CZ87393A3 - Light-type agents for dish washing, which contain alkyl-ethoxy-carboxylate surface-active agent and calcium or magnesium ions - Google Patents

Light-type agents for dish washing, which contain alkyl-ethoxy-carboxylate surface-active agent and calcium or magnesium ions Download PDF

Info

Publication number: CZ87393A3
Authority: CZ; Czechia
Prior art keywords: alkyl; calcium; carbon atoms; compositions; composition
Prior art date: 1990-11-16

Application number

CS93873A

Other languages

Czech (cs)

English (en)

Inventor

Thomas Anthony Cripe

Kofi Ofosu-Asante

Original Assignee

Procter & Gamble

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-11-16

Filing date

1991-11-08

Publication date

1994-07-13

1991-11-08 Application filed by Procter & Gamble filed Critical Procter & Gamble

1994-07-13 Publication of CZ87393A3 publication Critical patent/CZ87393A3/cs

Links

239000004094 surface-active agent Substances 0.000 title claims abstract description 65
229910001425 magnesium ion Inorganic materials 0.000 title claims abstract description 35
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 34
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 title claims abstract description 34
239000011575 calcium Substances 0.000 title claims abstract description 34
229910001424 calcium ion Inorganic materials 0.000 title claims abstract description 32
238000004851 dishwashing Methods 0.000 title claims abstract description 17
239000003795 chemical substances by application Substances 0.000 title claims description 11
239000000203 mixture Substances 0.000 claims abstract description 227
-1 alkyl ethoxy carboxylate Chemical compound 0.000 claims abstract description 79
239000002738 chelating agent Substances 0.000 claims abstract description 36
239000007788 liquid Substances 0.000 claims abstract description 27
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 20
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 19
239000011777 magnesium Substances 0.000 claims abstract description 19
229910052749 magnesium Inorganic materials 0.000 claims abstract description 19
239000002244 precipitate Substances 0.000 claims abstract description 19
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims abstract description 15
230000015572 biosynthetic process Effects 0.000 claims abstract description 12
229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 10
239000003599 detergent Substances 0.000 claims abstract description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 88
125000000217 alkyl group Chemical group 0.000 claims description 68
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 52
235000014113 dietary fatty acids Nutrition 0.000 claims description 24
239000000194 fatty acid Substances 0.000 claims description 24
229930195729 fatty acid Natural products 0.000 claims description 24
150000004665 fatty acids Chemical class 0.000 claims description 18
229910052791 calcium Inorganic materials 0.000 claims description 17
150000001768 cations Chemical class 0.000 claims description 16
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 11
239000000872 buffer Substances 0.000 claims description 11
239000007864 aqueous solution Substances 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 9
239000000344 soap Substances 0.000 claims description 9
238000009826 distribution Methods 0.000 claims description 8
150000001412 amines Chemical class 0.000 claims description 7
239000006260 foam Substances 0.000 claims description 7
239000000463 material Substances 0.000 claims description 7
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 claims description 5
239000007998 bicine buffer Substances 0.000 claims description 5
150000008051 alkyl sulfates Chemical class 0.000 claims description 4
125000004429 atom Chemical group 0.000 claims description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical group OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
UYBWIEGTWASWSR-UHFFFAOYSA-N 1,3-diaminopropan-2-ol Chemical compound NCC(O)CN UYBWIEGTWASWSR-UHFFFAOYSA-N 0.000 claims description 3
229910052757 nitrogen Inorganic materials 0.000 claims description 3
239000003381 stabilizer Substances 0.000 claims description 3
150000003871 sulfonates Chemical class 0.000 claims description 3
PFARUPKOWSCVRX-UHFFFAOYSA-N 2-[carboxymethyl(2,3-dihydroxypropyl)amino]acetic acid Chemical class OCC(O)CN(CC(O)=O)CC(O)=O PFARUPKOWSCVRX-UHFFFAOYSA-N 0.000 claims description 2
JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 claims description 2
239000003093 cationic surfactant Substances 0.000 claims description 2
239000012188 paraffin wax Substances 0.000 claims description 2
FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims 2
108010077895 Sarcosine Proteins 0.000 claims 1
ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 claims 1
229940043230 sarcosine Drugs 0.000 claims 1
239000004519 grease Substances 0.000 abstract description 23
238000003860 storage Methods 0.000 abstract description 18
239000006172 buffering agent Substances 0.000 abstract description 5
239000003715 calcium chelating agent Substances 0.000 abstract description 2
235000010216 calcium carbonate Nutrition 0.000 abstract 1
235000019441 ethanol Nutrition 0.000 description 52
229960005069 calcium Drugs 0.000 description 28
238000009472 formulation Methods 0.000 description 25
238000000034 method Methods 0.000 description 19
239000000047 product Substances 0.000 description 18
150000002500 ions Chemical class 0.000 description 16
229940091250 magnesium supplement Drugs 0.000 description 16
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
150000001298 alcohols Chemical class 0.000 description 14
239000011734 sodium Substances 0.000 description 14
239000000243 solution Substances 0.000 description 14
239000003054 catalyst Substances 0.000 description 13
229910052708 sodium Inorganic materials 0.000 description 12
235000002639 sodium chloride Nutrition 0.000 description 12
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 10
230000008569 process Effects 0.000 description 10
150000007942 carboxylates Chemical class 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
150000001875 compounds Chemical class 0.000 description 9
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 9
239000000347 magnesium hydroxide Substances 0.000 description 9
229910001862 magnesium hydroxide Inorganic materials 0.000 description 9
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 8
229910052784 alkaline earth metal Inorganic materials 0.000 description 7
239000002585 base Substances 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
150000001336 alkenes Chemical class 0.000 description 6
230000008901 benefit Effects 0.000 description 6
239000006227 byproduct Substances 0.000 description 6
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 6
239000007858 starting material Substances 0.000 description 6
229910021653 sulphate ion Inorganic materials 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
239000004471 Glycine Substances 0.000 description 5
150000001408 amides Chemical class 0.000 description 5
239000003945 anionic surfactant Substances 0.000 description 5
229960003237 betaine Drugs 0.000 description 5
229940106681 chloroacetic acid Drugs 0.000 description 5
150000002191 fatty alcohols Chemical class 0.000 description 5
150000002194 fatty esters Chemical class 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
235000000346 sugar Nutrition 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
230000009471 action Effects 0.000 description 4
239000012190 activator Substances 0.000 description 4
LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 4
229940052299 calcium chloride dihydrate Drugs 0.000 description 4
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 4
239000000920 calcium hydroxide Substances 0.000 description 4
229910001861 calcium hydroxide Inorganic materials 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
239000002304 perfume Substances 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000080 wetting agent Substances 0.000 description 4
IOAOAKDONABGPZ-UHFFFAOYSA-N 2-amino-2-ethylpropane-1,3-diol Chemical compound CCC(N)(CO)CO IOAOAKDONABGPZ-UHFFFAOYSA-N 0.000 description 3
235000013162 Cocos nucifera Nutrition 0.000 description 3
244000060011 Cocos nucifera Species 0.000 description 3
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
239000007983 Tris buffer Substances 0.000 description 3
240000008042 Zea mays Species 0.000 description 3
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
235000002017 Zea mays subsp mays Nutrition 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
125000002252 acyl group Chemical group 0.000 description 3
125000003342 alkenyl group Chemical group 0.000 description 3
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
235000005822 corn Nutrition 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
230000000694 effects Effects 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
150000002430 hydrocarbons Chemical group 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
230000003993 interaction Effects 0.000 description 3
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 3
239000012071 phase Substances 0.000 description 3
230000005501 phase interface Effects 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
239000008234 soft water Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000006188 syrup Substances 0.000 description 3
235000020357 syrup Nutrition 0.000 description 3
229910052725 zinc Inorganic materials 0.000 description 3
239000011701 zinc Substances 0.000 description 3
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
238000012935 Averaging Methods 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
SEQKRHFRPICQDD-UHFFFAOYSA-N N-tris(hydroxymethyl)methylglycine Chemical compound OCC(CO)(CO)[NH2+]CC([O-])=O SEQKRHFRPICQDD-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
150000001242 acetic acid derivatives Chemical class 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
239000003513 alkali Substances 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
238000007046 ethoxylation reaction Methods 0.000 description 2
238000005187 foaming Methods 0.000 description 2
239000008103 glucose Substances 0.000 description 2
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
125000001165 hydrophobic group Chemical group 0.000 description 2
229910010272 inorganic material Inorganic materials 0.000 description 2
238000003780 insertion Methods 0.000 description 2
230000037431 insertion Effects 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
229940050906 magnesium chloride hexahydrate Drugs 0.000 description 2
DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
239000003921 oil Substances 0.000 description 2
235000019198 oils Nutrition 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
238000010979 pH adjustment Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000002243 precursor Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
150000003141 primary amines Chemical class 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000006268 reductive amination reaction Methods 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
150000008163 sugars Chemical class 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
239000003760 tallow Substances 0.000 description 2
HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
150000003626 triacylglycerols Chemical class 0.000 description 2
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HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
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230000001737 promoting effect Effects 0.000 description 1
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HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
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UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
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TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Dispersion Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

CS93873A 1990-11-16 1991-11-08 Light-type agents for dish washing, which contain alkyl-ethoxy-carboxylate surface-active agent and calcium or magnesium ions CZ87393A3 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US61453290A	1990-11-16	1990-11-16
US61453190A	1990-11-16	1990-11-16
PCT/US1991/008280 WO1992008777A1 (en)	1990-11-16	1991-11-08	Light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and calcium or magnesium ions

Publications (1)

Publication Number	Publication Date
CZ87393A3 true CZ87393A3 (en)	1994-07-13

Family

ID=27087270

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS93873A CZ87393A3 (en)	1990-11-16	1991-11-08	Light-type agents for dish washing, which contain alkyl-ethoxy-carboxylate surface-active agent and calcium or magnesium ions

Country Status (22)

Country	Link
EP (1)	EP0557426B1 (de)
JP (1)	JP3009464B2 (de)
CN (1)	CN1062371A (de)
AR (1)	AR244795A1 (de)
AT (1)	ATE149561T1 (de)
AU (1)	AU9063991A (de)
BR (1)	BR9106983A (de)
CZ (1)	CZ87393A3 (de)
DE (1)	DE69125022T2 (de)
DK (1)	DK0557426T3 (de)
ES (1)	ES2101078T3 (de)
FI (1)	FI932199A0 (de)
GR (1)	GR3023502T3 (de)
HU (1)	HUT64782A (de)
MA (1)	MA22342A1 (de)
MX (1)	MX9102078A (de)
MY (1)	MY131210A (de)
NO (1)	NO931738L (de)
PT (2)	PT99527A (de)
SK (1)	SK48093A3 (de)
TR (1)	TR26532A (de)
WO (1)	WO1992008777A1 (de)

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JPH06510326A (ja) *	1991-09-06	1994-11-17	ザ、プロクター、エンド、ギャンブル、カンパニー	カルシウム及びポリヒドロキシ脂肪酸アミド（ｐｆａ）を含む洗剤組成物
US5298195A (en) *	1992-03-09	1994-03-29	Amway Corporation	Liquid dishwashing detergent
NL9201339A (nl) *	1992-07-24	1994-02-16	Chem Y Gmbh	Vloeibare geconcentreerde oplossingen van alkylethercarbonzuurzouten in water.
US5269974A (en) *	1992-09-01	1993-12-14	The Procter & Gamble Company	Liquid or gel dishwashing detergent composition containing alkyl amphocarboxylic acid and magnesium or calcium ions
CA2143328A1 (en) *	1992-09-01	1994-03-17	Kofi Ofosu-Asante	Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate, divalent ions and alkylpolyethoxypolycarboxylate
CZ53895A3 (en) *	1992-09-01	1995-11-15	Procter & Gamble	Liquid or jellylike detergents containing calcium and agents for their stabilization
US5545354A (en) *	1992-09-01	1996-08-13	The Procter & Gamble Company	Liquid or gel dishwashing detergent containing a polyhydroxy fatty acid amide, calcium ions and an alkylpolyethoxypolycarboxylate
CA2148099A1 (en) *	1992-11-30	1994-06-09	Yi-Chang Fu	Detergent compositions with calcium ions and polyhydroxy fatty acid amide nonionic/selected anionic/soap surfactant mixture
US5415801A (en) *	1993-08-27	1995-05-16	The Procter & Gamble Company	Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar
US5474710A (en) *	1993-08-27	1995-12-12	Ofosu-Asanta; Kofi	Process for preparing concentrated surfactant mixtures containing magnesium
US5415814A (en) *	1993-08-27	1995-05-16	The Procter & Gamble Company	Concentrated liquid or gel light duty dishwashing detergent composition containing calcium xylene sulfonate
US5417893A (en) *	1993-08-27	1995-05-23	The Procter & Gamble Company	Concentrated liquid or gel light duty dishwashing detergent compositions containing calcium ions and disulfonate surfactants
RU2142981C1 (ru) *	1993-09-14	1999-12-20	Дзе Проктер Энд Гэмбл Компани	Удобная в эксплуатации жидкая или гелевая моющая композиция для мытья посуды и удобная в эксплуатации жидкая моющая композиция для мытья посуды
DE69434635D1 (en)	1993-10-08	2006-04-27	Novo Nordisk As	Amylasevarianten
DE19581539B4 (de)	1994-02-23	2009-09-17	Ecolab Inc., St. Paul	Alkalische Reiniger auf der Basis von Alkohol-Ethoxy-Carboxylaten
CA2147674C (en) *	1994-05-16	1999-03-30	David Robert Zint	Shaped semi-solid or solid dishwashing detergent
ZA955295B (en) *	1994-06-27	1996-02-13	Diversey Corp	Non-silicated soft metal safe product
US7404967B2 (en)	1994-12-21	2008-07-29	Cosmederm, Inc.	Topical product formulations containing strontium for reducing skin irritation
US5958436A (en) *	1995-12-21	1999-09-28	Cosmederm Technologies	Formulations and methods for reducing skin irritation
EP0946702A1 (de)	1996-12-20	1999-10-06	The Procter & Gamble Company	Geschirrspülmittel mit einem gehalt an alkanolamin
AR017745A1 (es)	1999-02-08	2001-09-12	Procter & Gamble	Composiciones detergentes para lavar vajilla, que contienen diaminas organicas y magnesio, para una mejor limpieza con aguas blandas.
JP4509292B2 (ja) *	2000-04-04	2010-07-21	ライオン株式会社	界面活性剤組成物
BRPI0808513A2 (pt)	2007-03-09	2014-08-19	Danisco Us Inc Genencor Div	Variantes de alfa-amilase de espécies de bacillus alcalifílico, composições compreendendo variantes de alfa-amilase e métodos de uso
MX364987B (es)	2008-06-06	2019-05-17	Danisco Us Inc	Alfa-amilasas variantes de bacillus subtilis y metodos de uso de las mismas.
BRPI0913378A2 (pt)	2008-06-06	2015-09-01	Danisco Us Inc	Produção de glicose a partir do amido usando alfa-amilase do bacillus subtilis
CA2726631A1 (en)	2008-06-06	2009-12-10	Danisco Us Inc.	Saccharification enzyme composition and method of saccharification thereof
ES2412684T3 (es)	2009-06-19	2013-07-12	The Procter & Gamble Company	Composición detergente de lavado de vajillas a mano líquida
EP2264138B2 (de) *	2009-06-19	2023-03-08	The Procter & Gamble Company	Flüssige Handspülmittelzusammensetzung
CA2778471A1 (en)	2009-10-23	2011-04-28	Danisco Us Inc.	Methods for reducing blue saccharide
SE1250261A1 (sv) *	2011-10-31	2013-05-01	Billerudkorsnaes Gaevle Froevi Ab	Bestrykningskomposition, ett förfarande för bestrykning av ett substrat, ettbestruket substrat, ett förpackningsmaterial och vätskeförpackning
US9096818B2 (en) *	2011-12-09	2015-08-04	Clariant International Ltd.	Automatic dishwashing detergent compositions comprising ethercarboxylic acids or their salts and nonionic surfactants with a high cloud point
MX378676B (es)	2012-12-07	2025-03-11	Colgate Palmolive Co	Composicion de limpieza.
RU2708734C2 (ru) *	2014-11-18	2019-12-11	Басф Се	Способ добычи нефти
MX386537B (es)	2015-01-15	2025-03-19	Ecolab Usa Inc	Espuma de limpieza de larga duración.
CN109126622A (zh) *	2017-06-27	2019-01-04	华南师范大学	一种阴离子表面活性剂、洗涤剂和洗涤剂组合物
JP2020090606A (ja) *	2018-12-05	2020-06-11	株式会社コープクリーン	洗浄剤組成物
JP2022088135A (ja) *	2020-12-02	2022-06-14	ライオン株式会社	食器用洗浄剤
EP4563681A1 (de) *	2023-11-29	2025-06-04	Clariant International Ltd	Mischung aus biobasierten fettalkoholalkoxylaten

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FR2014084A1 (de) *	1968-07-31	1970-04-10	Hoechst Ag
US4098818A (en) *	1976-12-10	1978-07-04	The Procter & Gamble Company	Process for making carboxyalkylated alkyl polyether surfactants with narrow polyethoxy chain distribution
DE2754210A1 (de) *	1976-12-10	1978-06-15	Procter & Gamble	Oberflaechenaktives mittel auf basis von carboxyalkylierten alkylpolyethern
DE3370164D1 (en) *	1982-10-28	1987-04-16	Procter & Gamble	Liquid detergent compositions
DE3905938A1 (de) *	1989-02-25	1990-08-30	Huels Chemische Werke Ag	Detergentienzusammensetzungen mit erhoehter viskositaet
ATE156514T1 (de) *	1989-05-22	1997-08-15	Procter & Gamble	Mildes, flüssiges oder gelförmiges spülwaschmittel, enthaltend ein alkyl-ethoxy- carboxylat als oberflächenaktiven stoff

1991
- 1991-11-08 AU AU90639/91A patent/AU9063991A/en not_active Abandoned
- 1991-11-08 AT AT92900582T patent/ATE149561T1/de not_active IP Right Cessation
- 1991-11-08 EP EP92900582A patent/EP0557426B1/de not_active Expired - Lifetime
- 1991-11-08 WO PCT/US1991/008280 patent/WO1992008777A1/en not_active Ceased
- 1991-11-08 HU HU9301418A patent/HUT64782A/hu unknown
- 1991-11-08 BR BR919106983A patent/BR9106983A/pt not_active Application Discontinuation
- 1991-11-08 CZ CS93873A patent/CZ87393A3/cs unknown
- 1991-11-08 SK SK480-93A patent/SK48093A3/sk unknown
- 1991-11-08 DE DE69125022T patent/DE69125022T2/de not_active Expired - Fee Related
- 1991-11-08 FI FI932199A patent/FI932199A0/fi unknown
- 1991-11-08 JP JP4502258A patent/JP3009464B2/ja not_active Expired - Lifetime
- 1991-11-08 ES ES92900582T patent/ES2101078T3/es not_active Expired - Lifetime
- 1991-11-08 DK DK92900582.5T patent/DK0557426T3/da active
- 1991-11-15 TR TR91/1103A patent/TR26532A/xx unknown
- 1991-11-15 PT PT99527A patent/PT99527A/pt not_active Application Discontinuation
- 1991-11-15 AR AR91321165A patent/AR244795A1/es active
- 1991-11-15 PT PT99530A patent/PT99530A/pt not_active Application Discontinuation
- 1991-11-15 MX MX9102078A patent/MX9102078A/es not_active IP Right Cessation
- 1991-11-15 MY MYPI91002116A patent/MY131210A/en unknown
- 1991-11-15 MA MA22625A patent/MA22342A1/fr unknown
- 1991-11-16 CN CN91111874.8A patent/CN1062371A/zh active Pending
1993
- 1993-05-13 NO NO93931738A patent/NO931738L/no unknown
1997
- 1997-05-20 GR GR970401152T patent/GR3023502T3/el unknown

Also Published As

Publication number	Publication date
JP3009464B2 (ja)	2000-02-14
FI932199A7 (fi)	1993-05-14
GR3023502T3 (en)	1997-08-29
DK0557426T3 (da)	1997-09-01
ES2101078T3 (es)	1997-07-01
NO931738D0 (no)	1993-05-13
DE69125022D1 (de)	1997-04-10
AR244795A1 (es)	1993-11-30
EP0557426B1 (de)	1997-03-05
AU9063991A (en)	1992-06-11
JPH06502884A (ja)	1994-03-31
PT99527A (pt)	1992-09-30
WO1992008777A1 (en)	1992-05-29
EP0557426A1 (de)	1993-09-01
TR26532A (tr)	1995-03-15
PT99530A (pt)	1992-09-30
FI932199L (fi)	1993-05-14
MX9102078A (es)	1992-06-01
HU9301418D0 (en)	1993-09-28
FI932199A0 (fi)	1993-05-14
MA22342A1 (fr)	1992-07-01
MY131210A (en)	2007-07-31
NO931738L (no)	1993-07-15
HUT64782A (en)	1994-02-28
ATE149561T1 (de)	1997-03-15
DE69125022T2 (de)	1997-09-25
CN1062371A (zh)	1992-07-01
BR9106983A (pt)	1993-08-24
SK48093A3 (en)	1994-01-12

Publication	Publication Date	Title
CZ87393A3 (en)	1994-07-13	Light-type agents for dish washing, which contain alkyl-ethoxy-carboxylate surface-active agent and calcium or magnesium ions
CA2055048C (en)	1996-05-14	Alkaline light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant, magnesium ions, chelator and buffer
US5378409A (en)	1995-01-03	Light duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and ions
US5417893A (en)	1995-05-23	Concentrated liquid or gel light duty dishwashing detergent compositions containing calcium ions and disulfonate surfactants
EP0399752B1 (de)	1997-08-06	Mildes, flüssiges oder gelförmiges Spülwaschmittel, enthaltend ein Alkyl-ethoxy-carboxylat als oberflächenaktiven Stoff
US5415814A (en)	1995-05-16	Concentrated liquid or gel light duty dishwashing detergent composition containing calcium xylene sulfonate
ES2237848T3 (es)	2005-08-01	Composiciones detergentes para lavar la vajilla, liquidas o en forma de gel, de accion suave que comprenden tensioactivos ramificados a mitad de cadena.
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