CN1800283A - Insulating mold coating and its uses - Google Patents

Insulating mold coating and its uses Download PDF

Info

Publication number
CN1800283A
CN1800283A CN 200510000149 CN200510000149A CN1800283A CN 1800283 A CN1800283 A CN 1800283A CN 200510000149 CN200510000149 CN 200510000149 CN 200510000149 A CN200510000149 A CN 200510000149A CN 1800283 A CN1800283 A CN 1800283A
Authority
CN
China
Prior art keywords
company
weight parts
agent
weight
insulating coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 200510000149
Other languages
Chinese (zh)
Other versions
CN100357378C (en
Inventor
张冬海
吴镇江
陈运法
叶树峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Process Engineering of CAS
Original Assignee
Institute of Process Engineering of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Process Engineering of CAS filed Critical Institute of Process Engineering of CAS
Priority to CNB2005100001490A priority Critical patent/CN100357378C/en
Publication of CN1800283A publication Critical patent/CN1800283A/en
Application granted granted Critical
Publication of CN100357378C publication Critical patent/CN100357378C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Paints Or Removers (AREA)

Abstract

本发明涉及一种隔热涂料，其组成包括：成膜物15～65重量份；纳米多孔SiO23～20重量份；纳米氧化铁黄1～12重量份；颜料5～30重量份；填料3～22重量份；助剂0.4～8重量份；溶剂6～30重量份。该隔热涂料可广泛应用于各种需要降温、隔热设备或建筑，特别是用于外墙、金属储罐、管道、仪器设备、运输业、工业建筑、民用建筑及飞行器等。20μm的涂层厚度即可明显改善隔热降温效果，最佳涂膜厚度为35～45μm。该隔热涂料对太阳热和红外辐射都有高反射率、隔热效率高、抗紫外线能力强，且具有超耐候性、强附着力及高自洁性性能。The invention relates to a heat-insulating paint, which comprises: 15-65 parts by weight of film-forming material; 3-20 parts by weight of nano-porous SiO 2 ; 1-12 parts by weight of nano-iron oxide yellow; 5-30 parts by weight of pigment; 3-22 parts by weight; 0.4-8 parts by weight of auxiliary agent; 6-30 parts by weight of solvent. The heat-insulating coating can be widely used in various cooling and heat-insulating equipment or buildings, especially for exterior walls, metal storage tanks, pipelines, instruments and equipment, transportation, industrial buildings, civil buildings, and aircraft. A coating thickness of 20 μm can significantly improve the heat insulation and cooling effect, and the optimum coating thickness is 35-45 μm. The thermal insulation coating has high reflectivity to solar heat and infrared radiation, high thermal insulation efficiency, strong UV resistance, super weather resistance, strong adhesion and high self-cleaning performance.

Description

一种隔热涂料及其用途A kind of heat insulation coating and its application

技术领域technical field

本发明涉及一种涂料，具体地说是涉及一种可广泛应用于各种需要降温、隔热设备或建筑的新型隔热涂料及其用途。The invention relates to a paint, in particular to a new type of heat-insulating paint that can be widely used in various cooling and heat-insulating equipment or buildings and its application.

背景技术Background technique

当今世界，人类对能源的消耗急剧增长，使得能源紧缺，从而带动能源及其相关系列产品的价格不断升高。以中国为例，近年来用电持续出现紧张，2004年共有近30个省级电网拉闸限电，大量工厂被迫停产，造成大量经济损失。2003年中国每天的原油消费量增长44万桶，对全球原油需求增长的贡献率达到35％；到2020年，中国的石油需求量的下限为4.5亿吨，上限为6.1亿吨，中国的能源需求总量将达到25亿吨标准煤，这个数字比2000年高出90％～152％，对海外资源的依存度至少将达到55％以上，与目前美国58％的对外依存度大体相当。虽然人类不断地尝试开发新能源，但目前还未找到一种可以完全替代石油、煤炭、天然气等关系到国计民生的新能源。因此，如何高效地利用能源、减少能源浪费就显得更加重要。In today's world, human's consumption of energy is increasing rapidly, which makes energy shortage, which drives up the price of energy and related products. Take China as an example. In recent years, power consumption has continued to be tense. In 2004, nearly 30 provincial-level power grids were shut down, and a large number of factories were forced to stop production, causing a lot of economic losses. In 2003, China's daily crude oil consumption increased by 440,000 barrels, contributing 35% to the growth of global crude oil demand; by 2020, the lower limit of China's oil demand will be 450 million tons, and the upper limit will be 610 million tons. The total demand will reach 2.5 billion tons of standard coal, which is 90% to 152% higher than that in 2000, and the dependence on overseas resources will reach at least 55%, which is roughly equivalent to the current US dependence on foreign countries of 58%. Although humans are constantly trying to develop new energy sources, they have not yet found a new energy source that can completely replace oil, coal, natural gas, etc., which are related to the national economy and people's livelihood. Therefore, how to efficiently use energy and reduce energy waste is even more important.

造成能源浪费的原因很多。以隔热领域为例，在炎热的夏季，由于太阳的辐射，石油化工、酒厂的金属和水泥储罐表面温度高达五六十度，罐内的温度甚至会更高，不仅造成大量的蒸发损耗，污染环境，而且会造成危险。传统涂刷银粉漆和使用喷淋水降温，腐蚀设备、浪费能源，而且设备使用寿命短，仅有两三年。粮仓粮库的升温会加速粮食的劣变和生虫，用空调降温用电量大，成本高。飞行器、工厂的仪器设备等由于受到热辐射或红外辐射而减少了使用寿命或降低了精确度，同样造成了浪费。总之，从工业建筑到民用建筑，从储罐、管道、厂房、仓库、仪器设备、飞行器到住宅楼、售货厅、电话厅等由于受辐射升温的影响而采用传统的方法去降温，都会造成大量的人力、物力、财力的浪费。There are many reasons for wasting energy. Take the field of heat insulation as an example. In the hot summer, due to the radiation of the sun, the surface temperature of metal and cement storage tanks in petrochemical and wineries is as high as fifty or sixty degrees, and the temperature inside the tank will be even higher, which not only causes a large amount of evaporation consumption, pollute the environment, and cause danger. The traditional method of painting with silver powder paint and using spray water to cool down will corrode the equipment and waste energy, and the service life of the equipment is short, only two or three years. The heating of granaries and granaries will accelerate the deterioration of grains and the infestation of insects. Using air conditioners to cool down consumes a lot of electricity and costs a lot. Aircraft, factory instruments and equipment, etc. have reduced service life or reduced accuracy due to heat radiation or infrared radiation, which also causes waste. In short, from industrial buildings to civil buildings, from storage tanks, pipelines, workshops, warehouses, instruments and equipment, aircraft to residential buildings, sales halls, telephone halls, etc. due to the influence of radiation heating, traditional methods to cool down will cause A lot of waste of manpower, material resources and financial resources.

人们早已认识到了这一问题的重要性，并提出和实施了多种解决办法。在现有的相关技术中，中国专利CN1204672A公开了一种白色改性丙烯酸醇酸类反射太阳热涂料，但其太阳热反射率低，仅有80％，且颜色单一，户外耐候性较差。中国专利CN1405248A公开了一种丙烯酸树脂太阳热反射涂料，但其附着力较差，冲击强度不高，太阳热吸收率随时间变化较大，且不具有反射红外辐射的性能。中国专利CN1257897A公开了一种既能反射太阳热，又有一定隔热和自清洁作用的隔热涂料，但效果都不是很好。另外，日本专利JP98-1209466、德国专利DE19501114、美国专利US5540998、中国专利CN1434063A都公开了的反射涂料，反射率都不高，隔热效率也不是很好。The importance of this problem has long been recognized, and various solutions have been proposed and implemented. In the existing related technology, Chinese patent CN1204672A discloses a white modified acrylic alkyd reflective solar heat coating, but its solar heat reflectance is low, only 80%, and the color is single, and the outdoor weather resistance is poor. Chinese patent CN1405248A discloses an acrylic resin solar heat reflective coating, but its adhesion is poor, its impact strength is not high, its solar heat absorption rate changes greatly with time, and it does not have the performance of reflecting infrared radiation. Chinese patent CN1257897A discloses a kind of heat-insulating coating that can not only reflect solar heat, but also have certain heat-insulating and self-cleaning effects, but the effects are not very good. In addition, the reflective coatings disclosed in Japanese Patent JP98-1209466, German Patent DE19501114, US Patent US5540998, and Chinese Patent CN1434063A all have low reflectivity and poor heat insulation efficiency.

发明内容Contents of the invention

本发明的目的在于克服现有的太阳热反射涂料的反射率低、隔热效率不是很好、而且颜色单一、户外耐候性和附着力较差、冲击强度不高的缺陷，从而提供一种对太阳热和红外辐射都有高反射率、隔热效率高、抗紫外线能力强，且具有超耐候性、强附着力及高自洁性性能的新型隔热涂料，及其用途。The purpose of the present invention is to overcome the defects of low reflectivity, poor heat insulation efficiency, single color, poor outdoor weather resistance and adhesion, and low impact strength of existing solar heat reflective coatings, thereby providing a Both solar heat and infrared radiation have high reflectivity, high heat insulation efficiency, strong UV resistance, and a new type of heat insulation coating with super weather resistance, strong adhesion and high self-cleaning performance, and its application.

本发明的目的是通过如下的技术方案实现的：The purpose of the present invention is achieved through the following technical solutions:

本发明提供的隔热涂料，其组成包括：The thermal insulation paint provided by the invention comprises:

      成膜物               15～65重量份；                                                                                                                                                                                                                                                                                                        

      纳米多孔SiO2        3～20重量份；3-20 parts by weight of nanoporous SiO 2 ;

      纳米氧化铁黄         1～12重量份；  Nano iron oxide yellow   1-12 parts by weight;

      颜料                 5～30重量份；Pigment 5-30 parts by weight;

      填料                 3～22重量份；Filler 3-22 parts by weight;

      助剂                 0.4～8重量份；Auxiliaries 0.4 to 8 parts by weight;

      溶剂                 6～30重量份；Solvent 6-30 parts by weight;

所述的成膜物包括聚酯树脂、醇酸树脂、环氧树脂、丙烯酸树脂、氨基树脂、酚醛树脂、聚氯乙烯树脂、有机硅改性聚酯树脂、有机硅改性丙烯酸树脂、有机硅树脂、氟碳树脂，根据不同的性能要求，选择不同的树脂。The film-forming material includes polyester resin, alkyd resin, epoxy resin, acrylic resin, amino resin, phenolic resin, polyvinyl chloride resin, organosilicon modified polyester resin, organosilicon modified acrylic resin, organosilicon Resin, fluorocarbon resin, according to different performance requirements, choose different resins.

所述的纳米多孔SiO2的粒径为10～600nm，其制备方法如下：在三口烧瓶中加入100ml乙醇，搅拌下加入0.2～1.2ml浓度为0.1M的盐水和0.1M聚合物的乙醇溶液，室温下继续搅拌，通氮保护，再加入0.8～4.2ml的正硅酸四乙酯(TEOS)，充分搅拌1～5h，静置，离心分离后用乙醇洗涤，反复数次，最后在230～460℃下烧结，过筛，即得到纳米多孔SiO2；The particle diameter of described nanoporous SiO2 is 10～600nm, and its preparation method is as follows: add 100ml ethanol in the there-necked flask, add 0.2～1.2ml concentration and be the ethanol solution of 0.1M brine and 0.1M polymer under stirring, Continue to stir at room temperature, nitrogen protection, then add 0.8 ~ 4.2ml of tetraethyl orthosilicate (TEOS), fully stir for 1 ~ 5h, let stand, wash with ethanol after centrifugation, repeat several times, finally at 230 ~ Sintering at 460°C and sieving to obtain nanoporous SiO 2 ;

其中，所述的盐包括NaCl、NaI、KBr、KCl、KI、KNO3、LiCl、CsCl等；Wherein, the salt includes NaCl, NaI, KBr, KCl, KI, KNO 3 , LiCl, CsCl, etc.;

所述的聚合物为RaO(CH2CH2O)bH，Ra为C6～C18的烷基，b＝3～15；或HO(CH2CH2O)x(CH(CH3)CH2O)y(CH2CH2O)zH，x，y，z＝1～65，且摩尔质量为1650～2900g/mol。The polymer is R a O(CH 2 CH 2 O) b H, R a is an alkyl group of C 6 to C 18 , b=3 to 15; or HO(CH 2 CH 2 O)x(CH( CH 3 )CH 2 O)y(CH 2 CH 2 O)zH, x, y, z=1-65, and the molar mass is 1650-2900 g/mol.

所述的纳米氧化铁黄的粒径为10～500nm，其制备方法如CN200410047955.3中所公开。The particle size of the nano iron oxide yellow is 10-500nm, and its preparation method is disclosed in CN200410047955.3.

所述的颜料为选自金红石钛白、酞菁蓝、酞菁绿、碳黑、氧化铁红、锌铬黄、中铬黄、柠檬铬黄、深铬黄、铬绿、钼铬红中的一种或几种。The pigment is selected from rutile titanium dioxide, phthalocyanine blue, phthalocyanine green, carbon black, iron oxide red, zinc chrome yellow, medium chrome yellow, lemon chrome yellow, deep chrome yellow, chrome green, molybdenum chrome red one or several.

所述的填料为选自氧化锌、硫酸钡、二氧化硅、滑石粉、绢云母、轻质碳酸钙、硅灰石粉中的一种或几种。The filler is one or more selected from zinc oxide, barium sulfate, silicon dioxide, talcum powder, sericite, light calcium carbonate, and wollastonite powder.

所述的助剂包括分散剂(如德国BYK Chemie公司的BYK-110、BYK-P104、Disperbyk-130；荷兰EFKA公司的Efka-766、Efka Polymer452)、消泡剂(如德国BYKChemie公司的BYK-065、BYK-052；荷兰EFKA公司的Efka-20；德国Tego公司的Airex970)、流平剂(如德国BYK Chemie公司的BYK-354、BYK-300；荷兰EFKA公司的Efka-30、Efka-772)、酸催化剂(如德国BYK Chemie公司的的BYK-Catalyst450；KIMG INDUSTRIES公司的NACURE155、1051、K-CURE1040)、防沉剂(如台湾德谦贸易公司的防沉剂902、201P；德国Bayer公司的BORCHIGEL THIXO Z等)、增塑剂(如上海溶剂厂的增塑剂DOP、磷酸三丁酯；德国Henkel公司的EDENOL344)、增滑剂(如台湾三化实业公司的840SL、AMA；Allied Signal公司的A-C6、Acumist B-6)、增稠剂(如德国Henkel公司的DEHYSOLR、RILANIT45)、固化剂(如台湾德谦贸易公司的KB、KC、DBTDL固化促进剂；江西泰兴涂料助剂厂的JTY固化促进剂)中的一种或几种。Described auxiliary agent comprises dispersant (as BYK-110, BYK-P104, Disperbyk-130 of BYK Chemie Company of Germany; Efka-766, Efka Polymer452 of EFKA Company of Holland), defoamer (BYK-104 such as BYK Chemie Company of Germany) 065, BYK-052; Efka-20 from EFKA in the Netherlands; Airex970 from Tego in Germany), leveling agents (such as BYK-354 and BYK-300 from BYK Chemie in Germany; Efka-30 and Efka-772 from EFKA in the Netherlands ), acid catalyst (such as BYK-Catalyst450 of BYK Chemie Company in Germany; NACURE155, 1051, K-CURE1040 of KIMG INDUSTRIES Company), anti-settling agent (such as anti-settling agent 902, 201P of Taiwan Deqian Trading Company; Bayer Company of Germany BORCHIGEL THIXO Z, etc.), plasticizer (such as plasticizer DOP, tributyl phosphate of Shanghai Solvent Factory; EDENOL ® 344 of German Henkel Company), slip agent (such as 840SL, AMA of Taiwan Sanhua Industrial Company; Allied Signal company's A-C6, Acumist B-6), thickener (such as DEHYSOL ® R, RILANIT ® 45 of Henkel Company in Germany), curing agent (such as KB, KC, DBTDL curing accelerator of Taiwan Deqian Trading Company ; Jiangxi Taixing Coating Auxiliary Factory's JTY curing accelerator) in one or more.

所述的溶剂选自乙酸乙酯、乙酸丁酯、乙二醇乙醚醋酸酯、二甲苯、乙二醇丁醚、丁醇、甲基异丁基酮、丙二醇甲醚乙酸酯、石油醚、200号油漆溶剂油、环己酮、芳烃溶剂100号、芳烃溶剂150号、芳烃溶剂200号、混合二元酸二酯中的一种或几种。Described solvent is selected from ethyl acetate, butyl acetate, ethylene glycol ethyl ether acetate, xylene, ethylene glycol butyl ether, butanol, methyl isobutyl ketone, propylene glycol methyl ether acetate, sherwood oil, One or more of No. 200 paint spirit, cyclohexanone, No. 100 aromatic solvent, No. 150 aromatic solvent, No. 200 aromatic solvent, and mixed dibasic acid diester.

将上述组份混合，经分散、研磨、调色后即得到本发明的隔热涂料。The above-mentioned components are mixed, dispersed, ground, and toned to obtain the heat-insulating coating of the present invention.

本发明提供的隔热涂料可广泛应用于各种需要降温、隔热设备或建筑，特别是用于外墙、金属储罐、管道、仪器设备、运输业、工业建筑、民用建筑及飞行器等。20μm的涂层厚度即可明显改善隔热降温效果，最佳涂膜厚度为35～45μm。The heat-insulating coating provided by the invention can be widely used in various cooling and heat-insulating equipment or buildings, especially for exterior walls, metal storage tanks, pipelines, instruments and equipment, transportation, industrial buildings, civil buildings, and aircraft. A coating thickness of 20 μm can significantly improve the heat insulation and cooling effect, and the optimum coating thickness is 35-45 μm.

在用于外墙、储罐、管道、仪器设备、飞行器等时，本发明提供的新型隔热涂料组成优选下述组成：When being used for exterior walls, storage tanks, pipelines, instruments and equipment, aircrafts, etc., the novel heat-insulating paint provided by the invention forms the preferred following composition:

      成膜物                15～50重量份；Film formers 15-50 parts by weight;

      纳米多孔SiO2         4～20重量份；4-20 parts by weight of nanoporous SiO 2 ;

      纳米氧化铁黄          1～9重量份；  Nano iron oxide yellow   1-9 parts by weight;

      颜料                  5～30重量份；Pigment 5-30 parts by weight;

      填料                  6～22重量份；Filler 6-22 parts by weight;

      助剂                  0.4～6重量份；Auxiliary 0.4-6 parts by weight;

      溶剂                  6～25重量份。Solvent 6-25 parts by weight.

在用于厂房、仓库、售货厅、电话厅等彩钢板时，本发明提供的新型隔热涂料组成优选下述组成：When used in color steel plates such as workshops, warehouses, sales halls, and telephone halls, the composition of the novel heat-insulating coating provided by the present invention is preferably as follows:

      成膜物                20～65重量份；Film formers 20-65 parts by weight;

      纳米多孔SiO2         3～18重量份；3-18 parts by weight of nanoporous SiO 2 ;

      纳米氧化铁黄          3～12重量份；  Nano iron oxide yellow   3-12 parts by weight;

      颜料                  5～30重量份；Pigment 5-30 parts by weight;

      填料                  3～20重量份；Filler 3-20 parts by weight;

      助剂                  0.6～8重量份；Auxiliary 0.6-8 parts by weight;

      溶剂                  10～30重量份。Solvent 10-30 parts by weight.

本发明提供的新型隔热涂料与现有的太阳热反射涂料相比，其优益之处在于：涂料附着力强，防腐性能优良，耐候性好，抗划伤能力强，既可作底漆也可作面漆；而且反射热辐射能力强，隔热效率高，20μm的涂层厚度即可明显改善隔热降温效果，最佳涂膜厚度为35～45μm；另外，该新型隔热涂料同时具有优良的自清洁性能，反射率随时间变化较小。Compared with the existing solar heat reflective coatings, the new heat-insulating coating provided by the invention has the advantages of strong coating adhesion, excellent anti-corrosion performance, good weather resistance, strong scratch resistance, and can be used as a primer It can also be used as a top coat; and it has a strong ability to reflect heat radiation and high heat insulation efficiency. A coating thickness of 20 μm can significantly improve the heat insulation and cooling effect, and the optimum coating thickness is 35-45 μm; It has excellent self-cleaning performance, and the reflectivity changes little with time.

具体实施方式Detailed ways

以下结合实例对本发明作进一步具体描述，但并不局限于此。The present invention is further described in detail below in conjunction with examples, but is not limited thereto.

其中，所述的纳米多孔SiO2为按下述方法自制：在三口烧瓶中加入100ml乙醇，搅拌下加入0.2～1.2ml浓度为0.1M的盐水(NaCl、NaI、KBr、KCl、KI、KNO3、LiCl或CsCl)和0.1M聚合物(RaO(CH2CH2O)bH，Ra为C6～C18的烷基，b＝3～15；或HO(CH2CH2O)x(CH(CH3)CH2O)y(CH2CH2O)zH，x，y，z＝1～65，且摩尔质量为1650～2900g/mol)的乙醇溶液，室温下继续搅拌，通氮保护，再加入0.8～4.2ml的正硅酸四乙酯(TEOS)，充分搅拌1～5h，静置，离心分离后用乙醇洗涤，反复数次，最后在230～460℃下烧结，过筛，即得到纳米多孔SiO2；Wherein, the nanoporous SiO2 is self-made according to the following method: add 100ml ethanol to a three-necked flask, and add 0.2 to 1.2ml of brine (NaCl, NaI, KBr, KCl, KI, KNO3 ) with a concentration of 0.1M under stirring. , LiCl or CsCl) and 0.1M polymer (R a O(CH 2 CH 2 O) b H, R a is C 6 ~ C 18 alkyl, b=3 ~ 15; or HO (CH 2 CH 2 O )x(CH(CH 3 )CH 2 O)y(CH 2 CH 2 O)zH, x, y, z=1～65, and the molar mass is 1650～2900g/mol) ethanol solution, continue to stir at room temperature , protected by nitrogen, then add 0.8~4.2ml tetraethyl orthosilicate (TEOS), fully stir for 1~5h, let stand, wash with ethanol after centrifugation, repeat several times, and finally sinter at 230~460°C , and sieved to obtain nanoporous SiO 2 ;

所述的纳米氧化铁黄的制备方法如CN200410047955.3中所公开。The preparation method of the nano iron oxide yellow is disclosed in CN200410047955.3.

实施例1、海蓝醇酸树脂新型外墙隔热涂料Example 1. Seablue Alkyd Resin Novel Exterior Wall Thermal Insulation Coating

本发明提供的海蓝醇酸树脂新型外墙隔热涂料的配方列于表1。The formula of the sea blue alkyd resin novel exterior wall thermal insulation paint provided by the invention is listed in Table 1.

         表1、海蓝醇酸树脂新型外墙隔热涂料的配方   物料   规格   用量/Kg   供应商   醇酸树脂纳米多孔SiO2纳米铁黄酞菁蓝钛白炭黑铅铬黄沉淀硫酸钡绢云母硅灰石分散剂消泡剂流平剂增稠剂增滑剂防沉剂增塑剂乙酸丁酯   SintalR05(油度35％)200nm300nmR1216-01BGSR960N110柠檬铬黄5011250m800目800目BYK-110BYK-065Efka-30DEHYSOLRMW-1875201PDOP溶剂   25413.870.10.13342.50.80.20.20.20.20.150.1510   Multi Resine公司自制自制深圳华苏化工公司美国DuPont公司苏州宝化炭黑公司上海一品颜料公司科创化工公司国利超细粉体公司国利超细粉体公司BYK Chemie公司BYK Chemie公司荷兰EFKA公司德国Henkel公司台湾德谦贸易公司台湾德谦贸易公司上海溶剂厂上海东盐化工公司 Table 1. The formula of the new type of exterior wall thermal insulation coating made of sea blue alkyd resin materials Specification Dosage/Kg supplier Alkyd Resin Nanoporous SiO 2 Nano Iron Yellow Phthalocyanine Blue Titanium White Carbon Black Lead Chrome Yellow Precipitated Barium Sulfate Sericite Wollastonite Dispersant Defoamer Leveling Agent Thickener Slip Agent Anti-sedimentation Agent Plasticizer Butyl Acetate SintalR05 (35% oil) 200nm300nmR1216-01BGSR960N110 lemon chrome yellow 5011250m800 mesh 800 mesh BYK-110BYK-065Efka-30DEHYSOL ® RMW-1875201PDOP solvent 25413.870.10.13342.50.80.20.20.20.20.150.1510 Multi Resine self-made Shenzhen Huasu Chemical Company American DuPont Company Suzhou Baohua Carbon Black Company Shanghai Yipin Pigment Company Kechuang Chemical Company Guoli Superfine Powder Company Guoli Superfine Powder Company BYK Chemie Company BYK Chemie Company Netherlands EFKA Company Germany Henkel Company Taiwan Deqian Trading Company Taiwan Deqian Trading Company Shanghai Solvent Factory Shanghai Dongyan Chemical Company

实施例2、白色丙烯酸树脂新型储罐用隔热涂料Embodiment 2, white acrylic resin novel storage tank heat-insulating paint

本发明提供的白色丙烯酸树脂新型储罐用隔热涂料的配方列于表2。The formula of the white acrylic resin novel storage tank heat-insulating paint provided by the invention is listed in Table 2.

         表2、白色丙烯酸树脂新型储罐用隔热涂料的配方   物料   规格   用量/Kg   供应商   丙烯酸树脂纳米多孔SiO2纳米铁黄钛白沉淀硫酸钡绢云母氧化锌轻质碳酸钙分散剂消泡剂酸催化剂流平剂防粘增滑剂增稠剂防沉剂增塑剂乙酸丁酯   4404(固含量50±1％)300nm350nmR9601250目800目A级99.7％1250目BYK-P104BYK-052BYK-Catalyst450Efka-772840SLDEHYSOLR201PAcumist B-6溶剂   3512424311240.70.31.20.20.30.20.20.1515   上海新华树脂厂自制自制美国DuPont公司科创化工公司国利超细粉体公司柳州锌品公司国利超细粉体公司德国BYK Chemie公司德国BYK Chemie公司德国BYK Chemie公司荷兰EFKA公司台湾三化实业公司德国Henkel公司台湾德谦贸易公司Allied Signal公司上海东盐化工公司 Table 2. Formulation of white acrylic resin new thermal insulation coating for storage tanks materials Specification Dosage/Kg supplier Acrylic resin nanoporous SiO 2 nano iron yellow titanium white precipitated barium sulfate sericite zinc oxide light calcium carbonate dispersant defoamer acid catalyst leveling agent anti-sticking slip agent thickener anti-sedimentation agent plasticizer butyl acetate 4404 (solid content 50±1%) 300nm350nmR9601250 mesh 800 mesh A grade 99.7% 1250 mesh BYK-P104BYK-052BYK-Catalyst450Efka-772840SLDEHYSOL ® R201PAcumist B-6 solvent 3512424311240.70.31.20.20.30.20.20.1515 Shanghai Xinhua Resin Factory self-made self-made U.S. DuPont Company Kechuang Chemical Company Guoli Superfine Powder Company Liuzhou Zinc Products Company Guoli Superfine Powder Company Germany BYK Chemie Company Germany BYK Chemie Company Germany BYK Chemie Company Netherlands EFKA Company Taiwan Sanhua Industry Company Germany Henkel Company Taiwan Deqian Trading Company Allied Signal Company Shanghai Dongyan Chemical Company

实施例3、用于机器设备防红外辐射的丙烯酸树脂新型隔热涂料Embodiment 3, be used for the acrylic resin novel heat-insulating paint of machine equipment anti-infrared radiation

本发明提供的用于机器设备防红外辐射的丙烯酸树脂新型隔热涂料的配方列于表3。The formulation of the novel acrylic resin heat-insulating coating for the anti-infrared radiation of machinery and equipment provided by the invention is listed in Table 3.

  表3、用于机器设备防红外辐射的丙烯酸树脂新型隔热涂料的配方   物料  规格   用量/Kg   供应商   丙烯酸树脂纳米多孔SiO2纳米铁黄  4550(固含量55±2％)150nm400nm   501512   上海新华树脂厂自制自制   酞菁蓝钛白炭黑中铬黄沉淀硫酸钡绢云母硅灰石分散剂消泡剂流平剂固化剂增稠剂防沉剂增塑剂乙酸丁酯   R1216-01 BGSR960N1151031250目800目800目Disperbyk-130Efka-20BYK-300DBTDLRILANIT45BORCHIGEL THIXO Z磷酸三丁酯溶剂   3.880.10.13312.50.50.150.154.60.20.150.1517   深圳华苏化工公司美国DuPont公司苏州宝化炭黑公司上海一品颜料公司科创化工公司国利超细粉体公司国利超细粉体公司德国BYK Chemie公司荷兰EFKA公司德国BYK Chemie公司台湾德谦贸易公司德国Henkel公司德国Bayer公司上海溶剂厂上海东盐化工公司 Table 3. The formula of the new acrylic resin heat-insulating coating used for preventing infrared radiation of machinery and equipment materials Specification Dosage/Kg supplier Acrylic Resin Nanoporous SiO2 Nano Iron Yellow 4550 (solid content 55±2%) 150nm400nm 501512 Shanghai Xinhua Resin Factory self-made Phthalocyanine Blue Titanium White Carbon Black Chrome Yellow Precipitated Barium Sulfate Sericite Wollastonite Dispersant Defoamer Leveling Agent Curing Agent Thickener Anti-sedimentation Agent Plasticizer Butyl Acetate R1216-01 BGSR960N1151031250 Mesh 800 Mesh 800 Mesh Disperbyk-130Efka-20BYK-300DBTDLRILANIT ® 45BORCHIGEL THIXO Z Tributyl Phosphate Solvent 3.880.10.13312.50.50.150.154.60.20.150.1517 Shenzhen Huasu Chemical Co., Ltd. American DuPont Co., Ltd. Suzhou Baohua Carbon Black Co., Ltd. Shanghai Yipin Pigment Co., Ltd. Kechuang Chemical Co., Ltd. Guoli Superfine Powder Co., Ltd. Guoli Superfine Powder Co., Ltd. Trading Company Germany Henkel Company Germany Bayer Company Shanghai Solvent Factory Shanghai Dongyan Chemical Company

实施例4、用于飞行器的亚光有机硅改性丙烯酸树脂新型隔热涂料Embodiment 4, the novel heat-insulating coating of matt organosilicon modified acrylic resin for aircraft

本发明提供的用于飞行器的亚光有机硅改性丙烯酸树脂新型隔热涂料的配方列于表4。The formulation of the novel heat-insulating paint for the matt silicone modified acrylic resin provided by the invention is listed in Table 4.

 表4、用于飞行器的亚光有机硅改性丙烯酸树脂新型隔热涂料的配方   物料  规格   用量/Kg   供应商   丙烯酸树脂  AU-2608(固含量60％)   30   美国Rohm&Haas公司   有机硅树脂纳米多孔SiO2纳米铁黄钛白氧化锌绢云母二氧化硅轻质碳酸钙  MSE100(固含量100％)30nm150nmR960A级99.7％800目800目1250目   121710113131   德国Wacker公司自制自制美国DuPont公司柳州锌品公司国利超细粉体公司国利超细粉体公司国利超细粉体公司   分散剂消泡剂增滑剂流平剂增稠剂防沉剂增塑剂固化剂乙酸丁酯   Efka Polymer452Airex970Ceraflour960Efka-30RILANIT45902EDENOL344KC溶剂   10.20.10.20.150.150.2415   荷兰EFKA公司德国Tego公司德国BYK Chemie公司荷兰EFKA公司德国Henkel公司台湾德谦贸易公司德国Henkel公司台湾德谦贸易公司上海东盐化工公司 Table 4. Formulation of new heat-insulating coatings for matte silicone-modified acrylic resins for aircraft materials Specification Dosage/Kg supplier Acrylic AU-2608 (solid content 60%) 30 American Rohm&Haas Company Silicone Resin Nanoporous SiO 2 Nano Iron Yellow Titanium White Zinc Oxide Sericite Silica Light Calcium Carbonate MSE100 (solid content 100%) 30nm150nmR960A grade 99.7% 800 mesh 800 mesh 1250 mesh 121710113131 German Wacker Company self-made American DuPont Company Liuzhou Zinc Products Company Guoli Superfine Powder Company Guoli Superfine Powder Company Guoli Superfine Powder Company Dispersant defoamer slip agent leveling agent thickener anti-settling agent plasticizer curing agent butyl acetate Efka Polymer452Airex970Ceraflour960Efka- 30RILANIT® 45902EDENOL® 344KC solvent 10.20.10.20.150.150.2415 Netherlands EFKA Company Germany Tego Company Germany BYK Chemie Company Netherlands EFKA Company Germany Henkel Company Taiwan Deqian Trading Company Germany Henkel Company Taiwan Deqian Trading Company Shanghai Dongyan Chemical Company

对实施例1～4制备的新型隔热涂料进行性能测试，列于表5。The performance tests of the novel heat-insulating coatings prepared in Examples 1-4 are listed in Table 5.

                表5、新型隔热涂料性能测试   检测项目   技术指标   测试标准   容器中状态固体含量％表干时间/h实干时间/h粘度(涂-4杯/23℃)/s附着力级别耐水性96h耐酸性24h 5％盐酸耐碱性48h10％NaOH粉化/级(500h)变色/级(500h)耐洗刷性/次耐紫外光2000h人工加速老化2000h热导率w/(m·k)接触角太阳反射率   均匀无硬块≥65≤0.5≤2490～1201级漆膜完好无变化漆膜完好无变化漆膜完好无变化0级0级≥10000漆膜完好无变化漆膜完好无变化0.048≥105°≥0.92   目测GB1725-79(89)GB1728-79(89)GB1728-79(89)GB1725-99GB1720-79(89)实测GB1763-79(89)GB1865-79(89)外委检测外委检测实测实测GB1865-80(89)GB10294实测外委检测 Table 5. Performance test of new thermal insulation coating Test items technical indicators standard test State solid content in the container % Surface dry time/h hard drying time/h viscosity (coating -4 cups/23°C)/s adhesion level water resistance 96h acid resistance 24h 5% hydrochloric acid alkali resistance 48h 10% NaOH powdering/grade ( 500h) discoloration/grade (500h) scrub resistance/second UV resistance 2000h artificial accelerated aging 2000h thermal conductivity w/(m·k) contact angle solar reflectance Uniform and no hard lumps ≥65≤0.5≤2490～1201 The paint film is intact and unchanged The paint film is intact and unchanged The paint film is intact and unchanged Level 0 Grade 0≥10000 The paint film is intact and unchanged The paint film is intact and unchanged 0.048≥105°≥0.92 Visual inspection GB1725-79(89)GB1728-79(89)GB1728-79(89)GB1725-99GB1720-79(89) Actual measurement GB1763-79(89)GB1865-79(89) External inspection External inspection External inspection Actual measurement GB1865- 80 (89) GB10294 actual measurement outsourced detection

实施例5、银灰聚酯卷材面漆新型隔热涂料Embodiment 5, silver-gray polyester coil topcoat novel heat-insulating coating

本发明提供的银灰聚酯卷材面漆新型隔热涂料的配方列于表6。The formulation of the novel heat-insulating coating for the silver-gray polyester coil topcoat provided by the present invention is listed in Table 6.

               表6、银灰聚酯卷材面漆新型隔热涂料的配方   物料   规格   用量/Kg   供应商   聚酯树脂纳米多孔SiO2纳米铁黄钛白炭黑氧化铁黄酞菁蓝氧化锌绢云母硅灰石轻质碳酸钙分散剂消泡剂增滑剂防粘增滑剂流平剂增稠剂酸催化剂固化剂防沉剂增塑剂环己酮芳烃溶剂100号乙二醇乙醚醋酸酯   Desmophen650(固含量65％)400nm30nmR960N115S313R1216-01BGSA级99.7％800目800目1250目Efka-766Airex970Ceraflour960AMABYK-354RILANIT451051JTY201PEDENOL344溶剂溶剂溶剂   507.54230.520.143220.80.20.10.10.20.21.150.250.28.5512   德国Bayer公司自制自制美国DuPont苏州宝化炭黑公司上海一品颜料公司深圳华苏化工公司柳州锌品公司国利超细粉体公司国利超细粉体公司国利超细粉体公司荷兰EFKA公司德国Tego公司德国BYK Chemie公司台湾三化实业公司德国BYK Chemie公司德国Henkel公司KING INDUSTRIES公司江西泰兴涂料助剂厂台湾德谦贸易公司德国Henkel公司瑞安市企征化工公司扬州华伦化工公司江苏宜兴助剂厂 Table 6. Formula of new heat-insulating coating for silver-gray polyester coil topcoat materials Specification Dosage/Kg supplier Polyester Resin Nanoporous SiO 2 Nano Iron Yellow Titanium White Carbon Black Iron Oxide Yellow Phthalocyanine Blue Oxide Zinc Sericite Wollastonite Light Calcium Carbonate Dispersant Curing agent anti-settling agent plasticizer cyclohexanone aromatic hydrocarbon solvent No. 100 ethylene glycol ethyl ether acetate Desmophen® 650 (solid content 65%) 400nm30nmR960N115S313R1216-01BGSA grade 99.7% 800 mesh 800 mesh 1250 mesh Efka-766Airex970Ceraflour960AMABYK - 354RILANIT ® 451051JTY201PEDENOL ® 344 solvent solvent 507.54230.520.143220.80.20.10.10.20.21.150.250.28.5512 German Bayer Company self-made American DuPont Suzhou Baohua Carbon Black Company Shanghai Yipin Pigment Company Shenzhen Huasu Chemical Company Liuzhou Zinc Products Company Guoli Superfine Powder Company Guoli Superfine Powder Company Guoli Superfine Powder Company Netherlands EFKA Company Germany Tego Company Germany BYK Chemie Company Taiwan Sanhua Industrial Company Germany BYK Chemie Company Germany Henkel Company KING INDUSTRIES Company Jiangxi Taixing Coating Auxiliary Factory Taiwan Deqian Trading Company Germany Henkel Company Ruian Qizheng Chemical Company Yangzhou Hualun Chemical Company Jiangsu Yixing Assistant Pharmacy

实施例6、氨基树脂固化聚酯卷材新型隔热涂料Embodiment 6, novel heat-insulating coating of amino resin cured polyester coil

本发明提供的氨基树脂固化聚酯卷材新型隔热涂料的配方列于表7。The formulation of the novel heat-insulating coating for amino resin-cured polyester coils provided by the present invention is listed in Table 7.

              表7、氨基树脂固化聚酯卷材新型隔热涂料的配方   物料   规格   用量/Kg   供应商   聚酯树脂氨基树脂纳米多孔SiO2纳米铁黄钛白氧化锌轻质碳酸钙绢云母分散剂消泡剂酸催化剂流平剂增稠剂增滑剂防沉剂增塑剂200号油漆溶剂油乙二醇乙醚醋酸酯芳烃溶剂100号   Desmophen1100(固含量100％)Resimene747(固含量＞98％)550nm500nmR960A级99.7％800目800目Disperbyk-130Airex970K-CURE1040Efka-30DEHYSOLRAcumist B-6902EDENOL344溶剂溶剂溶剂   605115223440.80.20.30.20.20.10.150.1581210   德国Bayer公司美国Solutia.Inc.公司自制自制美国DuPont公司柳州锌品公司国利超细粉体公司国利超细粉体公司德国BYK Chemie公司德国Tego公司KIMG INDUSTRIES公司荷兰EFKA公司德国Henkel公司Allied Signal公司台湾德谦贸易公司德国Henkel公司茂名市永嘉化工公司江苏宜兴助剂厂扬州华伦化工公司 Table 7. Formula of new thermal insulation coating for amino resin cured polyester coil materials Specification Dosage/Kg supplier Polyester resin, amino resin, nano-porous SiO 2 , nano-iron yellow titanium dioxide, zinc oxide, light calcium carbonate, sericite dispersant, defoamer, acid catalyst, leveling agent, thickener, slip agent, anti-sedimentation agent, plasticizer, No. 200 paint solvent oil B Glycol ether acetate aromatic hydrocarbon solvent No. 100 Desmophen ® 1100 (solid content 100%) Resimene 747 (solid content > 98%) 550nm 500nm R960A grade 99.7% 800 mesh 800 mesh Disperbyk-130Airex970K-CURE1040Efka-30DEHYSOL ® RAcumist B - 6902EDENOL ® 344 solvent solvent 605115223440.80.20.30.20.20.10.150.1581210 German Bayer Company, American Solutia.Inc. Company self-made self-made American DuPont Company Liuzhou Zinc Products Company Guoli Superfine Powder Company Guoli Superfine Powder Company German BYK Chemie Company German Tego Company KIMG INDUSTRIES Company Netherlands EFKA Company Germany Henkel Company Allied Signal Company Taiwan Deqian Trading Company Germany Henkel Company Maoming City Yongjia Chemical Company Jiangsu Yixing Auxiliary Factory Yangzhou Hualun Chemical Company

对实施例5、6制备的彩钢板用新型卷材隔热涂料进行性能测试，列于表8。The performance tests of the new coil heat-insulating coatings for color steel plates prepared in Examples 5 and 6 are listed in Table 8.

                        表8、新型隔热涂料性能测试   检测项目   技术指标   测试标准   细度/μm粘度(涂-4杯/23℃)/s固体份/％固化性能/s(℃)60°光泽/％T弯耐冲击/Kg.cm附着性/级铅笔硬度耐甲乙酮/次耐盐雾(2000h)耐湿热(2000h)耐紫外光(2000h)人工加速老化(2000h)热导率w/(m·k)接触角太阳热反射率   ≤2080～110≥6030～60(224～232)(PMT)≥85≤3T≥800≥H≥120漆膜完好无变化漆膜完好无变化漆膜完好无变化漆膜完好无变化0.048≥105°≥0.92   GB1724-79(89)GB1725-99GB1725-79(89)通过耐溶剂GB9754-88GB/T13448-92ASTM2794-93GB/T1732-93GB/T6739-96ASTMD5402GB1771-91GB/T1740-79(89)实测GB1865-80(89)GB10294实测外委检测 Table 8. Performance test of new thermal insulation coating Test items technical indicators standard test Fineness/μm Viscosity (coating-4 cups/23℃)/s solid content/% curing performance/s(℃)60°gloss/% T-bend impact resistance/Kg.cm adhesion/grade pencil hardness resistance to methyl ethyl ketone/time Resistance to salt spray (2000h) resistance to heat and humidity (2000h) resistance to ultraviolet light (2000h) artificial accelerated aging (2000h) thermal conductivity w/(m k) contact angle solar heat reflectance ≤2080～110≥6030～60(224～232)(PMT)≥85≤3T≥800≥H≥120 The paint film is intact and unchanged The paint film is intact and unchanged The paint film is intact and unchanged The paint film is intact and unchanged 0.048≥105° ≥0.92 GB1724-79(89)GB1725-99GB1725-79(89) passed the solvent resistance GB9754-88GB/T13448-92ASTM2794-93GB/T1732-93GB/T6739-96ASTMD5402GB1771-91GB/T1740-79(89) measured GB1865-80(89) GB10294 actual test outsourced testing

实施例7、性能实验1Embodiment 7, performance experiment 1

对本发明提供的新型隔热涂料的隔热性能进行测试时，是将其置于风小，天气晴朗，阳光充足的室外进行的，该方法适用范围广，对小型或大型实验样品均可测试。When the thermal insulation performance of the novel thermal insulation coating provided by the invention is tested, it is placed outdoors with little wind, clear weather and sufficient sunlight. This method has a wide range of applications and can be tested on small or large experimental samples.

取三块薄铁皮板，尺寸均为150mm×150mm，其中板II、板III的表面分别涂刷厚度均为40μm的市售的绿盾牌太阳热反射涂料LD-RFS和本发明实施例4制备的新型隔热涂料，另一块板I不涂刷任何涂料作为对照。在阳光充足的室外进行测试，铁皮板的表面温度采用红外测温仪测量，气温采用J207-1-100±0.1℃型温度计进行测量，检测数据列于表9。Get three thin iron sheets, the size of which is 150mm * 150mm, wherein the surface of plate II and plate III are respectively coated with commercially available green shield solar heat reflective coating LD-RFS and prepared in Example 4 of the present invention with a thickness of 40 μm. New heat-insulating paint, another board I is not painted with any paint as a control. The test was carried out outdoors in a sunny place. The surface temperature of the iron sheet was measured with an infrared thermometer, and the air temperature was measured with a J207-1-100±0.1°C thermometer. The test data are listed in Table 9.

                                表9、薄铁皮板测试数据Table 9. Test data of thin iron sheet

2004-07-15                晴                       风速≤2级   时间   气温(℃)  铁皮板I(℃)   铁皮板II(℃)   铁皮板III(℃)   10:0011:0012:0013:0014:0015:0016:00   27.630.533.436.137.234.431.6   3741.344.850.051.647.342.6   31.434.737.141.242.338.534.2   29.032.335.739.640.137.032.6 2004-07-15 sunny, wind speed ≤ grade 2 time Air temperature (℃) Iron sheet I(℃) Iron sheet II(℃) Iron sheet III(℃) 10:0011:0012:0013:0014:0015:0016:00 27.630.533.436.137.234.431.6 3741.344.850.051.647.342.6 31.434.737.141.242.338.534.2 29.032.335.739.640.137.032.6

由此可见，与不涂刷任何涂料的板I相比，涂刷了市售的绿盾牌太阳热反射涂料LD-RFS和本发明实施例4制备的新型隔热涂料的板II、板III的铁皮板的降温效果明显，尤其是涂刷了本发明的新型隔热涂料的板III，其隔热效果尤为明显。It can be seen that, compared with the plate I without any paint, the plate II and plate III of the new thermal insulation paint prepared by the commercially available Green Shield solar heat reflective paint LD-RFS and the embodiment of the present invention 4 are painted The cooling effect of the iron sheet board is obvious, especially the board III coated with the novel heat-insulating coating of the present invention, its heat-insulating effect is particularly obvious.

而且由于试验用的铁板小，影响因素多，而且平板散热快，所以温差不是很大。如果降低影响因素，用大表面积的密闭容器作测试，本发明提供的新型隔热涂料还可获得更为明显的降温效果，而且与太阳照射接触的面积越大，降温效果越好。And because the iron plate used in the test is small, there are many influencing factors, and the plate dissipates heat quickly, so the temperature difference is not very large. If the influencing factors are reduced and a closed container with a large surface area is used for testing, the novel heat-insulating coating provided by the invention can also obtain a more obvious cooling effect, and the larger the area in contact with the sun, the better the cooling effect.

实施例8、性能实验2Embodiment 8, performance experiment 2

将200L的汽油桶在空桶条件下，使用本发明实施例6制备的新型隔热涂料涂刷，编号甲桶；使用市售的绿盾牌太阳热反射涂料LD-RFS涂刷，编号乙桶。顶部和距底部80cm处的桶体侧面温度用红外测温仪测试，所有测试面均为迎光面，气温、桶体内部采用J207-1-100±0.1℃型温度计测试。测试结果列于表10。Paint the 200L gasoline drum with the new heat-insulating paint prepared in Example 6 of the present invention under the condition of an empty drum, and number it as drum A; use the commercially available Green Shield solar heat reflective coating LD-RFS to paint it, and number it as drum B. The temperature at the top and the side of the barrel at a distance of 80cm from the bottom is tested with an infrared thermometer. All test surfaces are facing the light, and the air temperature and the inside of the barrel are tested with a J207-1-100±0.1°C thermometer. The test results are listed in Table 10.

                                  表10、汽油桶测试数据Table 10. Gasoline tank test data

        2004-07-28                                      晴                                               风速盐≤2级   测试时间测试项目      10:00甲      乙        11:00甲        乙        12:00甲        乙        13:00甲        乙        14:00甲        乙        15:00甲        乙        16:00甲        乙   气温      28.8        30.5        32.2        35.0        36.2        34.4        33.0   侧面℃   30.1   32.1   33.1   35.4   35.3   38.7   38.8   43.1   39.8   44.5   38.0   42.1   36.7   39.8   温度差℃      2.0        2.3        3.4        4.3        4.7        4.1        3.1 顶部℃ 31.5 34.9 35.6 39.0 38.9 42.6 41.6 46.1 42.7 47.9 42.0 47.0 40.2 44.4   温度差℃      3.4        3.4        3.7        4.5        5.2        5.0        4.2 内部℃ 29.6 30.4 31.8 33.1 34.6 36.7 36.9 39.6 39.0 42.5 36.8 39.9 35.6 37.9   温度差℃      0.8        1.3        2.1        2.7        3.5        3.1        2.3 2004-07-28 sunny wind speed salt ≤ grade 2 test time test item 10:00 A B 11:00 A B 12:00 A B 13:00 A B 14:00 A B 15:00 A B 16:00 A B air temperature 28.8 30.5 32.2 35.0 36.2 34.4 33.0 Side °C 30.1 32.1 33.1 35.4 35.3 38.7 38.8 43.1 39.8 44.5 38.0 42.1 36.7 39.8 Temperature difference °C 2.0 2.3 3.4 4.3 4.7 4.1 3.1 top °C 31.5 34.9 35.6 39.0 38.9 42.6 41.6 46.1 42.7 47.9 42.0 47.0 40.2 44.4 Temperature difference °C 3.4 3.4 3.7 4.5 5.2 5.0 4.2 Internal °C 29.6 30.4 31.8 33.1 34.6 36.7 36.9 39.6 39.0 42.5 36.8 39.9 35.6 37.9 Temperature difference °C 0.8 1.3 2.1 2.7 3.5 3.1 2.3

由此可见，与涂刷了市售的绿盾牌太阳热反射涂料LD-RFS的乙桶相比，涂刷了本发明实施例6制备的新型隔热涂料的甲桶的降温效果更为显著，而且太阳直射温度越高降温越明显。It can be seen that, compared with the second bucket that has been painted with the commercially available green shield solar heat reflective paint LD-RFS, the cooling effect of the first bucket that has been painted with the novel heat-insulating coating prepared in Example 6 of the present invention is more remarkable, And the higher the direct sunlight temperature, the more obvious the cooling.

实施例9、性能实验3Embodiment 9, performance experiment 3

将某酒厂250m3不锈钢空酒罐，使用本发明实施例2制备的新型储罐用隔热涂料涂刷，编号甲罐；使用银粉涂刷的，编号乙罐。本次测温在空罐条件下，所有测试面均为迎光面；罐体表面温度采用红外测温仪测试，罐体内部温度采用J207-1-100±0.1℃温度计测试。测试结果列于表11。The 250m 3 empty stainless steel wine tanks of a certain winery were painted with the heat-insulating paint prepared by Example 2 of the present invention, numbered tank A; those painted with silver powder, numbered tank B. The temperature measurement is carried out under the condition of an empty tank, and all test surfaces are facing the light; the surface temperature of the tank is tested by an infrared thermometer, and the internal temperature of the tank is tested by a J207-1-100±0.1°C thermometer. The test results are listed in Table 11.

                                      表11、250m3不锈钢空酒罐测试数据Table 11, 250m 3 stainless steel empty wine tank test data

2004-08-03                                                      晴                                          风速≤2级   测试时间测试项目   9:00   10:00   11:00   12:00   13:00   14:00   15:00   甲   乙罐   罐   甲   乙罐   罐   甲   乙罐   罐   甲   乙罐   罐   甲   乙罐   罐   甲   乙罐   罐   甲   乙罐   罐   气温(℃)   31   32   33   33   34   34   34   湿度(％)   63   罐体侧面(℃)   34.2 45.3   35.4 46.7   37   47.1   384  6.8   38.6 44.5   39   43.9   40.5 44   温度差(℃)   11.1   11.3   10.1   8.8   5.9   4.9   3.5   罐体顶面(℃)   37.1 54.2   38.5 55.6   41.7 59.3   42.3 61.9   43.7 66.2   43.2 68.3   44   66.6   温度差(℃)   15.3   17.1   17.6   19.6   22.5   25.1   22.6   罐体内部距罐顶1m处(℃)   33.5 42.6   35.4 45.8   35.7 49.4   36.4 53.1   37.2 53.8   37.4 55.2   37.5 55   温度差(℃)罐体内部距罐顶5m处(℃)   9.132.8 41.2   10.434.6 43.4   13.734.9 44.2   16.735.5 46.4   16.636.4 48.7   17.836.8 50   17.537   51.3   温度差(℃)   8.4   8.8   9.3   10.9   12.3   13.2   14.3   罐体内部距罐顶8m处(℃)   32.6 40.4   34.2 41.8   34.6 42.4   35  44.1   35.9 44.5   36  45.1   36.3 46.8   温度差(℃)   7.8   7.6   7.8   9.1   8.6   9.1   10.5 2004-08-03 sunny wind speed ≤ grade 2 test time test item 9:00 10:00 11:00 12:00 13:00 14:00 15:00 A tank B tank A tank B tank A tank B tank A tank B tank A tank B tank A tank B tank A tank B tank Air temperature (℃) 31 32 33 33 34 34 34 humidity(%) 63 Tank side (℃) 34.2 45.3 35.4 46.7 37 47.1 384 6.8 38.6 44.5 39 43.9 40.5 44 Temperature difference(°C) 11.1 11.3 10.1 8.8 5.9 4.9 3.5 Tank top surface (℃) 37.1 54.2 38.5 55.6 41.7 59.3 42.3 61.9 43.7 66.2 43.2 68.3 44 66.6 Temperature difference(°C) 15.3 17.1 17.6 19.6 22.5 25.1 22.6 1m from the inside of the tank to the top of the tank (°C) 33.5 42.6 35.4 45.8 35.7 49.4 36.4 53.1 37.2 53.8 37.4 55.2 37.5 55 Temperature difference (°C) 5m from the inside of the tank to the top of the tank (°C) 9.132.8 41.2 10.434.6 43.4 13.734.9 44.2 16.735.5 46.4 16.636.4 48.7 17.836.8 50 17.537 51.3 Temperature difference(°C) 8.4 8.8 9.3 10.9 12.3 13.2 14.3 8m from the inside of the tank to the top of the tank (°C) 32.6 40.4 34.2 41.8 34.6 42.4 35 44.1 35.9 44.5 36 45.1 36.3 46.8 Temperature difference(°C) 7.8 7.6 7.8 9.1 8.6 9.1 10.5

测试实验数据表明，与涂刷银粉漆乙罐相比，涂刷了本发明实施例2制备的白色丙烯酸树脂新型储罐用隔热涂料的甲罐外表和内部温度下降都较明显，完全可以取代现有的涂银粉漆加喷淋水来降温的方法，而且使用寿命长，大大降低了成本。The test data show that, compared with the second tank painted with silver powder paint, the external and internal temperature drop of tank A coated with the white acrylic resin novel storage tank heat-insulating paint prepared in Example 2 of the present invention is more obvious, and it can completely replace The existing method of coating silver paint and adding spray water to cool down has a long service life and greatly reduces the cost.

Claims (10)

1, a kind of thermal insulating coating, its composition comprises:
Film forming matter 15～65 weight parts;
Nanoporous SiO 23～20 weight parts;
Nano iron oxide yellow 1～12 weight part;
Pigment 5～30 weight parts;
Filler 3～22 weight parts;
Auxiliary agent 0.4～8 weight part;
Solvent 6～30 weight parts;
Described film forming matter comprises vibrin, Synolac, Resins, epoxy, acrylic resin, aminoresin, resol, polyvinyl chloride (PVC) RESINS, organosilicon modified polyester resin, organosilicon modified crylic acid resin, silicone resin, fluorocarbon resin;
Described filler is to be selected from zinc oxide, barium sulfate, silicon-dioxide, talcum powder, sericite, light calcium carbonate, the wollastonite powder one or more;
Described auxiliary agent comprises one or more in dispersion agent, defoamer, flow agent, acid catalyst, anti-settling agent, softening agent, slip(ping)agent, thickening material, the solidifying agent;
Above-mentioned component is mixed, after disperseing, grind, mixing colours, promptly obtain thermal insulating coating of the present invention.
2, thermal insulating coating as claimed in claim 1 is characterized in that: described nanoporous SiO 2Particle diameter be 10～600nm.
3, thermal insulating coating as claimed in claim 1 or 2 is characterized in that: described nanoporous SiO 2For making: in there-necked flask, add 100ml ethanol by following method; adding 0.2～1.2ml concentration under stirring is the salt solution of 0.1M and the ethanolic soln of 0.1M polymkeric substance, continues under the room temperature to stir, and logical nitrogen is protected; the positive tetraethyl orthosilicate that adds 0.8～4.2ml again; fully stir 1～5h, leave standstill, use washing with alcohol after the centrifugation; repeatedly for several times; at 230～460 ℃ of following sintering, sieve at last, promptly obtain nanoporous SiO 2
Wherein, described salt comprises NaCl, NaI, KBr, KCl, KI, KNO 3, LiCl, CsCl;
Described polymkeric substance is R aO (CH 2CH 2O) bH, R aBe C 6～C 18Alkyl, b=3～15; Or HO (CH 2CH 2O) x (CH (CH 3) CH 2O) y (CH 2CH 2O) zH, x, y, z=1～65, and molar mass is 1650～2900g/mol.
4, thermal insulating coating as claimed in claim 1 is characterized in that: the particle diameter of described nano iron oxide yellow is 10～500nm.
5, thermal insulating coating as claimed in claim 1 is characterized in that: described pigment is to be selected from rutile titanium white, phthalocyanine blue, phthalocyanine green, carbon black, red iron oxide, zinc-chrome yellow, medium chrome yellow medium yellow, Lemon chrome yellow, deep chrome yellow, chrome green, the molybdenum red one or more.
6, thermal insulating coating as claimed in claim 1 is characterized in that: described dispersion agent is Efka-766, the EfkaPolymer452 of BYK-110, BYK-P104, the Disperbyk-130 of German BYK Chemie company, Dutch EFKA company;
Described defoamer is the Efka-20 of BYK-065, the BYK-052 of German BYK Chemie company, Dutch EFKA company; The Airex970 of Germany Tego company;
Described flow agent is Efka-30, the Efka-772 of BYK-354, the BYK-300 of German BYK Chemie company, Dutch EFKA company;
Described acid catalyst be German BYK Chemie company BYK-Catalyst450, NACURE155,1051, the K-CURE1040 of KIMGINDUSTRIES company;
Described anti-settling agent is the BORCHIGEL THIXO Z of the anti-settling agent 902,201P of the Taiwan modest trading company of moral, German Bayer company;
Described softening agent is the EDENOL of the plasticizer DOP, tributyl phosphate of Shanghai solvent factory, German Henkel company 344;
Described slip(ping)agent is 840SL, the AMA that industrial corporation is changed in Taiwan three; The A-C6 of Allied Signal company, Acumist B-6;
Described thickening material is the DEHYSOL of German Henkel company R, RILANIT 45;
Described solidifying agent is KB, KC, the DBTDL curing catalyst of the Taiwan modest trading company of moral, the JTY curing catalyst of Taixing, Jiangxi coatings additive(s) factory.
7, thermal insulating coating as claimed in claim 1 is characterized in that: described solvent is selected from one or more in ethyl acetate, butylacetate, ethylene glycol ether acetate, dimethylbenzene, butyl glycol ether, butanols, methyl iso-butyl ketone (MIBK), propylene glycol methyl ether acetate, sherwood oil, No. 200 varnish makers' and painters' naphtha, pimelinketone, No. 100, aromatic solvent, No. 150, aromatic solvent, No. 200, aromatic solvent, the mixed dibasic acid diester.
8, thermal insulating coating as claimed in claim 1 is characterized in that, its composition comprises:
Film forming matter 15～50 weight parts;
Nanoporous SiO 24～20 weight parts;
Nano iron oxide yellow 1～9 weight part;
Pigment 5～30 weight parts;
Filler 6～22 weight parts;
Auxiliary agent 0.4～6 weight part;
Solvent 6～25 weight parts.
9, thermal insulating coating as claimed in claim 1 is characterized in that, its composition comprises:
Film forming matter 20～65 weight parts;
Nanoporous SiO 23～18 weight parts;
Nano iron oxide yellow 3～12 weight parts;
Pigment 5～30 weight parts;
Filler 3～20 weight parts;
Auxiliary agent 0.6～8 weight part;
Solvent 10～30 weight parts.
10, claim 1,8 or 9 described thermal insulating coatings variously need to lower the temperature, heat insulation device or architectural application.
CNB2005100001490A 2005-01-05 2005-01-05 Insulating mold coating and its uses Expired - Fee Related CN100357378C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005100001490A CN100357378C (en) 2005-01-05 2005-01-05 Insulating mold coating and its uses

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005100001490A CN100357378C (en) 2005-01-05 2005-01-05 Insulating mold coating and its uses

Publications (2)

Publication Number Publication Date
CN1800283A true CN1800283A (en) 2006-07-12
CN100357378C CN100357378C (en) 2007-12-26

Family

ID=36810504

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005100001490A Expired - Fee Related CN100357378C (en) 2005-01-05 2005-01-05 Insulating mold coating and its uses

Country Status (1)

Country Link
CN (1) CN100357378C (en)

Cited By (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100371402C (en) * 2006-10-16 2008-02-27 陈东东 Infrared resistant coating and preparation process
CN100462395C (en) * 2006-10-20 2009-02-18 南京工业大学 A kind of transparent heat insulation film and preparation method thereof
CN101921517A (en) * 2010-09-08 2010-12-22 沈阳建筑大学 A kind of dark reflective exterior wall thermal insulation coating and preparation method thereof
CN101235243B (en) * 2008-01-23 2011-05-18 陈树望 Multifunctional protection composite coating material
CN101368019B (en) * 2007-08-16 2011-08-31 张振彬 Novel watersoluble fluorine paint
CN102234466A (en) * 2010-04-27 2011-11-09 北京航材百慕新材料技术工程股份有限公司 Long-acting solar heat reflection fluorocarbon coating
CN102337071A (en) * 2011-10-09 2012-02-01 常州豪邦纳米科技涂料有限公司 Priming paint for bakelite handle
CN102382546A (en) * 2010-09-06 2012-03-21 张子鹏 Special modified solvent-free epoxy paint for glass reinforced plastic
CN102492339A (en) * 2011-12-15 2012-06-13 西南科技大学 Preparation method for high-wave permeability super-hydrophobic moisture-proofing coating for antenna housing material
CN102816519A (en) * 2012-07-25 2012-12-12 江苏科技大学 Inorganic-organic high temperature-resistant coating and preparation method thereof
CN102838895A (en) * 2011-06-23 2012-12-26 江苏考普乐新材料股份有限公司 High performance coating composition
CN101328377B (en) * 2007-06-20 2013-03-06 铜联商务咨询（上海）有限公司 Copper heat interchanger anti-corrosive paint for gas fittings and processing method thereof
CN103013290A (en) * 2012-11-28 2013-04-03 天长市开林化工有限公司 Elastic coating of heat-insulating anticorrosion external protection layer
CN103059720A (en) * 2011-10-20 2013-04-24 无锡灵煌科技有限公司 Preparation method of transparent thermal insulation self-cleaning coating
CN101747828B (en) * 2008-12-15 2013-05-01 鞍钢股份有限公司 Alcohol-based paint and preparation method thereof
CN103275535A (en) * 2013-05-24 2013-09-04 苏州市德莱尔建材科技有限公司 Polyvinyl chloride waterproof paint for wood material
CN103509462A (en) * 2013-09-24 2014-01-15 上海纳米技术及应用国家工程研究中心有限公司 Heat insulation coating, preparation method and application thereof
CN103540211A (en) * 2013-09-30 2014-01-29 安徽华印机电股份有限公司 Organosilicon modifying acrylic resin fireproof coating
CN103555023A (en) * 2013-10-25 2014-02-05 安徽文峰电子科技集团有限公司 High-temperature yellowing resistant impregnating varnish and preparation method thereof
CN103587210A (en) * 2013-10-30 2014-02-19 溧阳市哈大成果转化中心有限公司 Aircraft wing housing with coating
CN103694843A (en) * 2013-11-29 2014-04-02 安徽祈艾特电子科技有限公司 Environment-friendly anticorrosive yellowing-resistant amino resin paint
CN103694868A (en) * 2013-11-29 2014-04-02 安徽祈艾特电子科技有限公司 Heat-resistant and flame-retardant anti-ultraviolet aging paint
CN103694858A (en) * 2013-11-29 2014-04-02 蚌埠市正园电子科技有限公司 High temperature-resistant acid-resistant anti-corrosion priming paint
CN103756488A (en) * 2014-01-26 2014-04-30 南通广泰生化制品有限公司 Preparation method of microporous nano-coating
CN103788810A (en) * 2014-01-26 2014-05-14 南通苏通分离工程科技有限公司 High temperature resistant anticorrosive paint and preparation process thereof
CN104119739A (en) * 2014-06-26 2014-10-29 苏州市盛百威包装设备有限公司 Packaging equipment paint and preparation method thereof
CN104194624A (en) * 2014-09-18 2014-12-10 山东大学 Yellow near-infrared high reflective coating and preparation method thereof
CN104212318A (en) * 2014-09-03 2014-12-17 句容金猴机械研究所有限公司 Heat-resistant and chemical-resistant paint for mechanical equipment and preparation method of heat-resistant and chemical-resistant paint
CN104293012A (en) * 2014-09-26 2015-01-21 无锡七点建材有限公司 Heat-reflecting thermal insulation coating and preparation method thereof
CN104327654A (en) * 2014-10-20 2015-02-04 浙江华特实业集团华特化工有限公司 Sun-reflection heat-insulation paint and manufacturing method thereof
CN104327676A (en) * 2014-11-26 2015-02-04 江苏博腾新材料股份有限公司 Anti-scratch wall paint
CN104403445A (en) * 2014-11-14 2015-03-11 无锡中洁能源技术有限公司 Solar cell backboard reflection paint and preparation method thereof
CN104403434A (en) * 2014-12-02 2015-03-11 苏州Ppg包装涂料有限公司 Coating composition
CN104403521A (en) * 2014-12-08 2015-03-11 成都锦汇科技有限公司 Weather-resistant steel plate
CN104449260A (en) * 2014-12-08 2015-03-25 成都锦汇科技有限公司 Heat-resisting steel plate
CN104497805A (en) * 2014-12-08 2015-04-08 成都锦汇科技有限公司 Heat-resistant steel plate and preparation process thereof
CN104513559A (en) * 2014-11-28 2015-04-15 蚌埠南自仪表有限公司 Electric power equipment cabinet use anti yellowing thermal insulation noise reduction paint and preparation method thereof
CN104693982A (en) * 2013-12-10 2015-06-10 常州之友梦琦涂料有限公司 Method for recycling and processing waste powder of powder coating into solvent type coating
CN104693985A (en) * 2015-02-12 2015-06-10 福建省台华化学工业有限公司 Solvent-type double-component coating and preparation method thereof
CN104877491A (en) * 2015-06-02 2015-09-02 柳州龙溪化工有限公司 Heat reflection and insulation type car paint mixing gloss oil and metal gleam finish coating
CN105295688A (en) * 2015-12-08 2016-02-03 常熟市裕茗企业管理咨询有限公司 Displacement measurement and detection device
CN105400301A (en) * 2015-12-24 2016-03-16 南京理工大学常熟研究院有限公司 Architectural thermal insulation coating
CN105694545A (en) * 2016-01-30 2016-06-22 欧阳杰 Quantum resonance coating and construction process thereof
CN105862443A (en) * 2016-05-27 2016-08-17 襄阳宏伟航空器有限责任公司 Balloon bag material for fire balloon and preparation method of balloon bag material
CN106047101A (en) * 2016-08-14 2016-10-26 安庆市沁之源电器有限公司 Gas stove anti-scratch coating and preparation method thereof
CN106118467A (en) * 2016-07-29 2016-11-16 江苏仁通节能科技有限公司 A kind of aqueous thermal-resistant thermal insulation coatings and its preparation method and application
CN106118390A (en) * 2016-06-29 2016-11-16 明光市永德包装有限公司 A kind of metal packaging coating
CN106147548A (en) * 2016-08-14 2016-11-23 安庆市沁之源电器有限公司 A kind of electric fan sound deadening coating and preparation method thereof
CN106554704A (en) * 2016-10-08 2017-04-05 江苏大使同丰涂料有限公司 A kind of solar energy reflective insulation coating and preparation method thereof
CN106634256A (en) * 2016-10-11 2017-05-10 安徽卡塔门窗有限公司 Aluminum alloy door-window easy to clean and preparation method of aluminum alloy door-window easy to clean
CN106752643A (en) * 2016-12-17 2017-05-31 吴德炳 A kind of insulating moulding coating and preparation method thereof
CN107163695A (en) * 2017-07-16 2017-09-15 镇江市神龙电器管件有限公司 A kind of fireproof coating for high security tray type cable bridge
CN107189559A (en) * 2017-07-16 2017-09-22 镇江市神龙电器管件有限公司 A kind of cable testing bridge with fire-proof function
CN104919010B (en) * 2012-11-05 2018-03-27 科莱恩金融(Bvi)有限公司 Thermal barrier coatings composition comprising blueness and green phthalocyanine pigment
CN108610725A (en) * 2018-06-04 2018-10-02 丹阳市银海镍铬化工有限公司 Multiband, multilayer electromagnetic matching camouflage paint system and its application
CN108753074A (en) * 2018-07-13 2018-11-06 芜湖多辉建设有限公司 A kind of heat-resistant antifriction modified on outer wall coating
CN109021638A (en) * 2018-06-22 2018-12-18 宁波蒙曼生物科技有限公司 A kind of low-cost environment-friendly water paint and its preparation and application
CN109135371A (en) * 2018-07-24 2019-01-04 张家港市五湖新材料技术开发有限公司 A kind of formula of anti-ultraviolet coating
CN110396340A (en) * 2019-08-27 2019-11-01 惠州市鸿泰建筑工程有限公司 A kind of uvioresistant exterior coating of wet-heat resisting and preparation method thereof
CN110499057A (en) * 2018-05-17 2019-11-26 (株)大水高科技 Antifouling coating composition and antifouling coating
CN110564286A (en) * 2019-09-26 2019-12-13 青岛天地彩涂料工程应用有限公司 A kind of self-conversion curing exterior wall coating and its manufacturing method
CN114410219A (en) * 2021-12-08 2022-04-29 中国科学技术大学先进技术研究院 Radiation cooling coating and preparation method thereof
CN114538880A (en) * 2022-01-27 2022-05-27 环秀(青岛)建材科技有限公司 Preparation and construction method of inorganic wear-resistant floor coating
CN115181469A (en) * 2022-09-14 2022-10-14 北京汉诺威自控技术有限公司 Protective coating for rubber oil seal and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101602909B (en) * 2009-07-01 2011-05-25 中山泰腾灯饰有限公司 Diffuse reflection coating

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1030142C (en) * 1992-06-30 1995-10-25 李成章 Novel thermal barrier coating composition
DE19501114C2 (en) * 1995-01-17 2001-01-18 Gerd Hugo Paint with reflective properties in two wavelength ranges and absorbent properties in a third wavelength range
JP3122375B2 (en) * 1996-10-18 2001-01-09 富士チタン工業株式会社 Infrared shielding material
KR100454110B1 (en) * 1997-01-13 2005-01-15 주식회사 코오롱 Preparation method of nylon film by primary coating solution comprising aqueous urethane resin, aqueous epoxy curing agent and amine-based compound, and drying, drawing to at least one direction and heat treating the coated one
CN1363636A (en) * 2001-01-02 2002-08-14 顾晓鸣 Energy-saving ultraviolet and infrared resistant paint
CN1405248A (en) * 2002-01-30 2003-03-26 北京京安固特化工有限责任公司 Acrylic resin sun-heat reflecting coating
CN1552785A (en) * 2003-06-05 2004-12-08 上海祥雅涂料有限公司 Orthobutyl titanate modified organic specific condensate coating material and its preparation

Cited By (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100371402C (en) * 2006-10-16 2008-02-27 陈东东 Infrared resistant coating and preparation process
CN100462395C (en) * 2006-10-20 2009-02-18 南京工业大学 A kind of transparent heat insulation film and preparation method thereof
CN101328377B (en) * 2007-06-20 2013-03-06 铜联商务咨询（上海）有限公司 Copper heat interchanger anti-corrosive paint for gas fittings and processing method thereof
CN101368019B (en) * 2007-08-16 2011-08-31 张振彬 Novel watersoluble fluorine paint
CN101235243B (en) * 2008-01-23 2011-05-18 陈树望 Multifunctional protection composite coating material
CN101747828B (en) * 2008-12-15 2013-05-01 鞍钢股份有限公司 Alcohol-based paint and preparation method thereof
CN102234466A (en) * 2010-04-27 2011-11-09 北京航材百慕新材料技术工程股份有限公司 Long-acting solar heat reflection fluorocarbon coating
CN102382546A (en) * 2010-09-06 2012-03-21 张子鹏 Special modified solvent-free epoxy paint for glass reinforced plastic
CN101921517B (en) * 2010-09-08 2012-07-18 沈阳建筑大学 Dark colour-system reflection-type outer wall thermal insulation coating and preparation method thereof
CN101921517A (en) * 2010-09-08 2010-12-22 沈阳建筑大学 A kind of dark reflective exterior wall thermal insulation coating and preparation method thereof
CN102838895A (en) * 2011-06-23 2012-12-26 江苏考普乐新材料股份有限公司 High performance coating composition
CN102337071A (en) * 2011-10-09 2012-02-01 常州豪邦纳米科技涂料有限公司 Priming paint for bakelite handle
CN103059720B (en) * 2011-10-20 2015-07-08 无锡灵煌科技有限公司 Preparation method of transparent thermal insulation self-cleaning coating
CN103059720A (en) * 2011-10-20 2013-04-24 无锡灵煌科技有限公司 Preparation method of transparent thermal insulation self-cleaning coating
CN102492339A (en) * 2011-12-15 2012-06-13 西南科技大学 Preparation method for high-wave permeability super-hydrophobic moisture-proofing coating for antenna housing material
CN102492339B (en) * 2011-12-15 2013-08-28 西南科技大学 Preparation method for high-wave permeability super-hydrophobic moisture-proofing coating for antenna housing material
CN102816519A (en) * 2012-07-25 2012-12-12 江苏科技大学 Inorganic-organic high temperature-resistant coating and preparation method thereof
CN104919010B (en) * 2012-11-05 2018-03-27 科莱恩金融(Bvi)有限公司 Thermal barrier coatings composition comprising blueness and green phthalocyanine pigment
CN103013290A (en) * 2012-11-28 2013-04-03 天长市开林化工有限公司 Elastic coating of heat-insulating anticorrosion external protection layer
CN103275535A (en) * 2013-05-24 2013-09-04 苏州市德莱尔建材科技有限公司 Polyvinyl chloride waterproof paint for wood material
CN103275535B (en) * 2013-05-24 2015-12-23 苏州市德莱尔建材科技有限公司 A kind of Polyvinyl chloride waterproof paint for wood material
CN103509462A (en) * 2013-09-24 2014-01-15 上海纳米技术及应用国家工程研究中心有限公司 Heat insulation coating, preparation method and application thereof
CN103540211A (en) * 2013-09-30 2014-01-29 安徽华印机电股份有限公司 Organosilicon modifying acrylic resin fireproof coating
CN103555023A (en) * 2013-10-25 2014-02-05 安徽文峰电子科技集团有限公司 High-temperature yellowing resistant impregnating varnish and preparation method thereof
CN103587210B (en) * 2013-10-30 2015-09-23 溧阳市哈大成果转化中心有限公司 The cated aircraft wing shell of a kind of tool
CN103587210A (en) * 2013-10-30 2014-02-19 溧阳市哈大成果转化中心有限公司 Aircraft wing housing with coating
CN103694868A (en) * 2013-11-29 2014-04-02 安徽祈艾特电子科技有限公司 Heat-resistant and flame-retardant anti-ultraviolet aging paint
CN103694858A (en) * 2013-11-29 2014-04-02 蚌埠市正园电子科技有限公司 High temperature-resistant acid-resistant anti-corrosion priming paint
CN103694843A (en) * 2013-11-29 2014-04-02 安徽祈艾特电子科技有限公司 Environment-friendly anticorrosive yellowing-resistant amino resin paint
CN104693982A (en) * 2013-12-10 2015-06-10 常州之友梦琦涂料有限公司 Method for recycling and processing waste powder of powder coating into solvent type coating
CN103756488A (en) * 2014-01-26 2014-04-30 南通广泰生化制品有限公司 Preparation method of microporous nano-coating
CN103788810A (en) * 2014-01-26 2014-05-14 南通苏通分离工程科技有限公司 High temperature resistant anticorrosive paint and preparation process thereof
CN103756488B (en) * 2014-01-26 2016-01-13 南通广泰生化制品有限公司 A kind of preparation method of microporous nano coating
CN104119739A (en) * 2014-06-26 2014-10-29 苏州市盛百威包装设备有限公司 Packaging equipment paint and preparation method thereof
CN104212318A (en) * 2014-09-03 2014-12-17 句容金猴机械研究所有限公司 Heat-resistant and chemical-resistant paint for mechanical equipment and preparation method of heat-resistant and chemical-resistant paint
CN104194624A (en) * 2014-09-18 2014-12-10 山东大学 Yellow near-infrared high reflective coating and preparation method thereof
CN104293012A (en) * 2014-09-26 2015-01-21 无锡七点建材有限公司 Heat-reflecting thermal insulation coating and preparation method thereof
CN104327654A (en) * 2014-10-20 2015-02-04 浙江华特实业集团华特化工有限公司 Sun-reflection heat-insulation paint and manufacturing method thereof
CN104403445A (en) * 2014-11-14 2015-03-11 无锡中洁能源技术有限公司 Solar cell backboard reflection paint and preparation method thereof
CN104327676A (en) * 2014-11-26 2015-02-04 江苏博腾新材料股份有限公司 Anti-scratch wall paint
CN104513559A (en) * 2014-11-28 2015-04-15 蚌埠南自仪表有限公司 Electric power equipment cabinet use anti yellowing thermal insulation noise reduction paint and preparation method thereof
CN104403434A (en) * 2014-12-02 2015-03-11 苏州Ppg包装涂料有限公司 Coating composition
CN104449260A (en) * 2014-12-08 2015-03-25 成都锦汇科技有限公司 Heat-resisting steel plate
CN104403521B (en) * 2014-12-08 2016-12-28 顾玉奎 A kind of anti weathering steel
CN104497805A (en) * 2014-12-08 2015-04-08 成都锦汇科技有限公司 Heat-resistant steel plate and preparation process thereof
CN104403521A (en) * 2014-12-08 2015-03-11 成都锦汇科技有限公司 Weather-resistant steel plate
CN104693985A (en) * 2015-02-12 2015-06-10 福建省台华化学工业有限公司 Solvent-type double-component coating and preparation method thereof
CN104877491A (en) * 2015-06-02 2015-09-02 柳州龙溪化工有限公司 Heat reflection and insulation type car paint mixing gloss oil and metal gleam finish coating
CN105295688A (en) * 2015-12-08 2016-02-03 常熟市裕茗企业管理咨询有限公司 Displacement measurement and detection device
CN105400301A (en) * 2015-12-24 2016-03-16 南京理工大学常熟研究院有限公司 Architectural thermal insulation coating
CN105694545A (en) * 2016-01-30 2016-06-22 欧阳杰 Quantum resonance coating and construction process thereof
CN105862443A (en) * 2016-05-27 2016-08-17 襄阳宏伟航空器有限责任公司 Balloon bag material for fire balloon and preparation method of balloon bag material
CN105862443B (en) * 2016-05-27 2018-03-27 襄阳宏伟航空器有限责任公司 A kind of balloon material for fire balloon and preparation method thereof
CN106118390A (en) * 2016-06-29 2016-11-16 明光市永德包装有限公司 A kind of metal packaging coating
CN106118467A (en) * 2016-07-29 2016-11-16 江苏仁通节能科技有限公司 A kind of aqueous thermal-resistant thermal insulation coatings and its preparation method and application
CN106147548A (en) * 2016-08-14 2016-11-23 安庆市沁之源电器有限公司 A kind of electric fan sound deadening coating and preparation method thereof
CN106047101A (en) * 2016-08-14 2016-10-26 安庆市沁之源电器有限公司 Gas stove anti-scratch coating and preparation method thereof
CN106554704A (en) * 2016-10-08 2017-04-05 江苏大使同丰涂料有限公司 A kind of solar energy reflective insulation coating and preparation method thereof
CN106634256A (en) * 2016-10-11 2017-05-10 安徽卡塔门窗有限公司 Aluminum alloy door-window easy to clean and preparation method of aluminum alloy door-window easy to clean
CN106752643A (en) * 2016-12-17 2017-05-31 吴德炳 A kind of insulating moulding coating and preparation method thereof
CN107189559A (en) * 2017-07-16 2017-09-22 镇江市神龙电器管件有限公司 A kind of cable testing bridge with fire-proof function
CN107189559B (en) * 2017-07-16 2019-05-24 镇江市神龙电器管件有限公司 A kind of cable testing bridge with fire-proof function
CN107163695A (en) * 2017-07-16 2017-09-15 镇江市神龙电器管件有限公司 A kind of fireproof coating for high security tray type cable bridge
CN110499057B (en) * 2018-05-17 2021-09-28 (株)大水高科技 Antifouling coating composition and antifouling coating material
CN110499057A (en) * 2018-05-17 2019-11-26 (株)大水高科技 Antifouling coating composition and antifouling coating
CN108610725A (en) * 2018-06-04 2018-10-02 丹阳市银海镍铬化工有限公司 Multiband, multilayer electromagnetic matching camouflage paint system and its application
CN109021638A (en) * 2018-06-22 2018-12-18 宁波蒙曼生物科技有限公司 A kind of low-cost environment-friendly water paint and its preparation and application
CN108753074A (en) * 2018-07-13 2018-11-06 芜湖多辉建设有限公司 A kind of heat-resistant antifriction modified on outer wall coating
CN109135371A (en) * 2018-07-24 2019-01-04 张家港市五湖新材料技术开发有限公司 A kind of formula of anti-ultraviolet coating
CN110396340A (en) * 2019-08-27 2019-11-01 惠州市鸿泰建筑工程有限公司 A kind of uvioresistant exterior coating of wet-heat resisting and preparation method thereof
CN110564286A (en) * 2019-09-26 2019-12-13 青岛天地彩涂料工程应用有限公司 A kind of self-conversion curing exterior wall coating and its manufacturing method
CN114410219A (en) * 2021-12-08 2022-04-29 中国科学技术大学先进技术研究院 Radiation cooling coating and preparation method thereof
CN114538880A (en) * 2022-01-27 2022-05-27 环秀(青岛)建材科技有限公司 Preparation and construction method of inorganic wear-resistant floor coating
CN114538880B (en) * 2022-01-27 2024-04-12 环秀(青岛)建材科技有限公司 Preparation and construction method of inorganic wear-resistant terrace coating
CN115181469A (en) * 2022-09-14 2022-10-14 北京汉诺威自控技术有限公司 Protective coating for rubber oil seal and preparation method thereof

Also Published As

Publication number Publication date
CN100357378C (en) 2007-12-26

Similar Documents

Publication Publication Date Title
CN1800283A (en) Insulating mold coating and its uses
CN103013241B (en) Fluorocarbon nanometer solar heat-insulation reflective paint, preparation method and using method thereof
CN102731052B (en) Aqueous organic-inorganic composite coating and preparation method thereof
CN104371531B (en) High-reflective acrylic polyurethane coating composition
CN103146289B (en) A kind of automatically cleaning anti-corrosion and super-weatherability powder coating and its preparation method and application
CN103319971B (en) A kind of metallic travel aqueous fluorocarbon coating and preparation method thereof for exterior wall
CN103059664B (en) Single-component water-based fluorine paint and solar cell backing film
CN102408220A (en) A kind of all-in-one waterborne inorganic-organic hybrid architectural coating and preparation method thereof
CN102964955B (en) Aqueous anti-corrosion and cooling multifunctional coating for storage tanks and tank cars and preparation method thereof
CN1434063A (en) Aqueous epoxy modified acrylic heat-reflecting thermo-insulating coating
CN101693801A (en) Rare earth modification exterior wall water-borne fluorocarbon coating and preparation method thereof
CN109971319A (en) A kind of weather-proof anticorrosion polyester type powder paint containing glass fibre and clay mineral
CN110964388A (en) Polyurea modified anti-pollution coating and preparation method and application thereof
CN1176119C (en) Nanometer acrylic acid microemulsion, water-thinned heat reflecting and isolating paint and their production process
CN100366687C (en) Ceramic heat insulation and anticorrosion coating
CN107083180A (en) A kind of automatically cleaning reflectance coating based on strawberry type microballoon and preparation method thereof
WO2021031673A1 (en) Uv nano anticorrosive coating, circuit board obtained by using same, and preparation method and application
CN116218293B (en) High weather-resistant exterior wall coating
CN116535941B (en) Weather-resistant anti-corrosion powder coating and preparation process thereof
CN107099201A (en) Water-dilutable polyvinyl fluoride paint and coating and forming method thereof
CN107523187B (en) Enhanced thermal insulation reflective coating
CN102786869B (en) PVDF ultraviolet light polymerization coil coating and preparation method thereof
CN115141506A (en) Environment-friendly transparent heat-insulating coating and preparation method thereof
JP2008031237A (en) Inorganic paint rich in zinc and method of forming multiple layer coated film using the same
CN114836110A (en) A kind of nano-modified hot-dip galvanized polyester coating and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20071226

Termination date: 20220105

CF01 Termination of patent right due to non-payment of annual fee