CN109338738A - A kind of preparation method of multi-functional composite material for decoration - Google Patents
A kind of preparation method of multi-functional composite material for decoration Download PDFInfo
- Publication number
- CN109338738A CN109338738A CN201811214956.6A CN201811214956A CN109338738A CN 109338738 A CN109338738 A CN 109338738A CN 201811214956 A CN201811214956 A CN 201811214956A CN 109338738 A CN109338738 A CN 109338738A
- Authority
- CN
- China
- Prior art keywords
- composite material
- decoration
- paste resin
- preparation
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005034 decoration Methods 0.000 title claims abstract description 49
- 239000002131 composite material Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 53
- 229920005989 resin Polymers 0.000 claims abstract description 53
- 239000000463 material Substances 0.000 claims abstract description 50
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 23
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 9
- 238000003825 pressing Methods 0.000 claims abstract description 6
- 238000000465 moulding Methods 0.000 claims abstract description 5
- 238000007711 solidification Methods 0.000 claims abstract 2
- 230000008023 solidification Effects 0.000 claims abstract 2
- 239000000835 fiber Substances 0.000 claims description 72
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000004642 Polyimide Substances 0.000 claims description 41
- 229920001721 polyimide Polymers 0.000 claims description 41
- 239000003365 glass fiber Substances 0.000 claims description 35
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 9
- 230000006855 networking Effects 0.000 claims description 9
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000004088 foaming agent Substances 0.000 claims description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000009941 weaving Methods 0.000 claims description 6
- 229910052582 BN Inorganic materials 0.000 claims description 5
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229960004756 ethanol Drugs 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 150000002466 imines Chemical class 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 16
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 230000003678 scratch resistant effect Effects 0.000 abstract description 4
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- 239000010410 layer Substances 0.000 description 18
- 239000003063 flame retardant Substances 0.000 description 14
- 239000004745 nonwoven fabric Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 241000894006 Bacteria Species 0.000 description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 7
- 238000003490 calendering Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 210000003491 skin Anatomy 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910010348 TiF3 Inorganic materials 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- -1 bonding Substances 0.000 description 3
- 238000009954 braiding Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 230000003471 anti-radiation Effects 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000000640 hydroxylating effect Effects 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- XJMOSONTPMZWPB-UHFFFAOYSA-M propidium iodide Chemical compound [I-].[I-].C12=CC(N)=CC=C2C2=CC=C(N)C=C2[N+](CCC[N+](C)(CC)CC)=C1C1=CC=CC=C1 XJMOSONTPMZWPB-UHFFFAOYSA-M 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0022—Glass fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
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- D—TEXTILES; PAPER
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- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
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Abstract
The invention belongs to decoration material fields, and in particular to a kind of preparation method of multi-functional composite material for decoration.The technical solution having are as follows: a kind of preparation method of composite material for decoration, specific steps are as follows: using nonwoven layer as base, in the nonwoven layer surface even spread PVC paste resin, form PVC paste resin layer；After PVC paste resin layer drying and moulding, then after PVC paste resin layer surface one layer of rolled material of pressing, dry solidification, form rolled material layer；Carbon nanotube is sprayed in rolled material layer surface, after dry, forms carbon nanotube coating material to get required composite material for decoration.The present invention has creatively used 4 layers of structure, provides a kind of visual appearance, facilitates printing, is safe and non-toxic, is high-intensitive, scratch-resistant, washable, anti-aging, fire prevention, waterproof, mould proof, cracking resistance, easy for construction, the good metope composite material for decoration of decorative effect.
Description
Technical field
The invention belongs to decoration material fields, and in particular to a kind of preparation method of multi-functional composite material for decoration.
Background technique
With the further promotion of people's living standard, people require also constantly promoted for the finishing of building, furniture,
The spies such as associated decorative material is enriched with changing style, color multiplicity, pattern, visual appearance, decorative effect are good are not required nothing more than
Point, it is also desirable to have fire-proof and water-proof, wear-resisting scratch resistance, safety and environmental protection, it is easy for construction, the characteristics such as be easily changed, this is just to traditional
More stringent requirements are proposed for the enterprises such as wallpaper, wall paper, decoration panel.
With the industries such as China's wallpaper, wall paper, decoration panel ripe day by day and people's safety and environmental protection realize reinforcement,
While people pay close attention to wallpaper, wall paper, decoration panel color and style varied, the practical and safety and environmental protection of product is also focused more on
Etc. performances.All kinds of scratch-resistants, easy to clean, ageing-resistant, high temperature resistant, fire prevention, waterproof with assorted style pattern, except formaldehyde, remove
Novel wall paper, wall paper, the decoration panel of the functions such as smelly, start market of selling well.Related product is mainly by paper base, Bu Ji or wood
The coating of material surface layer, bonding, hot melt or one or more layers compound functional coating, to reach corresponding fire-retardant, easy cleaning, heat preservation, resistance to
The functions such as scraping, waterproof, the Chinese patent of this respect have CN103074815, CN206127727, CN102776805,
CN103485504、CN100526554、CN107060235、CN206530006、CN107326749、CN206085878、
CN107143105, CN107053382, CN108032592 etc..Functional wallpaper, wall paper or the facing prepared by these methods
Plate, there is a problem of one it is important, be exactly its wallpaper, wall paper or decoration panel functionality it is more single, it is not all-round enough.
Therefore it provides a kind of multiple functional metope composite material for decoration has great high-end market demand.
Summary of the invention
The object of the present invention is to provide a kind of preparation methods of multi-functional composite material for decoration.
For achieving the above object, the technical scheme adopted by the invention is that: a kind of preparation side of composite material for decoration
Method specifically comprises the following steps:
(1) using nonwoven layer as base, in the nonwoven layer surface even spread PVC paste resin, PVC paste resin is formed
Layer；
(2) after PVC paste resin layer drying and moulding, then in PVC paste resin layer surface one layer of rolled material of pressing, drying is solid
After change, rolled material layer is formed；
(3) carbon nanotube is sprayed in rolled material layer surface, after dry, forms carbon nanotube coating material to get required
Composite material for decoration.
Preferably, the nonwoven layer is mixed by glass fibre and polyimide fiber.
Preferably, the formula of the composite material for decoration is, in parts by weight, 25~100 parts of glass fibre, polyimides
25~200 parts of fiber, 50~600 parts of PVC paste resin, 1~200 part of rolled material, ultra-thin carbon nanotube coating material 0.1~
1.2 part.
Preferably, the formula of the composite material for decoration is, in parts by weight, 50 parts of glass fibre, polyimide fiber
98 parts, 100 parts of PVC paste resin, 50 parts of rolled material, 0.3 part of ultra-thin carbon nanotube coating material.
Preferably, the production method of the nonwoven layer are as follows: fine with the glass fibre and the polyimides that add up to 2~6
Dimension is one group, mixed weaving forms fibre bundle, and the fibre bundle is combed networking, is reinforced to obtain the final product.
Preferably, the production method of the nonwoven layer are as follows: with 1 glass fibre and 2 polyimide fibers for one group,
It carries out being knitted to form fibre bundle by three bursts of fried dough twist pigtail formulas, the fibre bundle is combed into networking, is reinforced to obtain the final product.
Preferably, it after the glass fibre and polyimide fiber carry out plus are tough, then is woven；
Described plus tough mode are as follows: in parts by weight, 2~10 parts of carbon nanotubes are added in 100 parts of ethyl alcohol or chloroform, are surpassed
Sound is uniformly dispersed to get fiber reinforced dose；Glass fibre, polyimide fiber are submerged respectively in fiber reinforced dose, impregnated
Night then carefully takes out each fiber, under vacuum environment, 80~90 DEG C is slowly warming up to from room temperature, heat preservation drying, heat up speed
Degree control 0.5~0.8 DEG C/min to get add it is tough after glass fibre and polyimide fiber.
Preferably, the formula of the PVC paste resin are as follows: 30~35wt% dioctyl phthalate, 0.5wt% nanometer nitrogen
Change boron, 1~3wt% nano rutile-type titanium dioxide or Ti3+/TiO2, 2~4wt% micron barium sulfate, 38~48wt% paste resin
P450,10~20wt% polyimide powder, 0~7wt% microballoon foaming agent, 2wt% barium zinc type thermal stabilizing agent.
Preferably, the PVC paste resin the preparation method comprises the following steps: under normal temperature and pressure, phthalic acid is added in reaction kettle
Dioctyl ester, nm-class boron nitride, nano rutile-type titanium dioxide or Ti3+/TiO2, micron barium sulfate, in 12000r/min disperse
5min adds paste resin P450, polyimide powder, microballoon foaming agent, barium zinc type thermal stabilizing agent；
After mixing, follow these steps successively to be dispersed three times: 2000r/min disperses 5min, 6000r/min dispersion
2min, 3000r/min disperse 30min；After dispersion, then in 24~48h, in 2500r/min dispersion 15min to get PVC
Paste resin.
Preferably, the Ti3+/TiO2The preparation method comprises the following steps: by TiCl4It is completely dissolved in dehydrated alcohol, ultrasonic 10min,
Adding quality is TiCl4The simple substance zinc of quality 40%, is stirred to react 30min, and adding quality is TiCl41~1.5 times of quality
TiF3, ultrasonic 10min, then at 150 DEG C keep the temperature 20~14h；Cooling, drying is to get required Ti3+/TiO2。
The invention has the following advantages:
1, the present invention has creatively used 4 layers of structure, provides a kind of visual appearance, facilitates printing, is safe and non-toxic, is high
Intensity, scratch-resistant, washable, anti-aging, fire prevention, waterproof, mould proof, cracking resistance, easy for construction, the good metope of decorative effect is compound
Ornament materials.
2, the base material of composite material for decoration is non-woven fabrics, and when weaving non-woven fabrics, filament fiber is easily broken, surface light
Sliding, fiber is without curling, and networking performance is poor, is not easy to reinforce, so being difficult to be directly used in production non-woven fabrics.Typically first by long filament
It is cut into staple fiber, then combs networking, then pinprick reinforcement.But the characteristic of filament fiber is thus lost, and is easy loss
Fiber.The present invention creatively first carries out plus tough glass fibre and polyimide fiber with carbon nanotube, and fiber is avoided to compile
It is broken during knitting.The fiber after toughening is reused then with 1 glass fibre and 2 polyimide fibers for one group, by three
The mode of stock fried dough twist pigtail is woven；The fibre bundle after braiding is combed into networking again, generates non-woven fabrics after pinprick reinforcement.
This mode for preparing non-woven fabrics overcomes the crisp defect easy to break of glass fibre property itself, remains filament fiber sheet
The characteristic of body, has both glass fibre and the common advantage of polyamide-imide fibre, safe and non-toxic, excellent in mechanical performance, scratch-resistant,
Ageing-resistant, fire-proof and water-proof, gas permeability and excellent tenacity, dimensionally stable, it is applied widely, and there is self-cleaning ability.
3, in order to make nonwoven cloth material that there is more superior processing performance, it is more suitable for printing etc., the present invention is also in nonwoven
One layer of PVC paste resin is coated on cloth.But PVC paste resin is not prevented fires, and needs additionally to add fire retardant.Traditional fire retardant is mostly
Halogenated flame retardant (chlorine system, bromine system are representative), has certain toxicity, is unsuitable for the demanding field such as house ornamentation.And it is inorganic fire-retarded
Agent (such as aluminium hydroxide, magnesium hydroxide) or reactive flame retardant (MCA, TBP etc.) etc., otherwise it is exactly the decomposition product met after fire
It is toxic；Otherwise it is exactly that fire retardant will be slow selfdecomposition, gradually loses flame retardant effect；Or fire retardant additive amount is small fire-retardant
Effect is poor, additive amount is big can seriously affect the performance of PVC paste resin, undesirable.
The invention using polyimide powder as fire retardant, nontoxic, performance is stablized, and also can further improve
The performances such as wear-resisting, heat-resisting, ageing-resistant, anti-radiation of composite material.The oxygen index (OI) of polyimide powder itself is up to 48, is added to
After in PVC paste resin used in the present invention, prepared PVC paste resin oxygen index (OI) is up to 27 or more, belongs to fire retardant rank.
4, Ti is prepared the present invention also provides a kind of3+/TiO2And it is added to the method in PVC paste resin.TiO2Itself has
There is the ability of removal formaldehyde；Meanwhile the electronegative electronics being optically excited out has stronger bactericidal effect, can assign material
Material sterilization, self-cleaning ability.But common TiO2Because its forbidden bandwidth is larger, it is negative that band could be only generated under ultraviolet excitation
The electronics of electricity, and Ti3+It can be in TiO2Conduction band bottom introduce localized modes, to make TiO2It can be even infrared ray excited by visible light
Electronegative electronics out.
TiF3In F-Change TiO2Pattern, make its internal dissolution and to external diffusion, form ghost TiO2, in high temperature
In the process, TiO2Oxygen atom in lattice is detached from, and forms Lacking oxygen, attracts TiF3In Ti3+And wrap up to inside hollow structure,
Or it is adsorbed on TiO2Surface forms Ti3+/TiO2, make composite material for decoration in routine use, under common light environment
With except formaldehyde, sterilization, self-cleaning ability.
5, the present invention has pressed one layer of PVC calendering skin or PU calendering skin in the outer layer of PVC paste resin, can according to need pair
It carries out hitting the techniques such as convex, embossing, to assign the visual effect of composite material for decoration naked eye 3D.
PVC calendering skin or PU calendering skin itself are not prevented fires, and can not directly add fire proofing, so the present invention also creates
Property coat the carbon nanotube coating material of one layer ultra-thin (0.5~1.5 μm of thickness) in calendering epidermis face, with increase it is wear-resisting,
The performances such as fire-proof and water-proof, corrosion-resistant.
Specific embodiment
One, formula of the invention.
1, total formula of the invention are as follows: in parts by weight, 25~100 parts of glass fibre, polyimide fiber 25~200
Part, 50~600 parts of PVC paste resin, 1~200 part of rolled material, 0.1~1.2 part of ultra-thin carbon nanotube coating material.
2, in the formula, the preferred embodiment in addition to PVC paste resin is as follows:
(1) glass fibre is alkali-free glass fibre or medium-alkali glass fibre, average length > 50cm.
(2) polyimide fiber be ethers homopolymerization type polyimide fiber, tensile strength > 3cN/dtex, modulus >
9GPa.Preferred scheme are as follows: the polyimide fiber is P84 type polyimide powder, by aromatic diamine and aromatic series
Dianhydride synthesis.
The rolled material is that PVC calendered film or PU roll skin, with a thickness of 5~80.
The carbon nanotube coating material, preferably hydroxylated multi-walled carbon nanotubes/fluorine carbon emulsion；The hydroxylating multi wall
The caliber of carbon nanotube is 10~20nm, and 0.1~1.0 μm of length, purity > 98%, hydroxy radical content is 2.8~3.2%.
3, the formula of the PVC paste resin are as follows:
30~35wt% dioctyl phthalate (plasticizer, hereinafter referred to as DOP), 0.5wt% nm-class boron nitride, 1~
3wt% nano rutile-type titanium dioxide or Ti3+/TiO2, 2~4wt% micron barium sulfate, 38~48wt% paste resin P450,10
~20wt% polyimide powder, 0~7wt% microballoon foaming agent, 2wt% barium zinc type thermal stabilizing agent.
Two, concrete operation step of the invention.
1, non-woven fabrics is prepared.
(1) it prepares fiber reinforced dose: in parts by weight, 2~10 parts of carbon nanotubes being added in 100 parts of ethyl alcohol or chloroform,
Ultrasonic disperse is uniformly to get fiber reinforced dose.
(2) glass fibre, polyimide fiber are separately added into fiber reinforced dose, soaked overnight, then by each fiber
Carefully take out, under vacuum environment, be slowly warming up to 80~90 DEG C from room temperature, heat preservation drying, heating rate control 0.5~
0.8℃/min。
(3) by each fiber mixed weaving bunchy after toughening, preferably it is with 1 glass fibre, 2 polyimide fibers
One group, bunchy is woven in the way of three strands of fried dough twist pigtails.
(4) non-woven fabrics moulding process is used, fibre bundle is combed into networking, pinprick reinforcement to get required non-woven fabrics.
Tough step can also be added without fiber, directly will prepare again non-woven fabrics after each fibrage, only non-woven fabrics
Comprehensive performance can be declined.
2, PVC paste resin is prepared.
(1) Ti is prepared3+/TiO2: by TiCl4It is completely dissolved in dehydrated alcohol, ultrasonic 10min, adding quality is TiCl4
The simple substance zinc of quality 40%, is stirred to react 30min, and adding quality is TiCl4The TiF that 1~1.5 times of quality3, ultrasonic 10min,
Then in a sealed meter environment, 150 DEG C of 20~14h of heat preservation.After natural cooling, first rinsed sediment 1~2 time with dehydrated alcohol, then
It is rinsed sediment 1~2 time, is subsequently dried to get required Ti with deionized water3+/TiO2.Transmission electron microscope is carried out to product and is swept
Transmission electron microscope observing is retouched, finds the TiO of production2There is hollow structure in inside.
(2) it prepares PVC paste resin: at normal temperatures and pressures, DOP, nm-class boron nitride, nanometer being added in stainless steel stirred tank
Rutile type titanium white or Ti3+/TiO2, micron barium sulfate, disperse 5min in 12000r/min, add paste resin P450, poly-
(it is to be purchased from Japanese Matsumoto Yushi-Seiyaku Co., Ltd. that the present invention, which uses, model microballoon hair for acid imide powder, microballoon foaming agent
Infusion F-50, using other middle low-temperature expansion type microballoon foaming agents can also), barium zinc type thermal stabilizing agent.
Follow these steps successively to be dispersed three times: 2000r/min disperses 5min, and 6000r/min disperses 2min, 3000r/
Min disperses 30min.After dispersion, then in 24~48h, in 2500r/min dispersion 15min to get PVC paste resin.
If not using Ti3+/TiO2, titanium dioxide is directly used, also can achieve goal of the invention, the PVC paste only prepared
The sterilization of resin, self-cleaning ability accordingly decline.
3, composite material for decoration is prepared.
PVC paste resin is uniformly coated onto the nonwoven surface and rolled material is pressed together on PVC paste as needed after dry
Resin surface, specific process for pressing are the prior art, the realization such as pressing machine can be used, details are not described herein.Pressing terminates, does
After dry curing molding, then in surface spraying carbon nanotube, pass through one layer formed in body surface spraying and fast-curing process
Overlay film coating, coating layer thickness are 0.5~1.5 μm.Stamp is carried out after drying as needed, hits the techniques such as convex, embossing to get required
Composite material for decoration.
The present invention is further expalined combined with specific embodiments below.
Embodiment one: the effect of different fiber treatment modes is shown
1,11 groups of composite material for decoration are prepared by above-mentioned formula and operating procedure.Remaining condition is identical, at toughening
Reason and braiding processing, as a control group.
The parts by weight of glass fibre and polyimide fiber, processing mode, non-woven fabrics preparation method in each group, such as table 1
It is shown.Wherein, fibre bundle is not woven, refers to combing networking preparation nothing after directly mixing glass fibre and polyimide fiber
Woven fabric.In bundle weave mode, glass fibre is replaced with " glass "/" glass ", replaces polyimides fine with " poly- "/" poly- fibre "
Dimension, the number before " glass " and " poly- " respectively refer in mass of fibers beam, the quantity of glass fibre, polyimide fiber respectively；Such as 1
Glass 2 is poly- to refer to that 1 glass fibre and 2 polyimide fibers are one group.1 glass poly, which refers to, weighs fiber by each fibre weight number
Afterwards, by glass fibre and polyimide fiber, respectively actual quantity carries out ratio cut partition, is woven again according to dividing condition；
For example, having 10 containing glass fibre in the parts by weight, polyimide fiber after weighing two kinds of fibers of specified weight number
There are 30, is then that one group of carry out fried dough twist pigtail formula weaves with 1 glass fibre and 3 polyimide fibers.By specific weaving manner
After being woven, last extra filament fiber is voluntarily woven by the specific weaving manner；For example, in such a way that 1 glass 1 is poly-
After braiding, 10 polyimide fibers of last residue, not extra glass fibre is matched, then this 10 polyimides fibres
Dimension is mutually wound fibre bundle with 2 for one group.
1 each group fiber treatment mode list of table
2, each group non-woven fabrics is tested for the property.Wherein, shear strength test method by JC/T 773-2010 into
Row；Gas permeability is according to GB/T 24218.15-2018 " textile non-woven cloth test method " the 15th part: the measurement of gas permeability
In test method carry out；The results are shown in Table 2.
2 each group fiber treatment mode list of table
Embodiment two: the effect of different PVC paste resin treatment modes is shown
1, use the non-woven fabrics of 2 preparation of group in embodiment one as base, prepare 19 groups of composite material for decoration.Wherein, always
Formula are as follows: in parts by weight, 50 parts of rolled material, 0.3 part of ultra-thin carbon nanotube coating material；The rolled material selects PU pressure
Prolong skin.
The formula of PVC paste resin, processing mode, parts by weight in each group, as shown in table 3.PVC paste resin in table refers to
Parts by weight shared by PVC paste resin in total formula, each component refers to each component in PVC paste resin formula in PVC paste resin formula
In shared mass percent.Wherein, all PVC products and equal with the good barium zinc type thermal stabilizing agent of resin intermiscibility of capable of being used for
It can be used, for convenience, barium zinc type thermal stabilizing agent used in full text of the present invention is purchased from the city Dong Wan Han Zhi rubber and plastic Co., Ltd, type
Number be BZ-2321.Directly to use paste resin P450 as PVC paste resin, as a control group.
The processing mode list of each PVC paste resin of table 3
2, measure of merit is carried out to the composite material for decoration of each group preparation.
(1) presentation quality and basic physics performance
It is carried out by the experimental method and standard of JG/T 509-2016 " architectural decoration nonwoven wallpaper ", inspection item includes:
Colour fastness to rubbing, wet tensile load, adhesive erasible and washability.Wherein, in colour fastness to rubbing test, each group material
Material effect under the friction on dry friction, wet friction and different directions is suitable, at least top grade, so directly with rub resistance color
This index of fastness is shown, the different-effect not being listed in individually in the case of differentiated friction.Three weights of every group of test
Multiple, the results are shown in Table 4.
4 each group composite material for decoration effect of table shows one of table
(2) composite material antibacterial, mould proof, flame retardant property test
1) antibacterial ability is tested: being that Escherichia coli and 20 μ L staphylococcus aureuses are separately added into 100m meat by 20 μ L concentration
In soup culture medium, after culture by Mixed Microbes concentration dilution be 1 × 106CFU/ml obtains mixed bacteria liquid.With 5mL mixed bacteria liquid for one
Group is divided into 20 groups, and every group is separately added into each group composite material for decoration 1g, and 37 DEG C, culture is for 24 hours.
After culture, each group material is taken out, is gently cleaned each group material surface 3 times with sterilizing PBS solution, removes material
The bacterium that surface suspends or adheres to by tension of water etc. then carries out (the dye bacterium examination anyway of life or death Bacterial stain to each group material
Agent box, l-7012, hero Life Technologies, Inc.；2mL PBS solution containing 3 μ L SYTO and 3 μ L propidium iodide；
Red represents dead bacterium, and green represents bacterium living), it is placed under laser scanning microscope and observes, count red green fluorescence number and shared
Ratio.
Wherein, red (dead bacterium)+green (bacterium living)+black (background, no bacterium presence)=100%.
2) fungicidal properties is tested: being carried out according to " mildew " test method in GB/T2423.16-2008.
3) it tests and is classified according to the flame retardant property that the method for 5.1.1 in GB8624-2012 carries out composite material.
The results are shown in Table 5.
5 each group composite material for decoration effect of table shows the two of table
| Group | Red (%) | Green (%) | Mould proof grade | Flame retardant rating |
| Group 1 | 2.9 | 8.8 | 0 grade | B1(B) |
| Group 2 | 4.0 | 7.1 | 0 grade | B1(B) |
| Group 3 | 2.8 | 8.9 | 0 grade | B1(B) |
| Group 4 | 2.9 | 8.7 | 0 grade | B1(B) |
| Group 5 | 2.9 | 9.0 | 0 grade | B1(B) |
| Group 6 | 2.8 | 9.1 | 0 grade | B1(B) |
| Group 7 | 3.0 | 9.0 | 0 grade | B1(B) |
| Group 8 | 1.2 | 23.1 | 1 grade | B1(B) |
| Group 9 | 1.8 | 13.2 | 1 grade | B1(B) |
| Group 10 | 3.0 | 8.6 | 0 grade | B1(B) |
| Group 11 | 2.8 | 9.1 | 0 grade | B1(B) |
| Group 12 | 2.9 | 8.9 | 0 grade | B1(B) |
| Group 13 | 3.0 | 9.0 | 0 grade | B1(C) |
| Group 14 | 3.2 | 9.1 | 0 grade | B1(B) |
| Group 15 | 3.5 | 9.1 | 0 grade | B1(B) |
| Group 16 | 3.5 | 9.3 | 0 grade | B1(B) |
| Group 17 | 3.3 | 9.5 | 0 grade | B1(B) |
| Group 18 | 3.1 | 9.0 | 0 grade | B1(B) |
| Group 19 | 3.3 | 9.1 | 0 grade | B1(B) |
| Control group | 0.9 | 33.5 | 1 grade | B2(E) |
(3) composite material anti-pollution is tested
Each group composite material is sheared into two pieces of 5cm respectively2Sample, the common dirt of life is dripped on every piece of sample respectively
Stain after retaining for 24 hours at room temperature, carries out wiping processing with neutral detergent and alcohol respectively.Observe the spot of each group composite material
Residual condition.Wherein, it 5 represents without spot residual, 4, which represent slightly spot, remains, and 3 represent part spot residual, and 2 represent many dirts
Stain residual, 1 represents spot does not remove completely.The results are shown in Table 6.
6 each group composite material for decoration effect of table shows the three of table
Embodiment three: the effect that difference is always formulated is shown
1,7 groups of composite material for decoration are prepared by two group 2 of embodiment of method, wherein the recipe ingredient of each group such as 7 institute of table
Show.Rolled material number indicates its shared parts by weight in total formula, rolled material and carbon nanotube coating material in table
Ratio, the weight ratio both referred to (corresponding carbon nanotube coating material weight number is 0.1 part~1.2 parts).Not spray carbon
Nanotube coatings material is as a control group.
The recipe ingredient list of 7 each group of table
2, by the test method of embodiment two, the comprehensive performance of each group composite material is tested, effect is respectively such as 8~table of table 10
It is shown.
8 each group composite material for decoration effect of table shows one of table
9 each group composite material for decoration effect of table shows the two of table
| Group | Red (%) | Green (%) | Mould proof grade | Flame retardant rating |
| Group 1 | 4.1 | 6.9 | 0 grade | B1(B) |
| Group 2 | 2.7 | 8.8 | 0 grade | B1(B) |
| Group 3 | 2.9 | 8.9 | 0 grade | B1(B) |
| Group 4 | 2.9 | 8.7 | 0 grade | B1(B) |
| Group 5 | 3.0 | 9.3 | 0 grade | B1(C) |
| Group 6 | 2.8 | 9.1 | 0 grade | B1(B) |
| Group 7 | 3.0 | 9.0 | 0 grade | B1(B) |
| Control group | 1.5 | 16.3 | 1 grade | B2(E) |
10 each group composite material for decoration effect of table shows the three of table
Claims (10)
1. a kind of preparation method of composite material for decoration, it is characterised in that: specifically comprise the following steps:
(1) using nonwoven layer as base, in the nonwoven layer surface even spread PVC paste resin, PVC paste resin layer is formed；
(2) after PVC paste resin layer drying and moulding, then in PVC paste resin layer surface one layer of rolled material of pressing, dry solidification
Afterwards, rolled material layer is formed；
(3) carbon nanotube is sprayed in rolled material layer surface, after dry, forms carbon nanotube coating material to get required compound
Ornament materials.
2. the preparation method of composite material for decoration according to claim 1, it is characterised in that: the nonwoven layer is by glass
Fiber and polyimide fiber are mixed.
3. the preparation method of composite material for decoration according to claim 2, it is characterised in that: the composite material for decoration
Formula is, in parts by weight, 25~100 parts of glass fibre, 25~200 parts of polyimide fiber, 50~600 parts of PVC paste resin,
1~200 part of rolled material, 0.1~1.2 part of ultra-thin carbon nanotube coating material.
4. the preparation method of composite material for decoration according to claim 3, it is characterised in that: the composite material for decoration
Formula is, in parts by weight, 50 parts of glass fibre, 98 parts of polyimide fiber, 100 parts of PVC paste resin, 50 parts of rolled material,
0.3 part of ultra-thin carbon nanotube coating material.
5. the preparation method of composite material for decoration according to claim 2, it is characterised in that: the production of the nonwoven layer
Mode are as follows: glass fibre and polyimide fiber to add up to 2~6 are one group, mixed weaving forms fibre bundle, will be described
Fibre bundle combing networking is reinforced to obtain the final product.
6. the preparation method of composite material for decoration according to claim 5, it is characterised in that: the production of the nonwoven layer
Mode are as follows: with 1 glass fibre and 2 polyimide fibers for one group, carry out being knitted to form fibre bundle by three bursts of fried dough twist pigtail formulas,
The fibre bundle is combed into networking, is reinforced to obtain the final product.
7. the preparation method of composite material for decoration according to claim 5, it is characterised in that: the glass fibre and polyamides
After imine fiber carries out plus is tough, then woven；
Described plus tough mode are as follows: in parts by weight, 2~10 parts of carbon nanotubes are added in 100 parts of ethyl alcohol or chloroform, ultrasound point
It dissipates uniformly to get fiber reinforced dose；Glass fibre, polyimide fiber are submerged respectively in fiber reinforced dose, soaked overnight, with
Each fiber is carefully taken out afterwards, under vacuum environment, 80~90 DEG C are slowly warming up to from room temperature, heat preservation is dried, heating rate control
Make 0.5~0.8 DEG C/min to get add it is tough after glass fibre and polyimide fiber.
8. the preparation method of composite material for decoration according to claim 3, it is characterised in that: the PVC paste resin is matched
Side are as follows: 30~35wt% dioctyl phthalate, 0.5wt% nm-class boron nitride, 1~3wt% nano rutile-type titanium dioxide
Or Ti3+/TiO2, 2~4wt% micron barium sulfate, 38~48wt% paste resin P450,10~20wt% polyimide powder, 0~
7wt% microballoon foaming agent, 2wt% barium zinc type thermal stabilizing agent.
9. the preparation method of composite material for decoration according to claim 8, it is characterised in that: the system of the PVC paste resin
Preparation Method are as follows: under normal temperature and pressure, dioctyl phthalate, nm-class boron nitride, nano rutile-type titanium are added in reaction kettle
White powder or Ti3+/TiO2, micron barium sulfate, in 12000r/min disperse 5min, add paste resin P450, polyimide powder,
Microballoon foaming agent, barium zinc type thermal stabilizing agent；
After mixing, follow these steps successively to be dispersed three times: 2000r/min disperses 5min, and 6000r/min disperses 2min,
3000r/min disperses 30min；After dispersion, then in 24~48h, in 2500r/min dispersion 15min to get PVC paste tree
Rouge.
10. the preparation method of composite material for decoration according to claim 8, it is characterised in that: the Ti3+/TiO2System
Preparation Method are as follows: by TiCl4It is completely dissolved in dehydrated alcohol, ultrasonic 10min, adding quality is TiCl4The simple substance of quality 40%
Zinc is stirred to react 30min, and adding quality is TiCl4The TiF that 1~1.5 times of quality3, ultrasonic 10min then protects at 150 DEG C
20~14h of temperature；Cooling, drying is to get required Ti3+/TiO2。
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| CN111716928A (en) * | 2020-06-24 | 2020-09-29 | 深圳市博泰数码智能技术有限公司 | Pattern printing method applied to non-woven fabric |
| CN112227079A (en) * | 2020-08-20 | 2021-01-15 | 安徽紫荆花墙饰材料股份有限公司 | Cloth-based antibacterial wallpaper |
| CN114921860A (en) * | 2022-06-27 | 2022-08-19 | 浙江鼎艺新材料科技有限公司 | Fine denier chinlon 6DTY and production method thereof |
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