CN1053124C - 烟道气处理系统 - Google Patents
烟道气处理系统 Download PDFInfo
- Publication number
- CN1053124C CN1053124C CN95121714A CN95121714A CN1053124C CN 1053124 C CN1053124 C CN 1053124C CN 95121714 A CN95121714 A CN 95121714A CN 95121714 A CN95121714 A CN 95121714A CN 1053124 C CN1053124 C CN 1053124C
- Authority
- CN
- China
- Prior art keywords
- slurry
- flue gas
- running status
- value
- absorption tower
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003546 flue gas Substances 0.000 title claims abstract description 99
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 239000002002 slurry Substances 0.000 claims abstract description 130
- 229940043430 calcium compound Drugs 0.000 claims abstract description 33
- 150000001674 calcium compounds Chemical class 0.000 claims abstract description 33
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 24
- 230000023556 desulfurization Effects 0.000 claims abstract description 24
- 239000000428 dust Substances 0.000 claims abstract description 14
- 238000001514 detection method Methods 0.000 claims abstract description 13
- 238000010521 absorption reaction Methods 0.000 claims description 114
- 239000003153 chemical reaction reagent Substances 0.000 claims description 91
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 76
- 239000012716 precipitator Substances 0.000 claims description 38
- 239000010440 gypsum Substances 0.000 claims description 20
- 229910052602 gypsum Inorganic materials 0.000 claims description 20
- 239000012535 impurity Substances 0.000 claims description 20
- 230000001276 controlling effect Effects 0.000 claims description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 10
- 239000000523 sample Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 230000001105 regulatory effect Effects 0.000 claims description 9
- 239000002250 absorbent Substances 0.000 abstract description 85
- 230000002745 absorbent Effects 0.000 abstract description 85
- 239000007789 gas Substances 0.000 abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 11
- 230000004044 response Effects 0.000 abstract description 5
- 239000002585 base Substances 0.000 description 79
- 235000019738 Limestone Nutrition 0.000 description 23
- 239000006028 limestone Substances 0.000 description 22
- 230000009467 reduction Effects 0.000 description 20
- 230000000694 effects Effects 0.000 description 14
- 239000003513 alkali Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000010586 diagram Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000008186 active pharmaceutical agent Substances 0.000 description 5
- 239000004020 conductor Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000002912 waste gas Substances 0.000 description 3
- 239000002956 ash Substances 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000008141 laxative Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001543 purgative effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/346—Controlling the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/504—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP96773/95 | 1995-04-21 | ||
| JP09677395A JP3272565B2 (ja) | 1995-04-21 | 1995-04-21 | 排煙処理装置 |
| JP96773/1995 | 1995-04-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1133750A CN1133750A (zh) | 1996-10-23 |
| CN1053124C true CN1053124C (zh) | 2000-06-07 |
Family
ID=14173961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95121714A Expired - Fee Related CN1053124C (zh) | 1995-04-21 | 1995-12-28 | 烟道气处理系统 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5770161A (fr) |
| EP (1) | EP0738537B1 (fr) |
| JP (1) | JP3272565B2 (fr) |
| KR (1) | KR0158541B1 (fr) |
| CN (1) | CN1053124C (fr) |
| DK (1) | DK0738537T3 (fr) |
| ES (1) | ES2170194T3 (fr) |
| IN (1) | IN191869B (fr) |
| PL (3) | PL183093B1 (fr) |
| TR (1) | TR199600022A2 (fr) |
| TW (1) | TW303420B (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100483081C (zh) * | 2005-03-10 | 2009-04-29 | 上海昌吉地质仪器有限公司 | 水下砼灌注标高定位仪 |
| CN101995345B (zh) * | 2009-08-11 | 2012-12-12 | 大连华城电子有限公司 | 烟气脱硫ph值测量装置 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7536232B2 (en) * | 2004-08-27 | 2009-05-19 | Alstom Technology Ltd | Model predictive control of air pollution control processes |
| US7522963B2 (en) * | 2004-08-27 | 2009-04-21 | Alstom Technology Ltd | Optimized air pollution control |
| JP4850162B2 (ja) * | 2007-10-15 | 2012-01-11 | 中国電力株式会社 | 排ガス脱硫装置におけるガス/ガス熱交換器の水洗方法 |
| CN102188894B (zh) * | 2010-03-08 | 2013-08-14 | 华北电力科学研究院有限责任公司 | 一种烟道脱硫吸收剂供应方法及系统 |
| JP5598245B2 (ja) * | 2010-10-15 | 2014-10-01 | 栗田工業株式会社 | 酸性ガスの処理方法 |
| JP5834469B2 (ja) * | 2011-04-27 | 2015-12-24 | 栗田工業株式会社 | 酸性ガスの処理方法 |
| KR101326812B1 (ko) * | 2011-05-17 | 2013-11-07 | 현대자동차 주식회사 | 배기가스 후처리 방법 |
| JP5898885B2 (ja) * | 2011-08-30 | 2016-04-06 | 千代田化工建設株式会社 | 排煙脱硫装置における不活性化現象の予防方法 |
| JP6223654B2 (ja) * | 2011-10-31 | 2017-11-01 | 三菱日立パワーシステムズ株式会社 | 排煙脱硫装置 |
| JP2013154329A (ja) * | 2012-01-31 | 2013-08-15 | Mitsubishi Heavy Ind Ltd | 海水排煙脱硫システムおよび発電システム |
| JP6095923B2 (ja) * | 2012-09-14 | 2017-03-15 | 三菱日立パワーシステムズ株式会社 | 排ガス中の水銀処理システム |
| JP6056638B2 (ja) | 2013-04-30 | 2017-01-11 | 株式会社Ihi | 圧縮機不純物分離機構のアルカリ調整剤供給方法及び装置 |
| US9910413B2 (en) | 2013-09-10 | 2018-03-06 | General Electric Technology Gmbh | Automatic tuning control system for air pollution control systems |
| FR3016370B1 (fr) * | 2014-01-10 | 2017-06-16 | Ifp Energies Now | Procede de craquage catalytique permettant une valorisation amelioree des calories des fumees de combustion. |
| CN105169923B (zh) * | 2015-07-21 | 2017-06-20 | 大唐华银电力股份有限公司金竹山火力发电分公司 | 一种改进石灰石/石灰‑石膏湿法烟气脱硫工艺 |
| CN105320819B (zh) * | 2015-11-30 | 2018-04-03 | 中国能源建设集团广东省电力设计研究院有限公司 | 锅炉烟尘排放浓度测算方法及系统 |
| CN109012131B (zh) * | 2018-08-28 | 2021-05-04 | 贵阳振兴铝镁科技产业发展有限公司 | 一种烟气净化工艺系统脱硫浆液物料平衡控制方法 |
| CN108911280A (zh) * | 2018-09-20 | 2018-11-30 | 西安热工研究院有限公司 | 一种烟气冷凝水综合处理装置及方法 |
| CN110175400B (zh) * | 2019-05-27 | 2023-04-07 | 浙江大学城市学院 | 一种基于高压天然气处理装置的co2吸收动态模型与控制方法 |
| CN111729481B (zh) * | 2020-06-05 | 2022-05-17 | 浙江浩普智能科技有限公司 | 一种燃煤电厂湿法脱硫石灰石浆液脉冲控制方法及系统 |
| CN117085477B (zh) * | 2023-09-20 | 2026-01-20 | 南方电网电力科技股份有限公司 | 一种脱硫双供浆系统自动控制方法、系统和相关设备 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3899294A (en) * | 1974-07-18 | 1975-08-12 | Olin Corp | Method for automatic feed forward control of effluent ph |
| US4094959A (en) * | 1977-02-02 | 1978-06-13 | Phillips Petroleum Company | Process measurement and control |
| EP0038961A1 (fr) * | 1980-04-24 | 1981-11-04 | Combustion Engineering, Inc. | Régulation de la température pour un système de lavage à sec de SO2 |
| US4322392A (en) * | 1979-03-30 | 1982-03-30 | Research-Cottrell, Inc. | SO2 Scrubbing system for flue gas desulfurization |
| US4687649A (en) * | 1983-09-09 | 1987-08-18 | Babcock-Hitachi Kabushiki Kaisha | Flue gas desulfurization process |
| EP0244346A2 (fr) * | 1986-02-24 | 1987-11-04 | Mitsubishi Jukogyo Kabushiki Kaisha | Méthode pour traiter un gaz de queue |
| EP0246758A2 (fr) * | 1986-04-23 | 1987-11-25 | Babcock-Hitachi Kabushiki Kaisha | Méthode pour régler un procédé humide de désulfurisation de gaz de fumées |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4100266A (en) * | 1977-09-29 | 1978-07-11 | Phillips Petroleum Company | Control system for a sulfur process |
| US4431618A (en) * | 1982-10-12 | 1984-02-14 | Fmc Corporation | Process control of continuous sodium-limestone flue gas desulfurization system |
| DK155502B (da) * | 1985-02-04 | 1989-04-17 | Niro Atomizer As | Fremgangsmaade og anlaeg til rensning af varm spildgas, som forekommer i varierende maengder |
-
1995
- 1995-04-21 JP JP09677395A patent/JP3272565B2/ja not_active Expired - Fee Related
- 1995-11-29 US US08/564,409 patent/US5770161A/en not_active Expired - Fee Related
- 1995-12-06 TW TW084113000A patent/TW303420B/zh active
- 1995-12-06 IN IN1611MA1995 patent/IN191869B/en unknown
- 1995-12-28 CN CN95121714A patent/CN1053124C/zh not_active Expired - Fee Related
-
1996
- 1996-01-12 TR TR96/00022A patent/TR199600022A2/xx unknown
- 1996-01-24 PL PL96347802A patent/PL183093B1/pl not_active IP Right Cessation
- 1996-01-24 PL PL96312458A patent/PL182465B1/pl not_active IP Right Cessation
- 1996-01-24 PL PL96347819A patent/PL183264B1/pl not_active IP Right Cessation
- 1996-03-05 KR KR1019960005655A patent/KR0158541B1/ko not_active Expired - Fee Related
- 1996-04-18 ES ES96201002T patent/ES2170194T3/es not_active Expired - Lifetime
- 1996-04-18 EP EP96201002A patent/EP0738537B1/fr not_active Expired - Lifetime
- 1996-04-18 DK DK96201002T patent/DK0738537T3/da active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3899294A (en) * | 1974-07-18 | 1975-08-12 | Olin Corp | Method for automatic feed forward control of effluent ph |
| US4094959A (en) * | 1977-02-02 | 1978-06-13 | Phillips Petroleum Company | Process measurement and control |
| US4322392A (en) * | 1979-03-30 | 1982-03-30 | Research-Cottrell, Inc. | SO2 Scrubbing system for flue gas desulfurization |
| EP0038961A1 (fr) * | 1980-04-24 | 1981-11-04 | Combustion Engineering, Inc. | Régulation de la température pour un système de lavage à sec de SO2 |
| US4687649A (en) * | 1983-09-09 | 1987-08-18 | Babcock-Hitachi Kabushiki Kaisha | Flue gas desulfurization process |
| EP0244346A2 (fr) * | 1986-02-24 | 1987-11-04 | Mitsubishi Jukogyo Kabushiki Kaisha | Méthode pour traiter un gaz de queue |
| EP0246758A2 (fr) * | 1986-04-23 | 1987-11-25 | Babcock-Hitachi Kabushiki Kaisha | Méthode pour régler un procédé humide de désulfurisation de gaz de fumées |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100483081C (zh) * | 2005-03-10 | 2009-04-29 | 上海昌吉地质仪器有限公司 | 水下砼灌注标高定位仪 |
| CN101995345B (zh) * | 2009-08-11 | 2012-12-12 | 大连华城电子有限公司 | 烟气脱硫ph值测量装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1133750A (zh) | 1996-10-23 |
| KR0158541B1 (ko) | 1998-11-16 |
| ES2170194T3 (es) | 2002-08-01 |
| PL182465B1 (pl) | 2002-01-31 |
| US5770161A (en) | 1998-06-23 |
| EP0738537A2 (fr) | 1996-10-23 |
| TW303420B (fr) | 1997-04-21 |
| TR199600022A2 (tr) | 1996-11-21 |
| JPH08290036A (ja) | 1996-11-05 |
| IN191869B (fr) | 2004-01-10 |
| PL183093B1 (pl) | 2002-05-31 |
| EP0738537B1 (fr) | 2002-01-23 |
| KR960037100A (ko) | 1996-11-19 |
| JP3272565B2 (ja) | 2002-04-08 |
| PL183264B1 (pl) | 2002-06-28 |
| DK0738537T3 (da) | 2002-05-13 |
| EP0738537A3 (fr) | 1996-12-27 |
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