CS221813B2 - Method of preparation of water dispersions of the styrene copolymere of the acryl or methacryl acid and butyles her of the maleici acid - Google Patents

Method of preparation of water dispersions of the styrene copolymere of the acryl or methacryl acid and butyles her of the maleici acid Download PDF

Info

Publication number: CS221813B2
Authority: CS; Czechoslovakia
Prior art keywords: amount; styrene; acid; weight; mixture
Prior art date: 1980-01-10

Application number

CS81174A

Other languages

Czech (cs)

English (en)

Inventor

Maria Knypl

Eugeniusz Knypl

Marian Starzak

Eva Mieczkowska

Urszula Pawlus

Romauld Palubicki

Mieczyslaw Ficek

Jozef Goldynia

Original Assignee

Os Bad Rozwojowy Kauczukow

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-01-10

Filing date

1981-01-08

Publication date

1983-04-29

1981-01-08 Application filed by Os Bad Rozwojowy Kauczukow filed Critical Os Bad Rozwojowy Kauczukow

1983-04-29 Publication of CS221813B2 publication Critical patent/CS221813B2/cs

Links

239000006185 dispersion Substances 0.000 title claims abstract description 69
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 37
238000000034 method Methods 0.000 title claims abstract description 36
229920001577 copolymer Polymers 0.000 title claims abstract description 15
239000002253 acid Substances 0.000 title claims description 7
238000002360 preparation method Methods 0.000 title claims description 6
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 title claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 39
-1 acryl Chemical group 0.000 title abstract description 15
125000005641 methacryl group Chemical group 0.000 title 1
239000000203 mixture Substances 0.000 claims abstract description 32
239000000839 emulsion Substances 0.000 claims abstract description 21
239000000178 monomer Substances 0.000 claims abstract description 9
PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims abstract description 4
239000000872 buffer Substances 0.000 claims abstract description 4
229940047670 sodium acrylate Drugs 0.000 claims abstract description 4
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract 2
235000011114 ammonium hydroxide Nutrition 0.000 claims abstract 2
230000008569 process Effects 0.000 claims description 16
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
229910052708 sodium Inorganic materials 0.000 claims description 7
239000011734 sodium Substances 0.000 claims description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 2
239000011976 maleic acid Substances 0.000 claims 2
239000007870 radical polymerization initiator Substances 0.000 claims 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
101150104365 Tomt gene Proteins 0.000 claims 1
239000008346 aqueous phase Substances 0.000 claims 1
125000004122 cyclic group Chemical group 0.000 claims 1
238000007720 emulsion polymerization reaction Methods 0.000 claims 1
159000000000 sodium salts Chemical class 0.000 claims 1
239000007787 solid Substances 0.000 claims 1
238000000576 coating method Methods 0.000 abstract description 43
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 35
239000011248 coating agent Substances 0.000 abstract description 27
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 11
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 11
JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 abstract description 10
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 6
238000006116 polymerization reaction Methods 0.000 abstract description 5
230000001681 protective effect Effects 0.000 abstract description 5
239000011541 reaction mixture Substances 0.000 abstract description 4
238000006243 chemical reaction Methods 0.000 abstract description 3
125000004432 carbon atom Chemical group C* 0.000 abstract description 2
239000000470 constituent Substances 0.000 abstract description 2
239000003995 emulsifying agent Substances 0.000 abstract description 2
239000012875 nonionic emulsifier Substances 0.000 abstract description 2
UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 abstract 3
125000002947 alkylene group Chemical group 0.000 abstract 1
239000004566 building material Substances 0.000 abstract 1
WGINADDHJLYSAK-CFYXSCKTSA-N dibutyl (z)-but-2-enedioate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)\C=C/C(=O)OCCCC WGINADDHJLYSAK-CFYXSCKTSA-N 0.000 abstract 1
DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 abstract 1
239000004568 cement Substances 0.000 description 11
238000001035 drying Methods 0.000 description 11
238000012360 testing method Methods 0.000 description 11
229920000642 polymer Polymers 0.000 description 9
239000011521 glass Substances 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 5
230000008961 swelling Effects 0.000 description 5
208000034656 Contusions Diseases 0.000 description 4
238000009835 boiling Methods 0.000 description 4
238000007710 freezing Methods 0.000 description 4
230000008014 freezing Effects 0.000 description 4
230000009477 glass transition Effects 0.000 description 4
239000000047 product Substances 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
230000015271 coagulation Effects 0.000 description 3
238000005345 coagulation Methods 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
239000002245 particle Substances 0.000 description 3
238000003860 storage Methods 0.000 description 3
239000000758 substrate Substances 0.000 description 3
SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
235000008733 Citrus aurantifolia Nutrition 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
235000011941 Tilia x europaea Nutrition 0.000 description 2
ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000012752 auxiliary agent Substances 0.000 description 2
239000002585 base Substances 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
230000000694 effects Effects 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000004571 lime Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
235000019645 odor Nutrition 0.000 description 2
239000000049 pigment Substances 0.000 description 2
239000011253 protective coating Substances 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
235000017281 sodium acetate Nutrition 0.000 description 2
239000001632 sodium acetate Substances 0.000 description 2
238000010561 standard procedure Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 2
MCRZWYDXIGCFKO-UHFFFAOYSA-N 2-butylpropanedioic acid Chemical compound CCCCC(C(O)=O)C(O)=O MCRZWYDXIGCFKO-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
235000006679 Mentha X verticillata Nutrition 0.000 description 1
235000002899 Mentha suaveolens Nutrition 0.000 description 1
235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
230000000844 anti-bacterial effect Effects 0.000 description 1
239000007798 antifreeze agent Substances 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
239000003899 bactericide agent Substances 0.000 description 1
208000034526 bruise Diseases 0.000 description 1
XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000005034 decoration Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000004438 eyesight Effects 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
238000005187 foaming Methods 0.000 description 1
230000037406 food intake Effects 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229940051250 hexylene glycol Drugs 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
239000007974 sodium acetate buffer Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
238000004347 surface barrier Methods 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000010257 thawing Methods 0.000 description 1
238000004017 vitrification Methods 0.000 description 1
KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 1
210000002268 wool Anatomy 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Paints Or Removers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

CS81174A 1980-01-10 1981-01-08 Method of preparation of water dispersions of the styrene copolymere of the acryl or methacryl acid and butyles her of the maleici acid CS221813B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PL1980221298A PL126989B1 (en)	1980-01-10	1980-01-10	Method of producing watery dispersions of styrene,butylmaleate and/met/acrylic acid copolymers used for protectively and decoratively coating structural components of a building using thermal methods

Publications (1)

Publication Number	Publication Date
CS221813B2 true CS221813B2 (en)	1983-04-29

Family

ID=20000797

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS81174A CS221813B2 (en)	1980-01-10	1981-01-08	Method of preparation of water dispersions of the styrene copolymere of the acryl or methacryl acid and butyles her of the maleici acid

Country Status (5)

Country	Link
US (1)	US4388438A (pl)
CS (1)	CS221813B2 (pl)
DD (1)	DD156977A5 (pl)
PL (1)	PL126989B1 (pl)
YU (1)	YU324980A (pl)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5844711B2 (ja) *	1979-07-04	1983-10-05	日東電工株式会社	水溶性感圧接着剤組成物
DE3305361A1 (de) *	1983-02-17	1984-08-23	Röhm GmbH, 6100 Darmstadt	Bindemittel fuer giessereiformsande
DE3433085A1 (de) *	1984-09-08	1986-03-20	Basf Ag, 6700 Ludwigshafen	Stark dilatante polymerdispersionen mit verminderter temperaturabhaengigkeit der kritischen schergeschwindigkeit
CA1333822C (en) *	1986-11-07	1995-01-03	Robert S. Beyersdorf	Latex compositions useful as binders in composite board having dimensional stability and strength
ITMC20070008A1 (it) *	2007-01-17	2008-07-18	Diasen Srl	Impermeabilizzante riduttore di propagazione del fuoco.
PL241665B1 (pl)	2020-07-21	2022-11-14	Politechnika Gdanska	Reaktor i sposób do przeprowadzania pirolizy materiałów wybranych z grupy składającej się ze zrębków, drewna podkładowego, odpadów drzewnych, odpadów leśnych, osadów ściekowych, koksu naftowego, komunalnych odpadów stałych (MSW), paliw pochodzących z odpadów (RDF) lub dowolnej kombinacji paliw z biomasy i oczyszczania gazu pirolitycznego
CN114044857B (zh) *	2021-12-02	2024-04-09	万华化学集团股份有限公司	表面富含羧基的聚丙烯酸酯水性分散体的制备方法、分散体及其应用
CN116715796A (zh) *	2023-07-10	2023-09-08	广东衡光新材料科技有限公司	一种苯丙乳液、制备方法及其应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2962465A (en) *	1958-01-22	1960-11-29	Monsanto Chemicals	Production of acrylate interpolymer aqueous latices
US3164562A (en) *	1960-10-14	1965-01-05	Grace W R & Co	Vinyl acetate emulsion
US3472681A (en) *	1966-07-28	1969-10-14	Pennwalt Corp	Protective coated asbestos cement panels
DE1745360C3 (de) *	1968-01-27	1974-11-21	Reichhold-Albert-Chemie Ag, 2000 Hamburg	Verfahren zur Herstellung von geruchsarmen Dispersionen
US4059665A (en) *	1970-05-11	1977-11-22	Rohm And Haas Company	Bonded non-woven fabric and method for making it
US3736287A (en) *	1971-02-19	1973-05-29	Celanese Corp	Aqueous vinyl acrylic interpolymer emulsion and use thereof in latex paints
US3736286A (en) *	1971-06-30	1973-05-29	Rohm & Haas	Aqueous pigmented acrylic dispersion compositions having improved rheology
US3862075A (en) *	1972-06-01	1975-01-21	Desoto Inc	Aqeous polymerization of unsaturated monomers utilizing trihydric or tetrahydric alcohols to produce emulsifier-free dispersions
SE419748B (sv)	1973-07-19	1981-08-24	Kubota Ltd	Forfarande for beleggning av en cementhaltig produkt

1980
- 1980-01-10 PL PL1980221298A patent/PL126989B1/pl unknown
- 1980-12-23 YU YU03249/80A patent/YU324980A/xx unknown
1981
- 1981-01-06 US US06/224,476 patent/US4388438A/en not_active Expired - Fee Related
- 1981-01-07 DD DD81226867A patent/DD156977A5/de unknown
- 1981-01-08 CS CS81174A patent/CS221813B2/cs unknown

Also Published As

Publication number	Publication date
YU324980A (en)	1983-02-28
PL221298A1 (pl)	1981-07-24
DD156977A5 (de)	1982-10-06
PL126989B1 (en)	1983-09-30
US4388438A (en)	1983-06-14

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