CN1067110C - 在电炉内熔炼的不锈钢上产生发泡炉渣的方法 - Google Patents

在电炉内熔炼的不锈钢上产生发泡炉渣的方法 Download PDF

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CN1067110C
CN1067110C CN97118425A CN97118425A CN1067110C CN 1067110 C CN1067110 C CN 1067110C CN 97118425 A CN97118425 A CN 97118425A CN 97118425 A CN97118425 A CN 97118425A CN 1067110 C CN1067110 C CN 1067110C
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slag
stainless steel
powder
carbon
oxide
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CN1180751A (zh
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Y·古劳特
L·索利尔
O·布莱顿
F·狄斯卡维斯
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According To Savoy Youjina Installation Co
Ugine Savoie SA
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • C21C5/5264Manufacture of alloyed steels including ferro-alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • C21C5/54Processes yielding slags of special composition
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/36Processes yielding slags of special composition
    • C21C2005/366Foam slags
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C2300/00Process aspects
    • C21C2300/02Foam creation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S75/00Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
    • Y10S75/961Treating flue dust to obtain metal other than by consolidation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Powder Metallurgy (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

一种在电炉内熔炼的不锈钢上产生发泡炉渣的方法,特点在于:
-向所说的炉渣内引入一种粉末,在其组成中含有至少一种金属氧化物和碳,
-在所说的粉末中存在的至少一种氧化物通过与碳进行的反应被还原,在炉渣中形成气泡,所说的气泡基本由气态形式的金属氧化物中的金属和一氧化碳组成,炉渣中存在的气泡使炉渣以温度的泡沫的形式存在。

Description

在电炉内熔炼的不锈钢上产生发泡炉渣的方法
本发明涉及一种在电炉内熔炼的不锈钢上产生发泡炉渣的方法。
在电炉内熔炼不锈钢的领域内,通过在电极和炉内的装料之间产生电弧,使炉内装料的铁渣、下脚料和铁基合金转变成金属液。
钢的生产容易产生灰尘等残余产物,通常用收尘器回收,其中约90%以球团的方式重新送入电炉内进行回收,其余10%含有太多的氧化锌,目前是储存起来。熔炼后除去炉渣。
在熔炼非不锈钢的领域内,炉渣发泡的原理是基于所用的炉渣内的氧化铁的还原。通过向炉内注入碳粉进行氧化铁的还原,这种还原反应产生一氧化碳。一氧化碳的气泡被限制在熔融的炉渣内使炉渣发泡,从而增大其体积。泡沫形式的炉渣涂敷在电极的端部,防护耐火材料受到的电辐射,这使得在电极消耗、电消耗和耐火材料消耗方面得到节约。
在熔炼不锈钢的情况下,炉渣不能足够地富含氧化铁,因此,在生产非不锈钢中采用的炉渣发泡的原理不再适用。
本发明的目的是提供一种在电炉内的熔融不锈钢上产生可以控制的稳定的发泡炉渣的方法,即通过使炉渣改性在所说的炉渣内产生发泡作用。
本发明的主题是提供一种在电炉内熔炼的不锈钢上产生发泡炉渣的方法,特点在于:
-向炉渣内引入一种粉末,其组成中含有至少一种金属氧化物和碳,
-粉末中存在的至少一种氧化物通过与碳反应被还原,在炉渣中形成基本由气态形式的金属氧化物的金属和一氧化碳组成的气泡,炉渣中存在的气泡使炉渣以稳定的泡沫形式存在。
本发明的其它特点是:
-所说的金属氧化物是易挥发元素的氧化物,
-所说的金属氧化物选自氧化锌和氧化铅,
-至少一部分粉末来自用电炉生产所说的钢产生的灰尘,
-通过干流体的喷射引入所说的粉末,
-所说的流体选自氮气和氩气。
下面的描述将使本发明更好地被理解。
本发明涉及一种在电炉内生产的不锈钢上产生发泡炉渣的方法。
根据本发明,以粉末的形式向生产不锈钢的电炉内和炉渣内引入一种金属氧化物和碳,金属氧化物通过与碳进行的还原反应,一方面形成金属氧化物的金属元素的气体,另一方面,形成一氧化碳,由这些气体产生包裹在炉渣内的气泡,使炉渣以稳定的泡沫的形式存在。
根据本发明,所说的粉末在其组成中含有氧化锌。所说的粉末由高锌含量的电炉灰组成,这种高锌含量的电炉灰是在钢厂中回收所说的炉灰时,由于ZnO的逐渐富集而产生的。
高锌含量的电炉灰的适用使得使用来自不锈钢生产的副产品成为可能。优选地使用的氧化锌中的锌元素参与气泡的形成,因为锌在所说的炉渣的温度下以气态存在。
氧化锌被碳还原得到气态的锌和一氧化碳,根据反应:
这两种物质都会引起炉渣的发泡。
在应用实施例中,通过喷射器向电炉内喷射500~1000kg高锌含量的粉末。为了避免由于空气中水分的影响产生爆炸的危险,喷射的流体优选的是氮气。
根据本发明,生产不锈钢的碱性炉渣的组成为:35%~40%的SiO2、40%~45%的CaO、5%的Cr2O3、5%的Al2O3、其余的由少量的MnO和MgO以及少于1%的FeO构成。这种炉渣实际上不合氧化铁。
由于氧化锌被碳还原以及所得的气体,发现碱性炉渣的厚度增大,达到了几十厘米,所说的炉渣以泡沫的形式涂敷在供电电极上。得到的发泡的炉渣是可以控制的并且是稳定的。

Claims (4)

1、在电炉内熔炼的不锈钢上产生发泡炉渣的方法,特点在于:
-向所说的炉渣内引入一种粉末,其组成中含有至少一种选自氧化锌和氧化铅的金属氧化物和碳,
-在所说的粉末中存在的至少一种氧化物通过与碳进行的反应被还原在所说的炉渣内形成气泡,所说的气泡基本由气态形式的所说的金属氧化物中的金属和一氧化碳组成,在所说的炉渣中存在的气泡使炉渣以稳定的泡沫的形式存在。
2、根据权利要求1的方法,特点在于至少一部分粉末来自通过电炉生产所说的钢产生的灰尘。
3、根据权利要求1或2的方法,特点在于所说的粉末通过干流体的喷射引入。
4、根据权利要求3的方法,特点在于所说的流体选自氮气和氩气。
CN97118425A 1996-09-12 1997-09-11 在电炉内熔炼的不锈钢上产生发泡炉渣的方法 Expired - Fee Related CN1067110C (zh)

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Application Number Priority Date Filing Date Title
FR9611120A FR2753205B1 (fr) 1996-09-12 1996-09-12 Procede pour realiser un laitier moussant au-dessus d'un acier inoxydable en fusion dans un four electrique
FR9611120 1996-09-12

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US (1) US6228137B1 (zh)
EP (1) EP0829545B1 (zh)
JP (1) JPH1088223A (zh)
KR (1) KR100262876B1 (zh)
CN (1) CN1067110C (zh)
AT (1) ATE203280T1 (zh)
AU (1) AU719924B2 (zh)
BR (1) BR9704689A (zh)
CA (1) CA2210505A1 (zh)
DE (1) DE69705685T2 (zh)
ES (1) ES2158468T3 (zh)
FR (1) FR2753205B1 (zh)
ID (1) ID19645A (zh)
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ZA (1) ZA978124B (zh)

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ID19645A (id) 1998-07-23
ES2158468T3 (es) 2001-09-01
EP0829545B1 (fr) 2001-07-18
FR2753205A1 (fr) 1998-03-13
CN1180751A (zh) 1998-05-06
FR2753205B1 (fr) 1998-12-04
CA2210505A1 (fr) 1998-03-12
ATE203280T1 (de) 2001-08-15
US6228137B1 (en) 2001-05-08
JPH1088223A (ja) 1998-04-07
DE69705685D1 (de) 2001-08-23
EP0829545A1 (fr) 1998-03-18
AU3424797A (en) 1998-03-19
ZA978124B (en) 1998-03-03
TW357195B (en) 1999-05-01
AU719924B2 (en) 2000-05-18
DE69705685T2 (de) 2001-11-22
KR19980024214A (ko) 1998-07-06
MX9706898A (es) 1998-07-31
KR100262876B1 (ko) 2000-08-01
BR9704689A (pt) 1998-12-29

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