CN103534029B - 高活性双金属氰化物催化剂的制备方法及其在聚醚多元醇的合成中的用途 - Google Patents

高活性双金属氰化物催化剂的制备方法及其在聚醚多元醇的合成中的用途 Download PDF

Info

Publication number
CN103534029B
CN103534029B CN201280023184.2A CN201280023184A CN103534029B CN 103534029 B CN103534029 B CN 103534029B CN 201280023184 A CN201280023184 A CN 201280023184A CN 103534029 B CN103534029 B CN 103534029B
Authority
CN
China
Prior art keywords
catalyst
ppg
organic complexing
complexing agent
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280023184.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN103534029A (zh
Inventor
马里亚·多洛雷斯·布兰科冈萨雷斯
费尔南多·普列托诺格拉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol SA
Original Assignee
Repsol SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Repsol SA filed Critical Repsol SA
Publication of CN103534029A publication Critical patent/CN103534029A/zh
Application granted granted Critical
Publication of CN103534029B publication Critical patent/CN103534029B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Polyethers (AREA)
  • Catalysts (AREA)
CN201280023184.2A 2011-05-17 2012-05-16 高活性双金属氰化物催化剂的制备方法及其在聚醚多元醇的合成中的用途 Active CN103534029B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11382156.5 2011-05-17
EP11382156 2011-05-17
PCT/EP2012/059081 WO2012156431A1 (en) 2011-05-17 2012-05-16 Process for preparing highly active double metal cyanide catalysts and their use in the synthesis of polyether polyols

Publications (2)

Publication Number Publication Date
CN103534029A CN103534029A (zh) 2014-01-22
CN103534029B true CN103534029B (zh) 2016-05-11

Family

ID=44310200

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280023184.2A Active CN103534029B (zh) 2011-05-17 2012-05-16 高活性双金属氰化物催化剂的制备方法及其在聚醚多元醇的合成中的用途

Country Status (9)

Country Link
US (2) US9221947B2 (de)
EP (1) EP2709757B1 (de)
KR (1) KR20140053020A (de)
CN (1) CN103534029B (de)
BR (1) BR112013029119A2 (de)
ES (1) ES2672497T3 (de)
PT (1) PT2709757T (de)
SA (2) SA116370919B1 (de)
WO (1) WO2012156431A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7977501B2 (en) 2006-07-24 2011-07-12 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (DMC) catalysis
SA116370919B1 (ar) 2011-05-17 2017-05-08 ريبسول، اس. ايه. عملية لتحضير مُحفِّز من مُعقَّد سيانيدي مزدوج المعدن
EP2837648A1 (de) 2013-08-12 2015-02-18 Repsol, S.A. Verfahren zur Herstellung von Polyethercarbonatpolyolen
WO2016120406A1 (en) 2015-01-28 2016-08-04 Repsol, S.A. A polyurethane adhesive formulation based on polyether carbonate polyol
WO2016120399A1 (en) 2015-01-28 2016-08-04 Repsol, S.A. A thermoplastic polyurethane based on polyether carbonate polyol
CA2982534A1 (en) * 2015-04-13 2016-10-20 Repsol, S.A. New formulations for polyurethane applications
EP3106221A1 (de) 2015-06-15 2016-12-21 Universität Hamburg Verfahren zur herstellung von doppelmetallcyanidkatalysatoren und deren verwendung in polymerisierungsreaktionen
ES2796342T3 (es) * 2015-08-04 2020-11-26 Repsol Sa Nuevas formulaciones para adhesivos sensibles a la presión
EP3328915B1 (de) 2016-10-18 2019-04-24 Repsol, S.A. Neue hochmolekulare polymere aus abfallrohstoffen
SG11202003038YA (en) 2017-10-10 2020-04-29 Stepan Co Polymeric dispersants from aralkylated phenols
MX2020004369A (es) 2017-10-10 2020-08-20 Stepan Co Dispersante polimerico de fenil glicidil eter.
RU2687105C1 (ru) * 2018-09-03 2019-05-07 Публичное Акционерное Общество "Нижнекамскнефтехим" Способ получения простого полиэфира с высокой молекулярной массой на основе пропиленоксида на двойном кобальтцианидном катализаторе
CN111087600B (zh) * 2018-10-23 2023-03-03 中国石油化工股份有限公司 聚氨酯弹性体树脂及其制备方法
CA3132874A1 (en) 2019-03-08 2020-09-17 Stepan Company Reactive surfactants
CN117916020A (zh) * 2021-09-08 2024-04-19 株式会社Lg化学 双金属氰化物催化剂、制备其的方法和使用其制备聚亚烷基碳酸酯的方法
CN113845867A (zh) * 2021-09-27 2021-12-28 淮安巴德聚氨酯科技有限公司 一种基于高分子聚醚多元醇的ms密封胶及其制备方法
CN115850681B (zh) * 2022-12-19 2025-03-25 万华化学集团股份有限公司 一种dmc催化剂及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072687C (zh) * 1994-09-08 2001-10-10 阿克奥化学技术有限公司 固体双金属氰化物催化剂及其制法和环氧化物聚合方法
WO2001089685A1 (en) * 2000-05-19 2001-11-29 The Dow Chemical Company Dispersion of supported metal catalysts using sulfone or sulfoxide compounds as a dispersant
CN1116334C (zh) * 1996-04-19 2003-07-30 阿科化学技术公司 高活性双金属氰化物催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3427256A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
US3427334A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3941849A (en) 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
AU551979B2 (en) 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
AU552988B2 (en) 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5712216A (en) 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5714428A (en) 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
JP4207388B2 (ja) 1998-07-10 2009-01-14 旭硝子株式会社 アルキレンオキシド開環重合用触媒、その製造方法およびその用途
ES2199666B1 (es) 2002-02-25 2005-06-01 Repsol Quimica, S.A. Procedimiento de produccion de polioleteres.
SA116370919B1 (ar) 2011-05-17 2017-05-08 ريبسول، اس. ايه. عملية لتحضير مُحفِّز من مُعقَّد سيانيدي مزدوج المعدن

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072687C (zh) * 1994-09-08 2001-10-10 阿克奥化学技术有限公司 固体双金属氰化物催化剂及其制法和环氧化物聚合方法
CN1116334C (zh) * 1996-04-19 2003-07-30 阿科化学技术公司 高活性双金属氰化物催化剂
WO2001089685A1 (en) * 2000-05-19 2001-11-29 The Dow Chemical Company Dispersion of supported metal catalysts using sulfone or sulfoxide compounds as a dispersant

Also Published As

Publication number Publication date
US9605111B2 (en) 2017-03-28
KR20140053020A (ko) 2014-05-07
SA112330512B1 (ar) 2016-11-17
WO2012156431A1 (en) 2012-11-22
SA116370919B1 (ar) 2017-05-08
ES2672497T3 (es) 2018-06-14
CN103534029A (zh) 2014-01-22
PT2709757T (pt) 2018-06-12
EP2709757B1 (de) 2018-03-07
BR112013029119A2 (pt) 2017-02-07
US20160068631A1 (en) 2016-03-10
US9221947B2 (en) 2015-12-29
EP2709757A1 (de) 2014-03-26
US20140243497A1 (en) 2014-08-28

Similar Documents

Publication Publication Date Title
US9605111B2 (en) Process for preparing highly active double metal cyanide catalysts and their use in the synthesis of polyether polyols
JP4043061B2 (ja) 改良されたポリエーテル含有二重金属シアン化物触媒並びにその製法および用途
JP4413998B2 (ja) 高活性二重金属シアン化物触媒
CN105531299B (zh) 用于制备聚醚碳酸酯多元醇的方法
JP4122064B2 (ja) 官能化ポリマーを含有する二重金属シアン化物触媒
CN100434176C (zh) 不饱和叔醇作为配体在活性dmc催化剂中的应用
KR101466803B1 (ko) 이중금속시안염 촉매 및 이를 제조하는 방법
KR101342899B1 (ko) 새로운 유기 착화물제를 이용하여 합성한 이중금속 시안염 촉매 또는 다중금속 시안염 촉매를 이용한 에폭시계 단량체의 개환 중합에 의한 폴리올 제조
KR101203843B1 (ko) 새로운 유기 착화물제를 이용하여 합성한 이중금속 시안염 촉매 또는 다중금속 시안염 촉매를 이용한 에폭시계 단량체의 개환 중합에 의한 폴리올 제조
CN105051091B (zh) 用于制备具有较低量的高分子量尾料的多元醇的催化剂
KR20020080824A (ko) 폴리올 제조용 복금속 시안계 착화합물 촉매
CN102036749A (zh) 用于制备多元醇的具有可控反应性的双金属氰化物催化剂及其制备方法
KR100908351B1 (ko) 랜덤 폴리올 제조용 복금속 시안계 촉매
KR101129344B1 (ko) 나노 크기 이중금속 혹은 다중금속 시안염 촉매 및 그 제조방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant