CS334391A3 - Stabilized pesticide emulsion of the oil-in-water type - Google Patents

Stabilized pesticide emulsion of the oil-in-water type Download PDF

Info

Publication number: CS334391A3
Authority: CS; Czechoslovakia
Prior art keywords: emulsion; water; pesticidal; stabilized; oil
Prior art date: 1990-11-07

Application number

CS913343A

Other languages

Czech (cs)

English (en)

Inventor

Mohammad Dookhith

Hubert Linares

Original Assignee

Rhone Poulenc Agrochimie

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-11-07

Filing date

1991-11-05

Publication date

1992-05-13

1991-11-05 Application filed by Rhone Poulenc Agrochimie filed Critical Rhone Poulenc Agrochimie

1992-05-13 Publication of CS334391A3 publication Critical patent/CS334391A3/cs

Links

239000000839 emulsion Substances 0.000 title claims abstract description 191
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 80
239000000575 pesticide Substances 0.000 title claims description 63
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 104
230000000361 pesticidal effect Effects 0.000 claims abstract description 83
239000000126 substance Substances 0.000 claims abstract description 56
239000004408 titanium dioxide Substances 0.000 claims abstract description 35
239000007787 solid Substances 0.000 claims abstract description 24
239000004907 Macro-emulsion Substances 0.000 claims abstract description 21
239000002270 dispersing agent Substances 0.000 claims abstract description 21
239000004548 suspo-emulsion Substances 0.000 claims abstract description 17
230000001804 emulsifying effect Effects 0.000 claims abstract description 10
239000000203 mixture Substances 0.000 claims description 103
239000012071 phase Substances 0.000 claims description 69
239000003921 oil Substances 0.000 claims description 66
-1 ethoprofos Chemical compound 0.000 claims description 61
239000002245 particle Substances 0.000 claims description 38
239000008346 aqueous phase Substances 0.000 claims description 30
239000003795 chemical substances by application Substances 0.000 claims description 28
239000004094 surface-active agent Substances 0.000 claims description 27
239000003995 emulsifying agent Substances 0.000 claims description 26
230000008018 melting Effects 0.000 claims description 23
238000002844 melting Methods 0.000 claims description 23
239000000843 powder Substances 0.000 claims description 19
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical class OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 17
150000002148 esters Chemical class 0.000 claims description 16
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 15
239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 14
239000007764 o/w emulsion Substances 0.000 claims description 14
238000003860 storage Methods 0.000 claims description 13
230000002209 hydrophobic effect Effects 0.000 claims description 11
239000003381 stabilizer Substances 0.000 claims description 11
239000002562 thickening agent Substances 0.000 claims description 11
238000009826 distribution Methods 0.000 claims description 10
238000002360 preparation method Methods 0.000 claims description 10
239000000654 additive Substances 0.000 claims description 9
239000003960 organic solvent Substances 0.000 claims description 9
150000003839 salts Chemical class 0.000 claims description 9
239000002890 Aclonifen Substances 0.000 claims description 8
DDBMQDADIHOWIC-UHFFFAOYSA-N aclonifen Chemical compound C1=C([N+]([O-])=O)C(N)=C(Cl)C(OC=2C=CC=CC=2)=C1 DDBMQDADIHOWIC-UHFFFAOYSA-N 0.000 claims description 8
230000000087 stabilizing effect Effects 0.000 claims description 8
DQKWXTIYGWPGOO-UHFFFAOYSA-N (2,6-dibromo-4-cyanophenyl) octanoate Chemical compound CCCCCCCC(=O)OC1=C(Br)C=C(C#N)C=C1Br DQKWXTIYGWPGOO-UHFFFAOYSA-N 0.000 claims description 7
VJYIFXVZLXQVHO-UHFFFAOYSA-N chlorsulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)Cl)=N1 VJYIFXVZLXQVHO-UHFFFAOYSA-N 0.000 claims description 6
IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical class CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 claims description 5
XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 claims description 5
239000005573 Linuron Substances 0.000 claims description 5
239000005591 Pendimethalin Substances 0.000 claims description 5
MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 claims description 5
238000002156 mixing Methods 0.000 claims description 5
IUQJDHJVPLLKFL-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetate;dimethylazanium Chemical compound CNC.OC(=O)COC1=CC=C(Cl)C=C1Cl IUQJDHJVPLLKFL-UHFFFAOYSA-N 0.000 claims description 4
UWHURBUBIHUHSU-UHFFFAOYSA-N 2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 UWHURBUBIHUHSU-UHFFFAOYSA-N 0.000 claims description 4
CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical class N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 claims description 4
UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 claims description 4
239000005484 Bifenox Substances 0.000 claims description 4
SUSRORUBZHMPCO-UHFFFAOYSA-N MC-4379 Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC)=CC(OC=2C(=CC(Cl)=CC=2)Cl)=C1 SUSRORUBZHMPCO-UHFFFAOYSA-N 0.000 claims description 4
230000008859 change Effects 0.000 claims description 4
238000000227 grinding Methods 0.000 claims description 4
CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 claims description 4
BBPLSOGERZQYQC-UHFFFAOYSA-N 6-methylheptyl 2-(2,4-dichlorophenoxy)acetate Chemical compound CC(C)CCCCCOC(=O)COC1=CC=C(Cl)C=C1Cl BBPLSOGERZQYQC-UHFFFAOYSA-N 0.000 claims description 3
239000005496 Chlorsulfuron Substances 0.000 claims description 3
CHNUNORXWHYHNE-UHFFFAOYSA-N Oxadiazon Chemical compound C1=C(Cl)C(OC(C)C)=CC(N2C(OC(=N2)C(C)(C)C)=O)=C1Cl CHNUNORXWHYHNE-UHFFFAOYSA-N 0.000 claims description 3
XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 3
239000007798 antifreeze agent Substances 0.000 claims description 3
239000005489 Bromoxynil Substances 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 claims description 2
230000035515 penetration Effects 0.000 claims description 2
IOUNQDKNJZEDEP-UHFFFAOYSA-N phosalone Chemical compound C1=C(Cl)C=C2OC(=O)N(CSP(=S)(OCC)OCC)C2=C1 IOUNQDKNJZEDEP-UHFFFAOYSA-N 0.000 claims description 2
230000005945 translocation Effects 0.000 claims description 2
239000000080 wetting agent Substances 0.000 claims description 2
UMPSXRYVXUPCOS-UHFFFAOYSA-N 2,3-dichlorophenol Chemical class OC1=CC=CC(Cl)=C1Cl UMPSXRYVXUPCOS-UHFFFAOYSA-N 0.000 claims 1
239000006260 foam Substances 0.000 claims 1
239000004480 active ingredient Substances 0.000 abstract description 17
238000003801 milling Methods 0.000 abstract description 2
235000019198 oils Nutrition 0.000 description 56
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 44
239000002904 solvent Substances 0.000 description 23
239000007788 liquid Substances 0.000 description 20
235000013772 propylene glycol Nutrition 0.000 description 16
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 15
239000005562 Glyphosate Substances 0.000 description 15
150000001875 compounds Chemical class 0.000 description 15
229940097068 glyphosate Drugs 0.000 description 15
239000002253 acid Substances 0.000 description 12
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
239000000047 product Substances 0.000 description 8
238000004581 coalescence Methods 0.000 description 7
238000000034 method Methods 0.000 description 7
125000004343 1-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C([H])([H])[H] 0.000 description 6
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
229920001222 biopolymer Polymers 0.000 description 6
MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
239000013543 active substance Substances 0.000 description 5
238000005516 engineering process Methods 0.000 description 5
OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 4
125000003762 3,4-dimethoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C(OC([H])([H])[H])C([H])=C1* 0.000 description 4
ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 4
ADTJISSNQWNGFP-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid;propan-2-amine Chemical compound CC(C)N.CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 ADTJISSNQWNGFP-UHFFFAOYSA-N 0.000 description 4
MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical class OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 4
241000350481 Pterogyne nitens Species 0.000 description 4
229910010413 TiO 2 Inorganic materials 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
125000002947 alkylene group Chemical group 0.000 description 4
239000007859 condensation product Substances 0.000 description 4
230000005496 eutectics Effects 0.000 description 4
238000009472 formulation Methods 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
239000004530 micro-emulsion Substances 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
229920000847 nonoxynol Polymers 0.000 description 4
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 4
IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 4
150000002989 phenols Chemical class 0.000 description 4
239000007921 spray Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
239000007762 w/o emulsion Substances 0.000 description 4
238000009736 wetting Methods 0.000 description 4
KNGWEAQJZJKFLI-UHFFFAOYSA-N 2,2-dimethyl-4h-1,3-benzodioxine-6-carbaldehyde Chemical compound O=CC1=CC=C2OC(C)(C)OCC2=C1 KNGWEAQJZJKFLI-UHFFFAOYSA-N 0.000 description 3
YIVXMZJTEQBPQO-UHFFFAOYSA-N 2,4-DB Chemical class OC(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-N 0.000 description 3
CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical class N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 description 3
LLWADFLAOKUBDR-UHFFFAOYSA-N 2-methyl-4-chlorophenoxybutyric acid Chemical compound CC1=CC(Cl)=CC=C1OCCCC(O)=O LLWADFLAOKUBDR-UHFFFAOYSA-N 0.000 description 3
HSSBORCLYSCBJR-UHFFFAOYSA-N Chloramben Chemical compound NC1=CC(Cl)=CC(C(O)=O)=C1Cl HSSBORCLYSCBJR-UHFFFAOYSA-N 0.000 description 3
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VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
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125000004432 carbon atom Chemical group C* 0.000 description 3
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RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 3
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BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
MGLWZSOBALDPEK-UHFFFAOYSA-N simetryn Chemical compound CCNC1=NC(NCC)=NC(SC)=N1 MGLWZSOBALDPEK-UHFFFAOYSA-N 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000002639 sodium chloride Nutrition 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
239000011775 sodium fluoride Substances 0.000 description 1
235000013024 sodium fluoride Nutrition 0.000 description 1
JGFYQVQAXANWJU-UHFFFAOYSA-M sodium fluoroacetate Chemical compound [Na+].[O-]C(=O)CF JGFYQVQAXANWJU-UHFFFAOYSA-M 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000007962 solid dispersion Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
125000005504 styryl group Chemical group 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 description 1
CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 description 1
IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
229960005199 tetramethrin Drugs 0.000 description 1
239000004308 thiabendazole Substances 0.000 description 1
WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
235000010296 thiabendazole Nutrition 0.000 description 1
229960004546 thiabendazole Drugs 0.000 description 1
230000008719 thickening Effects 0.000 description 1
DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
229960002447 thiram Drugs 0.000 description 1
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1
WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical class [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/02—Organic and inorganic agents containing, except water

Landscapes

Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Toxicology (AREA)
Dentistry (AREA)
Dispersion Chemistry (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Agronomy & Crop Science (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Colloid Chemistry (AREA)
Edible Oils And Fats (AREA)
Paints Or Removers (AREA)
Lubricants (AREA)

CS913343A 1990-11-07 1991-11-05 Stabilized pesticide emulsion of the oil-in-water type CS334391A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/610,392 US5206021A (en)	1988-05-09	1990-11-07	Stabilized oil-in-water emulsions or suspoemulsions containing pesticidal substances in both oil and water phases

Publications (1)

Publication Number	Publication Date
CS334391A3 true CS334391A3 (en)	1992-05-13

Family

ID=24444837

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS913343A CS334391A3 (en)	1990-11-07	1991-11-05	Stabilized pesticide emulsion of the oil-in-water type

Country Status (29)

Country	Link
US (1)	US5206021A (fr)
EP (1)	EP0485207B1 (fr)
JP (1)	JPH04288002A (fr)
KR (1)	KR920009290A (fr)
CN (1)	CN1061132A (fr)
AT (1)	ATE153499T1 (fr)
AU (1)	AU659616B2 (fr)
BG (1)	BG95426A (fr)
BR (1)	BR9104981A (fr)
CA (1)	CA2055133A1 (fr)
CS (1)	CS334391A3 (fr)
DE (1)	DE69126275T2 (fr)
DK (1)	DK0485207T3 (fr)
ES (1)	ES2104674T3 (fr)
FI (1)	FI915243A7 (fr)
GR (1)	GR3024545T3 (fr)
HU (1)	HUT60099A (fr)
IE (1)	IE913877A1 (fr)
IL (1)	IL99951A0 (fr)
MA (1)	MA22336A1 (fr)
MY (1)	MY129943A (fr)
NZ (1)	NZ240456A (fr)
OA (1)	OA09748A (fr)
PL (1)	PL292296A1 (fr)
PT (1)	PT99441B (fr)
TR (1)	TR25517A (fr)
YU (1)	YU176691A (fr)
ZA (1)	ZA918807B (fr)
ZW (1)	ZW15491A1 (fr)

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DE2205590A1 (de) *	1972-02-07	1973-08-16	Hoechst Ag	Verdunstungshemmendes zusatzmittel fuer konzentrierte pflanzenschutzmitteldispersionen
US3948636A (en) *	1972-11-09	1976-04-06	Diamond Shamrock Corporation	Flowable aqueous composition of water-insoluble pesticide
US4188202A (en) *	1975-11-12	1980-02-12	Fisons Limited	Composition
GB2022418B (en) *	1978-05-31	1982-04-07	Ici Ltd	Agrochemical formulations
US4313847A (en) *	1978-06-15	1982-02-02	Ici Americas Inc.	Surfactant compositions
DE3033335A1 (de) *	1980-09-04	1982-04-22	Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München	Verfahren zur herstellung einer lagerstabilen, konzentrierten emulsion von herbizid wirkenden phenoxyalkancarbonsaeureestern
US4372943A (en) *	1981-01-26	1983-02-08	Zoecon Corporation	Novel pesticidal formulation
US4411692A (en) *	1981-03-26	1983-10-25	Monsanto Company	Flowable herbicides
US4440562A (en) *	1981-07-20	1984-04-03	Monsanto Company	Herbicidal emulsions
FR2510870A1 (fr) *	1981-08-10	1983-02-11	Rhone Poulenc Agrochimie	Suspensions aqueuses concentrees a base de neburon
CA1198369A (fr) *	1982-01-15	1985-12-24	Leonard Mackles	Suspensions de liquide huileux et de liquide polaire, et leur preparation
HU191184B (en) *	1982-07-09	1987-01-28	Chinoin Gyogyszer Es Vegyeszeti Termekek Gyara Rt,Hu	Stabilized herbicide suspension
DE3302648A1 (de) *	1983-01-27	1984-08-02	Hoechst Ag, 6230 Frankfurt	Pflanzenschutzmittel in form von mischdispersionen
DE3614788A1 (de) *	1986-05-02	1987-11-05	Hoechst Ag	Herbizide emulsionen
US4818536A (en) *	1986-06-05	1989-04-04	The Dow Chemical Company	Emulsfiable polymer concentrate controlled delivery and release system
US4828835A (en) *	1986-06-05	1989-05-09	The Dow Chemical Company	Emulsifiable polymer concentrate
GB8614647D0 (en) *	1986-06-16	1986-07-23	Sandoz Ltd	Oil in water emulsion
US4810279A (en) *	1987-01-27	1989-03-07	American Cyanamid Company	Herbicidal oil in water combination compositions of pendimethalin
US4822405A (en) *	1987-01-27	1989-04-18	American Cyanamid Company	Herbicidal oil in water combination compositions of imidazolinone herbicides
US4851217A (en) *	1987-05-05	1989-07-25	Basf Corporation	All aqueous formulations of organo-phosphorous pesticides
FR2630885B1 (fr) *	1988-05-09	1991-03-01	Rhone Poulenc Agrochimie	Emulsion pesticide huile dans l'eau, procede de mise en oeuvre

1990
- 1990-11-07 US US07/610,392 patent/US5206021A/en not_active Expired - Fee Related
1991
- 1991-11-04 NZ NZ240456A patent/NZ240456A/en unknown
- 1991-11-04 IL IL99951A patent/IL99951A0/xx unknown
- 1991-11-05 CS CS913343A patent/CS334391A3/cs unknown
- 1991-11-05 BG BG095426A patent/BG95426A/bg unknown
- 1991-11-05 MA MA22618A patent/MA22336A1/fr unknown
- 1991-11-06 EP EP91310294A patent/EP0485207B1/fr not_active Expired - Lifetime
- 1991-11-06 ZA ZA918807A patent/ZA918807B/xx unknown
- 1991-11-06 AT AT91310294T patent/ATE153499T1/de active
- 1991-11-06 FI FI915243A patent/FI915243A7/fi not_active Application Discontinuation
- 1991-11-06 ZW ZW154/91A patent/ZW15491A1/xx unknown
- 1991-11-06 PT PT99441A patent/PT99441B/pt not_active IP Right Cessation
- 1991-11-06 DE DE69126275T patent/DE69126275T2/de not_active Expired - Fee Related
- 1991-11-06 DK DK91310294.3T patent/DK0485207T3/da active
- 1991-11-06 YU YU176691A patent/YU176691A/sh unknown
- 1991-11-06 IE IE387791A patent/IE913877A1/en not_active Application Discontinuation
- 1991-11-06 AU AU87022/91A patent/AU659616B2/en not_active Ceased
- 1991-11-06 ES ES91310294T patent/ES2104674T3/es not_active Expired - Lifetime
- 1991-11-06 PL PL29229691A patent/PL292296A1/xx unknown
- 1991-11-07 KR KR1019910019736A patent/KR920009290A/ko not_active Ceased
- 1991-11-07 CA CA002055133A patent/CA2055133A1/fr not_active Abandoned
- 1991-11-07 TR TR91/1084A patent/TR25517A/xx unknown
- 1991-11-07 BR BR919104981A patent/BR9104981A/pt not_active Application Discontinuation
- 1991-11-07 HU HU913506A patent/HUT60099A/hu unknown
- 1991-11-07 JP JP3291757A patent/JPH04288002A/ja active Pending
- 1991-11-07 MY MYPI91002061A patent/MY129943A/en unknown
- 1991-11-07 OA OA60093A patent/OA09748A/fr unknown
- 1991-11-07 CN CN91110728A patent/CN1061132A/zh active Pending
1997
- 1997-08-26 GR GR970402185T patent/GR3024545T3/el unknown

Also Published As

Publication number	Publication date
PT99441B (pt)	1999-04-30
CN1061132A (zh)	1992-05-20
PT99441A (pt)	1992-09-30
OA09748A (fr)	1993-11-30
FI915243L (fi)	1992-05-08
AU659616B2 (en)	1995-05-25
HU913506D0 (en)	1992-01-28
DK0485207T3 (da)	1997-12-22
GR3024545T3 (en)	1997-12-31
YU176691A (sh)	1994-01-20
ATE153499T1 (de)	1997-06-15
EP0485207A1 (fr)	1992-05-13
ZW15491A1 (en)	1992-05-20
ZA918807B (en)	1992-09-30
BG95426A (bg)	1993-12-24
DE69126275T2 (de)	1998-01-15
PL292296A1 (en)	1992-07-27
CA2055133A1 (fr)	1992-05-08
IE913877A1 (en)	1992-05-20
JPH04288002A (ja)	1992-10-13
TR25517A (tr)	1993-05-01
KR920009290A (ko)	1992-06-25
EP0485207B1 (fr)	1997-05-28
US5206021A (en)	1993-04-27
MA22336A1 (fr)	1992-07-01
IL99951A0 (en)	1992-08-18
DE69126275D1 (de)	1997-07-03
AU8702291A (en)	1992-05-14
HUT60099A (en)	1992-08-28
BR9104981A (pt)	1992-06-23
ES2104674T3 (es)	1997-10-16
NZ240456A (en)	1993-10-26
MY129943A (en)	2007-05-31
FI915243A7 (fi)	1992-05-08
FI915243A0 (fi)	1991-11-06

Publication	Publication Date	Title
CS334391A3 (en)	1992-05-13	Stabilized pesticide emulsion of the oil-in-water type
US5096711A (en)	1992-03-17	Titanium dioxide stabilized oil in water pesticidal emulsion
DE3875251T2 (de)	1993-02-25	Agrochemische zusammensetzungen auf basis von latex.
EP2334172B1 (fr)	2015-01-21	Compositions d'huile agrochimique comportant des adjuvants alkylpolysiloxanes à haute teneur en silice
US6077522A (en)	2000-06-20	Microcapsules containing suspensions of biologically active compounds and ultraviolet protectant
AU736800B2 (en)	2001-08-02	Microemulsion and method
DE69219373T2 (de)	1997-09-25	Biozide und agrochemische Suspensionen
US5834006A (en)	1998-11-10	Latex-based agricultural compositions
CN1290126A (zh)	2001-04-04	农药组合物
HU215709B (hu)	1999-02-01	Biocid és agrokémiai szuszpenziók
CA2399748C (fr)	2012-02-07	Modification morphologique d'agents actifs agricoles par des amidons dispersables dans l'eau
SK17432002A3 (sk)	2003-07-01	Kvapalná suspenzia mikrokapsúl a postup na jej výrobu
US20010008873A1 (en)	2001-07-19	Inhibiting phase separation in low viscosity water-based pesticide suspensions
JPS601101A (ja)	1985-01-07	水性懸濁農薬製剤
US5254344A (en)	1993-10-19	Oil-in-water pesticidal emulsion, process for application
AU665060B2 (en)	1995-12-14	Antifoams for solid crop protection agents
Winkle	2018	Suspoemulsion Technology and Trends
JPH08277201A (ja)	1996-10-22	改良された農薬製剤
US5679618A (en)	1997-10-21	Antifoams for solid crop protection agents
Winkle	1996	Suspoemulsion Technology