DD140034A5 - Verfahren zur herstellung ungesaettigter aldehyde und saeuren - Google Patents

Verfahren zur herstellung ungesaettigter aldehyde und saeuren Download PDF

Info

Publication number: DD140034A5
Authority: DD; German Democratic Republic
Prior art keywords: item; catalyst; elements; catalysts; mixture
Prior art date: 1977-07-28

Application number

DD78206895A

Other languages

German (de)

English (en)

Inventor

Andrew T Guttmann

Robert K Grasselli

Original Assignee

Standard Oil Co Ohio

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-28

Filing date

1978-07-24

Publication date

1980-02-06

1978-07-24 Application filed by Standard Oil Co Ohio filed Critical Standard Oil Co Ohio

1980-02-06 Publication of DD140034A5 publication Critical patent/DD140034A5/de

Links

150000001299 aldehydes Chemical class 0.000 title claims abstract description 12
238000004519 manufacturing process Methods 0.000 title description 4
239000003054 catalyst Substances 0.000 claims abstract description 78
238000000034 method Methods 0.000 claims abstract description 37
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 11
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 11
239000002253 acid Substances 0.000 claims abstract description 10
150000007513 acids Chemical class 0.000 claims abstract description 8
230000003647 oxidation Effects 0.000 claims abstract description 8
238000007254 oxidation reaction Methods 0.000 claims abstract description 8
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 6
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 5
229910001882 dioxygen Inorganic materials 0.000 claims abstract description 5
239000012808 vapor phase Substances 0.000 claims abstract description 4
239000000203 mixture Substances 0.000 claims description 21
229910052804 chromium Inorganic materials 0.000 claims description 20
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
229910052718 tin Inorganic materials 0.000 claims description 16
229910052721 tungsten Inorganic materials 0.000 claims description 16
229910052802 copper Inorganic materials 0.000 claims description 15
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
229910052749 magnesium Inorganic materials 0.000 claims description 13
229910052698 phosphorus Inorganic materials 0.000 claims description 13
229910052748 manganese Inorganic materials 0.000 claims description 11
229910052700 potassium Inorganic materials 0.000 claims description 10
229910052732 germanium Inorganic materials 0.000 claims description 9
229910052701 rubidium Inorganic materials 0.000 claims description 8
229910052792 caesium Inorganic materials 0.000 claims description 7
229910052782 aluminium Inorganic materials 0.000 claims description 6
229910052796 boron Inorganic materials 0.000 claims description 6
229910052738 indium Inorganic materials 0.000 claims description 6
229910052759 nickel Inorganic materials 0.000 claims description 6
229910052787 antimony Inorganic materials 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 4
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 4
229910052797 bismuth Inorganic materials 0.000 claims description 3
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
229910052745 lead Inorganic materials 0.000 claims description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
229910052777 Praseodymium Inorganic materials 0.000 claims description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
125000004429 atom Chemical group 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
229910052790 beryllium Inorganic materials 0.000 claims description 2
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 2
229910052793 cadmium Inorganic materials 0.000 claims description 2
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
239000011575 calcium Substances 0.000 claims description 2
125000004430 oxygen atom Chemical group O* 0.000 claims description 2
229910052705 radium Inorganic materials 0.000 claims description 2
HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 claims description 2
229910052709 silver Inorganic materials 0.000 claims description 2
239000004332 silver Substances 0.000 claims description 2
229910052712 strontium Inorganic materials 0.000 claims description 2
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
229910052714 tellurium Inorganic materials 0.000 claims description 2
229910052716 thallium Inorganic materials 0.000 claims description 2
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
239000011701 zinc Substances 0.000 claims description 2
-1 B Co Inorganic materials 0.000 claims 1
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 13
239000000243 solution Substances 0.000 description 11
230000000694 effects Effects 0.000 description 10
150000001336 alkenes Chemical class 0.000 description 9
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 8
230000000052 comparative effect Effects 0.000 description 7
230000003197 catalytic effect Effects 0.000 description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
229910004298 SiO 2 Inorganic materials 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
229910052733 gallium Inorganic materials 0.000 description 3
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
229910052746 lanthanum Inorganic materials 0.000 description 3
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
238000003756 stirring Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000002585 base Substances 0.000 description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
208000012839 conversion disease Diseases 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
229910052750 molybdenum Inorganic materials 0.000 description 2
239000011733 molybdenum Substances 0.000 description 2
239000011591 potassium Substances 0.000 description 2
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000003990 capacitor Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000000047 product Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

DD78206895A 1977-07-28 1978-07-24 Verfahren zur herstellung ungesaettigter aldehyde und saeuren DD140034A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US81973377A	1977-07-28	1977-07-28

Publications (1)

Publication Number	Publication Date
DD140034A5 true DD140034A5 (de)	1980-02-06

Family

ID=25228904

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD78206895A DD140034A5 (de)	1977-07-28	1978-07-24	Verfahren zur herstellung ungesaettigter aldehyde und saeuren

Country Status (13)

Country	Link
EP (1)	EP0000663B1 (fr)
AT (1)	AT359055B (fr)
BR (1)	BR7804848A (fr)
CA (1)	CA1133505A (fr)
DD (1)	DD140034A5 (fr)
DE (1)	DE2861192D1 (fr)
ES (1)	ES472082A1 (fr)
IN (1)	IN148201B (fr)
IT (1)	IT1118241B (fr)
NO (1)	NO151083C (fr)
PT (1)	PT68313A (fr)
RO (1)	RO75319A (fr)
YU (1)	YU182978A (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1127137A (fr) *	1977-12-20	1982-07-06	Dev D. Suresh	Ammoxydation d'olefines sur de nouveaux catalyseurs a l'antimonate
GB2077257B (en) *	1980-05-19	1984-06-27	Asahi Chemical Ind	Process for producing methacrolein
US4532365A (en) *	1982-09-20	1985-07-30	The Halcon Sd Group, Inc.	Conversion of alkanes to unsaturated aldehydes
EP0279374B1 (fr) *	1987-02-17	1992-01-02	Nippon Shokubai Kagaku Kogyo Co., Ltd	Catalyseur d'oxydation d'oléfines ou d'alcool tertiaire et procédé pour sa préparation
US5162578A (en) *	1987-06-12	1992-11-10	Union Carbide Chemicals & Plastics Technology Corporation	Acetic acid from ethane, ethylene and oxygen

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5112603B1 (fr) *	1971-05-26	1976-04-21
CA1049553A (fr) *	1973-04-30	1979-02-27	The Standard Oil Company	Synthese d'acide acrylique ou methacrylique a partir de propylene ou d'isobutylene
NL171440C (nl) *	1973-05-10	1983-04-05	Japan Synthetic Rubber Co Ltd	Werkwijze voor het bereiden van methacroleien door katalytische oxydatie van isobuteen.
US3972920A (en) *	1973-06-11	1976-08-03	Mitsubishi Rayon Co., Ltd.	Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes
US4001317A (en) *	1974-07-22	1977-01-04	Standard Oil Company	Process for the oxidation of olefins using catalysts containing various promoter elements
GB1523772A (en) *	1974-07-22	1978-09-06	Standard Oil Co	Oxidation catalysts
GB1489559A (en) *	1975-03-03	1977-10-19	Mitsubishi Rayon Co	Catalytic process for the preparation of acrylic acid or methacrylic acid
GB1490683A (en) *	1975-03-12	1977-11-02	Mitsubishi Rayon Co	Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
IN142430B (fr) *	1975-04-21	1977-07-09	Standard Oil Co
US4118419A (en) *	1975-12-03	1978-10-03	Mitsubishi Rayon Company, Ltd.	Catalytic process for the preparation of an unsaturated carboxylic acid
DE2626887B2 (de) *	1976-06-16	1978-06-29	Basf Ag, 6700 Ludwigshafen	Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
US4065507A (en) *	1976-08-02	1977-12-27	Standard Oil Company	Preparation of methacrylic derivatives from tertiary butyl-containing compounds

1978
- 1978-06-28 CA CA306,381A patent/CA1133505A/fr not_active Expired
- 1978-07-11 IN IN516/DEL/78A patent/IN148201B/en unknown
- 1978-07-18 PT PT68313A patent/PT68313A/pt unknown
- 1978-07-24 DD DD78206895A patent/DD140034A5/de unknown
- 1978-07-25 DE DE7878300199T patent/DE2861192D1/de not_active Expired
- 1978-07-25 EP EP78300199A patent/EP0000663B1/fr not_active Expired
- 1978-07-26 IT IT26141/78A patent/IT1118241B/it active
- 1978-07-27 RO RO7894818A patent/RO75319A/fr unknown
- 1978-07-27 NO NO782583A patent/NO151083C/no unknown
- 1978-07-27 BR BR7804848A patent/BR7804848A/pt unknown
- 1978-07-27 ES ES472082A patent/ES472082A1/es not_active Expired
- 1978-07-28 YU YU01829/78A patent/YU182978A/xx unknown
- 1978-07-28 AT AT551778A patent/AT359055B/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
IT1118241B (it)	1986-02-24
ATA551778A (de)	1980-03-15
EP0000663B1 (fr)	1981-10-21
BR7804848A (pt)	1979-04-10
EP0000663A1 (fr)	1979-02-07
NO151083C (no)	1985-02-06
CA1133505A (fr)	1982-10-12
RO75319A (fr)	1980-11-30
IN148201B (fr)	1980-11-29
NO782583L (no)	1979-01-30
DE2861192D1 (en)	1981-12-24
PT68313A (en)	1978-08-01
IT7826141A0 (it)	1978-07-26
AT359055B (de)	1980-10-27
ES472082A1 (es)	1979-04-16
YU182978A (en)	1982-08-31
NO151083B (no)	1984-10-29

Publication	Publication Date	Title
DE3300044C2 (de)	1987-01-29	Katalysator für die Oxidation von Propylen
EP0088328B1 (fr)	1986-07-30	Catalyseur d'oxydation, en particulier pour la préparation d'acide méthacrylique par l'oxydation de la méthacroléine
DE69210288T2 (de)	1996-10-10	Verfahren zur Herstellung von Methanolein und Verfahren zur Herstellung eines Katalysators zur Verwendung in dem Methacrolein-Verfahren
DE2610249C2 (de)	1986-08-21	Verfahren zur Herstellung von Acrylsäure bzw. Methacrylsäure
EP0124706B1 (fr)	1988-12-14	Procédé et catalyseur pour la préparation d'acide méthacrylique
DE2608583A1 (de)	1976-09-09	Katalytisches verfahren zur herstellung ungesaettigter carbonsaeure
DE2505844C2 (de)	1983-04-28	Oxidationskatalysator auf Basis von Vanadin und fünfwertigem Phosphor und seine Verwendung
DE1593186A1 (de)	1970-09-03	Verfahren zur Herstellung olefinisch ungesaettigter Aldehyde durch katalytische Oxydation von Olefinen
DE1242599B (de)	1967-06-22	Verfahren zur Herstellung von Acrylsaeurenitril oder Methacrylsaeurenitril durch Umsetzung von Propylen oder Isobutylen mit Sauerstoff und Ammoniak
DE2424934A1 (de)	1975-01-02	Verfahren zur katalytischen herstellung ungesaettigter nitrile
DE2414797A1 (de)	1974-10-10	Verfahren zur herstellung von acrylsaeure oder methacrylsaeure durch oxidation von acrolein oder methacrolein und katalysator zur durchfuehrung des verfahrens
EP0255639B1 (fr)	1989-05-31	Mélanges d'hétéropolymolybdates et leur utilisation comme catalyseurs
DE2420281C2 (de)	1983-08-04	Verfahren zur Herstellung von Acrylsäure
DE1816739B2 (de)	1973-11-08	Verfahren zur Herstellung von Isopren
DE3111401A1 (de)	1982-05-13	"stabiler molybdaenkatalysator zur umwandlung von c(pfeil abwaerts)3(pfeil abwaerts)- und c(pfeil abwaerts)4(pfeil abwaerts)-olefinen in ungesaettigte aldehyde und saeuren"
DE2523983B2 (fr)	1978-11-30
DE3047102A1 (de)	1981-09-24	Verfahren zur herstellung von phenol
DD140034A5 (de)	1980-02-06	Verfahren zur herstellung ungesaettigter aldehyde und saeuren
DE1768602C3 (de)	1980-01-10	Verfahren zur Herstellung eines Gemisches aus Acrylsäure und Acrolein durch Umsetzung von Propylen
EP0009239A1 (fr)	1980-04-02	Procédé de préparation de benzaldéhydes p-substitués
DE19530454A1 (de)	1997-02-20	Verfahren zur Gewinnung von Propen durch Umsetzung von Propan mit Sauerstoff an Katalysatoren
DE2228989C3 (de)	1978-04-13	Molybdän, Eisen, Wismut, Nickel, Thallium sowie gegebenenfalls Magnesium, Mangan, Kobalt und Phosphor enthaltender Oxid-Trägerkatalysator und seine Verwendung zur Herstellung von Acrolein
DE2603770A1 (de)	1976-09-16	Verfahren zur herstellung von maleinsaeureanhydrid
DE2133110C3 (de)	1974-10-03	Verfahren zur Herstellung von Acrolein
DE2040455C3 (de)	1974-11-14	Verfahren zur Herstellung von Essigsäure