CS331191A3 - Process for purifying acetic acid and/or acetanhydride - Google Patents

Process for purifying acetic acid and/or acetanhydride Download PDF

Info

Publication number: CS331191A3
Authority: CS; Czechoslovakia
Prior art keywords: acetic acid; resin; exchange resin; acetic anhydride; drying
Prior art date: 1990-10-31

Application number

CS913311A

Other languages

Czech (cs)

English (en)

Inventor

Michael David Jones

Original Assignee

British Petroleum Co Plc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-10-31

Filing date

1991-10-31

Publication date

1992-05-13

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10684615&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CS331191(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1991-10-31 Application filed by British Petroleum Co Plc filed Critical British Petroleum Co Plc

1992-05-13 Publication of CS331191A3 publication Critical patent/CS331191A3/cs

Links

WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 title claims abstract description 86
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract description 72
238000000034 method Methods 0.000 title claims abstract description 30
229920005989 resin Polymers 0.000 claims abstract description 47
239000011347 resin Substances 0.000 claims abstract description 47
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 27
238000001035 drying Methods 0.000 claims abstract description 19
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 9
239000003729 cation exchange resin Substances 0.000 claims abstract description 9
239000007788 liquid Substances 0.000 claims abstract description 9
150000004694 iodide salts Chemical class 0.000 claims abstract description 7
239000002253 acid Substances 0.000 claims abstract description 5
229910052709 silver Inorganic materials 0.000 claims description 13
239000004332 silver Substances 0.000 claims description 13
230000002378 acidificating effect Effects 0.000 claims description 6
239000007787 solid Substances 0.000 claims description 4
239000002994 raw material Substances 0.000 claims description 2
125000002091 cationic group Chemical group 0.000 claims 2
238000004132 cross linking Methods 0.000 abstract description 3
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 10
YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical compound COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 description 8
229920001429 chelating resin Polymers 0.000 description 7
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 7
230000000052 comparative effect Effects 0.000 description 5
239000012535 impurity Substances 0.000 description 5
229910001923 silver oxide Inorganic materials 0.000 description 5
239000000203 mixture Substances 0.000 description 4
150000001351 alkyl iodides Chemical class 0.000 description 3
239000012153 distilled water Substances 0.000 description 3
INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 3
ANOOTOPTCJRUPK-UHFFFAOYSA-N 1-iodohexane Chemical compound CCCCCCI ANOOTOPTCJRUPK-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
230000006315 carbonylation Effects 0.000 description 2
238000005810 carbonylation reaction Methods 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000007423 decrease Effects 0.000 description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
239000008188 pellet Substances 0.000 description 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
101100515513 Arabidopsis thaliana XI-E gene Proteins 0.000 description 1
238000004438 BET method Methods 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000003957 anion exchange resin Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000003947 neutron activation analysis Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/573—Separation; Purification; Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/12—Acetic anhydride

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Furan Compounds (AREA)
Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Nitrogen Condensed Heterocyclic Rings (AREA)

CS913311A 1990-10-31 1991-10-31 Process for purifying acetic acid and/or acetanhydride CS331191A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB909023634A GB9023634D0 (en)	1990-10-31	1990-10-31	Process for purifying acetic acid and/or acetic anhydride

Publications (1)

Publication Number	Publication Date
CS331191A3 true CS331191A3 (en)	1992-05-13

Family

ID=10684615

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS913311A CS331191A3 (en)	1990-10-31	1991-10-31	Process for purifying acetic acid and/or acetanhydride

Country Status (22)

Country	Link
US (1)	US5227524A (de)
EP (1)	EP0484020B1 (de)
JP (1)	JPH04282339A (de)
KR (1)	KR0162095B1 (de)
CN (1)	CN1033270C (de)
AT (1)	ATE132845T1 (de)
AU (1)	AU642779B2 (de)
BR (1)	BR9104743A (de)
CA (1)	CA2054025A1 (de)
CS (1)	CS331191A3 (de)
DE (1)	DE69116310T2 (de)
ES (1)	ES2082155T3 (de)
FI (1)	FI101471B (de)
GB (1)	GB9023634D0 (de)
HU (1)	HUT59652A (de)
IN (1)	IN184595B (de)
MX (1)	MX174344B (de)
MY (1)	MY108637A (de)
NO (1)	NO174924C (de)
RU (1)	RU2044721C1 (de)
YU (1)	YU47574B (de)
ZA (1)	ZA918390B (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9122168D0 (en) *	1991-10-18	1991-11-27	Bp Chem Int Ltd	Process
GB9211671D0 (en) *	1992-06-02	1992-07-15	Bp Chem Int Ltd	Process
EP0759022B1 (de) *	1994-05-13	2000-01-26	Acetex Chimie	Verfahren zur herstellung von carbonsäuren oder ihrer ester in gegenwart eines auf iridium basierten löslichen katalysators und löslicher jodide
FR2725983B1 (fr) *	1994-10-21	1996-12-20	Rhone Poulenc Chimie	Procede de preparation d'acides carboxyliques en presence d'un catalyseur a base d'iridium et d'iodures sous forme soluble
CA2234853C (en) *	1995-10-27	2005-01-11	Hoechst Celanese Corporation	Process for improving productivity of a carbonylation catalyst solution by removing corrosion metals
JP3281258B2 (ja) *	1996-04-26	2002-05-13	ダイセル化学工業株式会社	有機媒質中に含まれるヨウ素化合物を除去する際の運転方法
US5962735A (en)	1998-03-06	1999-10-05	Uop Llc	Method for treating an organic liquid contaminated with an iodide compound
US6506935B1 (en)	1998-03-06	2003-01-14	Uop Llc	Combination pretreatment/adsorption for treating a liquid stream contaminated with an iodine-containing compound
US6007724A (en) *	1998-12-21	1999-12-28	Uop Llc	Method for treating a liquid stream contaminated with an iodine-containing compound using a solid absorbent comprising a metal phthalocyanine
US6190562B1 (en)	1999-03-24	2001-02-20	Uop Llc	Method for treating a liquid stream contaminated with an iodine-containing compound using a cation-exchanged crystalline manganese phosphate
US6225498B1 (en) *	2000-03-24	2001-05-01	Celanese International Corporation	Method of removing organic iodides from organic media
US6657078B2 (en)	2001-02-07	2003-12-02	Celanese International Corporation	Low energy carbonylation process
JP4995522B2 (ja) *	2006-09-25	2012-08-08	千代田化工建設株式会社	有機酸からのヨウ素化合物除去方法
US7588690B1 (en) *	2009-02-10	2009-09-15	The Purolite Company	Method of iodide removal
US20110086929A1 (en) *	2009-10-13	2011-04-14	Brotech Corporation, doing business as The Purolite Company	Method of iodide removal
US8704010B2 (en)	2010-05-07	2014-04-22	Celanese International Corporation	Alcohol production process with impurity removal
US8394987B2 (en) *	2010-06-17	2013-03-12	Lyondell Chemical Technology, L.P.	Methyl iodide removal from acetic acid waste stream
BR112013016630B1 (pt)	2010-12-30	2022-03-03	Celanese International Corporation	Composição de resina de troca iônica, leito de proteção e processo para purificar uma composição de ácido acético bruto
WO2013070216A1 (en)	2011-11-09	2013-05-16	Celanese International Corporation	Integrated ethanol production from methanol via carbonylation and hydrogenation by extracting halides from acetic acid
US8975450B2 (en)	2013-03-15	2015-03-10	Celanese International Corporation	Ethanol and ethyl acetate production using an acetic acid and acetic anhydride mixed feed
CN106715379B (zh)	2014-10-02	2020-05-19	国际人造丝公司	用于生产乙酸的方法
MX2017009867A (es)	2015-01-30	2017-11-15	Celanese Int Corp	Procedimientos para producir acido acetico.
US9487464B2 (en)	2015-01-30	2016-11-08	Celanese International Corporation	Processes for producing acetic acid
US9561994B2 (en)	2015-01-30	2017-02-07	Celanese International Corporation	Processes for producing acetic acid
US9505696B2 (en)	2015-02-04	2016-11-29	Celanese International Corporation	Process to control HI concentration in residuum stream
US9908835B2 (en)	2015-11-13	2018-03-06	Celanese International Corporation	Processes for purifying acetic and hydrating anhydride

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1113570B (de) *	1957-04-20	1961-09-07	Bayer Ag	Verfahren zur Herstellung von Kationenaustauschern auf Basis von nicht sprosspolymerisierten vernetzten Polymerisaten
US4615806B1 (en) *	1985-03-07	1994-05-03	Hoechst Co American	Removal of iodide compounds from non-aqueous organic media

1990
- 1990-10-31 GB GB909023634A patent/GB9023634D0/en active Pending
1991
- 1991-10-18 DE DE69116310T patent/DE69116310T2/de not_active Revoked
- 1991-10-18 EP EP91309650A patent/EP0484020B1/de not_active Revoked
- 1991-10-18 AT AT91309650T patent/ATE132845T1/de not_active IP Right Cessation
- 1991-10-18 ES ES91309650T patent/ES2082155T3/es not_active Expired - Lifetime
- 1991-10-21 ZA ZA918390A patent/ZA918390B/xx unknown
- 1991-10-22 US US07/780,812 patent/US5227524A/en not_active Expired - Fee Related
- 1991-10-23 IN IN1012DE1991 patent/IN184595B/en unknown
- 1991-10-23 CA CA002054025A patent/CA2054025A1/en not_active Abandoned
- 1991-10-25 AU AU86772/91A patent/AU642779B2/en not_active Ceased
- 1991-10-28 YU YU171591A patent/YU47574B/sh unknown
- 1991-10-29 MY MYPI91002003A patent/MY108637A/en unknown
- 1991-10-30 JP JP3284363A patent/JPH04282339A/ja active Pending
- 1991-10-30 KR KR1019910019181A patent/KR0162095B1/ko not_active Expired - Fee Related
- 1991-10-30 HU HU913419A patent/HUT59652A/hu unknown
- 1991-10-30 RU SU915010063A patent/RU2044721C1/ru active
- 1991-10-30 NO NO914255A patent/NO174924C/no unknown
- 1991-10-31 BR BR919104743A patent/BR9104743A/pt not_active Application Discontinuation
- 1991-10-31 FI FI915145A patent/FI101471B/fi active
- 1991-10-31 MX MX9101867A patent/MX174344B/es not_active IP Right Cessation
- 1991-10-31 CS CS913311A patent/CS331191A3/cs unknown
- 1991-10-31 CN CN91111134A patent/CN1033270C/zh not_active Expired - Fee Related

Also Published As

Publication number	Publication date
KR0162095B1 (ko)	1999-01-15
NO914255L (no)	1992-05-04
US5227524A (en)	1993-07-13
NO914255D0 (no)	1991-10-30
FI915145L (fi)	1992-05-01
AU642779B2 (en)	1993-10-28
CN1062136A (zh)	1992-06-24
FI915145A0 (fi)	1991-10-31
ES2082155T3 (es)	1996-03-16
AU8677291A (en)	1992-05-07
JPH04282339A (ja)	1992-10-07
KR920007974A (ko)	1992-05-27
YU171591A (sh)	1994-04-05
NO174924C (no)	1994-08-03
HU913419D0 (en)	1992-01-28
IN184595B (de)	2000-09-09
CN1033270C (zh)	1996-11-13
HUT59652A (en)	1992-06-29
BR9104743A (pt)	1992-06-16
FI101471B1 (fi)	1998-06-30
MX174344B (es)	1994-05-09
CA2054025A1 (en)	1992-05-01
NO174924B (no)	1994-04-25
ZA918390B (en)	1993-04-21
EP0484020A3 (en)	1992-12-16
DE69116310D1 (de)	1996-02-22
MY108637A (en)	1996-10-31
RU2044721C1 (ru)	1995-09-27
YU47574B (sh)	1995-10-03
FI101471B (fi)	1998-06-30
EP0484020A2 (de)	1992-05-06
ATE132845T1 (de)	1996-01-15
GB9023634D0 (en)	1990-12-12
DE69116310T2 (de)	1996-05-23
EP0484020B1 (de)	1996-01-10

Publication	Publication Date	Title
CS331191A3 (en)	1992-05-13	Process for purifying acetic acid and/or acetanhydride
JP5507029B2 (ja)	2014-05-28	有機媒体から有機ヨウ化物を除去する方法
CN101516822B (zh)	2013-04-24	从有机酸除去碘化合物的方法
JPH0521031B2 (de)	1993-03-23
AU2001245941A2 (en)	2003-03-06	Method of removing organic iodides from organic media
AU2001245941A1 (en)	2001-12-20	Method of removing organic iodides from organic media
CN1039990C (zh)	1998-09-30	从羧酸和/或羧酸酐中除去碘化合物的方法
CN103298860B (zh)	2016-03-30	乙酸产物流的纯化
RU2214994C2 (ru)	2003-10-27	Заряженные ионообменные смолы, способы их получения и их применение
JP2004181351A (ja)	2004-07-02	非水液状物の精製方法
JPH0714488B2 (ja)	1995-02-22	カルボン酸からのハライドの除去
US6211408B1 (en)	2001-04-03	Method of removing iodides from non-aqueous organic media utilizing silver or mercury exchanged macroporous organofunctional polysiloxane resins
JPH10337484A (ja)	1998-12-22	イオン交換樹脂、その製造および使用
US3634497A (en)	1972-01-11	Acid reconstitution of spent alkaline wash solutions used in regenerating noble metal unsaturated ester synthesis catalysts
JP2004250619A (ja)	2004-09-09	触媒反応に用いる強酸性陽イオン交換樹脂
HK1184484B (en)	2017-06-30	Purification of acetic acid product streams
HK1051013A (en)	2003-07-18	Catalyst resins