CN112227079A - Cloth-based antibacterial wallpaper - Google Patents
Cloth-based antibacterial wallpaper Download PDFInfo
- Publication number
- CN112227079A CN112227079A CN202010840994.3A CN202010840994A CN112227079A CN 112227079 A CN112227079 A CN 112227079A CN 202010840994 A CN202010840994 A CN 202010840994A CN 112227079 A CN112227079 A CN 112227079A
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- cloth
- pvc
- surface layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 47
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 41
- 239000010410 layer Substances 0.000 claims abstract description 93
- 239000000843 powder Substances 0.000 claims abstract description 52
- 239000002344 surface layer Substances 0.000 claims abstract description 52
- 239000011347 resin Substances 0.000 claims abstract description 50
- 229920005989 resin Polymers 0.000 claims abstract description 50
- 238000000746 purification Methods 0.000 claims abstract description 46
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 44
- 239000010703 silicon Substances 0.000 claims abstract description 44
- 238000005187 foaming Methods 0.000 claims abstract description 42
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 42
- 229920000728 polyester Polymers 0.000 claims abstract description 42
- 239000002131 composite material Substances 0.000 claims abstract description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 28
- 239000004014 plasticizer Substances 0.000 claims abstract description 28
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 28
- 239000003549 soybean oil Substances 0.000 claims abstract description 28
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 22
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 22
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 22
- 239000011425 bamboo Substances 0.000 claims abstract description 22
- 239000003610 charcoal Substances 0.000 claims abstract description 22
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 22
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 22
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 19
- -1 silicon quaternary ammonium salt Chemical class 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 11
- 238000010023 transfer printing Methods 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 72
- 239000000463 material Substances 0.000 claims description 31
- 239000000853 adhesive Substances 0.000 claims description 22
- 230000001070 adhesive effect Effects 0.000 claims description 22
- 238000005266 casting Methods 0.000 claims description 22
- 241001330002 Bambuseae Species 0.000 claims description 21
- 239000004593 Epoxy Substances 0.000 claims description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 239000004745 nonwoven fabric Substances 0.000 claims description 16
- 238000005303 weighing Methods 0.000 claims description 16
- 238000011049 filling Methods 0.000 claims description 9
- 229920002522 Wood fibre Polymers 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000002025 wood fiber Substances 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 33
- 230000000694 effects Effects 0.000 abstract description 20
- 244000082204 Phyllostachys viridis Species 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 10
- 230000007613 environmental effect Effects 0.000 description 7
- 241000588724 Escherichia coli Species 0.000 description 6
- 241000191967 Staphylococcus aureus Species 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000005034 decoration Methods 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/06—Building materials
- D06N2211/063—Wall coverings
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
Abstract
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, and the formula of the bonding functional middle layer comprises 50-60 parts by weight of PVC paste resin, 6-10 parts by weight of organic silicon emulsion, 12-16 parts by weight of epoxidized soybean oil plasticizer, 4-8 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 10-20 parts by weight of composite filler, 6-10 parts by weight of PVC foaming regulator and 2-6 parts by weight of PET polyester heat stabilizer; the formula of the purification surface layer comprises, by weight, 20-30 parts of PVC paste resin, 10-14 parts of nano silicon oxide, 16-20 parts of nano titanium dioxide, 1-5 parts of bamboo charcoal powder, 3-7 parts of diatomite powder, 2-6 parts of PVC foaming regulator and 1-5 parts of PET polyester heat stabilizer. By adopting the technical scheme, the preparation process is simple, the operation and application effects are outstanding, and the antibacterial and formaldehyde purification performance of the prepared wallpaper is improved.
Description
Technical Field
The invention relates to the technical field of wallpaper, in particular to cloth-based antibacterial wallpaper.
Background
Because the wallpaper has the characteristics of various colors, rich patterns, luxury, safety, environmental protection, convenient construction, proper price and the like which are incomparable with various other interior decoration materials, the wallpaper is popularized to a great extent in developed countries and regions such as Europe and America, southeast Asia, Japan and the like. And more people pursuing quality of life and taste tend to create an atmosphere for the development of wallpaper, a pair of fashionable and personalized wallpaper is selected, a family with a distinctive feeling is determined, and the wallpaper is a very important private place for modern people. How to make up the house more attentively and fashionably is the demand of more and more people, and the wall paper just can satisfy such a requirement of masses, lets the individual character be ubiquitous. The existing wallpaper generally has uneven antibacterial effect and is easy to mildew in a humid environment, so that a cloth-based antibacterial wallpaper is designed.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention discloses cloth-based antibacterial wallpaper.
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, and the formula of the bonding functional middle layer comprises 50-60 parts by weight of PVC paste resin, 6-10 parts by weight of organic silicon emulsion, 12-16 parts by weight of epoxidized soybean oil plasticizer, 4-8 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 10-20 parts by weight of composite filler, 6-10 parts by weight of PVC foaming regulator and 2-6 parts by weight of PET polyester heat stabilizer; the formula of the purification surface layer comprises, by weight, 20-30 parts of PVC paste resin, 10-14 parts of nano silicon oxide, 16-20 parts of nano titanium dioxide, 1-5 parts of bamboo charcoal powder, 3-7 parts of diatomite powder, 2-6 parts of PVC foaming regulator and 1-5 parts of PET polyester heat stabilizer.
Preferably, the formula of the adhesive functional middle layer comprises, by weight, 54-56 parts of PVC paste resin, 7-9 parts of silicone emulsion, 13-15 parts of epoxidized soybean oil plasticizer, 5-7 parts of organosilicon quaternary ammonium salt antibacterial agent, 14-16 parts of composite filler, 7-9 parts of PVC foaming regulator and 3-5 parts of PET polyester heat stabilizer.
Preferably, the preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2-3h under the conditions of a stirring rotating speed of 2000 plus materials at 3000 r/min and a stirring temperature of 150 plus materials at 200 ℃, and preparing the treated mixed feed liquid by extrusion casting equipment to obtain an adhesive functional middle layer with the film thickness of 8-12 mm.
Preferably, the composite filler is prepared by proportionally mixing wood fibers, light calcium carbonate, talcum powder and shell powder after sieving the materials by a sieve of 80-90 meshes.
Preferably, the formula of the purification surface layer comprises, by weight, 24-26 parts of PVC paste resin, 11-13 parts of nano silicon oxide, 17-19 parts of nano titanium dioxide, 2-4 parts of bamboo charcoal powder, 4-6 parts of diatomite powder, 3-5 parts of PVC foaming regulator and 2-4 parts of PET polyester heat stabilizer.
Preferably, the preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, PVC foaming regulator and PET polyester heat stabilizer according to the weight ratio, putting the materials into a stirring reaction kettle, stirring and homogenizing for 1-2h under the conditions of a stirring rotating speed of 2500 plus materials at 3000 r/min and a stirring temperature of 200 plus materials at 300 ℃, and preparing the purified surface layer by extruding and casting equipment from the treated mixed material liquid, wherein the film thickness of the purified surface layer is 4-10 mm.
Preferably, the cloth base layer is a non-woven fabric base layer, and the thickness specification of the non-woven fabric base layer is 2-6 mm.
The beneficial effects are that:
1. the adhesive function middle layer is formed by printing and coating the adhesive function middle layer on the cloth base layer, and the adhesive function middle layer is prepared by forming a film by using PVC paste resin, organic silicon emulsion, epoxy soybean oil plasticizer, organic silicon quaternary ammonium salt antibacterial agent, composite filling material, PVC foaming regulator and PET polyester heat stabilizer, so that the antibacterial performance of the prepared wallpaper is improved, and the transitional combination printing and coating effect of the functional adhesive middle layer is improved by the compatibility of the components.
2. The purifying surface layer is printed and coated on the middle layer with the bonding function, and is prepared by forming a film by using PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, a PVC foaming regulator and a PET polyester heat stabilizer, so that the prepared wallpaper is improved in adsorbing and purifying indoor formaldehyde, has good environmental protection performance and is suitable for indoor use.
Detailed Description
The following will clearly and completely describe in conjunction with the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, the cloth base layer is a non-woven fabric base layer, the thickness specification of the non-woven fabric base layer is 2mm, the formula of the bonding functional middle layer comprises 50 parts by weight of PVC paste resin, 6 parts by weight of organic silicon emulsion, 12 parts by weight of epoxidized soybean oil plasticizer, 4 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 10 parts by weight of composite filler, 6 parts by weight of PVC foaming regulator and 2 parts by weight of PET polyester heat stabilizer, and the composite filler is prepared by proportionally mixing wood fiber, light calcium carbonate, talcum powder and shell powder after passing through a 80-.
The preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2 hours under the conditions of a stirring rotating speed of 2000 revolutions per minute and a stirring temperature of 150 ℃, and extruding and casting the treated mixed feed liquid to obtain an adhesive functional middle layer with the film thickness of 8 mm.
The formula of the purification surface layer comprises, by weight, 20 parts of PVC paste resin, 10 parts of nano silicon oxide, 16 parts of nano titanium dioxide, 1 part of bamboo charcoal powder, 3 parts of diatomite powder, 2 parts of PVC foaming regulator and 1 part of PET polyester heat stabilizer.
The preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, PVC foaming regulator and PET polyester heat stabilizer according to the weight ratio, putting into a stirring reaction kettle, stirring and homogenizing for 1h at the stirring rotation speed of 2500 rpm and the stirring temperature of 200 ℃, and extruding and casting the treated mixed feed liquid by using an extrusion casting device to prepare a purification surface layer with the film thickness of 4 mm.
The detection shows that the prepared wallpaper has environmental protection performance superior to the safety standard of GB18582-2001 interior decoration materials.
And (3) detecting the antibacterial and mildewproof effects: the antibacterial rate to staphylococcus aureus is 97.4 percent, and the antibacterial rate to escherichia coli is 98.2 percent; the mildew-proof grade is 0 grade, and no mildew phenomenon exists;
and (3) detecting the formaldehyde adsorption effect: at 1m3The test result of the test chamber in (2) on the formaldehyde reaches 92 percent.
Example 2
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, the cloth base layer is a non-woven fabric base layer, the thickness specification of the non-woven fabric base layer is 3mm, the formula of the bonding functional middle layer comprises 54 parts by weight of PVC paste resin, 7 parts by weight of organic silicon emulsion, 13 parts by weight of epoxidized soybean oil plasticizer, 5 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 14 parts by weight of composite filler, 7 parts by weight of PVC foaming regulator and 3 parts by weight of PET polyester heat stabilizer, and the composite filler is prepared by proportionally mixing wood fiber, light calcium carbonate, talcum powder and shell powder after being sieved by a 84.
The preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2.4 hours under the conditions of a stirring rotating speed of 2400 r/min and a stirring temperature of 160 ℃, and extruding and casting the treated mixed feed liquid by using extrusion casting equipment to obtain a bonding function middle layer with the film thickness of 9 mm.
The formula of the purification surface layer comprises 24 parts of PVC paste resin, 11 parts of nano silicon oxide, 17 parts of nano titanium dioxide, 2 parts of bamboo charcoal powder, 4 parts of diatomite powder, 3 parts of PVC foaming regulator and 4 parts of PET polyester heat stabilizer by weight.
The preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, a PVC foaming regulator and a PET polyester heat stabilizer according to the weight ratio, putting the materials into a stirring reaction kettle, stirring and homogenizing for 1.4 hours under the conditions of a stirring rotating speed of 2600 r/min and a stirring temperature of 240 ℃, and extruding and casting the treated mixed material liquid by using extrusion casting equipment to prepare a purification surface layer with the film thickness of 5 mm.
The detection shows that the prepared wallpaper has environmental protection performance superior to the safety standard of GB18582-2001 interior decoration materials.
And (3) detecting the antibacterial and mildewproof effects: the antibacterial rate to staphylococcus aureus is 97.8 percent, and the antibacterial rate to escherichia coli is 98.4 percent; the mildew-proof grade is 0 grade, and no mildew phenomenon exists;
and (3) detecting the formaldehyde adsorption effect: at 1m3The test result of the test chamber (2) on the formaldehyde reaches 93 percent.
Example 3
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, the cloth base layer is a non-woven fabric base layer, the thickness specification of the non-woven fabric base layer is 4mm, the formula of the bonding functional middle layer comprises 55 parts by weight of PVC paste resin, 8 parts by weight of organic silicon emulsion, 14 parts by weight of epoxidized soybean oil plasticizer, 6 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 15 parts by weight of composite filler, 8 parts by weight of PVC foaming regulator and 4 parts by weight of PET polyester heat stabilizer, and the composite filler is prepared by proportionally mixing wood fiber, light calcium carbonate, talcum powder and shell powder after being sieved by a sieve of.
The preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2.5 hours under the conditions of a stirring rotating speed of 2500 revolutions per minute and a stirring temperature of 170 ℃, and extruding and casting the treated mixed feed liquid by using extrusion casting equipment to obtain a bonding function middle layer with the film thickness of 10 mm.
The formula of the purification surface layer comprises, by weight, 25 parts of PVC paste resin, 12 parts of nano silicon oxide, 18 parts of nano titanium dioxide, 3 parts of bamboo charcoal powder, 5 parts of diatomite powder, 4 parts of PVC foaming regulator and 3 parts of PET polyester heat stabilizer. The preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, a PVC foaming regulator and a PET polyester heat stabilizer according to the weight ratio, putting the PVC paste resin, the nano silicon oxide, the nano titanium dioxide, the bamboo charcoal powder, the diatomite powder, the PVC foaming regulator and the PET polyester heat stabilizer into a stirring reaction kettle, stirring and homogenizing for 1.5 hours at the stirring rotating speed of 2700 revolutions per minute and the stirring temperature of 250 ℃, and preparing the treated mixed feed liquid by using extrusion casting equipment to obtain a purification surface layer, wherein the film forming thickness of the purification surface layer is 7 mm.
The detection shows that the prepared wallpaper has environmental protection performance superior to the safety standard of GB18582-2001 interior decoration materials.
And (3) detecting the antibacterial and mildewproof effects: the antibacterial rate to staphylococcus aureus is 98.2 percent, and the antibacterial rate to escherichia coli is 98.6 percent; the mildew-proof grade is 0 grade, and no mildew phenomenon exists;
and (3) detecting the formaldehyde adsorption effect: at 1m3The test result of the test chamber in (2) shows that the absorption effect of formaldehyde reaches 94%.
Example 4
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, the cloth base layer is a non-woven fabric base layer, the thickness specification of the non-woven fabric base layer is 4mm, the formula of the bonding functional middle layer comprises 56 parts by weight of PVC paste resin, 9 parts by weight of organic silicon emulsion, 15 parts by weight of epoxidized soybean oil plasticizer, 7 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 16 parts by weight of composite filler, 9 parts by weight of PVC foaming regulator and 5 parts by weight of PET polyester heat stabilizer, and the composite filler is prepared by proportionally mixing wood fiber, light calcium carbonate, talcum powder and shell powder after passing through a 86-.
The preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2.6 hours under the conditions of a stirring rotating speed of 2600 revolutions per minute and a stirring temperature of 180 ℃, and extruding and casting the treated mixed feed liquid by using equipment to obtain an adhesive functional middle layer with a film thickness of 10 mm.
The formula of the purification surface layer comprises 26 parts of PVC paste resin, 13 parts of nano silicon oxide, 19 parts of nano titanium dioxide, 4 parts of bamboo charcoal powder, 6 parts of diatomite powder, 5 parts of PVC foaming regulator and 4 parts of PET polyester heat stabilizer by weight.
The preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, a PVC foaming regulator and a PET polyester heat stabilizer according to the weight ratio, putting the PVC paste resin, the nano silicon oxide, the nano titanium dioxide, the bamboo charcoal powder, the diatomite powder, the PVC foaming regulator and the PET polyester heat stabilizer into a stirring reaction kettle, stirring and homogenizing for 1.6 hours at the stirring rotation speed of 2800 revolutions per minute and the stirring temperature of 260 ℃, and extruding and casting the treated mixed feed liquid to prepare a purification surface layer, wherein the film forming thickness of the purification surface layer is 8 mm.
The detection shows that the prepared wallpaper has environmental protection performance superior to the safety standard of GB18582-2001 interior decoration materials.
And (3) detecting the antibacterial and mildewproof effects: the antibacterial rate to staphylococcus aureus is 98.6 percent, and the antibacterial rate to escherichia coli is 98.8 percent; the mildew-proof grade is 0 grade, and no mildew phenomenon exists;
and (3) detecting the formaldehyde adsorption effect: at 1m3The test chamber in (2) detects the absorption effect of formaldehyde, and the absorption effect reaches 95%.
Example 5
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, the cloth base layer is a non-woven fabric base layer, the thickness specification of the non-woven fabric base layer is 5mm, the formula of the bonding functional middle layer comprises 58 parts by weight of PVC paste resin, 9 parts by weight of organic silicon emulsion, 15 parts by weight of epoxidized soybean oil plasticizer, 7 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 19 parts by weight of composite filler, 9 parts by weight of PVC foaming regulator and 5 parts by weight of PET polyester heat stabilizer, and the composite filler is prepared by proportionally mixing wood fiber, light calcium carbonate, talcum powder and shell powder after being sieved by 89 meshes.
The preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2.9 hours under the conditions of a stirring rotating speed of 2900 r/min and a stirring temperature of 190 ℃, and extruding and casting the treated mixed feed liquid to obtain an adhesive functional middle layer with the film forming thickness of 11 mm.
The formula of the purification surface layer comprises 28 parts of PVC paste resin, 13 parts of nano silicon oxide, 19 parts of nano titanium dioxide, 4 parts of bamboo charcoal powder, 6 parts of diatomite powder, 5 parts of PVC foaming regulator and 4 parts of PET polyester heat stabilizer by weight.
The preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, PVC foaming regulator and PET polyester heat stabilizer according to the weight ratio, putting into a stirring reaction kettle, stirring and homogenizing for 1.9h under the conditions of stirring rotation speed of 2900 r/min and stirring temperature of 290 ℃, and extruding and casting the treated mixed feed liquid by using extrusion casting equipment to obtain a purification surface layer, wherein the film forming thickness of the purification surface layer is 9 mm.
The detection shows that the prepared wallpaper has environmental protection performance superior to the safety standard of GB18582-2001 interior decoration materials.
And (3) detecting the antibacterial and mildewproof effects: the antibacterial rate to staphylococcus aureus is 98.8 percent, and the antibacterial rate to escherichia coli is 98.9 percent; the mildew-proof grade is 0 grade, and no mildew phenomenon exists;
and (3) detecting the formaldehyde adsorption effect: at 1m3The test chamber in (2) detects the absorption effect of formaldehyde, and the absorption effect reaches 96%.
Example 6
The invention discloses cloth-based antibacterial wallpaper, which comprises a cloth base layer, a functional bonding middle layer and a purification surface layer, wherein the cloth base layer, the bonding functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process to prepare the required wallpaper, the cloth base layer is a non-woven fabric base layer, the thickness specification of the non-woven fabric base layer is 6mm, the formula of the bonding functional middle layer comprises 60 parts by weight of PVC paste resin, 10 parts by weight of organic silicon emulsion, 16 parts by weight of epoxidized soybean oil plasticizer, 8 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 20 parts by weight of composite filler, 10 parts by weight of PVC foaming regulator and 6 parts by weight of PET polyester heat stabilizer, and the composite filler is prepared by proportionally mixing wood fiber, light calcium carbonate, talcum powder and shell powder after being sieved by a 90-.
The preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 3 hours under the conditions of a stirring rotating speed of 3000 revolutions per minute and a stirring temperature of 200 ℃, and extruding and casting the treated mixed feed liquid to obtain a bonding function middle layer with the film thickness of 12 mm.
The formula of the purification surface layer comprises, by weight, 30 parts of PVC paste resin, 14 parts of nano silicon oxide, 20 parts of nano titanium dioxide, 5 parts of bamboo charcoal powder, 7 parts of diatomite powder, 6 parts of PVC foaming regulator and 5 parts of PET polyester heat stabilizer. The preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, PVC foaming regulator and PET polyester heat stabilizer according to the weight ratio, putting into a stirring reaction kettle, stirring and homogenizing for 2 hours under the conditions of a stirring rotating speed of 3000 revolutions per minute and a stirring temperature of 300 ℃, and preparing the purified surface layer by extruding and casting the treated mixed feed liquid through an extruding and casting device, wherein the film forming thickness of the purified surface layer is 10 mm.
And (3) detecting the antibacterial and mildewproof effects: the antibacterial rate to staphylococcus aureus is 99 percent, and the antibacterial rate to escherichia coli is 99 percent; the mildew-proof grade is 0 grade, and no mildew phenomenon exists;
and (3) detecting the formaldehyde adsorption effect: at 1m3The test result of the test chamber (2) on the formaldehyde absorption effect reaches 97%.
The detection results of the wallpaper prepared in the above embodiment are shown in the attached table 1
Attached table 1
Finally, it should be noted that: the above embodiments are only used to illustrate the present invention and do not limit the technical solutions described in the present invention; thus, while the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted; all such modifications and variations are intended to be included herein within the scope of this disclosure and the present invention and protected by the following claims.
Claims (7)
1. A cloth-based antibacterial wallpaper comprises a cloth base layer, a functional adhesive middle layer and a purification surface layer, and is characterized in that the cloth base layer, the adhesive functional middle layer and the purification surface layer are compounded through a thermal transfer printing coating process in sequence to obtain the required wallpaper, and the formula of the adhesive functional middle layer comprises 50-60 parts by weight of PVC paste resin, 6-10 parts by weight of organic silicon emulsion, 12-16 parts by weight of epoxidized soybean oil plasticizer, 4-8 parts by weight of organic silicon quaternary ammonium salt antibacterial agent, 10-20 parts by weight of composite filler, 6-10 parts by weight of PVC foaming regulator and 2-6 parts by weight of PET polyester heat stabilizer; the formula of the purification surface layer comprises, by weight, 20-30 parts of PVC paste resin, 10-14 parts of nano silicon oxide, 16-20 parts of nano titanium dioxide, 1-5 parts of bamboo charcoal powder, 3-7 parts of diatomite powder, 2-6 parts of PVC foaming regulator and 1-5 parts of PET polyester heat stabilizer.
2. The cloth-based antibacterial wallpaper as claimed in claim 1, wherein: the formula of the adhesive functional middle layer comprises, by weight, 54-56 parts of PVC paste resin, 7-9 parts of organosilicon emulsion, 13-15 parts of epoxidized soybean oil plasticizer, 5-7 parts of organosilicon quaternary ammonium salt antibacterial agent, 14-16 parts of composite filler, 7-9 parts of PVC foaming regulator and 3-5 parts of PET polyester heat stabilizer.
3. A cloth-based antibacterial wallpaper according to claim 1 or 2, characterized in that: the preparation method of the adhesive functional middle layer comprises the following steps: weighing PVC paste resin, organic silicon emulsion and epoxy soybean oil plasticizer according to the weight ratio, putting the PVC paste resin, the organic silicon emulsion and the epoxy soybean oil plasticizer into a stirring reaction kettle, stirring uniformly, then sequentially adding an organic silicon quaternary ammonium salt antibacterial agent, a composite filling material, a PVC foaming regulator and a PET polyester heat stabilizer, stirring and homogenizing for 2-3h under the conditions of a stirring rotating speed of 2000 plus materials at 3000 r/min and a stirring temperature of 150 plus materials at 200 ℃, and preparing the treated mixed feed liquid by extrusion casting equipment to obtain an adhesive functional middle layer with the film thickness of 8-12 mm.
4. A cloth-based antibacterial wallpaper according to claim 1 or 2, characterized in that: the composite filler is prepared by proportionally mixing wood fibers, light calcium carbonate, talcum powder and shell powder after sieving the materials by a sieve of 80-90 meshes.
5. The cloth-based antibacterial wallpaper as claimed in claim 1, wherein: the formula of the purification surface layer comprises, by weight, 24-26 parts of PVC paste resin, 11-13 parts of nano silicon oxide, 17-19 parts of nano titanium dioxide, 2-4 parts of bamboo charcoal powder, 4-6 parts of diatomite powder, 3-5 parts of PVC foaming regulator and 2-4 parts of PET polyester heat stabilizer.
6. A cloth-based antibacterial wallpaper as claimed in claim 1 or 5, characterized in that: the preparation method of the purification surface layer comprises the following steps: weighing PVC paste resin, nano silicon oxide, nano titanium dioxide, bamboo charcoal powder, diatomite powder, PVC foaming regulator and PET polyester heat stabilizer according to the weight ratio, putting the materials into a stirring reaction kettle, stirring and homogenizing for 1-2h under the conditions of a stirring rotating speed of 2500 plus materials at 3000 r/min and a stirring temperature of 200 plus materials at 300 ℃, and preparing the purified surface layer by extruding and casting equipment from the treated mixed material liquid, wherein the film thickness of the purified surface layer is 4-10 mm.
7. The cloth-based antibacterial wallpaper as claimed in claim 1, wherein: the cloth base layer is a non-woven fabric base layer, and the thickness specification of the non-woven fabric base layer is 2-6 mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010840994.3A CN112227079A (en) | 2020-08-20 | 2020-08-20 | Cloth-based antibacterial wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010840994.3A CN112227079A (en) | 2020-08-20 | 2020-08-20 | Cloth-based antibacterial wallpaper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112227079A true CN112227079A (en) | 2021-01-15 |
Family
ID=74116864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010840994.3A Pending CN112227079A (en) | 2020-08-20 | 2020-08-20 | Cloth-based antibacterial wallpaper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112227079A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119082927A (en) * | 2024-10-11 | 2024-12-06 | 中山市安贝尔塑胶制品有限公司 | Antibacterial textile fabric and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102926199A (en) * | 2012-11-28 | 2013-02-13 | 福建思嘉环保材料科技有限公司 | PVC (polyvinyl chloride) coated fabric paste and preparation method thereof |
| CN103726414A (en) * | 2013-11-29 | 2014-04-16 | 淮北龙盘工贸有限责任公司 | Formaldehyde-resistant environment-friendly ecologic wall paper |
| CN104404831A (en) * | 2014-10-09 | 2015-03-11 | 浙江贝思德壁纸制造有限公司 | Antibiosis foaming wallpaper and preparation method thereof |
| WO2017067504A1 (en) * | 2015-10-21 | 2017-04-27 | 大电塑料（上海）有限公司 | Foamed pvc material, preparation method and use thereof |
| CN107794806A (en) * | 2017-10-31 | 2018-03-13 | 江西卓亚实业有限公司 | A kind of matte PVC wallpaper thickener, matte PVC wallpaper and preparation method thereof |
| CN107903530A (en) * | 2017-10-31 | 2018-04-13 | 江西卓亚实业有限公司 | A kind of PVC foam Wallpaper paste material, PVC foam wallpaper and preparation method thereof |
| WO2018076730A1 (en) * | 2016-10-25 | 2018-05-03 | 东台市富安合成材料有限公司 | Composite home decorative wall covering synthetic leather and preparation method therefor |
| CN109338738A (en) * | 2018-10-18 | 2019-02-15 | 安徽紫荆花壁纸股份有限公司 | A kind of preparation method of multi-functional composite material for decoration |
| CN110317552A (en) * | 2018-03-31 | 2019-10-11 | 寿光市永昌防水材料有限公司 | A kind of PVC waterproof roll and preparation method thereof having self-cleaning function |
| CN111423674A (en) * | 2020-04-11 | 2020-07-17 | 南通正德塑胶制品有限公司 | PVC film and processing technology thereof |
-
2020
- 2020-08-20 CN CN202010840994.3A patent/CN112227079A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102926199A (en) * | 2012-11-28 | 2013-02-13 | 福建思嘉环保材料科技有限公司 | PVC (polyvinyl chloride) coated fabric paste and preparation method thereof |
| CN103726414A (en) * | 2013-11-29 | 2014-04-16 | 淮北龙盘工贸有限责任公司 | Formaldehyde-resistant environment-friendly ecologic wall paper |
| CN104404831A (en) * | 2014-10-09 | 2015-03-11 | 浙江贝思德壁纸制造有限公司 | Antibiosis foaming wallpaper and preparation method thereof |
| WO2017067504A1 (en) * | 2015-10-21 | 2017-04-27 | 大电塑料（上海）有限公司 | Foamed pvc material, preparation method and use thereof |
| WO2018076730A1 (en) * | 2016-10-25 | 2018-05-03 | 东台市富安合成材料有限公司 | Composite home decorative wall covering synthetic leather and preparation method therefor |
| CN107794806A (en) * | 2017-10-31 | 2018-03-13 | 江西卓亚实业有限公司 | A kind of matte PVC wallpaper thickener, matte PVC wallpaper and preparation method thereof |
| CN107903530A (en) * | 2017-10-31 | 2018-04-13 | 江西卓亚实业有限公司 | A kind of PVC foam Wallpaper paste material, PVC foam wallpaper and preparation method thereof |
| CN110317552A (en) * | 2018-03-31 | 2019-10-11 | 寿光市永昌防水材料有限公司 | A kind of PVC waterproof roll and preparation method thereof having self-cleaning function |
| CN109338738A (en) * | 2018-10-18 | 2019-02-15 | 安徽紫荆花壁纸股份有限公司 | A kind of preparation method of multi-functional composite material for decoration |
| CN111423674A (en) * | 2020-04-11 | 2020-07-17 | 南通正德塑胶制品有限公司 | PVC film and processing technology thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119082927A (en) * | 2024-10-11 | 2024-12-06 | 中山市安贝尔塑胶制品有限公司 | Antibacterial textile fabric and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112227079A (en) | Cloth-based antibacterial wallpaper | |
| CN109367313B (en) | Ultrathin thermal sublimation transfer paper | |
| CN103290733B (en) | A kind of attapulgite modified dehumidifying wallpaper | |
| CN105401487A (en) | A kind of preparation method of moisture-proof and antibacterial wallpaper | |
| GB2623887A (en) | Barrier and heat-sealable cellulose film, preparation method therefor, and application thereof | |
| CN106366638B (en) | A kind of preparation method of the extraordinary synthetic paper with antibacterial functions | |
| CN106827346A (en) | A kind of laminating colored drawing soft glass and preparation method thereof | |
| CN107366195A (en) | A kind of light soft sound insulation high-adhesiveness wallpaper and its manufacture method | |
| CN103881362A (en) | Waterproof breathable polyurethane film and preparation method thereof | |
| KR100983826B1 (en) | A syntheti lining paper of nonwiven fabrics having functions | |
| CN112095348A (en) | Environment-friendly composite wallpaper with antibacterial and antibacterial properties | |
| CN112172266A (en) | Durable nano antibacterial wall cloth and preparation method thereof | |
| CN113956603A (en) | A high-hardness antibacterial plastic handle acupuncture needle and preparation method thereof | |
| CN110409178B (en) | Hydrophobic plastic forming agent for waterproof coiled material tire base cloth and preparation method and application thereof | |
| CN107116917A (en) | A kind of water resistance heat transfer printing carbon tape and preparation method thereof | |
| CN103819131A (en) | Diatomite floor and production method thereof | |
| CN117461923A (en) | Highly moisture-permeable protective clothing and preparation process | |
| CN114539580B (en) | Milk-free cover film and preparation method thereof | |
| CN113185924B (en) | Preparation method of non-woven fabric with support and hot melt adhesive coating function | |
| JP2010521571A (en) | Water-permeable protective material | |
| CN117734283B (en) | Embroidery with PU layer and processing technology thereof | |
| CN111576089B (en) | Rice paper for ink-jet printing and preparation method thereof | |
| CN206174346U (en) | Remove formaldehyde art wall paper that discolours | |
| CN115737449B (en) | Pressed powder product with complete pattern on surface and preparation method thereof | |
| KR100403848B1 (en) | Cover film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210115 |
|
| RJ01 | Rejection of invention patent application after publication |