CS30792A3 - Polymerization and co-polymerization process - Google Patents
Polymerization and co-polymerization processInfo
- Publication number
- CS30792A3 CS30792A3 CS92307A CS30792A CS30792A3 CS 30792 A3 CS30792 A3 CS 30792A3 CS 92307 A CS92307 A CS 92307A CS 30792 A CS30792 A CS 30792A CS 30792 A3 CS30792 A3 CS 30792A3
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- mol
- catalyst system
- contg
- pref
- polymerisation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000007334 copolymerization reaction Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- -1 polypropylene Polymers 0.000 abstract 3
- 239000004743 Polypropylene Substances 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- 229920001155 polypropylene Polymers 0.000 abstract 2
- 229910000077 silane Inorganic materials 0.000 abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001924 cycloalkanes Chemical class 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 abstract 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 abstract 1
- OANIYCQMEVXZCJ-UHFFFAOYSA-N ditert-butyl(dimethoxy)silane Chemical compound CO[Si](OC)(C(C)(C)C)C(C)(C)C OANIYCQMEVXZCJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 150000002895 organic esters Chemical class 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000005691 triesters Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Dental Preparations (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65044391A | 1991-02-04 | 1991-02-04 | |
| US07/793,821 US5218052A (en) | 1991-02-04 | 1991-11-18 | Olefin polymerization and copolymerization process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS30792A3 true CS30792A3 (en) | 1992-08-12 |
| CZ287574B6 CZ287574B6 (cs) | 2000-12-13 |
Family
ID=27095865
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5218052A (cs) |
| EP (2) | EP0498603B1 (cs) |
| JP (1) | JPH05105722A (cs) |
| KR (1) | KR100263263B1 (cs) |
| AT (1) | ATE146806T1 (cs) |
| CA (1) | CA2059838C (cs) |
| CZ (1) | CZ287574B6 (cs) |
| DE (1) | DE69216117T2 (cs) |
| SK (1) | SK280948B6 (cs) |
Families Citing this family (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7074871B2 (en) * | 1992-05-29 | 2006-07-11 | Basell Poliolefine Italia S.R.L. | Crystalline polymers of propylene having improved processability in the molten state and process for their preparation |
| IT1260497B (it) * | 1992-05-29 | 1996-04-09 | Himont Inc | Polimeri cristallini del propilene aventi migliorata processabilita' allo stato e processo per la loro preparazione |
| TW300235B (cs) † | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| DE69412954T2 (de) * | 1993-01-11 | 1999-03-11 | Mitsui Chemicals, Inc., Tokio/Tokyo | Propylenpolymer zusammensetzung |
| JPH07173214A (ja) * | 1993-10-27 | 1995-07-11 | Nippon Oil Co Ltd | オレフィン類重合用触媒成分 |
| US5409992A (en) * | 1994-02-28 | 1995-04-25 | Himont Incorporated | Calenderable blends containing broad molecular weight distribution propylene polymer material |
| KR100364470B1 (ko) * | 1994-07-15 | 2003-02-05 | 이데미쓰세끼유가가꾸가부시끼가이샤 | 고강성 폴리프로필렌계수지 및 그것을 이용한 블로우성형체 |
| KR100341040B1 (ko) * | 1994-08-18 | 2002-11-23 | 칫소가부시키가이샤 | 고강성프로필렌-에틸렌블록공중합체조성물및이의제조방법 |
| FI944761A0 (fi) * | 1994-10-11 | 1994-10-11 | Borealis Holding As | Ny polypropylenkomposition med vid molekylvikt distribution |
| WO1996011982A1 (en) * | 1994-10-12 | 1996-04-25 | Kimberly-Clark Worldwide, Inc. | Melt-extrudable thermoplastic polypropylene composition and nonwoven web prepared therefrom |
| DE69517337T2 (de) * | 1994-12-20 | 2000-10-19 | Engelhard Corp., Iselin | Verfahren zur reinigung von aromatischen polycarbonsäuren |
| USH1722H (en) * | 1995-05-05 | 1998-04-07 | Goode; Mark Gregory | Process for producing polypropylene impact block copolymers |
| ATE245665T1 (de) * | 1995-09-28 | 2003-08-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
| US5738745A (en) * | 1995-11-27 | 1998-04-14 | Kimberly-Clark Worldwide, Inc. | Method of improving the photostability of polypropylene compositions |
| DE19606510A1 (de) | 1996-02-22 | 1997-08-28 | Hoechst Ag | Hochmolekulares Polypropylen mit breiter Molmassenverteilung |
| DE19621022B4 (de) † | 1996-05-24 | 2014-12-31 | Basell Polyolefine Gmbh | Hochmolekulares Ethylen/Propylen-Reaktorblend mit breiter Molmassenverteilung |
| WO1998010016A1 (en) | 1996-09-04 | 1998-03-12 | Exxon Chemical Patents Inc. | Improved propylene polymers for oriented films |
| US6583227B2 (en) | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
| US6576306B2 (en) | 1996-09-04 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
| US5948720A (en) * | 1997-01-07 | 1999-09-07 | Huntsman Polymers Corporation | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof |
| US6100351A (en) * | 1997-01-07 | 2000-08-08 | Huntsman Polymers Corporation | Olefin polymerization process and products thereof |
| US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
| US6080818A (en) * | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
| DE69820399T2 (de) | 1997-05-30 | 2004-10-07 | Mitsui Chemicals Inc | Polypropylenharz-Zusammensetzung und spritzgegossener Gegenstand |
| US6350828B1 (en) | 1997-08-05 | 2002-02-26 | Grand Polymer Co Ltd | Polypropylene resin composition and use thereof |
| FI973816A0 (fi) | 1997-09-26 | 1997-09-26 | Borealis As | Polypropen med hoeg smaeltstyrka |
| SG71878A1 (en) * | 1997-12-11 | 2000-04-18 | Sumitomo Chemical Co | Propylene-based polymer composition and foamed article thereof |
| US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
| ES2220058T3 (es) * | 1998-05-13 | 2004-12-01 | Exxonmobil Chemical Patents Inc. | Homopolimeros de propileno y metodos de fabricarlos. |
| US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
| US7354880B2 (en) * | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| KR100565151B1 (ko) | 1999-02-04 | 2006-03-30 | 미쓰이 가가쿠 가부시키가이샤 | 폴리프로필렌 블록 공중합체 수지 및 제조 방법 |
| US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
| KR100546499B1 (ko) * | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| WO2001032757A1 (en) * | 1999-11-04 | 2001-05-10 | Exxonmobil Chemical Patents Inc. | Foamable polypropylene polymers and their use |
| KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
| US6566294B2 (en) | 2000-12-21 | 2003-05-20 | Exxonmobil Chemical Patents Inc. | Multi-donor catalyst system for the polymerization of olefins |
| WO2002051882A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Chelate catalyst for olefin polymerization and olefin polymerization method using the same |
| JP2004516379A (ja) * | 2000-12-22 | 2004-06-03 | サムソン ジェネラル ケミカルズ カンパニー リミテッド | 表面硬度及び耐スクラッチ性が向上されたポリプロピレン樹脂組成物 |
| ATE305490T1 (de) * | 2000-12-22 | 2005-10-15 | Samsung General Chemicals Co | Polyolefinharzzusammensetzung |
| EP1362131A4 (en) * | 2000-12-22 | 2005-03-02 | Samsung General Chemicals Co | POLYPROPYL FLAME RETARDANT COMPOSITION |
| KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| JP4174425B2 (ja) * | 2002-01-03 | 2008-10-29 | イネオス・ユーエスエイ・エルエルシー | 二重供与体触媒系を用いる気相オレフィン重合 |
| CN100389148C (zh) * | 2002-09-06 | 2008-05-21 | 丁少忠 | 一种可生物降解的餐具及其制备方法 |
| WO2005035594A1 (en) * | 2003-09-23 | 2005-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process |
| US20060223956A1 (en) * | 2003-09-23 | 2006-10-05 | Linfeng Chen | Catalyst composition with mixed sca and propylene polymerization process |
| US7491670B2 (en) | 2003-09-23 | 2009-02-17 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
| EP1726603A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| EP1726602A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| EP1899415B1 (en) * | 2005-07-01 | 2011-08-10 | Basell Poliolefine Italia S.r.l. | Propylene polymers having broad molecular weight distribution |
| US9694522B2 (en) * | 2007-07-18 | 2017-07-04 | Sumitomo Chemical Company, Limited | Thermoplastic elastomer composition and composite molded body |
| KR101576308B1 (ko) | 2007-08-24 | 2015-12-09 | 더블유.알. 그레이스 앤드 캄파니-콘. | 조절된 알루미늄 대 sca 비를 갖는 자기-제한성 촉매 시스템 및 방법 |
| JP5740159B2 (ja) | 2007-12-21 | 2015-06-24 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 二座内部供与体を有する自己制限性触媒組成物 |
| RU2487897C2 (ru) | 2008-08-21 | 2013-07-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Ударопрочный пропиленовый сополимер с высокой скоростью течения расплава и способ его получения |
| CN102186889B (zh) | 2008-08-21 | 2013-11-06 | 陶氏环球技术有限责任公司 | 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 |
| US8916250B2 (en) * | 2008-10-01 | 2014-12-23 | Borealis Ag | Sewage pipe comprising beta nucleated polypropylene material with improved properties |
| US8604118B2 (en) | 2008-12-26 | 2013-12-10 | Dow Global Technologies Llc | Antifoulant for impact copolymers and method |
| JP5501384B2 (ja) * | 2009-02-20 | 2014-05-21 | イネオス ユーエスエイ リミテッド ライアビリティ カンパニー | 水平撹拌気相反応器で製造されるポリオレフィン材料の分子量分布の拡大法 |
| EP2516489B1 (en) * | 2009-12-21 | 2014-07-02 | W.R. Grace & CO. - CONN. | Gas-phase polymerization process having multiple flow regimes |
| US9272965B2 (en) * | 2009-12-22 | 2016-03-01 | Catalytic Distillation Technologies | Process for the conversion of alcohols to olefins |
| US10647790B2 (en) | 2011-06-30 | 2020-05-12 | W. R. Grace & Co.-Conn. | Process for gas-phase polymerization having high bed bulk density |
| JP5785809B2 (ja) * | 2011-07-28 | 2015-09-30 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、オレフィン類重合触媒およびオレフィン類重合体の製造方法 |
| WO2019155393A1 (en) * | 2018-02-07 | 2019-08-15 | Relianceindustries Limited | A ziegler-natta catalyst system with self-extinguishing properties suitable for olefin polymerization |
| CN116635432A (zh) * | 2020-12-21 | 2023-08-22 | 三井化学株式会社 | 固体状钛催化剂成分、烯烃聚合用催化剂、烯烃的聚合方法和丙烯聚合物 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5847402B2 (ja) * | 1976-02-13 | 1983-10-22 | 三井化学株式会社 | 成形用重合体組成物およびその製法 |
| GB2055388B (en) * | 1979-07-27 | 1983-02-23 | El Paso Polyolefins | Block copolymerization process and product |
| JPS5661415A (en) * | 1979-10-24 | 1981-05-26 | Mitsubishi Chem Ind Ltd | Preparation of propylene-ethylene block copolymer |
| US4284738A (en) * | 1980-08-11 | 1981-08-18 | El Paso Polyolefins Company | Ethylene-propylene block copolymerization process and product |
| JPS5883016A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | プロピレンブロツク共重合体の製法 |
| JPS58201806A (ja) * | 1982-05-19 | 1983-11-24 | Chisso Corp | 後加工シ−ト用および吹込成形用高溶融粘弾性ポリプロピレンとその製造法 |
| JPS58219207A (ja) * | 1982-06-15 | 1983-12-20 | Chisso Corp | 高剛性高溶融粘弾性ポリプロピレンとその製造法 |
| JPS59122506A (ja) * | 1982-12-28 | 1984-07-16 | Sumitomo Chem Co Ltd | 軟質プロピレン重合体 |
| US4866022A (en) * | 1984-03-23 | 1989-09-12 | Amoco Corporation | Olefin polymerization catalyst |
| US4612299A (en) * | 1984-07-09 | 1986-09-16 | Amoco Corporation | Magnesium carboxylate supports |
| US4829038A (en) * | 1986-06-17 | 1989-05-09 | Amoco Corporation | Alpha-olefin polymerization catalyst system including an advantageous modifier component |
| DE3640924A1 (de) * | 1986-11-29 | 1988-06-01 | Hoechst Ag | 1-olefin-stereoblockpolymer und verfahren zu seiner herstellung |
| CA2018829C (en) * | 1989-06-19 | 1996-06-11 | Jun Saito | Process for producing a high-stiffness polypropylene and a highly stereoregular polypropylene |
| US4990478A (en) * | 1989-09-21 | 1991-02-05 | Amoco Corporation | Silane-modified supported polyolefin catalyst to produce a broadened molecular weight distribution product |
-
1991
- 1991-11-18 US US07/793,821 patent/US5218052A/en not_active Expired - Lifetime
-
1992
- 1992-01-22 CA CA002059838A patent/CA2059838C/en not_active Expired - Lifetime
- 1992-01-31 KR KR1019920001519A patent/KR100263263B1/ko not_active Expired - Lifetime
- 1992-02-03 EP EP92300907A patent/EP0498603B1/en not_active Revoked
- 1992-02-03 JP JP4017667A patent/JPH05105722A/ja active Pending
- 1992-02-03 EP EP96109556A patent/EP0736552A3/en not_active Withdrawn
- 1992-02-03 DE DE69216117T patent/DE69216117T2/de not_active Revoked
- 1992-02-03 AT AT92300907T patent/ATE146806T1/de not_active IP Right Cessation
- 1992-02-04 SK SK307-92A patent/SK280948B6/sk not_active IP Right Cessation
- 1992-02-04 CZ CS1992307A patent/CZ287574B6/cs not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2059838A1 (en) | 1992-08-05 |
| KR100263263B1 (ko) | 2000-08-01 |
| EP0498603B1 (en) | 1996-12-27 |
| DE69216117T2 (de) | 1997-07-17 |
| CA2059838C (en) | 2002-05-28 |
| DE69216117D1 (de) | 1997-02-06 |
| JPH05105722A (ja) | 1993-04-27 |
| EP0498603A3 (en) | 1992-09-02 |
| EP0498603A2 (en) | 1992-08-12 |
| SK280948B6 (sk) | 2000-09-12 |
| EP0736552A3 (en) | 1997-03-26 |
| KR920016478A (ko) | 1992-09-24 |
| CZ287574B6 (cs) | 2000-12-13 |
| US5218052A (en) | 1993-06-08 |
| ATE146806T1 (de) | 1997-01-15 |
| EP0736552A2 (en) | 1996-10-09 |
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| Date | Code | Title | Description |
|---|---|---|---|
| PD00 | Pending as of 2000-06-30 in czech republic | ||
| MK4A | Patent expired |
Effective date: 20120204 |