DD201811A5 - Membrane, elektrochemische zelle und elektrolyseverfahren - Google Patents

Membrane, elektrochemische zelle und elektrolyseverfahren Download PDF

Info

Publication number: DD201811A5
Authority: DD; German Democratic Republic
Prior art keywords: item; membrane according; membrane; layer; polymer
Prior art date: 1981-01-16

Application number

DD82236796A

Other languages

German (de)

English (en)

Inventor

Thomas C Bissot

Walther G Grot

Paul R Resnick

Original Assignee

Du Pont

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-01-16

Filing date

1982-01-15

Publication date

1983-08-10

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27397505&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DD201811(A5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1982-01-15 Application filed by Du Pont filed Critical Du Pont

1983-08-10 Publication of DD201811A5 publication Critical patent/DD201811A5/de

Links

239000012528 membrane Substances 0.000 title claims abstract description 186
238000005868 electrolysis reaction Methods 0.000 title claims description 12
230000003014 reinforcing effect Effects 0.000 claims abstract description 62
229920002313 fluoropolymer Polymers 0.000 claims abstract description 31
239000003014 ion exchange membrane Substances 0.000 claims abstract description 21
125000000524 functional group Chemical group 0.000 claims abstract description 13
239000012876 carrier material Substances 0.000 claims abstract description 10
239000002243 precursor Substances 0.000 claims abstract description 10
229920000642 polymer Polymers 0.000 claims description 91
239000004744 fabric Substances 0.000 claims description 61
239000000835 fiber Substances 0.000 claims description 50
150000003254 radicals Chemical class 0.000 claims description 44
-1 polytetrafluoroethylene Polymers 0.000 claims description 33
239000000123 paper Substances 0.000 claims description 30
239000000203 mixture Substances 0.000 claims description 26
239000000463 material Substances 0.000 claims description 20
TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 19
238000000034 method Methods 0.000 claims description 16
229920001343 polytetrafluoroethylene Polymers 0.000 claims description 14
239000004810 polytetrafluoroethylene Substances 0.000 claims description 14
238000002360 preparation method Methods 0.000 claims description 14
239000007788 liquid Substances 0.000 claims description 13
239000000460 chlorine Substances 0.000 claims description 11
229910052731 fluorine Inorganic materials 0.000 claims description 11
239000010411 electrocatalyst Substances 0.000 claims description 10
229920005594 polymer fiber Polymers 0.000 claims description 10
229910052739 hydrogen Inorganic materials 0.000 claims description 9
239000004753 textile Substances 0.000 claims description 9
229920000297 Rayon Polymers 0.000 claims description 8
229910052801 chlorine Inorganic materials 0.000 claims description 8
239000002964 rayon Substances 0.000 claims description 8
239000012267 brine Substances 0.000 claims description 7
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 7
239000002759 woven fabric Substances 0.000 claims description 7
239000003513 alkali Substances 0.000 claims description 6
230000008569 process Effects 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
239000000853 adhesive Substances 0.000 claims description 3
230000001070 adhesive effect Effects 0.000 claims description 3
239000003518 caustics Substances 0.000 claims description 3
239000012530 fluid Substances 0.000 claims description 3
239000011737 fluorine Substances 0.000 claims description 3
239000002655 kraft paper Substances 0.000 claims description 3
229910052708 sodium Inorganic materials 0.000 claims description 3
238000005341 cation exchange Methods 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
239000010410 layer Substances 0.000 abstract description 100
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract description 19
239000002344 surface layer Substances 0.000 abstract description 11
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract description 2
239000000178 monomer Substances 0.000 description 36
229920001577 copolymer Polymers 0.000 description 27
238000005342 ion exchange Methods 0.000 description 20
230000007062 hydrolysis Effects 0.000 description 14
238000006460 hydrolysis reaction Methods 0.000 description 14
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 11
229920000728 polyester Polymers 0.000 description 10
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 10
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239000011230 binding agent Substances 0.000 description 5
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238000012360 testing method Methods 0.000 description 5
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
238000003490 calendering Methods 0.000 description 4
150000007942 carboxylates Chemical class 0.000 description 4
125000001309 chloro group Chemical group Cl* 0.000 description 4
238000003475 lamination Methods 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
239000012783 reinforcing fiber Substances 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
239000002131 composite material Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000000470 constituent Substances 0.000 description 3
239000003792 electrolyte Substances 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
239000011888 foil Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 3
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239000002245 particle Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 description 2
TUFKHKZLBZWCAW-UHFFFAOYSA-N 2-(1-ethenoxypropan-2-yloxy)ethanesulfonyl fluoride Chemical compound C=COCC(C)OCCS(F)(=O)=O TUFKHKZLBZWCAW-UHFFFAOYSA-N 0.000 description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
239000005708 Sodium hypochlorite Substances 0.000 description 2
230000009471 action Effects 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
239000002585 base Substances 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000005538 encapsulation Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
ZQBFAOFFOQMSGJ-UHFFFAOYSA-N hexafluorobenzene Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1F ZQBFAOFFOQMSGJ-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
238000002955 isolation Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
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239000001301 oxygen Substances 0.000 description 2
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BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
239000000843 powder Substances 0.000 description 2
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239000002002 slurry Substances 0.000 description 2
239000011734 sodium Substances 0.000 description 2
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
239000002904 solvent Substances 0.000 description 2
BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 2
230000009466 transformation Effects 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
QIROQPWSJUXOJC-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6-undecafluoro-6-(trifluoromethyl)cyclohexane Chemical compound FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F QIROQPWSJUXOJC-UHFFFAOYSA-N 0.000 description 1
TXGPGHBYAPBDAG-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluoro-4,4-bis(trifluoromethyl)cyclobutane Chemical compound FC(F)(F)C1(C(F)(F)F)C(F)(F)C(F)(F)C1(F)F TXGPGHBYAPBDAG-UHFFFAOYSA-N 0.000 description 1
VQUGQIYAVYQSAB-UHFFFAOYSA-N 1,1,2,2-tetrafluoro-2-(1,2,2-trifluoroethenoxy)ethanesulfonyl fluoride Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)S(F)(=O)=O VQUGQIYAVYQSAB-UHFFFAOYSA-N 0.000 description 1
AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
JYHIPQZCAWVGMM-UHFFFAOYSA-N 1-(2-ethoxypropoxy)ethanesulfonyl fluoride Chemical compound CCOC(C)COC(C)S(F)(=O)=O JYHIPQZCAWVGMM-UHFFFAOYSA-N 0.000 description 1
MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910001209 Low-carbon steel Inorganic materials 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
YJZATOSJMRIRIW-UHFFFAOYSA-N [Ir]=O Chemical class [Ir]=O YJZATOSJMRIRIW-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
238000005576 amination reaction Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000001246 colloidal dispersion Methods 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
229920001002 functional polymer Polymers 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
238000007646 gravure printing Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000007731 hot pressing Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000009434 installation Methods 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
230000005865 ionizing radiation Effects 0.000 description 1
229910000457 iridium oxide Inorganic materials 0.000 description 1
238000010030 laminating Methods 0.000 description 1
239000002346 layers by function Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000003607 modifier Substances 0.000 description 1
150000002825 nitriles Chemical group 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000035515 penetration Effects 0.000 description 1
YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000004627 regenerated cellulose Substances 0.000 description 1
229910001925 ruthenium oxide Inorganic materials 0.000 description 1
238000009738 saturating Methods 0.000 description 1
238000007650 screen-printing Methods 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
125000000542 sulfonic acid group Chemical group 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
230000003746 surface roughness Effects 0.000 description 1
230000008961 swelling Effects 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2275—Heterogeneous membranes
- C08J5/2281—Heterogeneous membranes fluorine containing heterogeneous membranes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Inorganic Chemistry (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)

DD82236796A 1981-01-16 1982-01-15 Membrane, elektrochemische zelle und elektrolyseverfahren DD201811A5 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date
US22564181A	1981-01-16	1981-01-16
US31999181A	1981-11-12	1981-11-12
US33060681A	1981-12-15	1981-12-15

Publications (1)

Publication Number	Publication Date
DD201811A5 true DD201811A5 (de)	1983-08-10

Family

ID=27397505

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD82236796A DD201811A5 (de)	1981-01-16	1982-01-15	Membrane, elektrochemische zelle und elektrolyseverfahren

Country Status (10)

Country	Link
EP (1)	EP0056707B1 (no)
AU (1)	AU553802B2 (no)
BR (1)	BR8200152A (no)
CA (1)	CA1223842A (no)
DD (1)	DD201811A5 (no)
DE (1)	DE3267950D1 (no)
IL (1)	IL64776A0 (no)
MX (1)	MX161404A (no)
NO (1)	NO161629C (no)
NZ (1)	NZ199500A (no)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4539084A (en) *	1983-03-10	1985-09-03	E. I. Du Pont De Nemours And Company	Unreinforced membrane, electrochemical cell and electrolysis process
US4552631A (en) *	1983-03-10	1985-11-12	E. I. Du Pont De Nemours And Company	Reinforced membrane, electrochemical cell and electrolysis process
JP2688902B2 (ja) *	1987-08-26	1997-12-10	旭化成工業株式会社	強化されたイオン交換膜及びその製造法
BR9000773A (pt) *	1989-02-28	1991-01-22	Du Pont	Processo para a fabricacao de uma membrana de troca de catio; processo para a fabricacao de um tecido revestido; processo para a fabricacao de um fio revestido; membrana de troca de cation; processo aperfeicoado para a eletrolise de um haleto de metal alcalino; tecido de troca de cation e fio de troca de cation
JP5793444B2 (ja) *	2012-02-13	2015-10-14	旭化成ケミカルズ株式会社	陽イオン交換膜及びこれを用いた電解槽
JP5774514B2 (ja) *	2012-02-13	2015-09-09	旭化成ケミカルズ株式会社	陽イオン交換膜、及びこれを用いた電解槽

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4021327A (en) *	1975-04-29	1977-05-03	E. I. Du Pont De Nemours And Company	Reinforced cation permeable separator
DE2857627C2 (de) *	1977-12-09	1982-12-30	General Electric Co., Schenectady, N.Y.	Kombinierte Elektrolyt- und Elektrodenstruktur
US4176215A (en) *	1978-03-13	1979-11-27	E. I. Du Pont De Nemours And Company	Ion-exchange structures of copolymer blends useful in electrolytic cells

1982
- 1982-01-13 BR BR8200152A patent/BR8200152A/pt unknown
- 1982-01-13 DE DE8282300175T patent/DE3267950D1/de not_active Expired
- 1982-01-13 EP EP82300175A patent/EP0056707B1/en not_active Expired
- 1982-01-14 IL IL64776A patent/IL64776A0/xx not_active IP Right Cessation
- 1982-01-14 CA CA000394131A patent/CA1223842A/en not_active Expired
- 1982-01-15 AU AU79559/82A patent/AU553802B2/en not_active Ceased
- 1982-01-15 NO NO820120A patent/NO161629C/no unknown
- 1982-01-15 MX MX191006A patent/MX161404A/es unknown
- 1982-01-15 DD DD82236796A patent/DD201811A5/de not_active IP Right Cessation
- 1982-01-15 NZ NZ199500A patent/NZ199500A/en unknown

Also Published As

Publication number	Publication date
DE3267950D1 (en)	1986-01-30
CA1223842A (en)	1987-07-07
NO161629B (no)	1989-05-29
EP0056707A2 (en)	1982-07-28
AU553802B2 (en)	1986-07-31
MX161404A (es)	1990-09-21
NO820120L (no)	1982-07-19
AU7955982A (en)	1982-07-22
BR8200152A (pt)	1982-11-03
NZ199500A (en)	1985-10-11
IL64776A0 (en)	1982-03-31
EP0056707B1 (en)	1985-12-18
NO161629C (no)	1989-09-06
EP0056707A3 (en)	1982-08-11

Legal Events

Date	Code	Title	Description
1996-02-01	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
US4437951A (en)	1984-03-20	Membrane, electrochemical cell, and electrolysis process
US4552631A (en)	1985-11-12	Reinforced membrane, electrochemical cell and electrolysis process
DE69220528T2 (de)	1997-10-09	Fluorenthaltende Kationaustauschermembran für Elektrolyse
DE112013001160B4 (de)	2024-05-23	Verstärkte Elektrolytmembran und Verfahren für ihre Herstellung
DE2607242C2 (de)	1985-11-14	Kationendurchlässiges Diaphragma und Verfahren zur Herstellung desselben
DE2713816A1 (de)	1977-10-06	Verfahren zur elektrolyse von natriumchloridloesungen
DE102019125363B4 (de)	2025-11-06	Verfahren zur Herstellung einer Elektrode
DE3882925T2 (de)	1994-03-17	Verfahren zur herstellung von alkalimetallhydroxid.
DE4142417A1 (de)	1992-06-25	Multiaxial verstaerkte membran
DE3201119A1 (de)	1982-09-02	Verfahren zur herstellung eines kationenpermeablen membrane mit eingebettetem verstaerkungsgewebe und die dabei erhaltene membrane
DE3044767A1 (de)	1981-09-24	Ionenaustauschermembranzelle und elektrolyseverfahren unter verwendung derselben
DE3201092A1 (de)	1982-10-21	Membrane, elektrolyseverfahren und verwendung der membrane in einer elektrochemischen zelle
DE3885387T2 (de)	1994-03-17	Verstärkte Ionenaustauschermembran und Verfahren zur Herstellung derselben.
DE3201154A1 (de)	1982-08-12	Elektrolyseverfahren und elektrochemische zelle
DD283952A5 (de)	1990-10-31	Homogene mischungen von organischen, polymeren stoffen
DE2926603A1 (de)	1980-04-17	Kationenaustauschmembran und verfahren zu ihrer herstellung
DE69014222T2 (de)	1995-06-29	Verstärkte Kationenaustauschermembran und Verfahren.
DE10296830T5 (de)	2004-04-29	Fluorkohlenstoffharz-Ionenaustaschermembran
DE2817344C2 (no)	1990-11-15
DD201811A5 (de)	1983-08-10	Membrane, elektrochemische zelle und elektrolyseverfahren
DE68907351T2 (de)	1993-12-23	Elektrolyseverfahren zur Herstellung konzentrierter Natriumhydroxyde, mittels einer Membran.
DE4206298A1 (de)	1992-09-03	Bestrahlung von kationenaustauschmembranen
JPS617338A (ja)	1986-01-14	イオン交換樹脂膜
DE4237114A1 (no)	1993-05-06
US4477321A (en)	1984-10-16	Sacrificial reinforcements in cation exchange membrane