CS236454B4 - Catalyst for alpha-olefins polymerization and method of its production - Google Patents

Catalyst for alpha-olefins polymerization and method of its production Download PDF

Info

Publication number: CS236454B4
Authority: CS; Czechoslovakia
Prior art keywords: solid product; catalyst; alpha; polymerization; added
Prior art date: 1978-12-01

Application number

CS794012A

Other languages

Czech (cs)

English (en)

Inventor

Kazutsune Kikuta

Masami Tachibana

Akihiro Sato

Original Assignee

Chisso Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-12-01

Filing date

1979-06-11

Publication date

1985-05-15

1979-06-11 Application filed by Chisso Corp filed Critical Chisso Corp

1985-05-15 Publication of CS236454B4 publication Critical patent/CS236454B4/cs

Links

239000003054 catalyst Substances 0.000 title claims abstract description 107
238000006116 polymerization reaction Methods 0.000 title claims abstract description 77
238000000034 method Methods 0.000 title claims abstract description 63
239000004711 α-olefin Substances 0.000 title claims abstract description 30
238000004519 manufacturing process Methods 0.000 title abstract description 12
239000012265 solid product Substances 0.000 claims abstract description 141
150000001875 compounds Chemical class 0.000 claims abstract description 41
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 5
238000006243 chemical reaction Methods 0.000 claims description 74
-1 alkaline earth metal carbonate Chemical class 0.000 claims description 46
230000008569 process Effects 0.000 claims description 28
150000002148 esters Chemical class 0.000 claims description 11
229910052782 aluminium Inorganic materials 0.000 claims description 9
150000004820 halides Chemical class 0.000 claims description 8
239000007795 chemical reaction product Substances 0.000 claims description 7
229920001296 polysiloxane Polymers 0.000 claims description 7
230000004913 activation Effects 0.000 claims description 6
125000005234 alkyl aluminium group Chemical group 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
150000002576 ketones Chemical class 0.000 claims description 6
150000001298 alcohols Chemical class 0.000 claims description 5
150000001412 amines Chemical class 0.000 claims description 5
150000002170 ethers Chemical class 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 4
150000001299 aldehydes Chemical class 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
235000014113 dietary fatty acids Nutrition 0.000 claims description 3
239000000194 fatty acid Substances 0.000 claims description 3
229930195729 fatty acid Natural products 0.000 claims description 3
150000004665 fatty acids Chemical class 0.000 claims description 3
230000000737 periodic effect Effects 0.000 claims description 3
150000003003 phosphines Chemical class 0.000 claims description 3
125000005538 phosphinite group Chemical group 0.000 claims description 3
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 3
150000003568 thioethers Chemical class 0.000 claims description 3
150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 2
125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
239000012948 isocyanate Substances 0.000 claims description 2
150000002513 isocyanates Chemical class 0.000 claims description 2
150000002825 nitriles Chemical class 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
229910002091 carbon monoxide Inorganic materials 0.000 claims 1
239000004927 clay Substances 0.000 claims 1
150000002899 organoaluminium compounds Chemical class 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 49
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract description 24
239000000370 acceptor Substances 0.000 abstract description 14
229910001507 metal halide Inorganic materials 0.000 abstract description 12
150000005309 metal halides Chemical class 0.000 abstract description 12
229910052751 metal Inorganic materials 0.000 abstract description 10
239000002184 metal Substances 0.000 abstract description 10
239000002245 particle Substances 0.000 abstract description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 5
229920000098 polyolefin Polymers 0.000 abstract description 4
229910052723 transition metal Inorganic materials 0.000 abstract description 4
150000003624 transition metals Chemical class 0.000 abstract description 3
229910003074 TiCl4 Inorganic materials 0.000 abstract description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 66
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 66
230000000052 comparative effect Effects 0.000 description 37
238000002360 preparation method Methods 0.000 description 35
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 34
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
239000002904 solvent Substances 0.000 description 20
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 18
239000001257 hydrogen Substances 0.000 description 15
229910052739 hydrogen Inorganic materials 0.000 description 15
238000003756 stirring Methods 0.000 description 15
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 14
239000000047 product Substances 0.000 description 14
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
238000000227 grinding Methods 0.000 description 13
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
239000005977 Ethylene Substances 0.000 description 12
230000000694 effects Effects 0.000 description 12
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 12
239000007787 solid Substances 0.000 description 11
229910052719 titanium Inorganic materials 0.000 description 11
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 10
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 9
150000002736 metal compounds Chemical class 0.000 description 9
230000036961 partial effect Effects 0.000 description 9
229920001155 polypropylene Polymers 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000000395 magnesium oxide Substances 0.000 description 8
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 8
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 8
239000000463 material Substances 0.000 description 8
239000000203 mixture Substances 0.000 description 8
239000010936 titanium Substances 0.000 description 8
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 7
239000002253 acid Substances 0.000 description 7
238000010438 heat treatment Methods 0.000 description 7
238000002156 mixing Methods 0.000 description 7
239000000725 suspension Substances 0.000 description 7
ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 6
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 6
AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 5
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
238000010908 decantation Methods 0.000 description 5
238000001035 drying Methods 0.000 description 5
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 5
238000003801 milling Methods 0.000 description 5
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
241000894007 species Species 0.000 description 5
150000003623 transition metal compounds Chemical class 0.000 description 5
239000004215 Carbon black (E152) Substances 0.000 description 4
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 4
229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 4
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 4
RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000004677 hydrates Chemical class 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
239000007788 liquid Substances 0.000 description 4
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 4
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 4
239000000347 magnesium hydroxide Substances 0.000 description 4
229910001862 magnesium hydroxide Inorganic materials 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
230000037048 polymerization activity Effects 0.000 description 4
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
239000005711 Benzoic acid Substances 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
125000003545 alkoxy group Chemical group 0.000 description 3
238000000498 ball milling Methods 0.000 description 3
235000010233 benzoic acid Nutrition 0.000 description 3
238000001914 filtration Methods 0.000 description 3
150000002367 halogens Chemical group 0.000 description 3
230000006872 improvement Effects 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
239000001095 magnesium carbonate Substances 0.000 description 3
229910000021 magnesium carbonate Inorganic materials 0.000 description 3
150000002894 organic compounds Chemical class 0.000 description 3
230000009467 reduction Effects 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
125000004104 aryloxy group Chemical group 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
230000007547 defect Effects 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
KBEBGUQPQBELIU-UHFFFAOYSA-N ethyl 3-phenylprop-2-enoate Chemical compound CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000002685 polymerization catalyst Substances 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
239000000843 powder Substances 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
239000005049 silicon tetrachloride Substances 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
239000001119 stannous chloride Substances 0.000 description 2
235000011150 stannous chloride Nutrition 0.000 description 2
235000002906 tartaric acid Nutrition 0.000 description 2
239000011975 tartaric acid Substances 0.000 description 2
FWPIDFUJEMBDLS-UHFFFAOYSA-L tin(II) chloride dihydrate Chemical compound O.O.Cl[Sn]Cl FWPIDFUJEMBDLS-UHFFFAOYSA-L 0.000 description 2
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
DWKNOLCXIFYNFV-HSZRJFAPSA-N 2-[[(2r)-1-[1-[(4-chloro-3-methylphenyl)methyl]piperidin-4-yl]-5-oxopyrrolidine-2-carbonyl]amino]-n,n,6-trimethylpyridine-4-carboxamide Chemical compound CN(C)C(=O)C1=CC(C)=NC(NC(=O)[C@@H]2N(C(=O)CC2)C2CCN(CC=3C=C(C)C(Cl)=CC=3)CC2)=C1 DWKNOLCXIFYNFV-HSZRJFAPSA-N 0.000 description 1
CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical compound CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 description 1
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
CLWSOSCMXFUYNY-UHFFFAOYSA-N 3-ethyl-4-methylbenzoic acid Chemical compound CCC1=CC(C(O)=O)=CC=C1C CLWSOSCMXFUYNY-UHFFFAOYSA-N 0.000 description 1
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
FVFVNNKYKYZTJU-UHFFFAOYSA-N 6-chloro-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(Cl)=N1 FVFVNNKYKYZTJU-UHFFFAOYSA-N 0.000 description 1
JJDGTGGQXAAVQX-UHFFFAOYSA-N 6-methyl-1-(6-methylheptoxy)heptane Chemical compound CC(C)CCCCCOCCCCCC(C)C JJDGTGGQXAAVQX-UHFFFAOYSA-N 0.000 description 1
DFVOXRAAHOJJBN-UHFFFAOYSA-N 6-methylhept-1-ene Chemical compound CC(C)CCCC=C DFVOXRAAHOJJBN-UHFFFAOYSA-N 0.000 description 1
241000584629 Aosa Species 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
XSWXGPZTTSGDNP-UHFFFAOYSA-N C(C)(C)(CC(C)(C)C)[Al](C(C)(C)CC(C)(C)C)C(C)(C)CC(C)(C)C Chemical compound C(C)(C)(CC(C)(C)C)[Al](C(C)(C)CC(C)(C)C)C(C)(C)CC(C)(C)C XSWXGPZTTSGDNP-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
FNGLQNMQHOAIJQ-UHFFFAOYSA-N Cl[S](Cl)Cl Chemical compound Cl[S](Cl)Cl FNGLQNMQHOAIJQ-UHFFFAOYSA-N 0.000 description 1
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 description 1
DULCUDSUACXJJC-UHFFFAOYSA-N Ethyl phenylacetate Chemical compound CCOC(=O)CC1=CC=CC=C1 DULCUDSUACXJJC-UHFFFAOYSA-N 0.000 description 1
235000004109 Gymnanthemum amygdalinum Nutrition 0.000 description 1
241001635503 Gymnanthemum amygdalinum Species 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
FEXQDZTYJVXMOS-UHFFFAOYSA-N Isopropyl benzoate Chemical compound CC(C)OC(=O)C1=CC=CC=C1 FEXQDZTYJVXMOS-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
229910004809 Na2 SO4 Inorganic materials 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
HDVDLQFPDLTOSI-UHFFFAOYSA-L O[AlH]O Chemical class O[AlH]O HDVDLQFPDLTOSI-UHFFFAOYSA-L 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
YPWFISCTZQNZAU-UHFFFAOYSA-N Thiane Chemical compound C1CCSCC1 YPWFISCTZQNZAU-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000005325 alkali earth metal hydroxides Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
150000005215 alkyl ethers Chemical class 0.000 description 1
125000005376 alkyl siloxane group Chemical group 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical compound [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
230000008901 benefit Effects 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
YCURFOQQPNHZAO-UHFFFAOYSA-N butyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCCCC)=CC=CC2=C1 YCURFOQQPNHZAO-UHFFFAOYSA-N 0.000 description 1
235000015115 caffè latte Nutrition 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
239000002775 capsule Substances 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
239000012295 chemical reaction liquid Substances 0.000 description 1
229940068911 chloride hexahydrate Drugs 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
229930003836 cresol Natural products 0.000 description 1
230000009089 cytolysis Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012636 effector Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
238000010828 elution Methods 0.000 description 1
NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
125000004494 ethyl ester group Chemical group 0.000 description 1
XCTLDQQOHIEUCJ-UHFFFAOYSA-N ethyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC)=CC=CC2=C1 XCTLDQQOHIEUCJ-UHFFFAOYSA-N 0.000 description 1
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
JLHMVTORNNQCRM-UHFFFAOYSA-N ethylphosphine Chemical compound CCP JLHMVTORNNQCRM-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
VOAPTKOANCCNFV-UHFFFAOYSA-N hexahydrate;hydrochloride Chemical compound O.O.O.O.O.O.Cl VOAPTKOANCCNFV-UHFFFAOYSA-N 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
239000011656 manganese carbonate Substances 0.000 description 1
235000006748 manganese carbonate Nutrition 0.000 description 1
229940093474 manganese carbonate Drugs 0.000 description 1
IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 1
229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229940043265 methyl isobutyl ketone Drugs 0.000 description 1
230000000802 nitrating effect Effects 0.000 description 1
GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
229940127240 opiate Drugs 0.000 description 1
150000002900 organolithium compounds Chemical class 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
QCAJADRKKXQEGQ-UHFFFAOYSA-J oxolane;titanium(4+);tetrachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Ti+4].C1CCOC1 QCAJADRKKXQEGQ-UHFFFAOYSA-J 0.000 description 1
239000013618 particulate matter Substances 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
125000006368 phosphonoyl group Chemical group [*:1]P([*:2])=O 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920013639 polyalphaolefin Polymers 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000007420 reactivation Effects 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
238000004513 sizing Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
210000004243 sweat Anatomy 0.000 description 1
PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical class C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CS794012A 1978-12-01 1979-06-11 Catalyst for alpha-olefins polymerization and method of its production CS236454B4 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP53148728A JPS588686B2 (ja)	1978-12-01	1978-12-01	α↓−オレフイン重合体の製造方法

Publications (1)

Publication Number	Publication Date
CS236454B4 true CS236454B4 (en)	1985-05-15

Family

ID=15459275

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS794012A CS236454B4 (en)	1978-12-01	1979-06-11	Catalyst for alpha-olefins polymerization and method of its production

Country Status (7)

Country	Link
US (1)	US4287328A (ja)
JP (1)	JPS588686B2 (ja)
CS (1)	CS236454B4 (ja)
DE (1)	DE2922751C2 (ja)
FR (1)	FR2442860A1 (ja)
GB (1)	GB2037300B (ja)
IT (1)	IT1117192B (ja)

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DE2830039A1 (de) *	1978-07-07	1980-01-17	Hoechst Ag	Verfahren zur herstellung eines mischkatalysators
JPS5825362B2 (ja) *	1980-02-15	1983-05-27	チッソ株式会社	α−オレフイン重合体の製造方法
JPS56129206A (en) *	1980-03-14	1981-10-09	Chisso Corp	Production of alpha-olefin polymer
JPS56133303A (en) *	1980-03-22	1981-10-19	Chisso Corp	Production of alpha-olefin polymer
JPS56136806A (en) *	1980-03-29	1981-10-26	Mitsui Petrochem Ind Ltd	Storage of solid titanium catalyst component containing highly active magnesium
US4618661A (en) *	1980-05-02	1986-10-21	Phillips Petroleum Company	Supported high efficiency polyolefin catalyst component and methods of making and using the same
US4405769A (en) *	1980-08-12	1983-09-20	Capshew Charles E	Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4325837A (en)	1980-08-12	1982-04-20	Phillips Petroleum Company	Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4410671A (en) *	1980-08-12	1983-10-18	Phillips Petroleum Company	Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4326988A (en)	1980-08-12	1982-04-27	Phillips Petroleum Company	Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
JPS57153005A (en) *	1981-03-19	1982-09-21	Ube Ind Ltd	Polymerization of alpha-olefin
US4774300A (en) *	1982-08-20	1988-09-27	Phillips Petroleum Company	Supported polyolefin catalyst components and methods of making and using the same
FR2541683B1 (fr) *	1983-02-28	1986-05-09	Ato Chimie	Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
US4461846A (en) *	1983-03-28	1984-07-24	National Distillers And Chemical Corporation	Catalyst dispersion having improved stability against phase separation
JPS59206418A (ja) *	1983-05-11	1984-11-22	Mitsui Petrochem Ind Ltd	４−メチル−１−ペンテン重合体の製法
JPS6031504A (ja) *	1983-07-29	1985-02-18	Nippon Oil Co Ltd	ポリオレフインの製造方法
USH179H (en)	1984-11-28	1986-12-02		Polybutylene
US4767735A (en) *	1987-02-02	1988-08-30	Cosden Technology, Inc.	Catalyst pretreatment process
FR2616789B1 (fr) *	1987-06-16	1991-07-26	Atochem	Procede de traitement de composante catalytique sur support d'oxyde metallique poreux pour la polymerisation des olefines en phase gazeuse. application du catalyseur obtenu a la polymerisation des olefines
US5378672A (en) *	1992-03-04	1995-01-03	Fina Technology, Inc.	Methods and systems for multi-component catalyst formulation
EP0641362B1 (en) *	1992-04-20	1998-11-11	Exxon Chemical Patents Inc.	Ethylene/branched olefin copolymers
US5459117A (en) *	1993-08-27	1995-10-17	Ewen; John A.	Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en)	1993-09-24	1997-05-20	Montell Technology Company B.V.	Stereospecific metallocene catalysts with stereolocking α-CP substituents
US6403772B1 (en) *	1995-09-11	2002-06-11	Montell Technology Company, Bv	Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
TR199901635T2 (xx) *	1996-11-15	2000-02-21	Montell Technology Company Bv	Heterosiklik metalosenler ve polimerizasyon kataliz�rleri.
US6160072A (en) *	1997-05-02	2000-12-12	Ewen; John A.	Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6417299B1 (en)	1999-06-07	2002-07-09	Eastman Chemical Company	Process for producing ethylene/olefin interpolymers
CN103626895B (zh) *	2012-08-23	2016-03-30	中国石油化工股份有限公司	用于烯烃聚合反应的催化剂组分及其催化剂制备方法
CN103626893B (zh) *	2012-08-23	2016-03-30	中国石油化工股份有限公司	用于烯烃聚合反应的催化剂组分及其催化剂制备方法
CN103626894B (zh) *	2012-08-23	2016-03-30	中国石油化工股份有限公司	用于烯烃聚合反应的催化剂组分及其催化剂制备方法
RU2692246C1 (ru)	2017-06-15	2019-06-24	Индийская Нефтяная Корпорация Лимитэд	Внешний донор для полимеризации олефинов
CN117843839B (zh) *	2024-01-08	2025-11-07	中化泉州石化有限公司	一种络合型催化剂在合成聚α-烯烃中的应用

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US3067183A (en) *	1956-10-15	1962-12-04	Eastman Kodak Co	Polymerization of olefins with a catalyst slurry preactivated with ethylene
US3900454A (en) *	1968-02-03	1975-08-19	Chisso Corp	Method for polymerizing monomers comprising alpha-olefin
US4103078A (en) *	1969-08-01	1978-07-25	Chisso Corporation	Method for producing polymers of alpha-olefin
US4027087A (en) *	1972-10-30	1977-05-31	Chisso Corporation	Method for producing ethylene polymers
US3992322A (en) *	1975-04-11	1976-11-16	Universal Oil Products Company	Preparation of polymerization catalyst systems
JPS5330681A (en) *	1976-09-02	1978-03-23	Mitsui Petrochem Ind Ltd	Preparation of polyalpha-olefin

1978
- 1978-12-01 JP JP53148728A patent/JPS588686B2/ja not_active Expired
1979
- 1979-03-21 US US06/022,613 patent/US4287328A/en not_active Expired - Lifetime
- 1979-05-25 GB GB7918292A patent/GB2037300B/en not_active Expired
- 1979-06-05 DE DE2922751A patent/DE2922751C2/de not_active Expired
- 1979-06-11 CS CS794012A patent/CS236454B4/cs unknown
- 1979-06-15 IT IT49436/79A patent/IT1117192B/it active
- 1979-08-21 FR FR7921049A patent/FR2442860A1/fr active Granted

Also Published As

Publication number	Publication date
GB2037300A (en)	1980-07-09
JPS5575409A (en)	1980-06-06
DE2922751C2 (de)	1987-01-29
DE2922751A1 (de)	1980-06-04
IT1117192B (it)	1986-02-17
FR2442860A1 (fr)	1980-06-27
FR2442860B1 (ja)	1982-07-02
GB2037300B (en)	1983-01-19
IT7949436A0 (it)	1979-06-15
JPS588686B2 (ja)	1983-02-17
US4287328A (en)	1981-09-01

Publication	Publication Date	Title
CS236454B4 (en)	1985-05-15	Catalyst for alpha-olefins polymerization and method of its production
EP0314165B1 (en)	1991-08-07	Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution
CA1151142A (en)	1983-08-02	PROCESS FOR PRODUCING .alpha.-OLEFIN POLYMERS
JPS61293207A (ja)	1986-12-24	徹底予備重合させた担持アルフア−オレフイン重合触媒
NO163779B (no)	1990-04-15	Etylen-kopolymer, samt fremgangsmaate ved fremstilling derav.
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