DD238959A5 - Stabilisierter und phlegmatisierter rieselfaehiger roter phosphor und verfahren zur herstellung - Google Patents

Stabilisierter und phlegmatisierter rieselfaehiger roter phosphor und verfahren zur herstellung Download PDF

Info

Publication number: DD238959A5
Authority: DD; German Democratic Republic
Prior art keywords: red phosphorus; phosphorus; stabilized; epoxy resin; red
Prior art date: 1984-10-03

Application number

DD85281257A

Other languages

German (de)

English (en)

Inventor

Horst Staendeke

Ursus Thuemmler

Original Assignee

Hoechst Ag,De

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-10-03

Filing date

1985-10-01

Publication date

1986-09-10

1985-10-01 Application filed by Hoechst Ag,De filed Critical Hoechst Ag,De

1986-09-10 Publication of DD238959A5 publication Critical patent/DD238959A5/de

Links

238000000034 method Methods 0.000 title claims abstract description 19
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 131
239000003822 epoxy resin Substances 0.000 claims abstract description 33
229920000647 polyepoxide Polymers 0.000 claims abstract description 33
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
239000002245 particle Substances 0.000 claims abstract description 23
239000007900 aqueous suspension Substances 0.000 claims abstract description 21
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 18
OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 claims abstract description 15
239000007788 liquid Substances 0.000 claims abstract description 11
150000002894 organic compounds Chemical class 0.000 claims abstract description 11
238000002360 preparation method Methods 0.000 claims abstract description 8
230000008569 process Effects 0.000 claims abstract description 7
230000003647 oxidation Effects 0.000 claims description 29
238000007254 oxidation reaction Methods 0.000 claims description 29
239000003381 stabilizer Substances 0.000 claims description 23
239000000243 solution Substances 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 12
230000006641 stabilisation Effects 0.000 claims description 12
238000011105 stabilization Methods 0.000 claims description 12
239000000839 emulsion Substances 0.000 claims description 9
239000003795 chemical substances by application Substances 0.000 claims description 8
238000003756 stirring Methods 0.000 claims description 6
238000009835 boiling Methods 0.000 claims description 5
238000001914 filtration Methods 0.000 claims description 5
239000006185 dispersion Substances 0.000 claims description 4
230000001476 alcoholic effect Effects 0.000 claims description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
238000001556 precipitation Methods 0.000 claims description 3
238000001035 drying Methods 0.000 claims 1
239000000725 suspension Substances 0.000 abstract description 10
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 20
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
229910052698 phosphorus Inorganic materials 0.000 description 16
239000011574 phosphorus Substances 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
239000000428 dust Substances 0.000 description 13
238000012360 testing method Methods 0.000 description 11
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 10
229910052782 aluminium Inorganic materials 0.000 description 10
239000004848 polyfunctional curative Substances 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 9
239000000047 product Substances 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
238000004458 analytical method Methods 0.000 description 8
239000013065 commercial product Substances 0.000 description 7
235000011121 sodium hydroxide Nutrition 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 6
238000005259 measurement Methods 0.000 description 6
239000004033 plastic Substances 0.000 description 6
229920003023 plastic Polymers 0.000 description 6
238000012545 processing Methods 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
239000007789 gas Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
239000004803 Di-2ethylhexylphthalate Substances 0.000 description 4
239000002253 acid Substances 0.000 description 4
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 4
239000000706 filtrate Substances 0.000 description 4
150000004715 keto acids Chemical class 0.000 description 4
238000002156 mixing Methods 0.000 description 4
235000011007 phosphoric acid Nutrition 0.000 description 4
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
238000007323 disproportionation reaction Methods 0.000 description 3
238000004880 explosion Methods 0.000 description 3
239000003063 flame retardant Substances 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
229910000073 phosphorus hydride Inorganic materials 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000000523 sample Substances 0.000 description 3
238000004448 titration Methods 0.000 description 3
238000005406 washing Methods 0.000 description 3
YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000009826 distribution Methods 0.000 description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
239000000347 magnesium hydroxide Substances 0.000 description 2
229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
150000003016 phosphoric acids Chemical class 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
238000010992 reflux Methods 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
238000007873 sieving Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000001993 wax Substances 0.000 description 2
KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000009471 action Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000007664 blowing Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
RLRMXWDXPLINPJ-UHFFFAOYSA-N dioctan-2-yl benzene-1,2-dicarboxylate Chemical compound CCCCCCC(C)OC(=O)C1=CC=CC=C1C(=O)OC(C)CCCCCC RLRMXWDXPLINPJ-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
239000005007 epoxy-phenolic resin Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000008187 granular material Substances 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
229910021514 lead(II) hydroxide Inorganic materials 0.000 description 1
239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
238000005580 one pot reaction Methods 0.000 description 1
150000002924 oxiranes Chemical class 0.000 description 1
150000003009 phosphonic acids Chemical class 0.000 description 1
229920000962 poly(amidoamine) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
238000000746 purification Methods 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 1
238000013112 stability test Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/003—Phosphorus
- C01B25/006—Stabilisation

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Glanulating (AREA)
Compositions Of Macromolecular Compounds (AREA)
Luminescent Compositions (AREA)
Pigments, Carbon Blacks, Or Wood Stains (AREA)

DD85281257A 1984-10-03 1985-10-01 Stabilisierter und phlegmatisierter rieselfaehiger roter phosphor und verfahren zur herstellung DD238959A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19843436159 DE3436159A1 (de)	1984-10-03	1984-10-03	Stabilisierter und phlegmatisierter rieselfaehiger roter phosphor

Publications (1)

Publication Number	Publication Date
DD238959A5 true DD238959A5 (de)	1986-09-10

Family

ID=6246922

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD85281257A DD238959A5 (de)	1984-10-03	1985-10-01	Stabilisierter und phlegmatisierter rieselfaehiger roter phosphor und verfahren zur herstellung

Country Status (7)

Country	Link
EP (1)	EP0176834B1 (fr)
JP (1)	JPH0637287B2 (fr)
CN (1)	CN85107353A (fr)
CA (1)	CA1282576C (fr)
DD (1)	DD238959A5 (fr)
DE (2)	DE3436159A1 (fr)
IN (1)	IN166171B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4879067A (en) *	1986-06-19	1989-11-07	Rinkagaku Kogyo Co., Ltd.	Red phosphorus flame retardant and nonflammable resinous composition containing the same
JP2877821B2 (ja) *	1988-10-13	1999-04-05	日本化学工業株式会社	安定化赤リンおよびその製造法
JP2832672B2 (ja) *	1993-08-12	1998-12-09	燐化学工業株式会社	赤リン系難燃剤及び難燃性樹脂組成物

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2635953A (en) *	1947-10-08	1953-04-21	Martin S Silverstein	Inflammable compositions including red phosphorus
DE2813151A1 (de) *	1978-03-25	1979-09-27	Hoechst Ag	Stabilisierter roter phosphor
DE2945118C2 (de) *	1979-11-08	1981-12-03	Hoechst Ag, 6000 Frankfurt	Stabilisierter roter Phosphor sowie Verfahren zu seiner Herstellung

1984
- 1984-10-03 DE DE19843436159 patent/DE3436159A1/de not_active Withdrawn
1985
- 1985-09-02 IN IN685/MAS/85A patent/IN166171B/en unknown
- 1985-09-05 CA CA000490078A patent/CA1282576C/fr not_active Expired - Fee Related
- 1985-09-13 DE DE8585111588T patent/DE3581684D1/de not_active Expired - Lifetime
- 1985-09-13 EP EP85111588A patent/EP0176834B1/fr not_active Expired - Lifetime
- 1985-09-30 CN CN85107353A patent/CN85107353A/zh active Pending
- 1985-10-01 DD DD85281257A patent/DD238959A5/de not_active IP Right Cessation
- 1985-10-02 JP JP60218181A patent/JPH0637287B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPH0637287B2 (ja)	1994-05-18
CA1282576C (fr)	1991-04-09
JPS6186407A (ja)	1986-05-01
DE3581684D1 (de)	1991-03-14
DE3436159A1 (de)	1986-04-10
IN166171B (fr)	1990-03-24
EP0176834A2 (fr)	1986-04-09
EP0176834A3 (en)	1988-11-23
EP0176834B1 (fr)	1991-02-06
CN85107353A (zh)	1986-10-01

Legal Events

Date	Code	Title	Description
1995-06-08	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
EP0283759B1 (fr)	1990-07-11	Phosphore rouge stabilisé et son procédé de préparation
EP0176836B1 (fr)	1991-02-06	Phosphore rouge phlegmatisé
EP0028744B1 (fr)	1983-03-16	Phosphore rouge stabilisé et procédé pour sa fabrication
EP0009175B1 (fr)	1982-06-16	Procédé pour la production de phosphate de zinc comme pigment pour la protection contre la corrosion
EP0004305B1 (fr)	1981-11-11	Phosphore rouge stabilisé
DE1592549C3 (de)	1980-02-14	Verfahren zur Herstellung eines Zirkonium-Sols
EP0967252A1 (fr)	1999-12-29	Silice précipitée hydrophobe
EP1211220B1 (fr)	2005-03-30	Phosphore rouge stabilisé et procédé pour sa préparation
EP0017784A1 (fr)	1980-10-29	Procédé de préparation d'un pigment anti-corrosion à base de phosphate
DD238959A5 (de)	1986-09-10	Stabilisierter und phlegmatisierter rieselfaehiger roter phosphor und verfahren zur herstellung
EP1195354B1 (fr)	2005-12-28	Procédé de séparation des composés arséniques de la queue de distillation lors de la préparation de fluorure d'hydrogène
DE2647093C2 (de)	1984-12-06	Stabilisierter pulverförmiger roter Phosphor sowie Verfahren zu seiner Herstellung
DE2632296C2 (de)	1979-02-01	Stabilisierter roter Phosphor sowie Verfahren zu seiner Herstellung
DE2655739C2 (de)	1978-12-14	Stabilisierter roter Phosphor sowie Verfahren zu seiner Herstellung
DE2631532A1 (de)	1978-01-19	Stabilisierter, roter phosphor sowie verfahren zu seiner herstellung
EP0490109B1 (fr)	1994-04-06	Phosphore rouge stabilisé et son procédé de préparation
DE3900965C1 (fr)	1989-10-19
EP0490110B1 (fr)	1994-05-04	Phosphore rouge stabilisé et son procédé de préparation
DE19619701A1 (de)	1996-11-21	Stabilisierter roter Phosphor und seine Verwendung als flammhemmendes Mittel für Plastikmaterialien
EP0384203B1 (fr)	1993-02-03	Phosphore rouge désensibilisé
DE3225277C2 (fr)	1987-11-12
DD293507A5 (de)	1991-09-05	Verfahren zur herstellung eines katalysators fuer die methylchlorsilansynthese
DE1238882B (de)	1967-04-20	Verfahren zur Herstellung von Thoriumdioxyd/Urandioxyd-Aquasolen
DE2950549A1 (de)	1981-06-19	Verfahren zur herstellung von dialkylphosphaten