CN114717715A - Waterproof and antifouling fabric and preparation method thereof - Google Patents
Waterproof and antifouling fabric and preparation method thereof Download PDFInfo
- Publication number
- CN114717715A CN114717715A CN202210463962.5A CN202210463962A CN114717715A CN 114717715 A CN114717715 A CN 114717715A CN 202210463962 A CN202210463962 A CN 202210463962A CN 114717715 A CN114717715 A CN 114717715A
- Authority
- CN
- China
- Prior art keywords
- fabric
- thread
- cotton
- waterproof
- antifouling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000004744 fabric Substances 0.000 title claims abstract description 207
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229920000742 Cotton Polymers 0.000 claims abstract description 132
- 229920000728 polyester Polymers 0.000 claims abstract description 68
- 239000000835 fiber Substances 0.000 claims abstract description 53
- 238000005507 spraying Methods 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 244000025254 Cannabis sativa Species 0.000 claims abstract description 26
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims abstract description 26
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims abstract description 26
- 235000009120 camo Nutrition 0.000 claims abstract description 26
- 235000005607 chanvre indien Nutrition 0.000 claims abstract description 26
- 239000011487 hemp Substances 0.000 claims abstract description 26
- 239000004677 Nylon Substances 0.000 claims abstract description 25
- 229920001778 nylon Polymers 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000002344 surface layer Substances 0.000 claims abstract description 8
- 239000012790 adhesive layer Substances 0.000 claims abstract description 7
- 230000008569 process Effects 0.000 claims abstract description 7
- 239000003292 glue Substances 0.000 claims description 37
- 238000005406 washing Methods 0.000 claims description 30
- 239000004743 Polypropylene Substances 0.000 claims description 26
- -1 polypropylene Polymers 0.000 claims description 26
- 229920001155 polypropylene Polymers 0.000 claims description 26
- 238000001035 drying Methods 0.000 claims description 20
- 238000011282 treatment Methods 0.000 claims description 18
- 239000003513 alkali Substances 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 12
- 239000002759 woven fabric Substances 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 10
- 238000006297 dehydration reaction Methods 0.000 claims description 10
- 238000002791 soaking Methods 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 3
- 239000005871 repellent Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 6
- 238000013461 design Methods 0.000 abstract description 4
- 238000009423 ventilation Methods 0.000 abstract 1
- 238000009941 weaving Methods 0.000 description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 238000009960 carding Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000675 fabric finishing Substances 0.000 description 5
- 238000009962 finishing (textile) Methods 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000011056 performance test Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 3
- 230000003075 superhydrophobic effect Effects 0.000 description 3
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- KJLPSBMDOIVXSN-UHFFFAOYSA-N 4-[4-[2-[4-(3,4-dicarboxyphenoxy)phenyl]propan-2-yl]phenoxy]phthalic acid Chemical compound C=1C=C(OC=2C=C(C(C(O)=O)=CC=2)C(O)=O)C=CC=1C(C)(C)C(C=C1)=CC=C1OC1=CC=C(C(O)=O)C(C(O)=O)=C1 KJLPSBMDOIVXSN-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
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- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
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- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
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- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/442—Cut or abrasion resistant yarns or threads
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- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
- D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
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- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
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- D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
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- D03—WEAVING
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- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/527—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads waterproof or water-repellent
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
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- D03D15/58—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads characterised by the coefficients of friction
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/02—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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- D10B2201/01—Natural vegetable fibres
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- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
Abstract
本发明涉及一种防水、防污面料，所述面料由面料用线采用平纹或斜纹的方式织造而成，所述面料用线的单丝直径80～120μm，克重385～445g/m2；所述面料用线由芯线和外包线混纺而成，所述外包线经全氟整理剂和交联剂浸润处理；所述芯线包括50～55％棉、20～25％锦纶、20～25％涤纶和3～5％导湿纤维，所述外包线包括35～40％棉、20～30％耐磨涤纶、25～30％涤棉和5～10％麻，所述芯线单丝直径60～70μm，所述外包线单丝直径17～21μm；所述面料外侧表层经磨毛处理，所述面料表层经喷洒工艺喷有防水胶层。本发明还设计了上述面料的制备方法。本发明通过特殊的材质和混纺工艺结合，使面料具有外部阻水、防污，内侧向外能够单向透气，同时与皮肤接触的柔软度和舒适度均较佳。The invention relates to a waterproof and antifouling fabric. The fabric is woven from fabric threads in a plain weave or twill weave manner, the monofilament diameter of the fabric threads is 80-120 μm, and the gram weight is 385-445 g/m 2 ; The fabric thread is made by blending a core thread and an outer thread, and the outer thread is infiltrated with a perfluorinated finishing agent and a cross-linking agent; the core thread includes 50-55% cotton, 20-25% nylon, 20- 25% polyester and 3-5% moisture-conducting fibers, the outer wire comprises 35-40% cotton, 20-30% wear-resistant polyester, 25-30% polyester-cotton and 5-10% hemp, the core monofilament The diameter is 60-70 μm, and the diameter of the outer wire monofilament is 17-21 μm; the outer surface layer of the fabric is sanded, and the surface layer of the fabric is sprayed with a waterproof adhesive layer through a spraying process. The present invention also designs the preparation method of the above-mentioned fabric. Through the combination of special material and blending process, the invention enables the fabric to have external water resistance and antifouling, and unidirectional ventilation from the inside to the outside, while the softness and comfort in contact with the skin are better.
Description
技术领域technical field
本发明涉及纺织材料技术领域，特别涉及一种防水、防污面料及其制备方法。The invention relates to the technical field of textile materials, in particular to a waterproof and antifouling fabric and a preparation method thereof.
背景技术Background technique
传统的服装面料以棉、麻、丝等材料织造的面料为主。这类面料的材质是纯天然的，与人体的亲和力较佳，与皮肤接触较为舒适，不易致敏。随着市场的变化，人们对服装舒适性、功能性的要求不断提高，传统的棉、麻面料很难适应目前市场功能性的要求。现有的服装对于防水、防污面料的需求日益增大。例如，近年来十分流行的户外功能性服装，其面料是针对户外运动爱好者的穿着场景而特殊设计的，要求面料具备防水、防污、透气等功能。再例如，近年来流行的轻薄羽绒服，其面料设计为了锁住羽绒，一般十分致密，且通常会附有涂层。这类羽绒服一般不能随意清洗，一旦破坏涂层，则会丧失锁羽绒的功能。这类面料通常也需要其具备防水、防污的功能。Traditional clothing fabrics are mainly made of cotton, linen, silk and other materials. The material of this type of fabric is pure natural, which has a better affinity with the human body, is more comfortable in contact with the skin, and is not easy to cause allergies. With the changes in the market, people's requirements for the comfort and functionality of clothing continue to increase, and it is difficult for traditional cotton and linen fabrics to meet the functional requirements of the current market. There is an increasing demand for waterproof and stain-resistant fabrics in existing garments. For example, the fabrics of the very popular outdoor functional clothing in recent years are specially designed for the wearing scenes of outdoor sports enthusiasts, and the fabrics are required to have functions such as waterproof, antifouling, and breathability. For another example, the light and thin down jackets that have become popular in recent years, the fabrics are designed to lock down the down, and are generally very dense and usually have a coating attached. Such down jackets generally cannot be washed at will. Once the coating is damaged, the function of locking down will be lost. This type of fabric usually also needs to have the function of waterproof and anti-fouling.
现有的防水、防污面料，有两种生产方式。一种是将面料浸渍防水整理剂，使防水剂附着在面料外层，通过选择具备防水、防污效果的整理剂，从而达到防水、防污的效果；另一种是在面料外层涂覆防水、防污涂层，也同样能实现防水、防污效果。There are two production methods for existing waterproof and antifouling fabrics. One is to impregnate the fabric with a waterproof finishing agent, so that the waterproofing agent is attached to the outer layer of the fabric. By choosing a finishing agent with waterproof and antifouling effects, the effect of waterproofing and antifouling can be achieved; the other is to coat the outer layer of the fabric. Waterproof and antifouling coating can also achieve waterproof and antifouling effect.
发明内容SUMMARY OF THE INVENTION
本发明针对现有技术中存在的至少一种技术问题，提供一种防水、防污面料及其制备方法，通过特殊的材质和混纺工艺结合，使面料具有外部阻水、防污，内侧向外能够单向透气，同时与皮肤接触的柔软度和舒适度均较佳。Aiming at at least one technical problem existing in the prior art, the present invention provides a waterproof and antifouling fabric and a preparation method thereof. Through the combination of special material and blending process, the fabric has external water resistance and antifouling, and the inner side is outward. It can breathable in one direction, and the softness and comfort in contact with the skin are better.
本发明解决上述技术问题的技术方案如下：一种防水、防污面料，所述面料由面料用线采用平纹或斜纹的方式织造而成，所述面料用线的单丝直径80～120μm，克重385～445g/m2；所述面料用线由芯线和外包线混纺而成，所述外包线经过全氟整理剂和交联剂浸润处理；所述芯线包括50～55％棉、20～25％锦纶、20～25％涤纶和3～5％导湿纤维，所述外包线包括35～40％棉、20～30％耐磨涤纶、25～30％涤棉和5～10％麻，所述芯线单丝直径60～70μm，所述外包线单丝直径17～21μm；所述面料外侧表层经磨毛处理，所述面料表层经喷洒工艺喷有防水胶层。The technical solution of the present invention to solve the above-mentioned technical problems is as follows: a waterproof and antifouling fabric, the fabric is woven by the fabric thread using plain weave or twill weave, the monofilament diameter of the fabric thread is 80-120 μm, g The weight is 385-445g/m 2 ; the fabric thread is blended with the core thread and the outer thread, and the outer thread is soaked with a perfluorinated finishing agent and a cross-linking agent; the core thread includes 50-55% cotton, 20-25% nylon, 20-25% polyester, and 3-5% moisture-conducting fibers, the outer wire comprises 35-40% cotton, 20-30% wear-resistant polyester, 25-30% polyester-cotton and 5-10% Hemp, the diameter of the core wire monofilament is 60-70 μm, and the diameter of the outer wire monofilament is 17-21 μm; the outer surface layer of the fabric is sanded, and the surface layer of the fabric is sprayed with a waterproof glue layer through a spraying process.
在上述技术方案的基础上，本发明还可以做如下改进。On the basis of the above technical solutions, the present invention can also be improved as follows.
进一步，所述面料用线的单丝直径90～100μm，克重420～425g/m2。Further, the monofilament diameter of the thread for fabrics is 90-100 μm, and the gram weight is 420-425 g/m 2 .
进一步，所述芯线包括52％棉、20～22％锦纶、23～24％涤纶和3～4％导湿纤维。Further, the core wire comprises 52% cotton, 20-22% nylon, 23-24% polyester and 3-4% moisture-conducting fibers.
进一步，所述外包线包括38％棉、24～26％耐磨涤纶、28～30％涤棉和6～8％麻。Further, the outer thread comprises 38% cotton, 24-26% wear-resistant polyester, 28-30% polyester-cotton and 6-8% hemp.
进一步，所述导湿纤维采用聚丙烯纤维。Further, the moisture-conducting fibers are polypropylene fibers.
进一步，所述防水胶层采用XF-5003防水胶。Further, the waterproof adhesive layer adopts XF-5003 waterproof adhesive.
本发明还设计了上述防水、防污面料的制备方法，包括以下步骤：The present invention also designs the preparation method of the above-mentioned waterproof and antifouling fabric, comprising the following steps:
S1、制备芯线：依据芯线配比，采用短纤维原料，将原料经抓棉、混棉、精梳和防静电处理成线，而后将处理得到的线经柔软整理剂处理，再经脱水、烘干后制得芯线；S1. Preparation of core yarns: According to the ratio of core yarns, short fiber raw materials are used, and the raw materials are processed into yarns by picking cotton, cotton blending, combing and anti-static treatment, and then the processed yarns are treated with a softening finishing agent, and then dehydrated. , The core wire is obtained after drying;
S2、制备外包线：依据外包线配比，采用短纤维原料，将原料经抓棉、混棉、精梳和防静电处理成线，而后将处理得到的线经全氟整理剂和交联剂浸润处理，再经脱水、烘干后制得外包线；S2. Preparation of outer thread: According to the ratio of outer thread, short fiber raw material is used, and the raw material is processed into thread by cotton picking, cotton blending, combing and anti-static treatment, and then the processed thread is treated with perfluorinated finishing agent and cross-linking agent. After soaking treatment, dehydration and drying, the outer wire is obtained;
S3、制备面料用线：将步骤S1和步骤S2制备的芯线和外包线以1根芯线配3～6根外包线的配比，以芯线在内，外包线外侧包裹的方式混纺成面料用线；S3, fabric preparation thread: the core wire and the outer thread prepared in step S1 and step S2 are blended in a ratio of 1 core thread and 3 to 6 outer threads, with the core thread inside and the outer thread wrapped around the outer side. fabric thread;
S4、织造面料：平纹或斜纹的织造方式，将面料用线织造成面料，对织造成的面料外侧表层进行磨毛处理；S4, woven fabric: plain weave or twill weave, weave the fabric into a fabric with threads, and sand the outer surface of the woven fabric;
S5、整理：采用两次水洗中间夹一次碱洗的方式对步骤S4织造而成的面料进行清洗整理，而后脱水、烘干面料；S5, finishing: the fabric woven in step S4 is cleaned and arranged by two times of water washing and one alkali washing in the middle, and then the fabric is dehydrated and dried;
S6、喷涂：采用喷雾喷涂的方式，将防水胶以喷雾的方式在面料表面均匀喷洒，而后待喷胶后的面料自然干燥，制得防水、防污面料。S6. Spraying: spraying the waterproof glue evenly on the surface of the fabric by spraying, and then the fabric after spraying glue is naturally dried to obtain a waterproof and antifouling fabric.
在上述技术方案的基础上，本发明还可以做如下改进。On the basis of the above technical solutions, the present invention can also be improved as follows.
进一步，所述步骤S1和步骤S2中，所述全氟整理剂和交联剂浸润处理的浸润时间控制在18～22min。Further, in the step S1 and the step S2, the soaking time of the perfluorinated finishing agent and the crosslinking agent soaking treatment is controlled within 18-22 minutes.
进一步，所述步骤S1和步骤S2中，脱水后烘干温度控制在90～105℃，烘干时间控制在3～5min；所述步骤S5种，烘干温度控制在80～85℃，烘干时间控制在5～8min。Further, in the steps S1 and S2, the drying temperature after dehydration is controlled at 90-105°C, and the drying time is controlled at 3-5min; in the step S5, the drying temperature is controlled at 80-85°C, and the drying time is controlled at 80-85°C. The time is controlled at 5 to 8 minutes.
进一步，所述步骤S6中，喷洒防水胶的时间控制在25～30s。Further, in the step S6, the time for spraying the waterproof glue is controlled within 25-30s.
本发明的有益效果是：本发明采用包混的方式，采用特殊的材质设计，制备芯线和外包线，混纺出面料用线，在纺线环节采用整理剂进行整理，使面料用线具备较佳的拒水和防污性能，同时能够有效避免面料因磨损导致的防水、防污性能的下降；本发明的面料以棉为主，具有较佳的亲和性，芯线中加入了导湿纤维，使面料具有较好的导湿、透气性能；本发明在面料外侧表层进行了磨毛处理，并喷有防水胶，在面料表层形成有一层超疏水结构的防水、防污层，能够有效阻水、防污；本发明的外包线经过防水、防污整理剂处理，能够与防水胶有较好的结合性能，可以有效避免防水胶脱落。The beneficial effects of the present invention are as follows: the present invention adopts the method of wrapping and blending, adopts special material design, prepares the core thread and the outer thread, blends the thread for fabric, and uses finishing agent for finishing in the spinning link, so that the thread for fabric has a relatively high quality. It has excellent water repellency and antifouling performance, and at the same time can effectively avoid the decline of the waterproof and antifouling performance of the fabric due to wear; the fabric of the present invention is mainly cotton, which has better affinity, and the core wire is added with moisture conduction. fiber, so that the fabric has good moisture conduction and air permeability; the present invention is sanded on the outer surface of the fabric, and sprayed with waterproof glue, and a waterproof and anti-fouling layer with a super-hydrophobic structure is formed on the surface of the fabric, which can effectively Water blocking and antifouling; the outer wire of the present invention is treated with a waterproof and antifouling finishing agent, which can have good bonding performance with the waterproof glue, and can effectively prevent the waterproof glue from falling off.
具体实施方式Detailed ways
以下结合实施例和对比试验对本发明的原理和特征进行描述，所举实例只用于解释本发明，并非用于限定本发明的范围。The principles and features of the present invention will be described below with reference to the examples and comparative experiments. The examples are only used to explain the present invention, but not to limit the scope of the present invention.
本发明设计的一种防水、防污面料，所述面料由面料用线采用平纹或斜纹的方式织造而成，所述面料用线的单丝直径80～120μm，克重385～445g/m2。采用上述尺寸的线，并采用特殊设计的织造密度，织出的面料十分致密，表面未涂防水涂层的情况下便可以形成间距微小的、规则的编制缝隙，十分有利于制造出超疏水的表面结构。A waterproof and antifouling fabric designed by the present invention, the fabric is woven by the fabric thread using plain weave or twill weave, the monofilament diameter of the fabric thread is 80-120 μm, and the gram weight is 385-445 g/m 2 . Using the thread of the above size and using a specially designed weaving density, the woven fabric is very dense, and even if the surface is not coated with a waterproof coating, a small and regular weaving gap can be formed, which is very conducive to the manufacture of super-hydrophobic fabrics. surface structure.
本发明所述的面料用线由芯线和外包线混纺而成，所述外包线经全氟整理剂和交联剂浸润处理，芯线则不进行拒水、防污整理剂浸润处理。所述芯线包括50～55％棉、20～25％锦纶、20～25％涤纶和3～5％导湿纤维。所述外包线包括35～40％棉、20～30％耐磨涤纶、25～30％涤棉和5～10％麻。所述芯线单丝直径60～70μm，所述外包线单丝直径17～21μm。本发明的面料用线，采用芯线为主体，外侧包裹外包线的混纺方式纺成。The fabric thread of the present invention is made by blending a core thread and an outer thread, the outer thread is soaked with a perfluorinated finishing agent and a crosslinking agent, and the core thread is not soaked with a water-repellent and antifouling finishing agent. The core wire comprises 50-55% cotton, 20-25% nylon, 20-25% polyester and 3-5% moisture-conducting fibers. The outer thread comprises 35-40% cotton, 20-30% wear-resistant polyester, 25-30% polyester-cotton and 5-10% hemp. The diameter of the core wire monofilament is 60-70 μm, and the diameter of the outer wire monofilament is 17-21 μm. The thread for fabric of the present invention is spun in a blending method in which the core thread is used as the main body and the outer thread is wrapped on the outside.
本发明的所述面料外侧表层经磨毛处理，所述面料表层经喷洒工艺喷有防水胶层。本发明采用喷洒防水胶的方式制备防水胶层，而并不是采用涂覆的方式，制备的防水胶层并不成膜，有利于面料的透气。本发明的面料表面致密度经过精确设计，编制缝隙规则且间距极小，经磨毛处理后，喷洒的防水胶液滴会粘附在磨毛形成的粗糙面上，并渗入磨毛纤维团内，最终在面料表面形成一层由密集防水胶颗粒构成的规则的防水胶颗粒层。由于面料的编制间隙进行了精确的计算，防水胶液滴在干燥过程中，受表面张力的作用，形成类似圆形的扁平胶粒，使得编制间隙尺寸缩小，最终形成超疏水面。具有极佳的防水、防污效果。The outer surface layer of the fabric of the present invention is sanded, and the surface layer of the fabric is sprayed with a waterproof adhesive layer through a spraying process. In the present invention, the waterproof adhesive layer is prepared by spraying the waterproof adhesive instead of coating, and the prepared waterproof adhesive layer does not form a film, which is beneficial to the breathability of the fabric. The surface density of the fabric of the invention is precisely designed, the weaving gaps are regular and the spacing is extremely small, and after the sanding treatment, the sprayed waterproof glue droplets will adhere to the rough surface formed by the sanding and penetrate into the sanding fiber group. , and finally a regular layer of waterproof glue particles composed of dense waterproof glue particles is formed on the surface of the fabric. Due to the accurate calculation of the weaving gap of the fabric, the waterproof glue droplets are subjected to the action of surface tension during the drying process to form flat rubber particles similar to a circle, which reduces the size of the weaving gap and finally forms a super-hydrophobic surface. It has excellent waterproof and antifouling effect.
由于外包线先经过了全氟整理剂和交联剂浸润处理，这样使得外包线与防水胶之间具有较好的结合性能，同时磨毛处理可以进一步增加结合强度，这样的设计，可以使防水胶与面料的结合牢固度大幅提升，极大提升了面料的耐磨性能。Since the outer wire has been infiltrated with perfluorinated finishing agent and cross-linking agent, the outer wire has good bonding performance with the waterproof glue. At the same time, the sanding treatment can further increase the bonding strength. This design can make waterproof The bonding firmness of the glue and the fabric is greatly improved, which greatly improves the wear resistance of the fabric.
本发明的防水、防污面料，具体制备方法，包括以下步骤：The waterproof and antifouling fabric of the present invention, the specific preparation method, comprises the following steps:
S1、制备芯线：依据芯线配比，采用短纤维原料，将原料经抓棉、混棉、精梳和防静电处理成线，而后将处理得到的线经柔软整理剂处理，再经脱水、烘干后制得芯线；S1. Preparation of core yarns: According to the ratio of core yarns, short fiber raw materials are used, and the raw materials are processed into yarns by picking cotton, cotton blending, combing and anti-static treatment, and then the processed yarns are treated with a softening finishing agent, and then dehydrated. , The core wire is obtained after drying;
S2、制备外包线：依据外包线配比，采用短纤维原料，将原料经抓棉、混棉、精梳和防静电处理成线，而后将处理得到的线经全氟整理剂和交联剂浸润处理，再经脱水、烘干后制得外包线；S2. Preparation of outer thread: According to the ratio of outer thread, short fiber raw material is used, and the raw material is processed into thread by cotton picking, cotton blending, combing and anti-static treatment, and then the processed thread is treated with perfluorinated finishing agent and cross-linking agent. After soaking treatment, dehydration and drying, the outer wire is obtained;
S3、制备面料用线：将步骤S1和步骤S2制备的芯线和外包线以1根芯线配3～6根外包线的配比，以芯线在内，外包线外侧包裹的方式混纺成面料用线；S3, fabric preparation thread: the core wire and the outer thread prepared in step S1 and step S2 are blended in a ratio of 1 core thread and 3 to 6 outer threads, with the core thread inside and the outer thread wrapped around the outer side. fabric thread;
S4、织造面料：平纹或斜纹的织造方式，将面料用线织造成面料，对织造成的面料外侧表层进行磨毛处理；S4, woven fabric: plain weave or twill weave, weave the fabric into a fabric with threads, and sand the outer surface of the woven fabric;
S5、整理：采用两次水洗中间夹一次碱洗的方式对步骤S4织造而成的面料进行清洗整理，而后脱水、烘干面料；S5, finishing: the fabric woven in step S4 is cleaned and arranged by two times of water washing and one alkali washing in the middle, and then the fabric is dehydrated and dried;
S6、喷涂：采用喷雾喷涂的方式，将防水胶以喷雾的方式在面料表面均匀喷洒，而后待喷胶后的面料自然干燥，制得防水、防污面料。S6. Spraying: spraying the waterproof glue evenly on the surface of the fabric by spraying, and then the fabric after spraying glue is naturally dried to obtain a waterproof and antifouling fabric.
本发明中，所述导湿纤维优选采用聚丙烯纤维。In the present invention, polypropylene fibers are preferably used as the moisture-conducting fibers.
采用上述优选方案，不但导湿性佳，而且可以有效增强芯线的强度，聚丙烯纤维具有极佳的亲水性，少量添加，配合芯线中的棉，就能实现极佳的吸湿效果。The above preferred solution not only has good moisture conductivity, but also can effectively enhance the strength of the core.
本发明中，所述防水胶层优选采用XF-5003胶。In the present invention, the waterproof adhesive layer preferably adopts XF-5003 adhesive.
采用上述优选方案，XF-5003胶为环保、无毒的水性胶，可以用水为溶剂调配适宜的粘度，便于喷洒。而且该胶与经全氟整理剂和交联剂整理后的防水外包线的结合性能极佳，该胶的强度、耐磨性能也较好。Using the above preferred solution, XF-5003 glue is an environmentally friendly, non-toxic water-based glue, which can be formulated with water as a solvent to prepare a suitable viscosity for easy spraying. In addition, the adhesive has excellent bonding performance with the waterproof outer wire after finishing with perfluorinated finishing agent and cross-linking agent, and the strength and wear resistance of the adhesive are also good.
以下为本发明的实施例The following are examples of the present invention
本发明实施例所用各类试剂如下：The various reagents used in the embodiments of the present invention are as follows:
含氟乳液整理剂：杜邦公司OLEOPHOBOL CP-R型全氟整理剂。Fluorinated emulsion finishing agent: DuPont OLEOPHOBOL CP-R type perfluorinated finishing agent.
交联剂：荣正化工KH-792型。Cross-linking agent: Rongzheng Chemical KH-792 type.
抗静电整理剂：常州美胜生物材料有限公司SN-6型。Antistatic finishing agent: SN-6 type of Changzhou Meisheng Biomaterials Co., Ltd.
防水胶：大金公司XF-5003型。Waterproof glue: Daikin company XF-5003 type.
聚丙烯纤维：山东中鲁工程材料有限公司产聚丙烯短纤维。Polypropylene fiber: Shandong Zhonglu Engineering Materials Co., Ltd. produces polypropylene staple fiber.
实施例1Example 1
本实施例的面料采用以下步骤制备：The fabric of this embodiment is prepared by the following steps:
S1、芯线制备：按照50％棉、25％锦纶、20涤纶和5％聚丙烯纤维的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经抗静电整理剂整理后，脱水处理，然后100℃烘干5min，最终制得芯线。制备的芯线直径控制在60μm。S1. Core yarn preparation: According to the ratio of 50% cotton, 25% nylon, 20 polyester and 5% polypropylene fibers, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then into the mixed cotton Machine-blended cotton into rolls, and then carded and combed by a carding machine to form yarns. After finishing the yarns with antistatic finishing agent, dewatering treatment, and then drying at 100 °C for 5 minutes, the core yarns are finally obtained. The diameter of the prepared core wire is controlled at 60 μm.
S2、外包线制备：按照35％棉、30％耐磨涤纶、25％涤棉和10％麻的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经含氟乳液整理剂和交联剂浸润20min后，脱水处理，然后100℃烘干5min，最终制得外包线。制备的外包线直径控制在17μm。S2. Preparation of outer thread: According to the ratio of 35% cotton, 30% wear-resistant polyester, 25% polyester-cotton and 10% hemp, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then enter the The cotton blender mixes cotton into rolls, and then is carded and combed by the carding machine to form threads. The threads are soaked with fluorine-containing emulsion finishing agent and cross-linking agent for 20 minutes, dehydrated, and then dried at 100°C. 5min, and finally the outer line was obtained. The diameter of the prepared outer wire is controlled at 17 μm.
S3、面料用线制备：以芯线和外包线1:3的配比，采用包混的方式混纺，制成直径80μm的面料用线。S3. Fabric thread preparation: The core thread and the outer thread are blended in a ratio of 1:3 and blended to make a fabric thread with a diameter of 80 μm.
S4、织造面料：采用平纹织造的方式，将面料用线编织成面料，织造密度控制在445g/m2。织造完成后，用磨毛辊对面料表面进行磨毛处理。S4. Weaving fabrics: The fabrics are woven into fabrics by using plain weave, and the weaving density is controlled at 445g/m 2 . After weaving, the surface of the fabric is sanded with a sanding roller.
S5、面料整理：将织造好的面料，在60～65℃水温下第一次水洗，水洗后脱水处理；然后将水洗后的面料在6～8％的纯碱溶液中，在25～30℃水温下碱洗，碱洗后再次脱水；最后将碱洗后的面料，在25～30℃水温下第二次水洗，水洗后再次脱水。脱水处理后的面料，在80℃温度下，烘干8min。S5. Fabric finishing: Wash the woven fabric for the first time at a water temperature of 60-65 °C, and then dehydrate the washed fabric; then put the washed fabric in a 6-8% soda ash solution at a water temperature of 25-30 °C Alkaline washing, dehydration again after alkali washing; finally, the fabric after alkali washing is washed for the second time at 25-30 ℃ water temperature, and dehydrated again after washing. The dehydrated fabric was dried at 80°C for 8 minutes.
S6、喷胶：将整理后的面料，平铺后，利用喷雾型喷淋设备在面料外侧表面喷淋雾状防水胶，喷淋时间30s。喷淋后将面料在摊平状态下自然干燥，待面料完全干燥、防水胶完全干燥固化后，制得本实施例的防水、防污面料。S6. Spraying glue: After laying the finished fabric, use spray-type spraying equipment to spray mist-like waterproof glue on the outer surface of the fabric, and the spraying time is 30s. After spraying, the fabric is naturally dried in a flat state, and after the fabric is completely dried and the waterproof glue is completely dried and cured, the waterproof and antifouling fabric of this embodiment is prepared.
实施例2Example 2
本实施例的面料采用以下步骤制备：The fabric of this embodiment is prepared by the following steps:
S1、芯线制备：按照50％棉、25％锦纶、20涤纶和5％聚丙烯纤维的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经抗静电整理剂整理后，脱水处理，然后100℃烘干5min，最终制得芯线。制备的芯线直径控制在64μm。S1. Core yarn preparation: According to the ratio of 50% cotton, 25% nylon, 20 polyester and 5% polypropylene fibers, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then into the mixed cotton Machine-blended cotton into rolls, and then carded and combed by a carding machine to form yarns. After finishing the yarns with antistatic finishing agent, dewatering treatment, and then drying at 100 °C for 5 minutes, the core yarns are finally obtained. The diameter of the prepared core wire is controlled at 64 μm.
S2、外包线制备：按照35％棉、30％耐磨涤纶、25％涤棉和10％麻的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经含氟乳液整理剂和交联剂浸润20min后，脱水处理，然后95℃烘干4min，最终制得外包线。制备的外包线直径控制在18μm。S2. Preparation of outer thread: According to the ratio of 35% cotton, 30% wear-resistant polyester, 25% polyester-cotton and 10% hemp, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then enter the The cotton is mixed with a cotton blender to form a roll, and then it is carded and combed by a carding machine to form a thread. After soaking the prepared thread with a fluorine-containing emulsion finishing agent and a cross-linking agent for 20 minutes, dewatering treatment, and then drying at 95 ℃ 4min, and finally the outer line was obtained. The diameter of the prepared outer wire is controlled at 18 μm.
S3、面料用线制备：以芯线和外包线1:5的配比，采用包混的方式混纺，制成直径100μm的面料用线。S3. Fabric thread preparation: The core thread and the outer thread are blended in a ratio of 1:5 to make a fabric thread with a diameter of 100 μm.
S4、织造面料：采用平纹织造的方式，将面料用线编织成面料，织造密度控制在400g/m2。织造完成后，用磨毛辊对面料表面进行磨毛处理。S4. Weaving fabrics: The fabrics are woven into fabrics by plain weave, and the weaving density is controlled at 400g/m 2 . After weaving, the surface of the fabric is sanded with a sanding roller.
S5、面料整理：将织造好的面料，在60～65℃水温下第一次水洗，水洗后脱水处理；然后将水洗后的面料在6～8％的纯碱溶液中，在25～30℃水温下碱洗，碱洗后再次脱水；最后将碱洗后的面料，在25～30℃水温下第二次水洗，水洗后再次脱水。脱水处理后的面料，在80℃温度下，烘干8min。S5. Fabric finishing: Wash the woven fabric for the first time at a water temperature of 60-65 °C, and then dehydrate the washed fabric; then put the washed fabric in a 6-8% soda ash solution at a water temperature of 25-30 °C Alkaline washing, dehydration again after alkali washing; finally, the fabric after alkali washing is washed for the second time at 25-30 ℃ water temperature, and dehydrated again after washing. The dehydrated fabric was dried at 80°C for 8 minutes.
S6、喷胶：将整理后的面料，平铺后，利用喷雾型喷淋设备在面料外侧表面喷淋雾状防水胶，喷淋时间27s。喷淋后将面料在摊平状态下自然干燥，待面料完全干燥、防水胶完全干燥固化后，制得本实施例的防水、防污面料。S6. Spray glue: After laying the finished fabric, use a spray-type spraying equipment to spray mist-like waterproof glue on the outer surface of the fabric, and the spraying time is 27s. After spraying, the fabric is naturally dried in a flat state, and after the fabric is completely dried and the waterproof glue is completely dried and cured, the waterproof and antifouling fabric of this embodiment is prepared.
实施例3Example 3
本实施例的面料采用以下步骤制备：The fabric of this embodiment is prepared by the following steps:
S1、芯线制备：按照50％棉、25％锦纶、20涤纶和5％聚丙烯纤维的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经抗静电整理剂整理后，脱水处理，然后90℃烘干5min，最终制得芯线。制备的芯线直径控制在68μm。S1. Core yarn preparation: According to the ratio of 50% cotton, 25% nylon, 20 polyester and 5% polypropylene fibers, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then into the mixed cotton Machine-blended cotton into rolls, and then carded and combed by a carding machine to form yarns. After finishing the yarns with antistatic finishing agent, dewatering treatment, and then drying at 90 °C for 5 minutes, the core yarns are finally obtained. The diameter of the prepared core wire is controlled at 68 μm.
S2、外包线制备：按照35％棉、30％耐磨涤纶、25％涤棉和10％麻的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经含氟乳液整理剂和交联剂浸润20min后，脱水处理，然后100℃烘干5min，最终制得外包线。制备的外包线直径控制在20μm。S2. Preparation of outer thread: According to the ratio of 35% cotton, 30% wear-resistant polyester, 25% polyester-cotton and 10% hemp, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then enter the The cotton blender mixes cotton into rolls, and then is carded and combed by the carding machine to form threads. The threads are soaked with fluorine-containing emulsion finishing agent and cross-linking agent for 20 minutes, dehydrated, and then dried at 100°C. 5min, and finally the outer line was obtained. The diameter of the prepared outer wire is controlled at 20 μm.
S3、面料用线制备：以芯线和外包线1:3的配比，采用包混的方式混纺，制成直径90μm的面料用线。S3. Fabric thread preparation: The core thread and the outer thread are blended in a ratio of 1:3 and blended to make a fabric thread with a diameter of 90 μm.
S4、织造面料：采用平纹织造的方式，将面料用线编织成面料，织造密度控制在425g/m2。织造完成后，用磨毛辊对面料表面进行磨毛处理。S4. Weaving fabrics: The fabrics are woven into fabrics by means of plain weave, and the weaving density is controlled at 425g/m 2 . After weaving, the surface of the fabric is sanded with a sanding roller.
S5、面料整理：将织造好的面料，在60～65℃水温下第一次水洗，水洗后脱水处理；然后将水洗后的面料在6～8％的纯碱溶液中，在25～30℃水温下碱洗，碱洗后再次脱水；最后将碱洗后的面料，在25～30℃水温下第二次水洗，水洗后再次脱水。脱水处理后的面料，在85℃温度下，烘干5min。S5. Fabric finishing: Wash the woven fabric for the first time at a water temperature of 60-65 °C, and then dehydrate the washed fabric; then put the washed fabric in a 6-8% soda ash solution at a water temperature of 25-30 °C Alkaline washing, dehydration again after alkali washing; finally, the fabric after alkali washing is washed for the second time at 25-30 ℃ water temperature, and dehydrated again after washing. The dehydrated fabric was dried at 85°C for 5 minutes.
S6、喷胶：将整理后的面料，平铺后，利用喷雾型喷淋设备在面料外侧表面喷淋雾状防水胶，喷淋时间28s。喷淋后将面料在摊平状态下自然干燥，待面料完全干燥、防水胶完全干燥固化后，制得本实施例的防水、防污面料。S6. Spraying glue: After laying the finished fabric, use spray-type spraying equipment to spray mist-like waterproof glue on the outer surface of the fabric, and the spraying time is 28s. After spraying, the fabric is naturally dried in a flat state, and after the fabric is completely dried and the waterproof glue is completely dried and cured, the waterproof and antifouling fabric of this embodiment is prepared.
实施例4Example 4
本实施例的面料采用以下步骤制备：The fabric of this embodiment is prepared by the following steps:
S1、芯线制备：按照50％棉、25％锦纶、20涤纶和5％聚丙烯纤维的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经抗静电整理剂整理后，脱水处理，然后105℃烘干3min，最终制得芯线。制备的芯线直径控制在70μm。S1. Core yarn preparation: According to the ratio of 50% cotton, 25% nylon, 20 polyester and 5% polypropylene fibers, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then into the mixed cotton Machine-blended cotton into rolls, and then carded and combed by a carding machine to form yarns. After finishing the yarns with antistatic finishing agent, dewatering treatment, and then drying at 105 °C for 3 minutes, the core yarns are finally obtained. The diameter of the prepared core wire is controlled at 70 μm.
S2、外包线制备：按照35％棉、30％耐磨涤纶、25％涤棉和10％麻的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经含氟乳液整理剂和交联剂浸润20min后，脱水处理，然后105℃烘干3min，最终制得外包线。制备的外包线直径控制在21μm。S2. Preparation of outer thread: According to the ratio of 35% cotton, 30% wear-resistant polyester, 25% polyester-cotton and 10% hemp, the above four kinds of short fibers are weighed, put into the cotton grabbing machine for cotton processing, and then enter the The cotton is mixed into a roll by a cotton blender, and then carded and combed by a carding machine to form a thread. The thread is soaked with a fluorine-containing emulsion finishing agent and a cross-linking agent for 20 minutes, dehydrated, and then dried at 105 °C. 3min, and finally the outer line was obtained. The diameter of the prepared outer wire is controlled at 21 μm.
S3、面料用线制备：以芯线和外包线1:6的配比，采用包混的方式混纺，制成直径120μm的面料用线。S3. Fabric thread preparation: The core thread and the outer thread are blended in a ratio of 1:6 and blended to make a fabric thread with a diameter of 120 μm.
S4、织造面料：采用平纹织造的方式，将面料用线编织成面料，织造密度控制在385g/m2。织造完成后，用磨毛辊对面料表面进行磨毛处理。S4. Weaving fabrics: The fabrics are woven into fabrics by means of plain weave, and the weaving density is controlled at 385g/m 2 . After weaving, the surface of the fabric is sanded with a sanding roller.
S5、面料整理：将织造好的面料，在60～65℃水温下第一次水洗，水洗后脱水处理；然后将水洗后的面料在6～8％的纯碱溶液中，在25～30℃水温下碱洗，碱洗后再次脱水；最后将碱洗后的面料，在25～30℃水温下第二次水洗，水洗后再次脱水。脱水处理后的面料，在85℃温度下，烘干5min。S5. Fabric finishing: Wash the woven fabric for the first time at a water temperature of 60-65 °C, and then dehydrate the washed fabric; then put the washed fabric in a 6-8% soda ash solution at a water temperature of 25-30 °C Alkaline washing, dehydration again after alkali washing; finally, the fabric after alkali washing is washed for the second time at 25-30 ℃ water temperature, and dehydrated again after washing. The dehydrated fabric was dried at 85°C for 5 minutes.
S6、喷胶：将整理后的面料，平铺后，利用喷雾型喷淋设备在面料外侧表面喷淋雾状防水胶，喷淋时间25s。喷淋后将面料在摊平状态下自然干燥，待面料完全干燥、防水胶完全干燥固化后，制得本实施例的防水、防污面料。S6. Spray glue: After laying the finished fabric, use spray-type spraying equipment to spray mist-like waterproof glue on the outer surface of the fabric, and the spray time is 25s. After spraying, the fabric is naturally dried in a flat state, and after the fabric is completely dried and the waterproof glue is completely dried and cured, the waterproof and antifouling fabric of this embodiment is prepared.
以North Face冲锋衣防水面料为对比例1，以优衣库防水超轻羽绒服面料为对比例2。按照AATCC-22和AATCC-118标准，将本发明实施例1～4和对比例1～2的面料进行防水和防污的性能测试，而后将本发明实施例1～4和对比例1～2的面料水洗30次后再次进行性能测试，所得结果见表1。Take the North Face jacket waterproof fabric as the comparative example 1, and take the Uniqlo waterproof ultra-light down jacket fabric as the comparative example 2. According to AATCC-22 and AATCC-118 standards, the fabrics of Examples 1 to 4 and Comparative Examples 1 to 2 of the present invention were tested for their waterproof and antifouling properties, and then Examples 1 to 4 of the present invention and Comparative Examples 1 to 2 were tested. The fabric was washed for 30 times and then tested again for performance. The results are shown in Table 1.
表1面料防水、防污及耐水洗测试数据表Table 1 Fabric waterproof, anti-fouling and washing resistance test data table
通过表1的数据可知，本发明的面料防水和防油污的性能较为优异，防水等级能达到4.5级以上，防油污等级能达到6.5级以上，而且水洗30次后，本发明防水、防油污的性能并未有任何下降，性能远优于现有市面上的防水、防污面料。As can be seen from the data in Table 1, the fabric of the present invention has excellent waterproof and oil-proof performance, the waterproof level can reach above 4.5, the oil-proof grade can reach above 6.5, and after 30 times of washing, the waterproof and oil-proof of the present invention The performance has not declined in any way, and the performance is far superior to the existing waterproof and antifouling fabrics on the market.
从表1的数据还可以看出，本发明中，面料的防水和防油污性能与面料用线的尺寸和织造密度有密切的关联。采用90～100μm直径的面料用线，制造密度控制在400～425μm时，面料的防水、防油污性能最佳。发明人推测，采用上述参数的面料，表面形成的微槽结构，拒水、拒油污性能最佳，而超出上述尺寸范围后，表面的微槽结构，拒水、拒油污性能会下降。It can also be seen from the data in Table 1 that in the present invention, the waterproof and anti-oil stain properties of the fabric are closely related to the size and weaving density of the fabric thread. When the fabric wire with a diameter of 90-100 μm is used, and the manufacturing density is controlled at 400-425 μm, the waterproof and oil-proof performance of the fabric is the best. The inventor speculates that the micro-groove structure formed on the surface of the fabric with the above parameters has the best water and oil repellency performance, while beyond the above size range, the surface micro-groove structure, water and oil repellency performance will decline.
实施例5Example 5
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The difference is only in the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：55％棉、20％锦纶、20％涤纶和5％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 55% cotton, 20% nylon, 20% polyester and 5% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例6Example 6
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：55％棉、20％锦纶、22％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 55% cotton, 20% nylon, 22% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例7Example 7
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：55％棉、22％锦纶、20％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 55% cotton, 22% nylon, 20% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例8Example 8
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：55％棉、22％锦纶、20％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 55% cotton, 22% nylon, 20% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、20％耐磨涤纶、30％涤棉和10％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 20% wear-resistant polyester, 30% polyester cotton and 10% hemp.
实施例9Example 9
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：55％棉、22％锦纶、20％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 55% cotton, 22% nylon, 20% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、25％耐磨涤纶、30％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 25% wear-resistant polyester, 30% polyester cotton and 5% hemp.
实施例10Example 10
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：50％棉、25％锦纶、20％涤纶和5％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 50% cotton, 25% nylon, 20% polyester and 5% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例11Example 11
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：50％棉、20％锦纶、25％涤纶和5％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 50% cotton, 20% nylon, 25% polyester and 5% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例12Example 12
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：50％棉、25％锦纶、22％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 50% cotton, 25% nylon, 22% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例13Example 13
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：50％棉、22％锦纶、25％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 50% cotton, 22% nylon, 25% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：40％棉、30％耐磨涤纶、25％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 40% cotton, 30% wear-resistant polyester, 25% polyester cotton and 5% hemp.
实施例14Example 14
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：50％棉、25％锦纶、20％涤纶和5％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 50% cotton, 25% nylon, 20% polyester and 5% polypropylene fibers.
本实施例的外包线采用以下配比：35％棉、25％耐磨涤纶、30％涤棉和10％麻。The outer thread of this embodiment adopts the following proportions: 35% cotton, 25% wear-resistant polyester, 30% polyester cotton and 10% hemp.
实施例15Example 15
本实施例与实施例3采用基本相同的制备工序制备。This example and Example 3 were prepared by basically the same preparation process.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：50％棉、25％锦纶、20％涤纶和5％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 50% cotton, 25% nylon, 20% polyester and 5% polypropylene fibers.
本实施例的外包线采用以下配比：35％棉、30％耐磨涤纶、30％涤棉和5％麻。The outer thread of this embodiment adopts the following proportions: 35% cotton, 30% wear-resistant polyester, 30% polyester cotton and 5% hemp.
按照AATCC-22、AATCC-118、AATCC-79和GB/T5453-1997标准，将本发明实施例5～15和对比例1～2的面料进行防水和防污的性能测试，以及透气、吸湿测试。而后将本发明实施例5～15和对比例1～2的面料水洗30次后再次进行重复测试。全部测试所得结果见表2。According to AATCC-22, AATCC-118, AATCC-79 and GB/T5453-1997 standards, the fabrics of Examples 5-15 and Comparative Examples 1-2 of the present invention were tested for waterproof and antifouling performance, as well as breathability and moisture absorption tests . Then, the fabrics of Examples 5-15 of the present invention and the fabrics of Comparative Examples 1-2 were washed 30 times and then repeated the test again. The results of all tests are shown in Table 2.
表2面料防水、防污、吸湿、透气及耐水洗测试数据表Table 2 Waterproof, antifouling, moisture absorption, breathable and washable test data table of fabrics
由表2可以看出，本发明的面料，在防水、防污性能优异，且耐水洗的基础上，吸湿和透气性也较佳，远优于现有的防水、防污面料。且本发明的吸湿和透气性能，在水洗30次后，仅仅有略微的下降，也远优于现有的防水、防污面料。As can be seen from Table 2, the fabric of the present invention has excellent waterproof and antifouling properties and is resistant to washing, and has better moisture absorption and air permeability, which is far superior to the existing waterproof and antifouling fabrics. In addition, the moisture absorption and air permeability of the present invention are only slightly decreased after 30 times of washing, which is also far superior to the existing waterproof and antifouling fabrics.
从表2的数据可以看出，本发明的面料的吸湿和透气性能，与芯线和外包线的棉含量、聚丙烯纤维含量、麻含量和涤纶含量有密切关系，含棉量、含麻量和聚丙烯纤维含量越高，吸湿性越佳；而涤纶含量越高，透气性越佳。同时，防油污性能也与涤纶含量有关，涤纶含量越高，防油污性能越好。As can be seen from the data in Table 2, the moisture absorption and air permeability of the fabric of the present invention are closely related to the cotton content, polypropylene fiber content, hemp content and polyester content of the core thread and the outer thread. And the higher the polypropylene fiber content, the better the moisture absorption; and the higher the polyester content, the better the breathability. At the same time, the anti-oil performance is also related to the polyester content. The higher the polyester content, the better the anti-oil performance.
实施例16Example 16
本实施例的面料采用以下步骤制备：The fabric of this embodiment is prepared by the following steps:
S1、芯线制备：按照52％棉、20％锦纶、24％涤纶和4％聚丙烯纤维的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经抗静电整理剂整理后，脱水处理，然后95℃烘干5min，最终制得芯线。制备的芯线直径控制在65μm。S1. Preparation of core yarn: According to the ratio of 52% cotton, 20% nylon, 24% polyester and 4% polypropylene fibers, the above four kinds of short fibers are weighed, put into the cotton catching machine for catching cotton, and then entered into the mixing process. The cotton is mixed with cotton into rolls, and then carded and combed by the carding machine to form threads. After finishing the threads with antistatic finishing agent, dewatering is performed, and then dried at 95°C for 5 minutes to finally obtain core threads. . The diameter of the prepared core wire is controlled at 65 μm.
S2、外包线制备：按照38％棉、26％耐磨涤纶、28％涤棉和8％麻的配比，将上述四种短纤维称料后，放入抓棉机抓棉处理，而后进入混棉机混棉成卷，然后经梳棉机梳棉、精梳处理后成线，将制成的线经含氟乳液整理剂和交联剂浸润18min后，脱水处理，然后95℃烘干5min，最终制得外包线。制备的外包线直径控制在18μm。S2. Preparation of outer thread: According to the ratio of 38% cotton, 26% wear-resistant polyester, 28% polyester-cotton and 8% hemp, the above four kinds of short fibers are weighed, put into the cotton grabbing machine to grab the cotton, and then enter the The cotton is mixed with a cotton blender to form a roll, and then the cotton is carded and combed by a carding machine to form a thread. The thread is soaked with a fluorine-containing emulsion finishing agent and a cross-linking agent for 18 minutes, dehydrated, and then dried at 95 °C. 5min, and finally the outer line was obtained. The diameter of the prepared outer wire is controlled at 18 μm.
S3、面料用线制备：以芯线和外包线1:6的配比，采用包混的方式混纺，制成直径100μm的面料用线。S3. Fabric thread preparation: The core thread and the outer thread are blended in a ratio of 1:6 and blended to make a fabric thread with a diameter of 100 μm.
S4、织造面料：采用平纹织造的方式，将面料用线编织成面料，织造密度控制在420g/m2。织造完成后，用磨毛辊对面料表面进行磨毛处理。S4. Weaving fabrics: The fabrics are woven into fabrics by means of plain weave, and the weaving density is controlled at 420g/m 2 . After weaving, the surface of the fabric is sanded with a sanding roller.
S5、面料整理：将织造好的面料，在60～65℃水温下第一次水洗，水洗后脱水处理；然后将水洗后的面料在6～8％的纯碱溶液中，在25～30℃水温下碱洗，碱洗后再次脱水；最后将碱洗后的面料，在25～30℃水温下第二次水洗，水洗后再次脱水。脱水处理后的面料，在85℃温度下，烘干5min。S5. Fabric finishing: Wash the woven fabric for the first time at a water temperature of 60-65 °C, and then dehydrate the washed fabric; then put the washed fabric in a 6-8% soda ash solution at a water temperature of 25-30 °C Alkaline washing, dehydration again after alkali washing; finally, the fabric after alkali washing is washed for the second time at 25-30 ℃ water temperature, and dehydrated again after washing. The dehydrated fabric was dried at 85°C for 5 minutes.
S6、喷胶：将整理后的面料，平铺后，利用喷雾型喷淋设备在面料外侧表面喷淋雾状防水胶，喷淋时间28s。喷淋后将面料在摊平状态下自然干燥，待面料完全干燥、防水胶完全干燥固化后，制得本实施例的防水、防污面料。S6. Spraying glue: After laying the finished fabric, use spray-type spraying equipment to spray mist-like waterproof glue on the outer surface of the fabric, and the spraying time is 28s. After spraying, the fabric is naturally dried in a flat state, and after the fabric is completely dried and the waterproof glue is completely dried and cured, the waterproof and antifouling fabric of this embodiment is prepared.
实施例17Example 17
本实施例与实施例16采用基本相同的制备工序制备。This example and Example 16 were prepared by basically the same preparation procedure.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：52％棉、21％锦纶、23％涤纶和4％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 52% cotton, 21% nylon, 23% polyester and 4% polypropylene fibers.
本实施例的外包线采用以下配比：38％棉、26％耐磨涤纶、29％涤棉和7％麻。The outer thread of this embodiment adopts the following proportions: 38% cotton, 26% wear-resistant polyester, 29% polyester cotton and 7% hemp.
实施例18Example 18
本实施例与实施例16采用基本相同的制备工序制备。This example and Example 16 were prepared by basically the same preparation procedure.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：52％棉、22％锦纶、23％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 52% cotton, 22% nylon, 23% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：38％棉、25％耐磨涤纶、29％涤棉和8％麻。The outer thread of this embodiment adopts the following proportions: 38% cotton, 25% wear-resistant polyester, 29% polyester cotton and 8% hemp.
实施例19Example 19
本实施例与实施例16采用基本相同的制备工序制备。This example and Example 16 were prepared by basically the same preparation procedure.
区别仅在于芯线和外包线的配比。The only difference is the ratio of the core wire and the outer wire.
本实施例的芯线采用以下配比：52％棉、20％锦纶、23％涤纶和3％聚丙烯纤维。The core wire of this embodiment adopts the following proportions: 52% cotton, 20% nylon, 23% polyester and 3% polypropylene fibers.
本实施例的外包线采用以下配比：38％棉、24％耐磨涤纶、30％涤棉和6％麻。The outer thread of this embodiment adopts the following proportions: 38% cotton, 24% wear-resistant polyester, 30% polyester cotton and 6% hemp.
将实施例16～19依据前述标准方法进行综合性能测试，所得结果见表3。The comprehensive performance test of Examples 16-19 was carried out according to the aforementioned standard method, and the results obtained are shown in Table 3.
表3面料综合性能测试数据表Table 3 Fabric comprehensive performance test data table
将实施例16～19，按照GB/T21196-2007的方法，采用测试仪磨200次后，再次进行综合性能测试，所得结果见表4。For Examples 16 to 19, according to the method of GB/T21196-2007, after grinding 200 times with a tester, the comprehensive performance test was performed again, and the results obtained are shown in Table 4.
表4面料磨损后综合性能测试数据表Table 4 Comprehensive performance test data table of fabrics after wear
由表3、表4的数据可以看出，实施例16～19的综合性能要优于本发明的其它实施例。It can be seen from the data in Table 3 and Table 4 that the comprehensive performance of Examples 16 to 19 is better than that of other embodiments of the present invention.
将实施例1～15，以及实施例16～19进行接触舒适性、面料柔软性和耐磨性测试，实施例16～19的面料柔软性和接触舒适性均优于实施例1～15。Examples 1-15 and Examples 16-19 were tested for contact comfort, fabric softness and abrasion resistance, and the fabric softness and contact comfort of Examples 16-19 were better than those of Examples 1-15.
在兼顾防水、防油污、耐水洗和耐磨性能的同时，考虑面料的接触舒适性、柔软性、吸湿性和透气性，在上述因素综合考量下，本发明实施例16～19的技术效果相对最佳，综合性能远优于现有市面同类面料。While taking into account the waterproof, oil-proof, washable and wear-resistant properties, the contact comfort, softness, hygroscopicity and air permeability of the fabric are considered. Under the comprehensive consideration of the above factors, the technical effects of Examples 16 to 19 of the present invention are relatively The best, the comprehensive performance is far better than the existing similar fabrics on the market.
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included in the protection of the present invention. within the range.
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