CN105200802A - Preparation method of fragrant light-weight thin wool fabric with health function - Google Patents
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Abstract
本发明公开了一种具有保健功能的香氛轻薄羊毛面料的制备方法,包括面料制备、后处理、冷冻处理、乳香微胶囊抗皱整理等步骤。本发明通过对羊毛面料预先进行冷冻处理,再进行乳香微胶囊抗皱整理液浸轧整理,经冷冻处理后的羊毛面料内部纤维内部空隙增大,抗皱整理液深入润湿至纤维内部空隙,聚氨酯树脂与羊毛面料之间附着力增强,乳香通过微胶囊的形式整理到羊毛面料中,利用乳香低温脆高温软以及遇水溶胀的特性,可延长乳香微胶囊的缓释时间,赋予羊毛面料持久的香氛和保健功能。The invention discloses a method for preparing a fragrance light and thin wool fabric with health care function, which comprises the steps of fabric preparation, post-treatment, freezing treatment, frankincense microcapsule anti-wrinkle finishing and the like. In the present invention, the wool fabric is subjected to freezing treatment in advance, and then the frankincense microcapsule anti-wrinkle finishing liquid is applied to pad and roll finishing. After the freezing treatment, the internal fiber internal space of the wool fabric increases, and the anti-wrinkle finishing liquid deeply wets to the internal space of the fiber, and the polyurethane resin The adhesion between the frankincense and the wool fabric is enhanced, and the frankincense is organized into the wool fabric in the form of microcapsules. Using the characteristics of frankincense at low temperature, high temperature, softness and water swelling, the sustained release time of the frankincense microcapsules can be extended, and the wool fabric can be endowed with a long-lasting fragrance. atmosphere and health functions.
Description
技术领域 technical field
本发明涉及面料技术领域,具体涉及一种具有保健功能的香氛轻薄羊毛面料的制备方法。 The invention relates to the technical field of fabrics, in particular to a method for preparing a fragrance light wool fabric with a health care function.
背景技术 Background technique
随着目前纺织品功能化的不断深入,各种多功能面料应运而生。现有技术中的香氛面料主要是基于微胶囊技术,通过将香薰精油包覆在微胶囊中,穿着时面料之间的摩擦或者面料与人体皮肤之间的摩擦使微胶囊破裂,达到缓释的效果,使面料具有比较持久的香氛释放效果。同时,上述香氛面料的香薰精油通过人体呼吸吸收,可以达到一定的药用功能。201110401213.1中公开了一种将乳香微胶囊整理到纱线表面并纺织成面料的技术方案。但是,上述精油微胶囊整理所得面料存在以下技术缺陷:精油大多为非极性分子,不能与人体汗液或皮肤散发的水蒸气进行互溶,面料上的精油除了粘附在皮肤表面,还会分别向皮肤和空气中逸散,皮肤的精油吸收量较小;面料制成的服装需要进行清洗和熨烫,清洗操作和服装熨烫的高温是破坏面料中微胶囊的主要途径,会破坏微胶囊的缓释效果。另外,常温状态下羊毛纤维直径较小,整理液无法深入扩散至细胞内部,浸轧整理效果不佳,手感较差。 With the continuous deepening of the functionalization of textiles, various multifunctional fabrics have emerged as the times require. The fragrance fabrics in the prior art are mainly based on microcapsule technology. By coating the aromatherapy essential oil in the microcapsules, the friction between the fabrics or the friction between the fabrics and human skin will cause the microcapsules to break and achieve slow release. The effect makes the fabric have a relatively long-lasting fragrance release effect. At the same time, the aromatherapy essential oil of the above-mentioned fragrance fabric can be absorbed through human breathing, and can achieve certain medicinal functions. Disclosed in 201110401213.1 is a kind of technical scheme of arranging frankincense microcapsules on the yarn surface and weaving them into fabrics. But above-mentioned essential oil microcapsule finishing gained fabric has the following technical defects: essential oil is mostly non-polar molecule, can not carry out miscibility with human body sweat or the water vapor that skin emits, and the essential oil on the fabric will not only adhere to the skin surface, but also to Escaping from the skin and the air, the absorption of essential oils on the skin is small; clothing made of fabrics needs to be washed and ironed, and the high temperature of cleaning operations and clothing ironing is the main way to destroy the microcapsules in the fabric, which will destroy the microcapsules. Sustained release effect. In addition, the diameter of wool fiber is small at room temperature, and the finishing solution cannot penetrate deeply into the cells, so the padding finishing effect is not good, and the hand feeling is poor.
发明内容 Contents of the invention
本发明的目的在于克服现有技术中存在的缺陷,提供一种具有保健功能的香氛轻薄羊毛面料的制备方法,所得羊毛面料中含有兼具药用价值和香味的乳香树脂,使面料具有持久香味和保健功能。 The purpose of the present invention is to overcome the defects in the prior art, and provide a method for preparing a fragrance light wool fabric with health care function. The obtained wool fabric contains mastic resin with both medicinal value and fragrance, so that the fabric has a long-lasting Fragrance and health function.
为实现上述技术效果,本发明的技术方案为:一种具有保健功能的香氛轻薄羊毛面料的制备方法,其特征在于,包括以下步骤: In order to achieve the above-mentioned technical effects, the technical solution of the present invention is: a method for preparing a fragrance light wool fabric with a health care function, which is characterized in that it comprises the following steps:
S1:按重量比例配置美利奴羊毛和dralon超细异型腈纶纤维,将两种纤维纺成纤度为520~580公支的高支纺纱,然后对高支纺纱进行整经处理,将整经后的高支纺纱作为经纱和纬纱织得羊毛面料; S1: Configure merino wool and dralon superfine special-shaped acrylic fibers according to the weight ratio, spin the two fibers into high-count spinning yarns with a fineness of 520-580 metric counts, and then warp the high-count spinning yarns. The high-count spun yarn after warp is used as warp and weft to weave wool fabric;
S2:后处理,将S1所得布料经连续煮呢、退维、煮呢、烧毛、洗呢、剪毛处理,得羊毛面料半成品; S2: After-treatment, the fabric obtained in S1 is continuously boiled, de-dimensionalized, boiled, singed, washed, and sheared to obtain a semi-finished wool fabric;
S3:冷冻处理,将S2所得羊毛面料半成品置于-5~0℃的温度下静置20~30min; S3: freezing treatment, placing the semi-finished wool fabric obtained in S2 at a temperature of -5~0°C for 20~30min;
S4:乳香微胶囊抗皱整理,将S3所得冷冻处理后的羊毛面料浸渍在乳香微胶囊抗皱整理液中,二浸二轧,经预烘、焙烘,再经水洗烘干,制成保健功能的香氛轻薄羊毛面料成品; S4: Anti-wrinkle finishing with frankincense microcapsules. The frozen wool fabric obtained in S3 is dipped in frankincense microcapsules anti-wrinkle finishing liquid, soaked twice, rolled twice, pre-baked, baked, washed and dried to make a health-care product. Fragrance light wool fabric finished products;
其中,按重量份数计乳香微胶囊抗皱整理液包括:水溶性聚氨酯5~13份、柔软剂0.5~5份、表面活性剂0.01~1份、以纳米级乳香粉为主要囊芯组分的乳香微胶囊4~8份、水70份和柠檬酸,乳香微胶囊抗皱整理液的pH值为3~4。 Among them, the frankincense microcapsule anti-wrinkle finishing solution in parts by weight includes: 5-13 parts of water-soluble polyurethane, 0.5-5 parts of softener, 0.01-1 part of surfactant, and nano-scale frankincense powder as the main capsule core component. 4-8 parts of frankincense microcapsules, 70 parts of water and citric acid, the pH value of the frankincense microcapsules anti-wrinkle finishing solution is 3-4.
通过对羊毛面料进行冷冻处理,羊毛微观结构中纤维内部吸附的水分发生相变,即由液态水转变为固态水,并且伴随体积增大,羊毛纤维直径增大,且内部空隙增大,使整理液能深入浸渍到羊毛内部空隙中,可增加聚氨酯树脂与羊毛纤维之间的接触面积,提高两者之间的粘附力,提高羊毛面料的手感和服用性能。 By freezing the wool fabric, the moisture absorbed inside the fiber in the wool microstructure undergoes a phase change, that is, from liquid water to solid water, and with the increase in volume, the diameter of the wool fiber increases, and the internal voids increase, making finishing The liquid can be deeply impregnated into the internal space of wool, which can increase the contact area between polyurethane resin and wool fiber, improve the adhesion between the two, and improve the feel and wearability of wool fabric.
乳香粉为乳香树脂在低温状态下粉碎所得,乳香树脂为植物树皮渗出的树脂,为香薰原料,乳香含树脂60%~70%,树胶27%~35%,挥发油3%~8%,具有活血行气、通经止痛、消肿生肌的功效,质脆但加热后软化,遇水后表面吸水溶胀变成乳白色,具有粘性。乳香作为囊芯的微胶囊粘附在羊毛织物的表面,微胶囊破裂后乳香可以溶于汗液或皮肤表面蒸发出的水蒸气,由于水溶液的粘性可保证溶胀部分中的绝大部分粘附在皮肤表面,或者嵌入羊毛纤维的鳞片中,这一点有别于现有技术中的乳香精油微胶囊,乳香精油微胶囊破裂之后精油分子向皮肤表面的逸散量少,即最终被皮肤吸收的量少。粘附在皮肤表面的乳香中挥发油通过皮肤渗透或呼吸系统吸入被人体吸收,嵌入羊毛纤维的鳞片中树脂有助于改善干燥环境下羊毛织物的手感和服用性能。 Frankincense powder is obtained by crushing frankincense resin at low temperature. Frankincense resin is the resin exuded from plant bark. It is a raw material for aromatherapy. Frankincense contains 60% to 70% resin, 27% to 35% gum, and 3% to 8% volatile oil. It has the effects of activating blood and promoting qi, dredging menstrual flow, relieving pain, reducing swelling and promoting granulation. It is brittle but softens after heating. After contact with water, the surface absorbs water and swells to become milky white, which is sticky. Frankincense acts as a capsule core microcapsule that adheres to the surface of the wool fabric. After the microcapsule is broken, the frankincense can be dissolved in sweat or water vapor evaporated from the skin surface. The viscosity of the aqueous solution can ensure that most of the swollen part adheres to the skin. surface, or embedded in the scales of wool fibers, which is different from the frankincense essential oil microcapsules in the prior art. After the frankincense essential oil microcapsules are broken, the amount of essential oil molecules that escape to the skin surface is small, that is, the amount that is finally absorbed by the skin is small . The volatile oil in frankincense adhered to the skin surface is absorbed by the human body through skin penetration or inhalation through the respiratory system, and the resin embedded in the scales of wool fibers helps to improve the feel and wearing performance of wool fabrics in dry environments.
常温状态下乳香树脂的质地较硬,高温下其质地变软,因此在常温状态下发生微胶囊囊壁破裂后,剩余囊壁还附着在囊芯表面,水蒸气缓慢溶胀暴露的囊芯直至囊芯消耗完毕;面料高温熨烫时微胶囊可发生适当形变以缓冲其承受压力,保证高温熨烫对微胶囊的破坏,延长面料的香氛缓释时间。另外,经烘焙冷却后的乳香微胶囊经历囊芯形态固态-液态-固态的变化,呈结构稳定的球形或类球形,与液体香精囊芯的微胶囊相比,不易破裂。 The texture of frankincense resin is relatively hard at room temperature, and its texture becomes soft at high temperature. Therefore, after the microcapsule wall ruptures at room temperature, the remaining capsule wall is still attached to the surface of the capsule core, and the water vapor slowly swells the exposed capsule core until the microcapsule wall is broken. The core is consumed; when the fabric is ironed at high temperature, the microcapsules can be properly deformed to buffer the pressure, ensure the damage of the microcapsules by high temperature ironing, and prolong the fragrance release time of the fabric. In addition, the frankincense microcapsules after roasting and cooling undergo the change of capsule core form solid-liquid-solid, and are in a spherical or spherical shape with stable structure.
优选的技术方案为,乳香微胶囊为双层壁材微胶囊,与囊芯接触的内侧壁材主要组分为虫蜡和/或蜂蜡,位于乳香微胶囊外表面的外侧壁材主要组分为海藻酸钠和/或壳聚糖。内侧壁材虫蜡和蜂蜡中游离的脂肪醇与乳香中的乳香酸发生酯化交联作用,对囊芯材料进行有效包覆,从而形成疏水性的微胶囊,外层壁材的作用是在对面料加热熨烫的条件下,保证囊壁不融化。 The preferred technical scheme is that the frankincense microcapsule is a double-wall material microcapsule, the main component of the inner wall material in contact with the capsule core is insect wax and/or beeswax, and the main component of the outer wall material positioned at the outer surface of the frankincense microcapsule is Sodium Alginate and/or Chitosan. The free fatty alcohol in the insect wax and beeswax of the inner wall material and the boswellic acid in the frankincense undergo esterification and cross-linking, which effectively coats the capsule core material to form hydrophobic microcapsules. The function of the outer wall material is to Under the condition of heating and ironing the fabric, ensure that the capsule wall does not melt.
为了保证面料的蓬松度、透湿性、保暖性和服用性能,优选的技术方案为,S1所得羊毛面料中美利奴羊毛的重量占比为50~70%。 In order to ensure the bulkiness, moisture permeability, warmth retention and wearability of the fabric, the preferred technical solution is that the weight of merino wool in the wool fabric obtained in S1 is 50-70%.
优选的技术方案为,乳香微胶囊抗皱整理液还包括乳香微粉0.05~5份,所述乳香微粉的平均粒径为不大于100μm。在乳香微胶囊抗皱整理液中加入乳香微粉,经整理后乳香中的树脂和树胶被分散混合在聚氨酯中,可以赋予面料较浓的初始香氛和保健功能,乳香微粉的平均粒径过大不利于其在水溶液中的快速溶解。 The preferred technical solution is that the frankincense microcapsule anti-wrinkle finishing solution also includes 0.05-5 parts of frankincense micropowder, and the average particle diameter of the frankincense micropowder is not greater than 100 μm. Add frankincense micro-powder to frankincense microcapsule anti-wrinkle finishing solution. After finishing, the resin and gum in frankincense are dispersed and mixed in polyurethane, which can give the fabric a strong initial fragrance and health care function. If the average particle size of frankincense micro-powder is too large Facilitate its rapid dissolution in aqueous solution.
优选的技术方案为,乳香微胶囊抗皱整理液的配制方法为:将乳香微粉加入部分水中,高速剪切分散,加热至90~95℃保温2~5min,继续高速剪切分散冷却至室温,得到抗皱整理液A混合液;将水溶性聚氨酯、柔软剂、表面活性剂、以乳香为囊芯的乳香微胶囊依次添加到剩余的水中,搅拌混匀,得到抗皱整理液B混合液,将抗皱整理液A混合液与抗皱整理液B混合液混合搅拌均匀,配置成乳香微胶囊抗皱整理液。上述配制方法可使乳香组分更均匀的分散于整理液中,形成均一的分散液。 The preferred technical solution is that the preparation method of the frankincense microcapsules anti-wrinkle finishing solution is as follows: add the frankincense micropowder to part of the water, disperse with high speed shear, heat to 90~95°C and keep it for 2~5 minutes, continue to disperse with high speed shear and cool to room temperature to obtain Anti-wrinkle finishing solution A mixed solution; add water-soluble polyurethane, softener, surfactant, and frankincense microcapsules with frankincense as the capsule core to the remaining water in sequence, stir and mix well to obtain anti-wrinkle finishing solution B mixed solution, and put anti-wrinkle finishing solution The mixed solution of solution A and the mixed solution of anti-wrinkle finishing solution B are mixed and stirred evenly, and the frankincense microcapsule anti-wrinkle finishing solution is prepared. The above preparation method can disperse the frankincense component in the finishing liquid more uniformly and form a uniform dispersion liquid.
优选的技术方案为,S4中乳香微胶囊抗皱整理液的温度为5~10℃,浸渍时间为4~10min,浴比为1:(15~25)。较低的抗皱整理液浸轧温度可以维持冷冻处理后羊毛纤维的较大内部空隙,保证整理液的升入渗透。 The preferred technical solution is that the temperature of the frankincense microcapsule anti-wrinkle finishing solution in S4 is 5-10°C, the soaking time is 4-10 minutes, and the bath ratio is 1: (15-25). The lower padding temperature of the anti-wrinkle finishing solution can maintain the larger internal voids of the wool fiber after freezing treatment, and ensure the penetration of the finishing solution.
较高的焙烘温度会导致微胶囊的囊壁融化,海藻酸钠和壳聚糖都具有较高的熔点,而作为内侧壁材的虫蜡和蜂蜡融化则会对其内的乳香形成更有效的包覆,有助于增强微胶囊的整体强度,优选的技术方案为,S4中预烘温度为50~60℃,预烘时间为2~5min;焙烘温度为95~115℃,所述焙烘时间为5~13min。 Higher baking temperature will cause the capsule wall of microcapsules to melt, sodium alginate and chitosan have higher melting points, and the melting of insect wax and beeswax as the inner wall material will be more effective for the formation of frankincense inside The coating helps to enhance the overall strength of the microcapsules. The preferred technical solution is that the pre-baking temperature in S4 is 50-60 °C, and the pre-baking time is 2-5 minutes; the baking temperature is 95-115 °C. The baking time is 5~13min.
优选的技术方案为,乳香微胶囊的囊芯还包括纳米级海泡石粉末,囊芯中纳米级海泡石粉末与乳香的重量比为1:(2~3)。纳米级海泡石粉末可以吸附穿着者体表的异味,保证乳香所散发出的香味更完整。 The preferred technical solution is that the capsule core of the frankincense microcapsules also includes nano-scale sepiolite powder, and the weight ratio of the nano-scale sepiolite powder to the frankincense in the capsule core is 1: (2~3). Nano-scale sepiolite powder can absorb the peculiar smell of the wearer's body surface, ensuring a more complete fragrance of frankincense.
优选的技术方案为,柔软剂为选自含聚醚基团的氨基化聚硅氧烷和季铵型阳离子聚氨酯基聚醚嵌段亲水性有机硅柔软剂中的至少一种。分子结构中聚醚基团的引入使氨基聚有机硅柔软剂具备了亲水性并降低了黄变性,柔软剂分子间的空间位阻特别小,分子主链柔顺,可赋予羊毛面料独特的“柔糯”柔软风格,可改善羊毛面料因粘附微胶囊的较硬手感且不影响羊毛面料的亲水性。 The preferred technical solution is that the softener is at least one selected from aminated polysiloxanes containing polyether groups and quaternary ammonium cationic polyurethane-based polyether block hydrophilic silicone softeners. The introduction of polyether groups in the molecular structure makes the amino polysilicone softener hydrophilic and reduces yellowing. The steric hindrance between the softener molecules is particularly small, and the main chain of the molecule is supple, which can endow the wool fabric with a unique " "Soft and waxy" soft style, which can improve the hard feel of wool fabrics due to the adhesion of microcapsules without affecting the hydrophilicity of wool fabrics.
优选的技术方案为,表面活性剂为由刚性联接基团-CH2-联结的双季铵盐型双子表面活性剂。双季铵盐型双子表面活性剂CMC值较高,可降低整理液的表面张力,使其达到更深入渗透的目的。 The preferred technical solution is that the surfactant is a diquaternary ammonium salt type gemini surfactant linked by a rigid linking group -CH 2 -. The double quaternary ammonium salt type gemini surfactant has a higher CMC value, which can reduce the surface tension of the finishing solution and make it penetrate more deeply.
本发明的优点和有益效果在于: Advantage and beneficial effect of the present invention are:
本发明通过对羊毛面料预先进行冷冻处理,再进行乳香微胶囊抗皱整理液浸轧整理,经冷冻处理后的羊毛面料内部纤维内部空隙增大,抗皱整理液深入润湿至纤维内部空隙,聚氨酯树脂与羊毛面料之间附着力增强,乳香通过微胶囊的形式整理到羊毛面料中,利用乳香低温脆高温软以及遇水溶胀的特性,延长乳香微胶囊的缓释时间,赋予羊毛面料持久的香氛和保健功能。 In the present invention, the wool fabric is subjected to freezing treatment in advance, and then the frankincense microcapsule anti-wrinkle finishing liquid is applied to pad and roll finishing. After the freezing treatment, the internal fiber internal space of the wool fabric increases, and the anti-wrinkle finishing liquid deeply wets to the internal space of the fiber, and the polyurethane resin The adhesion between the frankincense and the wool fabric is enhanced, and the frankincense is organized into the wool fabric in the form of microcapsules. Using the characteristics of frankincense at low temperature, high temperature, softness and water swelling, the sustained release time of the frankincense microcapsules is extended, and the wool fabric is endowed with a long-lasting fragrance. and health functions.
具体实施方式 Detailed ways
下面结合实施例,对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。 The specific implementation of the present invention will be further described below in conjunction with the examples. The following examples are only used to illustrate the technical solution of the present invention more clearly, but not to limit the protection scope of the present invention.
实施例1 Example 1
一种具有保健功能的香氛轻薄羊毛面料的制备方法包括以下步骤: A method for preparing a fragrance light wool fabric with a health care function comprises the following steps:
S1:按重量比例配置美利奴羊毛和dralon超细异型腈纶纤维,将两种纤维纺成纤度为520公支的高支纺纱,然后对高支纺纱进行整经处理,将整经后的高支纺纱作为经纱和纬纱织得羊毛面料; S1: Configure merino wool and dralon superfine special-shaped acrylic fibers according to the weight ratio, spin the two fibers into high-count spinning yarns with a fineness of 520 metric counts, and then warp the high-count spinning yarns. The high-count spinning yarn is used as warp and weft to weave wool fabric;
S2:后处理,将S1所得布料经连续煮呢、退维、煮呢、烧毛、洗呢、剪毛处理,得羊毛面料半成品; S2: After-treatment, the fabric obtained in S1 is continuously boiled, de-dimensionalized, boiled, singed, washed, and sheared to obtain a semi-finished wool fabric;
S3:冷冻处理,将S2所得羊毛面料半成品置于-2~0℃的温度下静置20min; S3: freezing treatment, placing the semi-finished wool fabric obtained in S2 at a temperature of -2 to 0°C for 20 minutes;
S4:乳香微胶囊抗皱整理,将S3所得冷冻处理后的羊毛面料浸渍在乳香微胶囊抗皱整理液中,二浸二轧,经预烘、焙烘,再经水洗烘干,制成保健功能的香氛轻薄羊毛面料成品; S4: Anti-wrinkle finishing with frankincense microcapsules. The frozen wool fabric obtained in S3 is dipped in frankincense microcapsules anti-wrinkle finishing liquid, soaked twice, rolled twice, pre-baked, baked, washed and dried to make a health-care product. Fragrance light wool fabric finished products;
其中,按重量份数计乳香微胶囊抗皱整理液包括:水溶性聚氨酯13份、柔软剂0.5份、表面活性剂1份、以纳米级乳香粉为主要囊芯组分的乳香微胶囊4份、水70份和柠檬酸,乳香微胶囊抗皱整理液的pH值为4。 Wherein, the frankincense microcapsule anti-wrinkle finishing solution in parts by weight includes: 13 parts of water-soluble polyurethane, 0.5 part of softener, 1 part of surfactant, 4 parts of frankincense microcapsules with nano-scale frankincense powder as the main capsule core component, 70 parts of water and citric acid, the pH value of frankincense microcapsule anti-wrinkle finishing solution is 4.
乳香微胶囊为双层壁材微胶囊,与囊芯接触的内侧壁材主要组分为虫蜡,位于乳香微胶囊外表面的外侧壁材主要组分为海藻酸钠。 The frankincense microcapsule is a double wall material microcapsule, the main component of the inner wall material in contact with the capsule core is insect wax, and the main component of the outer wall material located on the outer surface of the frankincense microcapsule is sodium alginate.
S1所得羊毛面料中美利奴羊毛的重量占比为50%。 The weight ratio of merino wool in the wool fabric obtained in S1 is 50%.
乳香微胶囊抗皱整理液还包括乳香微粉5份,乳香微粉的平均粒径为50μm。 The frankincense microcapsule anti-wrinkle finishing liquid also includes 5 parts of frankincense micropowder, and the average particle diameter of frankincense micropowder is 50 μm.
乳香微胶囊抗皱整理液的配制方法为:将乳香微粉加入部分水中,高速剪切分散,加热至95℃保温2min,继续高速剪切分散冷却至室温,得到抗皱整理液A混合液;将水溶性聚氨酯、柔软剂、表面活性剂、以乳香为囊芯的乳香微胶囊依次添加到剩余的水中,搅拌混匀,得到抗皱整理液B混合液,将抗皱整理液A混合液与抗皱整理液B混合液混合搅拌均匀,配置成乳香微胶囊抗皱整理液。 The preparation method of frankincense microcapsules anti-wrinkle finishing solution is as follows: add frankincense micro-powder into part of water, high-speed shear dispersion, heat to 95°C for 2 minutes, continue high-speed shear dispersion and cool to room temperature to obtain anti-wrinkle finishing solution A mixed solution; water-soluble Polyurethane, softener, surfactant, and frankincense microcapsules with frankincense as the capsule core are sequentially added to the remaining water, stirred and mixed to obtain the anti-wrinkle finishing solution B mixed solution, and the anti-wrinkle finishing solution A mixed solution is mixed with the anti-wrinkle finishing solution B The liquid is mixed and stirred evenly, and is configured into the frankincense microcapsule anti-wrinkle finishing liquid.
S4中乳香微胶囊抗皱整理液的温度为10℃,浸渍时间为4min,浴比为1:25。 The temperature of frankincense microcapsule anti-wrinkle finishing solution in S4 is 10°C, the soaking time is 4min, and the liquor ratio is 1:25.
S4中预烘温度为50℃,预烘时间为5min;焙烘温度为95℃,焙烘时间为13min。 In S4, the pre-baking temperature is 50°C, and the pre-baking time is 5 minutes; the baking temperature is 95°C, and the baking time is 13 minutes.
乳香微胶囊的囊芯还包括纳米级海泡石粉末,囊芯中纳米级海泡石粉末与乳香的重量比为1:2。 The capsule core of the frankincense microcapsules also includes nano-scale sepiolite powder, and the weight ratio of the nano-scale sepiolite powder to the frankincense in the capsule core is 1:2.
柔软剂为含聚醚基团的氨基化聚硅氧烷。 The softener is aminated polysiloxane containing polyether groups.
表面活性剂为由刚性联接基团-CH2-联结的双季铵盐型双子表面活性剂。 The surfactant is a diquaternary ammonium salt type gemini surfactant linked by a rigid linking group -CH 2 -.
实施例2 Example 2
一种具有保健功能的香氛轻薄羊毛面料的制备方法包括以下步骤: A method for preparing a fragrance light wool fabric with a health care function comprises the following steps:
S1:按重量比例配置美利奴羊毛和dralon超细异型腈纶纤维,将两种纤维纺成纤度为550公支的高支纺纱,然后对高支纺纱进行整经处理,将整经后的高支纺纱作为经纱和纬纱织得羊毛面料; S1: Configure merino wool and dralon superfine special-shaped acrylic fibers according to the weight ratio, spin the two fibers into high-count spinning yarns with a fineness of 550 metric counts, and then warp the high-count spinning yarns. The high-count spinning yarn is used as warp and weft to weave wool fabric;
S2:后处理,将S1所得布料经连续煮呢、退维、煮呢、烧毛、洗呢、剪毛处理,得羊毛面料半成品; S2: After-treatment, the fabric obtained in S1 is continuously boiled, de-dimensionalized, boiled, singed, washed, and sheared to obtain a semi-finished wool fabric;
S3:冷冻处理,将S2所得羊毛面料半成品置于-4~-2℃的温度下静置25min; S3: freezing treatment, placing the semi-finished wool fabric obtained in S2 at a temperature of -4~-2°C for 25 minutes;
S4:乳香微胶囊抗皱整理,将S3所得冷冻处理后的羊毛面料浸渍在乳香微胶囊抗皱整理液中,二浸二轧,经预烘、焙烘,再经水洗烘干,制成保健功能的香氛轻薄羊毛面料成品; S4: Anti-wrinkle finishing with frankincense microcapsules. The frozen wool fabric obtained in S3 is dipped in frankincense microcapsules anti-wrinkle finishing liquid, soaked twice, rolled twice, pre-baked, baked, washed and dried to make a health-care product. Fragrance light wool fabric finished products;
其中,按重量份数计乳香微胶囊抗皱整理液包括:水溶性聚氨酯9份、柔软剂2.5份、表面活性剂0.5份、以纳米级乳香粉为主要囊芯组分的乳香微胶囊6份、水70份和柠檬酸,乳香微胶囊抗皱整理液的pH值为3.5。 Wherein, the frankincense microcapsule anti-wrinkle finishing solution in parts by weight includes: 9 parts of water-soluble polyurethane, 2.5 parts of softening agent, 0.5 part of surfactant, 6 parts of frankincense microcapsules with nano-scale frankincense powder as the main capsule core component, 70 parts of water and citric acid, the pH value of frankincense microcapsules anti-wrinkle finishing solution is 3.5.
乳香微胶囊为双层壁材微胶囊,与囊芯接触的内侧壁材主要组分为蜂蜡,位于乳香微胶囊外表面的外侧壁材主要组分为壳聚糖。 The frankincense microcapsule is a double-layer wall material microcapsule, the main component of the inner wall material in contact with the capsule core is beeswax, and the main component of the outer wall material located on the outer surface of the frankincense microcapsule is chitosan.
S1所得羊毛面料中美利奴羊毛的重量占比为60%。 The weight ratio of merino wool in the wool fabric obtained in S1 is 60%.
乳香微胶囊抗皱整理液还包括乳香微粉2.5份,乳香微粉的平均粒径为不大于65~95μm。 The frankincense microcapsule anti-wrinkle finishing liquid also includes 2.5 parts of frankincense micropowder, and the average particle diameter of frankincense micropowder is not greater than 65-95 μm.
乳香微胶囊抗皱整理液的配制方法为:将乳香微粉加入部分水中,高速剪切分散,加热至92℃保温3.5min,继续高速剪切分散冷却至室温,得到抗皱整理液A混合液;将水溶性聚氨酯、柔软剂、表面活性剂、以乳香为囊芯的乳香微胶囊依次添加到剩余的水中,搅拌混匀,得到抗皱整理液B混合液,将抗皱整理液A混合液与抗皱整理液B混合液混合搅拌均匀,配置成乳香微胶囊抗皱整理液。 The preparation method of frankincense microcapsules anti-wrinkle finishing solution is as follows: add frankincense micro-powder into part of water, high-speed shear dispersion, heat to 92°C for 3.5 minutes, continue high-speed shear dispersion and cool to room temperature to obtain anti-wrinkle finishing solution A mixed solution; Active polyurethane, softener, surfactant, and frankincense microcapsules with frankincense as the capsule core are sequentially added to the remaining water, stirred and mixed to obtain the anti-wrinkle finishing solution B mixed solution, and the anti-wrinkle finishing solution A mixed solution and the anti-wrinkle finishing solution B The mixed liquid is mixed and stirred evenly, and is configured into frankincense microcapsule anti-wrinkle finishing liquid.
S4中乳香微胶囊抗皱整理液的温度为7.5℃,浸渍时间为7min,浴比为1:20。 The temperature of frankincense microcapsule anti-wrinkle finishing solution in S4 is 7.5°C, the soaking time is 7min, and the liquor ratio is 1:20.
S4中预烘温度为55℃,预烘时间为3.5min;焙烘温度为105℃,焙烘时间为9min。 In S4, the pre-baking temperature is 55°C, and the pre-baking time is 3.5 minutes; the baking temperature is 105°C, and the baking time is 9 minutes.
乳香微胶囊的囊芯还包括纳米级海泡石粉末,囊芯中纳米级海泡石粉末与乳香的重量比为2:5。 The capsule core of the frankincense microcapsules also includes nano-scale sepiolite powder, and the weight ratio of the nano-scale sepiolite powder to the frankincense in the capsule core is 2:5.
柔软剂为季铵型阳离子聚氨酯基聚醚嵌段亲水性有机硅柔软剂。 The softener is a quaternary ammonium cationic polyurethane-based polyether block hydrophilic silicone softener.
表面活性剂为由刚性联接基团-CH2-联结的双季铵盐型双子表面活性剂。 The surfactant is a diquaternary ammonium salt type gemini surfactant linked by a rigid linking group -CH 2 -.
实施例3 Example 3
一种具有保健功能的香氛轻薄羊毛面料的制备方法包括以下步骤: A method for preparing a fragrance light wool fabric with a health care function comprises the following steps:
S1:按重量比例配置美利奴羊毛和dralon超细异型腈纶纤维,将两种纤维纺成纤度为580公支的高支纺纱,然后对高支纺纱进行整经处理,将整经后的高支纺纱作为经纱和纬纱织得羊毛面料; S1: Configure merino wool and dralon superfine special-shaped acrylic fibers according to the weight ratio, spin the two fibers into high-count spinning yarns with a fineness of 580 metric counts, and then warp the high-count spinning yarns. The high-count spinning yarn is used as warp and weft to weave wool fabric;
S2:后处理,将S1所得布料经连续煮呢、退维、煮呢、烧毛、洗呢、剪毛处理,得羊毛面料半成品; S2: After-treatment, the fabric obtained in S1 is continuously boiled, de-dimensionalized, boiled, singed, washed, and sheared to obtain a semi-finished wool fabric;
S3:冷冻处理,将S2所得羊毛面料半成品置于-5~-4℃的温度下静置30min; S3: freezing treatment, placing the semi-finished woolen fabric obtained in S2 at a temperature of -5~-4°C for 30 minutes;
S4:乳香微胶囊抗皱整理,将S3所得冷冻处理后的羊毛面料浸渍在乳香微胶囊抗皱整理液中,二浸二轧,经预烘、焙烘,再经水洗烘干,制成保健功能的香氛轻薄羊毛面料成品; S4: Anti-wrinkle finishing with frankincense microcapsules. The frozen wool fabric obtained in S3 is dipped in frankincense microcapsules anti-wrinkle finishing liquid, soaked twice, rolled twice, pre-baked, baked, washed and dried to make a health-care product. Fragrance light wool fabric finished products;
其中,按重量份数计乳香微胶囊抗皱整理液包括:水溶性聚氨酯5份、柔软剂5份、表面活性剂0.01份、以纳米级乳香粉为主要囊芯组分的乳香微胶囊8份、水70份和柠檬酸,乳香微胶囊抗皱整理液的pH值为3。 Wherein, the frankincense microcapsule anti-wrinkle finishing solution in parts by weight includes: 5 parts of water-soluble polyurethane, 5 parts of softening agent, 0.01 part of surfactant, 8 parts of frankincense microcapsules with nano-scale frankincense powder as the main capsule core component, 70 parts of water and citric acid, the pH value of frankincense microcapsule anti-wrinkle finishing liquid is 3.
乳香微胶囊为双层壁材微胶囊,与囊芯接触的内侧壁材主要组分为虫蜡和蜂蜡,位于乳香微胶囊外表面的外侧壁材主要组分为海藻酸钠和壳聚糖。 The frankincense microcapsules are double-layer wall material microcapsules, the main components of the inner wall material in contact with the capsule core are insect wax and beeswax, and the main components of the outer wall material located on the outer surface of the frankincense microcapsules are sodium alginate and chitosan.
S1所得羊毛面料中美利奴羊毛的重量占比为70%。 The weight ratio of merino wool in the wool fabric obtained in S1 is 70%.
乳香微胶囊抗皱整理液还包括乳香微粉0.05份,乳香微粉的平均粒径为40~60μm。 The frankincense microcapsule anti-wrinkle finishing liquid also includes 0.05 parts of frankincense micropowder, and the average particle diameter of frankincense micropowder is 40-60 μm.
乳香微胶囊抗皱整理液的配制方法为:将乳香微粉加入部分水中,高速剪切分散,加热至95℃保温2min,继续高速剪切分散冷却至室温,得到抗皱整理液A混合液;将水溶性聚氨酯、柔软剂、表面活性剂、以乳香为囊芯的乳香微胶囊依次添加到剩余的水中,搅拌混匀,得到抗皱整理液B混合液,将抗皱整理液A混合液与抗皱整理液B混合液混合搅拌均匀,配置成乳香微胶囊抗皱整理液。 The preparation method of frankincense microcapsules anti-wrinkle finishing solution is as follows: add frankincense micro-powder into part of water, high-speed shear dispersion, heat to 95°C for 2 minutes, continue high-speed shear dispersion and cool to room temperature to obtain anti-wrinkle finishing solution A mixed solution; water-soluble Polyurethane, softener, surfactant, and frankincense microcapsules with frankincense as the capsule core are sequentially added to the remaining water, stirred and mixed to obtain the anti-wrinkle finishing solution B mixed solution, and the anti-wrinkle finishing solution A mixed solution is mixed with the anti-wrinkle finishing solution B The liquid is mixed and stirred evenly, and is configured into the frankincense microcapsule anti-wrinkle finishing liquid.
S4中乳香微胶囊抗皱整理液的温度为10℃,浸渍时间为4min,浴比为1:15。 The temperature of frankincense microcapsule anti-wrinkle finishing solution in S4 is 10°C, the soaking time is 4min, and the bath ratio is 1:15.
S4中预烘温度为60℃,预烘时间为2min;焙烘温度为115℃,焙烘时间为5min。 In S4, the pre-baking temperature is 60°C, and the pre-baking time is 2 minutes; the baking temperature is 115°C, and the baking time is 5 minutes.
乳香微胶囊的囊芯还包括纳米级海泡石粉末,囊芯中纳米级海泡石粉末与乳香的重量比为1:3。 The capsule core of the frankincense microcapsules also includes nano-scale sepiolite powder, and the weight ratio of the nano-scale sepiolite powder to the frankincense in the capsule core is 1:3.
柔软剂为含聚醚基团的氨基化聚硅氧烷和季铵型阳离子聚氨酯基聚醚嵌段亲水性有机硅柔软剂重量比1:1的混合物。 The softener is a mixture of aminated polysiloxane containing polyether groups and a quaternary ammonium cationic polyurethane-based polyether block hydrophilic silicone softener in a weight ratio of 1:1.
表面活性剂为由刚性联接基团-CH2-联结的双季铵盐型双子表面活性剂。 The surfactant is a diquaternary ammonium salt type gemini surfactant linked by a rigid linking group -CH 2 -.
对比例1 Comparative example 1
对比例1中的试样不经过冷冻处理,其余工艺条件同实施例2。 The sample in Comparative Example 1 was not subjected to freezing treatment, and the rest of the process conditions were the same as in Example 2.
对比例2 Comparative example 2
对比例2中的乳香微胶囊抗皱整理液中乳香微胶囊为单层结构,即不包含位于乳香微胶囊外表面的外侧壁材,其余工艺条件同实施例2。 The frankincense microcapsules in the frankincense microcapsules anti-wrinkle finishing solution in Comparative Example 2 have a single-layer structure, that is, the outer wall material located on the outer surface of the frankincense microcapsules is not included, and the rest of the process conditions are the same as in Example 2.
对比例3 Comparative example 3
对比例3中的乳香微胶囊抗皱整理液中不含乳香微粉。 The frankincense microcapsule anti-wrinkle finishing solution in Comparative Example 3 does not contain frankincense micropowder.
香氛经人工感官对比,对比例3的试样初始香味远低于实施例2; Fragrance is compared by artificial sensory, and the sample initial fragrance of comparative example 3 is far lower than embodiment 2;
试样经称重对比,相同重量的试样经乳香微胶囊抗皱整理液干燥后,对比例1的重量增加略小于实施例2; The samples were compared by weighing, and after the samples of the same weight were dried through the frankincense microcapsule anti-wrinkle finishing solution, the weight increase of Comparative Example 1 was slightly less than that of Example 2;
试样经20次常温清洗和10次120~130℃熨烫,将试样置于高倍显微镜下观察,相同面积下实施例2的微胶囊个数比对比例2试样多30~40%。 After the sample was washed at room temperature for 20 times and ironed at 120-130°C for 10 times, the sample was observed under a high-power microscope. The number of microcapsules in Example 2 was 30-40% more than that in Comparative Example 2 under the same area.
实施例1-3中微胶囊的制备方法包括以下步骤: The preparation method of microcapsules in embodiment 1-3 comprises the following steps:
1、制备乳香海泡石复合微粉:将重量分数乳香树脂1份置于10份水中,升温至90~95℃,水混合溶液进行高速剪切20~40min,静置降温至室温,得乳香水溶液,按照乳香与纳米级海泡石粉末将乳香水溶液和纳米级海泡石粉末加入球磨机中,球磨1~4h,球磨机内温度保持在5~10℃,球磨所得混合液经冷冻干燥,得乳香海泡石复合微粉; 1. Preparation of frankincense sepiolite composite micropowder: Put 1 part of frankincense resin in 10 parts of water by weight, heat up to 90~95°C, perform high-speed shearing on the water mixed solution for 20~40min, let stand and cool down to room temperature, and obtain frankincense aqueous solution According to the frankincense and nano-scale sepiolite powder, add frankincense aqueous solution and nano-scale sepiolite powder into the ball mill, ball mill for 1-4 hours, keep the temperature in the ball mill at 5-10°C, and freeze-dry the mixed solution obtained from ball milling to obtain frankincense sea Paolite composite micropowder;
2、采用空气悬浮喷涂法将内侧壁材包覆在乳香海泡石复合微粉外表面。 2. Use the air suspension spraying method to coat the inner wall material on the outer surface of the frankincense sepiolite composite micropowder.
内侧壁材包覆乳香海泡石复合微粉的具体操作为:将内侧壁材溶解于溶剂中形成内侧壁材溶液(重量百分比为20~25%),用流化床将乳香海泡石复合微粉悬浮在空气中,用喷枪在3-5atm的压力下喷到囊芯表面,溶剂挥发,壁材附着在颗粒表面。可进行上述多次喷雾包覆,以达到预定的壁材厚度。 The specific operation of coating the mastic and sepiolite composite micropowder on the inner wall material is as follows: dissolve the inner wall material in a solvent to form an inner wall material solution (20~25% by weight), and use a fluidized bed to mix the mastic and sepiolite composite micropowder Suspended in the air, use a spray gun to spray on the surface of the capsule core under the pressure of 3-5atm, the solvent will volatilize, and the wall material will adhere to the particle surface. The above-mentioned spray coating can be carried out several times to achieve the predetermined thickness of the wall material.
3、采用喷雾冷凝法将外侧壁材依次包覆在乳香海泡石复合微粉外表面。 3. Use the spray condensation method to coat the outer wall material on the outer surface of the frankincense sepiolite composite micropowder in turn.
重量百分比为2~3%海藻酸钠壁材溶液与乳香海泡石复合微粉均匀混合后,通过喷雾器喷嘴雾化后喷入重量百分比2~3%氯化钙溶液中,钙离子与海藻酸钠交联反应形成微胶囊。 2~3% by weight of sodium alginate wall material solution and frankincense sepiolite composite micropowder are uniformly mixed, sprayed into 2~3% by weight of calcium chloride solution after atomization through the nozzle of the sprayer, calcium ions and sodium alginate The cross-linking reaction forms microcapsules.
虽然海藻酸钠和壳聚糖均可形成具有一定弹性的壁材,相比较而言,海藻酸钠具有更高的熔点,可以应对面料的高温熨烫操作。 Although both sodium alginate and chitosan can form a wall material with certain elasticity, in comparison, sodium alginate has a higher melting point and can cope with high-temperature ironing operations of fabrics.
该面料适用于制作秋冬季衬衫面料,贴身穿着状态下乳香中的乳香酸等有效组分能被人体更好的吸收。 The fabric is suitable for making autumn and winter shirt fabrics, and effective components such as boswellic acid in frankincense can be better absorbed by the human body when worn next to the body.
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。 The above is only a preferred embodiment of the present invention, it should be pointed out that for those of ordinary skill in the art, without departing from the technical principle of the present invention, some improvements and modifications can also be made. These improvements and modifications It should also be regarded as the protection scope of the present invention.
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