CN85109768A - 烷氧基硅烷簇-片状硅酸盐复合物 - Google Patents

烷氧基硅烷簇-片状硅酸盐复合物 Download PDF

Info

Publication number: CN85109768A
Authority: CN; China
Prior art keywords: silicate; ion; alkoxyl; group; swelling
Prior art date: 1984-12-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

CN198585109768A

Other languages

English (en)

Chinese (zh)

Inventor

索马斯·麦克尔·蒂蒙

弗朗克林·利·佛克斯

布特·弗里德里克·霍夫思

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Armstrong World Industries Inc

Original Assignee

Armstrong World Industries Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-12-31

Filing date

1985-12-30

Publication date

1986-09-24

1985-12-30 Application filed by Armstrong World Industries Inc filed Critical Armstrong World Industries Inc

1986-09-24 Publication of CN85109768A publication Critical patent/CN85109768A/zh

Status Withdrawn legal-status Critical Current

Links

BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims description 25
150000001875 compounds Chemical class 0.000 title claims description 18
125000003545 alkoxy group Chemical group 0.000 title description 3
239000000463 material Substances 0.000 claims abstract description 26
239000002808 molecular sieve Substances 0.000 claims abstract description 11
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 11
238000000034 method Methods 0.000 claims description 23
150000002500 ions Chemical class 0.000 claims description 16
-1 alkoxyl group alkane Chemical class 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
230000008961 swelling Effects 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 6
238000005342 ion exchange Methods 0.000 claims description 6
125000002091 cationic group Chemical group 0.000 claims description 5
229910000271 hectorite Inorganic materials 0.000 claims description 4
229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
239000011707 mineral Substances 0.000 claims description 4
239000002798 polar solvent Substances 0.000 claims description 4
229910052902 vermiculite Inorganic materials 0.000 claims description 4
239000010455 vermiculite Substances 0.000 claims description 4
235000019354 vermiculite Nutrition 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 3
125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 2
229910052796 boron Inorganic materials 0.000 claims 2
239000013078 crystal Substances 0.000 claims 2
239000011737 fluorine Substances 0.000 claims 2
229910052731 fluorine Inorganic materials 0.000 claims 2
239000010445 mica Substances 0.000 claims 2
229910052618 mica group Inorganic materials 0.000 claims 2
229910052628 phlogopite Inorganic materials 0.000 claims 2
239000000454 talc Substances 0.000 claims 2
229910052623 talc Inorganic materials 0.000 claims 2
235000012222 talc Nutrition 0.000 claims 2
150000001413 amino acids Chemical class 0.000 claims 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims 1
125000000217 alkyl group Chemical group 0.000 description 15
239000004927 clay Substances 0.000 description 15
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
125000004432 carbon atom Chemical group C* 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
125000003342 alkenyl group Chemical group 0.000 description 5
125000003710 aryl alkyl group Chemical group 0.000 description 5
125000003118 aryl group Chemical group 0.000 description 5
239000000203 mixture Substances 0.000 description 5
235000012239 silicon dioxide Nutrition 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
229960001866 silicon dioxide Drugs 0.000 description 5
150000001768 cations Chemical class 0.000 description 4
239000011229 interlayer Substances 0.000 description 4
239000010410 layer Substances 0.000 description 4
239000003960 organic solvent Substances 0.000 description 4
230000000694 effects Effects 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
238000009830 intercalation Methods 0.000 description 3
230000002687 intercalation Effects 0.000 description 3
239000007788 liquid Substances 0.000 description 3
150000004760 silicates Chemical class 0.000 description 3
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
239000003245 coal Substances 0.000 description 2
238000005336 cracking Methods 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
125000004337 3-ethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
238000013019 agitation Methods 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000002734 clay mineral Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000020335 dealkylation Effects 0.000 description 1
238000006900 dealkylation reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000005357 flat glass Substances 0.000 description 1
238000005189 flocculation Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910001416 lithium ion Inorganic materials 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
238000006053 organic reaction Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910052611 pyroxene Inorganic materials 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000010189 synthetic method Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000003643 water by type Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/06—Boron halogen compounds
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Ceramic Engineering (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Civil Engineering (AREA)
Materials Engineering (AREA)
Structural Engineering (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)

CN198585109768A 1984-12-31 1985-12-30 烷氧基硅烷簇-片状硅酸盐复合物 Withdrawn CN85109768A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US68785284A	1984-12-31	1984-12-31
US687,852		1984-12-31

Publications (1)

Publication Number	Publication Date
CN85109768A true CN85109768A (zh)	1986-09-24

Family

ID=24762135

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN198585109768A Withdrawn CN85109768A (zh)	1984-12-31	1985-12-30	烷氧基硅烷簇-片状硅酸盐复合物

Country Status (12)

Country	Link
JP (1)	JPS61163113A (de)
CN (1)	CN85109768A (de)
AU (1)	AU4931085A (de)
BE (1)	BE903974A (de)
DE (1)	DE3540102A1 (de)
ES (1)	ES8700962A1 (de)
FR (1)	FR2575484A1 (de)
GB (1)	GB2169274A (de)
IT (1)	IT1201509B (de)
LU (1)	LU86236A1 (de)
NL (1)	NL8503565A (de)
SE (1)	SE8506154L (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5462905A (en) *	1992-08-21	1995-10-31	Toyota Jidosha Kabushiki Kaisha	Exhaust gas purifying catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1571983A (en) *	1977-05-16	1980-07-23	Imai M	Sol of ultra-fine particles of layered structure material
US4239519A (en) *	1979-03-26	1980-12-16	Corning Glass Works	Inorganic gels and ceramic papers, films, fibers, boards, and coatings made therefrom
US4367163A (en) *	1981-04-15	1983-01-04	Research Corporation	Silica-clay complexes
US4510257A (en) *	1983-12-08	1985-04-09	Shell Oil Company	Silica-clay complexes

1985
- 1985-10-30 ES ES548368A patent/ES8700962A1/es not_active Expired
- 1985-11-04 AU AU49310/85A patent/AU4931085A/en not_active Abandoned
- 1985-11-12 DE DE19853540102 patent/DE3540102A1/de not_active Withdrawn
- 1985-12-12 JP JP60278122A patent/JPS61163113A/ja active Pending
- 1985-12-20 IT IT23350/85A patent/IT1201509B/it active
- 1985-12-24 FR FR8519134A patent/FR2575484A1/fr not_active Withdrawn
- 1985-12-24 NL NL8503565A patent/NL8503565A/nl not_active Application Discontinuation
- 1985-12-30 GB GB08531865A patent/GB2169274A/en not_active Withdrawn
- 1985-12-30 LU LU86236A patent/LU86236A1/de unknown
- 1985-12-30 CN CN198585109768A patent/CN85109768A/zh not_active Withdrawn
- 1985-12-30 SE SE8506154A patent/SE8506154L/ not_active Application Discontinuation
- 1985-12-31 BE BE0/216090A patent/BE903974A/fr unknown

Also Published As

Publication number	Publication date
GB8531865D0 (en)	1986-02-05
FR2575484A1 (fr)	1986-07-04
NL8503565A (nl)	1986-07-16
GB2169274A (en)	1986-07-09
IT8523350A0 (it)	1985-12-20
LU86236A1 (de)	1986-06-11
JPS61163113A (ja)	1986-07-23
SE8506154D0 (sv)	1985-12-30
DE3540102A1 (de)	1986-07-10
SE8506154L (sv)	1986-07-01
IT1201509B (it)	1989-02-02
ES8700962A1 (es)	1986-11-16
ES548368A0 (es)	1986-11-16
AU4931085A (en)	1986-07-10
BE903974A (fr)	1986-06-30

Legal Events

Date	Code	Title
1986-07-09	C10	Entry into substantive examination
1986-07-09	SE01	Entry into force of request for substantive examination
1986-09-24	C06	Publication
1986-09-24	PB01	Publication
1987-02-25	WW01	Invention patent application withdrawn after publication

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