CS207796B2 - Způsob výroby O,O-dimethyl-O-( 2,2-dichlorvinyl) -fosfátu - Google Patents
Způsob výroby O,O-dimethyl-O-( 2,2-dichlorvinyl) -fosfátu Download PDFInfo
- Publication number
- CS207796B2 CS207796B2 CS408979A CS408979A CS207796B2 CS 207796 B2 CS207796 B2 CS 207796B2 CS 408979 A CS408979 A CS 408979A CS 408979 A CS408979 A CS 408979A CS 207796 B2 CS207796 B2 CS 207796B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- dichlorvos
- dimethyl
- phosphate
- dichlorvinyl
- yield
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229910019142 PO4 Inorganic materials 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title 1
- 239000010452 phosphate Substances 0.000 title 1
- 238000000034 method Methods 0.000 claims description 20
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 150000003512 tertiary amines Chemical class 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 4
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 22
- 229950001327 dichlorvos Drugs 0.000 description 22
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229940014144 folate Drugs 0.000 description 1
- 239000011724 folic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL20763978A PL121528B1 (en) | 1978-06-15 | 1978-06-15 | Process for preparing 0,0-dimethyl-0-2,2-dichlorovinyl phosphateosfata |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS207796B2 true CS207796B2 (cs) | 1981-08-31 |
Family
ID=19989944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS408979A CS207796B2 (cs) | 1978-06-15 | 1979-06-13 | Způsob výroby O,O-dimethyl-O-( 2,2-dichlorvinyl) -fosfátu |
Country Status (6)
| Country | Link |
|---|---|
| BG (1) | BG30328A3 (de) |
| CS (1) | CS207796B2 (de) |
| DD (1) | DD144264A5 (de) |
| HU (1) | HU176401B (de) |
| PL (1) | PL121528B1 (de) |
| SU (1) | SU814280A3 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064688C (zh) * | 1996-06-17 | 2001-04-18 | 北京清华紫光英力化工技术有限责任公司 | 敌敌畏生产新工艺 |
| FR2862650B1 (fr) * | 2003-11-24 | 2007-04-20 | Rhodia Cons Spec Ltd | Nouveaux dendrimeres a terminaisons monophosphoniques, leur procede de preparation et leur utilisation |
-
1978
- 1978-06-15 PL PL20763978A patent/PL121528B1/pl not_active IP Right Cessation
-
1979
- 1979-06-13 SU SU792775804A patent/SU814280A3/ru active
- 1979-06-13 BG BG043933A patent/BG30328A3/xx unknown
- 1979-06-13 CS CS408979A patent/CS207796B2/cs unknown
- 1979-06-14 DD DD21362679A patent/DD144264A5/de unknown
- 1979-06-15 HU HUII000302 patent/HU176401B/hu unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DD144264A5 (de) | 1980-10-08 |
| HU176401B (hu) | 1981-02-28 |
| BG30328A3 (en) | 1981-05-15 |
| SU814280A3 (ru) | 1981-03-15 |
| PL207639A1 (de) | 1980-01-14 |
| PL121528B1 (en) | 1982-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4327039A (en) | Process for the production of 3-amino-1-hydroxypropane-1,1-diphosphonic acid | |
| Khorana et al. | 465. Studies on phosphorylation. Part XI. The reaction between carbodi-imides and acid esters of phosphoric acid. A new method for the preparation of pyrophosphates | |
| TW200307658A (en) | Removal of acids from chemical reaction mixtures with the aid of ionic liquids | |
| Hata et al. | Silyl phosphites. I. Reaction of silyl phosphites with diphenyl disulfide. Synthesis of S-phenyl nucleoside phosphorothioates | |
| Stawinski et al. | Nucleoside H-phosphonates. XI. A convenient method for the preparation of nucleoside H-phosphonates | |
| RU2074860C1 (ru) | Производные метиленбисфосфоновой кислоты | |
| CS207796B2 (cs) | Způsob výroby O,O-dimethyl-O-( 2,2-dichlorvinyl) -fosfátu | |
| Corby et al. | 223. Studies on phosphorylation. Part X. The preparation of tetraesters of pyrophosphoric acid from diesters of phosphoric acid by means of exchange reactions | |
| US3325546A (en) | Process for the preparation of detergent phosphine oxides | |
| Harger | Preparation and characterisation of N-(diphenylphosphinoyl) hydroxylamine, and conversion into O-sulphonyl derivatives that undergo Lossen-like rearrangement | |
| JP3115489B2 (ja) | リン酸モノエステルの製造方法 | |
| US3051757A (en) | Sulfone preparation process | |
| JPH08193089A (ja) | リン酸エステルの製造法 | |
| US3642960A (en) | Method of producing thiono- or dithio-phosphonic acid esters | |
| Banks et al. | The reaction between N-methyl-p-toluohydroxamic acid and tervalent phosphorous compounds: a thermal P III→ PV rearrangement proceeding by a radical mechanism | |
| Mukaiyama et al. | A Selective Phosphorylation by Means of Dibromomalonamide and Trialkyl Phosphites | |
| Hays et al. | Reaction of tetraalkylphosphonium salts with anhydrous sodium hydroxide | |
| Acock et al. | 18. Phosphorus–nitrogen compounds. Part V. Friedel–Crafts arylation of hexachlorocyclotriphosphazatriene | |
| JPS5838435B2 (ja) | リン酸モノエステルの製造法 | |
| US3150039A (en) | Insecticidal method using both pyrophosphoric and polyphosphoric acid partial ester ammonium salts and process for preparing same | |
| US2678334A (en) | Process for the preparation of bisisopropyl-amino-fluoro-phosphine oxide | |
| US3775470A (en) | Process for the preparation of organophosphonyl dichlorides | |
| Pianka | Organo‐phosphorus compounds. I. Interaction of organic phosphorohalogenides with solid alkalis: A new synthesis of schradan | |
| US4572807A (en) | Oligophosphonic acids, oligophosphinic acids, and process of preparation | |
| Rathke et al. | Synthesis of 2, 6, 7-trioxa-4-phosphabicyclo [2.2. 2] octane systems |