CS209809B2 - Method of preparation of the watery coating composition - Google Patents

Method of preparation of the watery coating composition Download PDF

Info

Publication number: CS209809B2
Authority: CS; Czechoslovakia
Prior art keywords: adduct; groups; residues; aqueous; coating composition
Prior art date: 1978-05-30

Application number

CS793727A

Other languages

Czech (cs)

English (en)

Inventor

Christopher E Caplen

John Gough

Original Assignee

Ici Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-05-30

Filing date

1979-05-30

Publication date

1981-12-31

1979-05-30 Application filed by Ici Ltd filed Critical Ici Ltd

1981-12-31 Publication of CS209809B2 publication Critical patent/CS209809B2/cs

Links

239000008199 coating composition Substances 0.000 title claims abstract description 12
238000000034 method Methods 0.000 title claims description 13
238000002360 preparation method Methods 0.000 title claims description 7
239000000203 mixture Substances 0.000 claims abstract description 20
239000002253 acid Substances 0.000 claims abstract description 12
239000012736 aqueous medium Substances 0.000 claims abstract description 10
239000011347 resin Substances 0.000 claims abstract description 7
229920005989 resin Polymers 0.000 claims abstract description 7
229920003180 amino resin Polymers 0.000 claims abstract description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 16
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
239000004971 Cross linker Substances 0.000 claims description 8
239000004310 lactic acid Substances 0.000 claims description 8
235000014655 lactic acid Nutrition 0.000 claims description 8
125000003700 epoxy group Chemical group 0.000 claims description 7
229920001568 phenolic resin Polymers 0.000 claims description 7
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
150000004985 diamines Chemical class 0.000 claims description 6
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims description 4
239000003125 aqueous solvent Substances 0.000 claims description 3
239000011874 heated mixture Substances 0.000 claims description 2
238000010438 heat treatment Methods 0.000 abstract description 12
239000006185 dispersion Substances 0.000 abstract description 9
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract description 8
239000003431 cross linking reagent Substances 0.000 abstract description 5
230000008021 deposition Effects 0.000 abstract description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 3
238000002156 mixing Methods 0.000 abstract description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
229920000642 polymer Polymers 0.000 description 19
239000000758 substrate Substances 0.000 description 19
239000000839 emulsion Substances 0.000 description 7
239000000047 product Substances 0.000 description 7
239000011248 coating agent Substances 0.000 description 6
238000000576 coating method Methods 0.000 description 6
239000003822 epoxy resin Substances 0.000 description 6
229920000647 polyepoxide Polymers 0.000 description 6
229920001807 Urea-formaldehyde Polymers 0.000 description 5
238000000151 deposition Methods 0.000 description 5
239000004593 Epoxy Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000002904 solvent Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
-1 bis-phenol A Chemical compound 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 3
238000004070 electrodeposition Methods 0.000 description 3
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
239000002184 metal Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000000126 substance Substances 0.000 description 3
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
229920000877 Melamine resin Polymers 0.000 description 2
125000003277 amino group Chemical group 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000049 pigment Substances 0.000 description 2
ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 2
150000003335 secondary amines Chemical class 0.000 description 2
238000003756 stirring Methods 0.000 description 2
229920001059 synthetic polymer Polymers 0.000 description 2
COVZYZSDYWQREU-UHFFFAOYSA-N Busulfan Chemical compound CS(=O)(=O)OCCCCOS(C)(=O)=O COVZYZSDYWQREU-UHFFFAOYSA-N 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
QLRYSABLGDVQMF-UHFFFAOYSA-N butan-1-ol;2-ethoxyethanol Chemical compound CCCCO.CCOCCO QLRYSABLGDVQMF-UHFFFAOYSA-N 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
239000004815 dispersion polymer Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
238000007746 phosphate conversion coating Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
210000002700 urine Anatomy 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/443—Polyepoxides
- C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
- C09D5/4438—Binder based on epoxy/amine adducts, i.e. reaction products of polyepoxides with compounds containing amino groups only
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Molecular Biology (AREA)
General Chemical & Material Sciences (AREA)
Paints Or Removers (AREA)
Epoxy Resins (AREA)

CS793727A 1978-05-30 1979-05-30 Method of preparation of the watery coating composition CS209809B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB23776/78A GB1604545A (en)	1978-05-30	1978-05-30	Coating compositions

Publications (1)

Publication Number	Publication Date
CS209809B2 true CS209809B2 (en)	1981-12-31

Family

ID=10201148

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS793727A CS209809B2 (en)	1978-05-30	1979-05-30	Method of preparation of the watery coating composition

Country Status (9)

Country	Link
AU (1)	AU4733879A (it)
CA (1)	CA1148678A (it)
CS (1)	CS209809B2 (it)
FR (1)	FR2427368A1 (it)
GB (1)	GB1604545A (it)
IT (1)	IT1121516B (it)
NZ (1)	NZ190540A (it)
PL (1)	PL215924A1 (it)
ZA (1)	ZA792636B (it)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3538548A1 (de) *	1985-10-30	1987-05-07	Hoechst Ag	Verfahren zur herstellung von loeslichen, von monomeren aminen freien kunstharzen mit nh-bindungen und deren verwendung
AT409964B (de)	2000-11-15	2002-12-27	Solutia Austria Gmbh	Selbstvernetzende wasserverdünnbare bindemittel
CN100436559C (zh) *	2006-11-21	2008-11-26	中国化工建设总公司常州涂料化工研究院	用于单组分环氧树脂烘烤涂料的交联剂

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1199497B (de) *	1962-10-23	1965-08-26	Albert Ag Chem Werke	Gemisch mit Phenol-Aldehyd-Kondensations-produkten als Haerter fuer Epoxyharze
ZA743472B (en) *	1973-06-04	1976-01-28	Dulux Australia Ltd	Aqueous coating composition

1978
- 1978-05-30 GB GB23776/78A patent/GB1604545A/en not_active Expired
1979
- 1979-05-23 AU AU47338/79A patent/AU4733879A/en not_active Abandoned
- 1979-05-24 NZ NZ190540A patent/NZ190540A/xx unknown
- 1979-05-28 IT IT23045/79A patent/IT1121516B/it active
- 1979-05-28 PL PL21592479A patent/PL215924A1/xx unknown
- 1979-05-29 FR FR7913570A patent/FR2427368A1/fr not_active Withdrawn
- 1979-05-29 ZA ZA792636A patent/ZA792636B/xx unknown
- 1979-05-30 CA CA000328722A patent/CA1148678A/en not_active Expired
- 1979-05-30 CS CS793727A patent/CS209809B2/cs unknown

Also Published As

Publication number	Publication date
CA1148678A (en)	1983-06-21
FR2427368A1 (fr)	1979-12-28
ZA792636B (en)	1980-11-26
IT1121516B (it)	1986-04-02
GB1604545A (en)	1981-12-09
PL215924A1 (it)	1980-02-25
IT7923045A0 (it)	1979-05-28
AU4733879A (en)	1979-12-06
NZ190540A (en)	1981-07-13

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US4119599A (en)	1978-10-10	Cathodic electrocoating compositions containing acid-functional aminoplast and flexibilized, epoxy-free, aminated resin
US8323470B2 (en)	2012-12-04	Electrodeposition coatings for use over aluminum substrates
US3994989A (en)	1976-11-30	Paint binder
US4507428A (en)	1985-03-26	Aqueous dispersions of polyamines and poly(dihydrobenzoxazines)
JPS5825326A (ja)	1983-02-15	非ゲル化樹脂の製法
US4064090A (en)	1977-12-20	Aqueous coating composition of epoxy-amine adduct and an acid with cross-linker
DE2541801A1 (de)	1977-03-31	Lackbindemittel
DE2426996A1 (de)	1974-12-19	Waessrige beschichtungszusammensetzung
US4724244A (en)	1988-02-09	Coating agents and their preparation, and cathodic electrocoating
US3960688A (en)	1976-06-01	Process for electrodepositing coatings on metal
JPS6050206B2 (ja)	1985-11-07	樹脂性バインダ−およびその製法
US4291147A (en)	1981-09-22	Polyadducts of ammonia and epoxide compounds, processes for their modification, and their use
US4719253A (en)	1988-01-12	Self-curable benzoxazine functional cathodic electrocoat resins and process
JPS6187762A (ja)	1986-05-06	熱硬化性被覆剤
US4172193A (en)	1979-10-23	Cathodic electrocoating binders
EP0159363A1 (en)	1985-10-30	Self-curing resin composition
US4396732A (en)	1983-08-02	Water soluble amine resins which are Mannich bases
GB2050381A (en)	1981-01-07	Aqueous coating composition
CA1148678A (en)	1983-06-21	Epoxy-amine adduct water soluble acid, and phenoplast or aminoplast crosslinker aqueous coating composition
JPH02110170A (ja)	1990-04-23	陰極電着塗装用の熱硬化性水性被覆材料
EP0385300B1 (de)	1995-05-03	Durch Protonieren mit Säure wasserverdünnbare polymere Umsetzungsprodukte
US4120768A (en)	1978-10-17	Process for electrocoating aqueous coating composition comprising dispersion in water of ionizable salt of epoxy amine adduct
DE2163143A1 (de)	1972-08-03	Elektrisch ablagerbare Epoxy Zubereitungen
US4387197A (en)	1983-06-07	Production of water soluble amine resins
EP0149989A2 (en)	1985-07-31	Aqueous dispersions of polyamines and poly (dihydrobenzoxazines)