CN1036657C - 聚二甲基硅氧烷嵌段共聚物的制备方法 - Google Patents

聚二甲基硅氧烷嵌段共聚物的制备方法 Download PDF

Info

Publication number
CN1036657C
CN1036657C CN93112841A CN93112841A CN1036657C CN 1036657 C CN1036657 C CN 1036657C CN 93112841 A CN93112841 A CN 93112841A CN 93112841 A CN93112841 A CN 93112841A CN 1036657 C CN1036657 C CN 1036657C
Authority
CN
China
Prior art keywords
reaction
hexamethylcyclotrisiloxane
polymerization
polymerizable monomer
anionically polymerizable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN93112841A
Other languages
English (en)
Chinese (zh)
Other versions
CN1089274A (zh
Inventor
R·J·霍克斯梅尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CN1089274A publication Critical patent/CN1089274A/zh
Application granted granted Critical
Publication of CN1036657C publication Critical patent/CN1036657C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicon Polymers (AREA)
  • Graft Or Block Polymers (AREA)
CN93112841A 1992-12-15 1993-12-14 聚二甲基硅氧烷嵌段共聚物的制备方法 Expired - Fee Related CN1036657C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/990,587 US5296574A (en) 1992-12-15 1992-12-15 Method of synthesis of block copolymers of vinyl aromatic hydrocarbons and polydimethylsiloxane
US990587 2001-11-19

Publications (2)

Publication Number Publication Date
CN1089274A CN1089274A (zh) 1994-07-13
CN1036657C true CN1036657C (zh) 1997-12-10

Family

ID=25536303

Family Applications (1)

Application Number Title Priority Date Filing Date
CN93112841A Expired - Fee Related CN1036657C (zh) 1992-12-15 1993-12-14 聚二甲基硅氧烷嵌段共聚物的制备方法

Country Status (11)

Country Link
US (1) US5296574A (2)
EP (1) EP0674676B1 (2)
JP (1) JP3499871B2 (2)
KR (1) KR100279347B1 (2)
CN (1) CN1036657C (2)
BR (1) BR9307638A (2)
DE (1) DE69312737T2 (2)
ES (1) ES2105620T3 (2)
MX (1) MX9307887A (2)
TW (1) TW262483B (2)
WO (1) WO1994013728A2 (2)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5260123A (en) * 1991-06-28 1993-11-09 Bridgestone Corporation Block copolymers of polysiloxanes and copolymers of conjugated dienes and aromatic vinyl compounds, and multilayer structures containing same
US5561210A (en) * 1995-05-30 1996-10-01 Dow Corning Corporation Synthesis of siloxane-functional telechelic hydrocarbon polymers
US5521255A (en) * 1995-05-30 1996-05-28 Dow Corning Corporation Synthesis of silyl-functional telechelic hydrocarbon polymers
JPH11506493A (ja) * 1995-06-06 1999-06-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレン及び環状シロキサンモノマーのアニオン重合ブロックコポリマー
EP1007998A1 (en) 1997-02-11 2000-06-14 Massachusetts Institute Of Technology Polymeric photonic band gap materials
US6031060A (en) * 1997-05-22 2000-02-29 Fmc Corporation Functionalized silicone polymers and processes for making the same
US6020430A (en) * 1998-05-20 2000-02-01 Fmc Corporation Functionalized diene and alkenylsubstituted aromatic silicone copolymers and processes for making the same
US6344521B1 (en) 1998-05-20 2002-02-05 Fmc Corporation Protected functionalized diene and alkenyl substituted aromatic silicone triblock copolymers and processes for making the same
WO2000002090A2 (en) 1998-07-02 2000-01-13 Massachusetts Institute Of Technology Periodic porous and relief nanostructured articles
US6258891B1 (en) 1998-12-03 2001-07-10 Shell Oil Company Solventless process for making polysiloxane polymers
US6090902A (en) * 1998-12-21 2000-07-18 Dow Corning Corporation Organopolysiloxane-modified graft copolymers
FR2802542A1 (fr) * 1999-12-20 2001-06-22 Michelin Soc Tech Composition de caoutchouc vulcanisable pour la fabrication d'un pneumatique et pneumatique dont la bande de roulement comprend une telle composition
KR100332466B1 (ko) 2000-05-17 2002-04-13 박찬구 할로겐으로 치환된 다가 반응성 폴리실록산 화합물 및 그제조방법
AU2002218750A1 (en) * 2000-07-06 2002-01-21 Massachusetts Institute Of Technology Photoactivated drug therapy
JP2002161139A (ja) * 2000-11-24 2002-06-04 Bridgestone Corp ブロック共重合体及びその製造方法、並びに、ゴム組成物
KR100515453B1 (ko) 2004-02-06 2005-09-20 금호석유화학 주식회사 공중합체의 제조방법
CN1986644A (zh) * 2005-12-21 2007-06-27 汉高股份两合公司 稳定的硅烷化聚合物乳液及其制备方法和应用
KR100953492B1 (ko) * 2007-04-13 2010-04-16 주식회사 엘지화학 광학 필름, 위상차 필름 및 이들을 포함하는 액정 표시장치
KR100961383B1 (ko) 2007-05-31 2010-06-07 주식회사 엘지화학 폴리실록산 말단변성 비닐 방향족 탄화수소-공액디엔 블록공중합체 및 이의 제조방법
JP5663146B2 (ja) * 2009-05-29 2015-02-04 株式会社ブリヂストン 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、ゴム組成物、空気入りタイヤ
KR101265254B1 (ko) 2011-10-07 2013-05-16 금호석유화학 주식회사 실리카 보강재에 대한 상용성이 우수한 말단변성 디엔계 공중합체 및 이의 제조방법
JP6558894B2 (ja) 2013-12-31 2019-08-14 ローム アンド ハース エレクトロニック マテリアルズ エルエルシーＲｏｈｍ ａｎｄ Ｈａａｓ Ｅｌｅｃｔｒｏｎｉｃ Ｍａｔｅｒｉａｌｓ ＬＬＣ コポリマーの設計、その製造方法およびそれを含む物品
JP2015129261A (ja) * 2013-12-31 2015-07-16 ローム アンド ハース エレクトロニック マテリアルズ エルエルシーＲｏｈｍ ａｎｄ Ｈａａｓ Ｅｌｅｃｔｒｏｎｉｃ Ｍａｔｅｒｉａｌｓ ＬＬＣ ブロックコポリマーのアニール方法およびブロックコポリマーから製造する物品
JP6702649B2 (ja) 2013-12-31 2020-06-03 ローム アンド ハース エレクトロニック マテリアルズ エルエルシーＲｏｈｍ ａｎｄ Ｈａａｓ Ｅｌｅｃｔｒｏｎｉｃ Ｍａｔｅｒｉａｌｓ ＬＬＣ ブロックコポリマーの性質を制御する方法及びブロックコポリマーから製造された物品
JP6299638B2 (ja) * 2015-03-20 2018-03-28 信越化学工業株式会社 オルガノポリフルオロシロキサンの製造方法
JP7076701B2 (ja) * 2018-03-05 2022-05-30 東京応化工業株式会社 ブロック共重合体及びその製造方法、ならびに相分離構造を含む構造体の製造方法
AU2019371419B2 (en) 2018-11-01 2022-06-16 Ppg Industries Ohio, Inc. Coating compositions containing acid functional polyol polymers and coatings formed therefrom
CN112430431A (zh) * 2020-11-25 2021-03-02 浙江欣苗化工有限公司 一种户外地板水性沥青防腐涂料及其制备方法
CN114763413A (zh) * 2021-01-14 2022-07-19 万华化学集团股份有限公司 一种制备烷基甲氧基硅油方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3051684A (en) * 1959-03-26 1962-08-28 Directors Of The University Of Organosiloxane polymers containing polydiene blocks
US3483270A (en) * 1966-04-11 1969-12-09 Gen Electric Stereospecific organosiloxane-macromolecular hydrocarbon block copolymers
GB1257304A (2) * 1968-03-29 1971-12-15
BR6915744D0 (pt) * 1969-03-10 1973-05-17 Dow Corning Processo para preparar um copolimero de bloco
GB1308459A (en) 1969-06-20 1973-02-21 Dow Corning Ltd Siloxane organic block copolymers
US3665052A (en) * 1970-08-25 1972-05-23 Dow Corning Method of preparing a block copolymer containing a poly-alpha-methylstyrene block and a polydiorganosiloxane block
US3760030A (en) * 1971-06-02 1973-09-18 Gen Electric Multiple sequence block copolymers of silicones and styrene
US3928490A (en) * 1972-03-07 1975-12-23 Firestone Tire & Rubber Co Block polymers of polysiloxanes and polybutadiene
CA1065334A (en) * 1974-12-16 1979-10-30 Eugene R. Martin Silylated polymers and silylated organic-organopolysiloxane block copolymers
US4273896A (en) * 1978-07-12 1981-06-16 Sws Silicones Corporation Silylated polymers and silylated organic-organopolysiloxane block copolymers
FR2436155A1 (fr) * 1978-09-13 1980-04-11 Rhone Poulenc Ind Elastomeres thermoplastiques polystyreniques-diorganopolysiloxaniques
US4768750A (en) * 1987-01-16 1988-09-06 Fisher Controls International, Inc. Valve joint connection

Also Published As

Publication number Publication date
ES2105620T3 (es) 1997-10-16
DE69312737D1 (de) 1997-09-04
JPH08504460A (ja) 1996-05-14
DE69312737T2 (de) 1997-12-04
US5296574A (en) 1994-03-22
WO1994013728A2 (en) 1994-06-23
BR9307638A (pt) 1999-08-31
CN1089274A (zh) 1994-07-13
WO1994013728A3 (en) 1994-08-04
EP0674676B1 (en) 1997-07-30
MX9307887A (es) 1994-06-30
TW262483B (2) 1995-11-11
EP0674676A1 (en) 1995-10-04
KR950704405A (ko) 1995-11-20
KR100279347B1 (ko) 2001-01-15
JP3499871B2 (ja) 2004-02-23

Similar Documents

Publication Publication Date Title
CN1036657C (zh) 聚二甲基硅氧烷嵌段共聚物的制备方法
CN1050144C (zh) 星形聚二甲基硅氧烷嵌段共聚物及其制备方法
EP0413294A2 (en) Narrow molecular weight distribution block polymers and process therefor
EP0255001A2 (en) Bimodal star-block copolymers showing excellent optical properties and resilience, and process for their manufacture
US10889676B2 (en) Method for synthesizing a thermoplastic elastomer comprising at least one poly(α-methylstyrene) block
JP3758703B2 (ja) 工業的に用いうる二官能性陰イオン重合開始剤の製造方法およびその使用
US4427837A (en) Process for preparation of diene-styrene-α-methylstyrene block polymers and polymers therefrom
US5837778A (en) Multifunctional initiator for obtaining star-shaped polymers by an anionic route, process for its manufacture and corresponding star-shaped polymers, process for their manufacture and their applications
JPS6035922B2 (ja) 分板状ブロック共重合物の製法
WO1994013729A2 (en) Process for the preparation of polydimethylsiloxane block copolymers
US4960831A (en) Block copolymer grafting process
EP0682041B1 (en) Process for the preparation of industrially applicable difunctional anionic polymerization initiators and their use
JPH0848709A (ja) 工業的に適用可能な二官能価アニオン重合イニシエーターの製造方法及び該イニシエーターの使用
CA1220588A (en) PROCESS FOR PREPARATION OF DIENE STYRENE .alpha.- METHYLSTYRENE BLOCK POLYMERS AND POLYMERS THEREFROM
US4678837A (en) Multilithium polymerization initiators
CN102120807B (zh) 一种苯乙烯-共轭二烯烃星型嵌段共聚物及其制备方法
JPS6223961B2 (2)
US4640958A (en) Novel coupling agent for star-block copolymers
US7396887B1 (en) Insitu removal of chelator from anionic polymerization reactions
KR910001024B1 (ko) 디엔 스티렌 α-메틸스티렌 블럭 폴리머의 제조방법
US4956415A (en) Preparation of triblock copolymers
WO2004113418A2 (en) Methods for synthesis of graft polymers
JPS6141927B2 (2)
MXPA97003558A (en) Anionic copolymerization of convinced yvinilarene dians in the presence of tetrahydropyranilo-meta alkileters

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 19971210

Termination date: 20100114