-04-16 2010-08-11 陕西美邦农药有限公司 一种含噻虫胺与马拉硫磷的杀虫组合物
CN101796962B (zh) * 2010-04-16 2013-04-10 陕西美邦农药有限公司 一种含噻虫胺与马拉硫磷的杀虫组合物
CN103098818A (zh) * 2013-01-04 2013-05-15 广西三晶化工科技有限公司 一种含噻虫胺和杀虫单的农药复配混合物和杀虫药肥及其生产方法

Also Published As

Publication number Publication date
ES2080359T3 (es) 1996-02-01
EP0665222B1 (en) 2001-06-20
DE68924787T2 (de) 1996-04-25
US5489603A (en) 1996-02-06
CA2006724C (en) 1998-01-27
DE68929307D1 (de) 2001-07-26
EP0493369A1 (en) 1992-07-01
KR0169469B1 (ko) 1999-01-15
EP0376279A3 (en) 1991-09-18
NL350044I1 (nl) 2010-03-01
DE68906668D1 (de) 1993-06-24
BR8906791A (pt) 1990-09-18
KR910002340A (ko) 1991-02-25
IE960442L (en) 1990-06-27
IL92724A (en) 1998-04-05
IN170288B (2) 1992-03-07
ES2055003T3 (es) 1994-08-16
CN1045261A (zh) 1990-09-12
DE68929307T2 (de) 2002-03-14
US5633375A (en) 1997-05-27
US5034404A (en) 1991-07-23
EP0376279B1 (en) 1993-05-19
IE960441L (en) 1990-06-27
DE68906668T2 (de) 1993-08-26
EP0665222A1 (en) 1995-08-02
DE68924787D1 (de) 1995-12-14
HUT53605A (en) 1990-11-28
CA2006724A1 (en) 1990-06-27
ATE202344T1 (de) 2001-07-15
IE71183B1 (en) 1997-01-29
IL92724A0 (en) 1990-09-17
ATE129998T1 (de) 1995-11-15
CA2202305A1 (en) 1990-06-27
NL350044I2 (nl) 2010-03-01
KR0164687B1 (ko) 1999-10-01
IE893973L (en) 1990-06-27
HU896723D0 (en) 1990-03-28
EP0376279A2 (en) 1990-07-04
EP0493369B1 (en) 1995-11-08
HU207291B (en) 1993-03-29

Similar Documents

Publication Publication Date Title
CN1026981C (zh) 胍衍生物的制备方法
CN1028592C (zh) 含新型的取代胍衍生物的杀虫组合物和应用
CN1027447C (zh) 一种含α-不饱和胺的杀虫/杀螨组合物
CN1040939C (zh) 杀虫剂和/或杀螨剂组合物及其制法和应用
CN1039080C (zh) 含有甲酰胺类衍生物的除草剂组合物
CN1255380C (zh) 吡咯酰胺和吡咯硫代酰胺杀菌剂
CN86106238A (zh) 新的硝基亚甲基衍生物
CN1078204C (zh) 氨基酸酰胺衍生物及其杀真菌的用途和制备方法
CN1016484B (zh) 含取代的四唑啉酮的组合物
CN1370047A (zh) 杀真菌剂
CN1057646A (zh) 肼甲酰胺衍生物及其生产方法和应用
CN1084171A (zh) 噁二嗪衍生物
CN1071924A (zh) 除草的三唑羧酸酰胺
CN1898207A (zh) 2－吡啶基乙基苯甲酰胺衍生物
CN1031265C (zh) 含四氢化嘧啶的控制害虫组合物
CN1096446C (zh) N－(邻位取代苄氧基)亚胺衍生物及其用作杀真菌剂、杀螨剂或杀虫剂的用途
CN1058776A (zh) 农药
CN1946695A (zh) 可用作杀真菌剂的2－吡啶基环烷基羧酰胺衍生物
CN1142152C (zh) 苯甲酰胺衍生物、农业与园艺用杀虫剂及其用途
CN1298395A (zh) 吡唑啉酮衍生物
CN1505611A (zh) 邻苯二酰胺衍生物、农用与园艺用杀虫剂及其施用方法
CN88103413A (zh) 吡喃化合物
CN1028988C (zh) 制备某些乙醛酰乙烯二酮的方法
CN1042729C (zh) N－磺酰基含氮6员芳环羧酸酰胺衍生物和杀虫除草剂
CN1077843A (zh) 胍衍生物杀虫剂组合物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
OR01 Other related matters
ASS Succession or assignment of patent right

Owner name: TAKEDA CHEMICAL INDUSTRIES LTD.

Free format text: FORMER OWNER: TAKEDA CHEMICAL INDUSTRIES, LTD.

Effective date: 20031211

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20031211

Address after: Tokyo, Japan

Patentee after: Sumitomo Chemical Takeda Agro

Address before: Osaka, Japan

Patentee before: Takeda Chemical Industries, Ltd.

C56 Change in the name or address of the patentee

Owner name: SUMITOMO CHEMICAL COMPANY LTD.

Free format text: FORMER NAME OR ADDRESS: TAKEDA CHEMICAL INDUSTRIES LTD.

CP03 Change of name, title or address

Address after: Osaka

Patentee after: Sumitomo Chemical Co., Ltd.

Address before: Tokyo, Japan

Patentee before: Sumitomo Chemical Takeda Agro

C56 Change in the name or address of the patentee

Owner name: SUMITOMO CHEMICAL CO.

Free format text: FORMER NAME OR ADDRESS: SUMITOMO CHEMICAL COMPANY LTD.

CP03 Change of name, title or address

Address after: Tokyo, Japan

Patentee after: Sumitomo Chemical Co., Ltd.

Address before: Osaka

Patentee before: Sumitomo Chemical Co., Ltd.

C17 Cessation of patent right
CX01 Expiry of patent term

Granted publication date: 19941214