DD298004A5 - Verfahren zur herstellung von alkalidichromaten und chromsaeuren durch elektrolyse - Google Patents

Verfahren zur herstellung von alkalidichromaten und chromsaeuren durch elektrolyse Download PDF

Info

Publication number: DD298004A5
Authority: DD; German Democratic Republic
Prior art keywords: sodium; solution; electrolysis; membranes; cation exchange
Prior art date: 1989-04-06

Application number

DD90339430A

Other languages

German (de)

English (en)

Inventor

Helmut Klotz

Rainer Weber

Norbert Loenhoff

Hans-Dieter Block

Dieter-Hans Pinter

Original Assignee

��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-04-06

Filing date

1990-04-04

Publication date

1992-01-30

1990-04-04 Application filed by ��@��k�� filed Critical ��@��k��

1992-01-30 Publication of DD298004A5 publication Critical patent/DD298004A5/de

Links

238000005868 electrolysis reaction Methods 0.000 title claims abstract description 24
238000000034 method Methods 0.000 title claims abstract description 18
238000002360 preparation method Methods 0.000 title claims abstract description 8
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title description 4
239000012528 membrane Substances 0.000 claims abstract description 42
238000005341 cation exchange Methods 0.000 claims abstract description 14
239000002356 single layer Substances 0.000 claims abstract description 13
229920000642 polymer Polymers 0.000 claims abstract description 4
125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 3
239000000243 solution Substances 0.000 claims description 52
JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 claims description 23
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 23
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 22
PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 claims description 12
239000007864 aqueous solution Substances 0.000 claims description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 23
229920000557 Nafion® Polymers 0.000 description 16
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 12
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
239000011734 sodium Substances 0.000 description 10
239000011651 chromium Substances 0.000 description 9
235000011121 sodium hydroxide Nutrition 0.000 description 8
-1 alkali metal dichromate Chemical class 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 7
239000010410 layer Substances 0.000 description 7
239000013078 crystal Substances 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
239000012452 mother liquor Substances 0.000 description 6
235000017557 sodium bicarbonate Nutrition 0.000 description 6
229910000030 sodium bicarbonate Inorganic materials 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 5
239000001569 carbon dioxide Substances 0.000 description 5
229910002092 carbon dioxide Inorganic materials 0.000 description 5
239000003513 alkali Substances 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
230000020477 pH reduction Effects 0.000 description 4
229910001415 sodium ion Inorganic materials 0.000 description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
238000010979 pH adjustment Methods 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
239000010936 titanium Substances 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
239000003012 bilayer membrane Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
238000000576 coating method Methods 0.000 description 2
230000029087 digestion Effects 0.000 description 2
230000005611 electricity Effects 0.000 description 2
239000007789 gas Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
150000001339 alkali metal compounds Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000003851 corona treatment Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
QZJQGEHKLBNSMN-UHFFFAOYSA-N disodium carbonic acid dioxido(dioxo)chromium Chemical compound C(O)(O)=O.[Cr](=O)(=O)([O-])[O-].[Na+].[Na+] QZJQGEHKLBNSMN-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
238000010828 elution Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910000457 iridium oxide Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000005192 partition Methods 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000007788 roughening Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
229910001427 strontium ion Inorganic materials 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1
LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/22—Inorganic acids
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/28—Per-compounds

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

DD90339430A 1989-04-06 1990-04-04 Verfahren zur herstellung von alkalidichromaten und chromsaeuren durch elektrolyse DD298004A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE3911065A DE3911065A1 (de)	1989-04-06	1989-04-06	Verfahren zur herstellung von alkalidichromaten und chromsaeuren durch elektrolyse

Publications (1)

Publication Number	Publication Date
DD298004A5 true DD298004A5 (de)	1992-01-30

Family

ID=6377951

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD90339430A DD298004A5 (de)	1989-04-06	1990-04-04	Verfahren zur herstellung von alkalidichromaten und chromsaeuren durch elektrolyse

Country Status (15)

Country	Link
US (1)	US5127999A (pl)
EP (1)	EP0391192B1 (pl)
JP (1)	JP2904860B2 (pl)
KR (1)	KR960016417B1 (pl)
AR (1)	AR246559A1 (pl)
BR (1)	BR9001593A (pl)
CA (1)	CA2013782A1 (pl)
DD (1)	DD298004A5 (pl)
DE (2)	DE3911065A1 (pl)
ES (1)	ES2075083T3 (pl)
PL (1)	PL163448B1 (pl)
RO (1)	RO108989B1 (pl)
RU (1)	RU1806221C (pl)
TR (1)	TR26262A (pl)
ZA (1)	ZA902626B (pl)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6063252A (en) *	1997-08-08	2000-05-16	Raymond; John L.	Method and apparatus for enriching the chromium in a chromium plating bath
AUPP521298A0 (en) *	1998-08-12	1998-09-03	Life Therapeutics Limited	Purification of fibrinogen
AUPP790698A0 (en)	1998-12-23	1999-01-28	Life Therapeutics Limited	Separation of microorganisms
US20050224355A1 (en) *	1999-12-23	2005-10-13	Brendon Conlan	Removal of biological contaminants
AUPP790898A0 (en)	1998-12-23	1999-01-28	Life Therapeutics Limited	Renal dialysis
US7077942B1 (en) *	1999-12-23	2006-07-18	Gradipore Limited	Removal of biological contaminants
AUPQ691400A0 (en)	2000-04-14	2000-05-11	Life Therapeutics Limited	Separation of micromolecules
AUPQ697300A0 (en)	2000-04-18	2000-05-11	Life Therapeutics Limited	Separation apparatus
WO2001078877A1 (en)	2000-04-18	2001-10-25	Gradipore Limited	Electrophoresis separation and treatment of samples
US6923896B2 (en) *	2000-09-22	2005-08-02	The Texas A&M University System	Electrophoresis apparatus and method
JP2004510170A (ja) *	2000-10-06	2004-04-02	グラディポア　リミテッド	マルチポート型分離装置および方法
AUPR222300A0 (en) *	2000-12-21	2001-01-25	Life Therapeutics Limited	Electrophoresis device and method
CN107587156B (zh) *	2017-09-07	2019-06-14	中国科学院青海盐湖研究所	利用铬铁制备铬酸酐的方法
JP2022531959A (ja)	2019-05-10	2022-07-12	マテリオンコーポレイション	高強度の銅－ベリリウム合金
CN116715270A (zh) *	2023-06-12	2023-09-08	青海省博鸿化工科技股份有限公司	一种水合氧化铬除去重铬酸钠母液中杂质离子的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3305463A (en) *	1962-03-16	1967-02-21	Pittsburgh Plate Glass Co	Electrolytic production of dichromates
US4273628A (en) *	1979-05-29	1981-06-16	Diamond Shamrock Corp.	Production of chromic acid using two-compartment and three-compartment cells
US4290864A (en) *	1979-05-29	1981-09-22	Diamond Shamrock Corporation	Chromic acid production process using a three-compartment cell

1989
- 1989-04-06 DE DE3911065A patent/DE3911065A1/de not_active Withdrawn
1990
- 1990-03-15 RO RO144465A patent/RO108989B1/ro unknown
- 1990-03-16 TR TR90/0281A patent/TR26262A/xx unknown
- 1990-03-24 ES ES90105661T patent/ES2075083T3/es not_active Expired - Lifetime
- 1990-03-24 EP EP90105661A patent/EP0391192B1/de not_active Expired - Lifetime
- 1990-03-24 DE DE59009265T patent/DE59009265D1/de not_active Expired - Fee Related
- 1990-04-02 JP JP2085086A patent/JP2904860B2/ja not_active Expired - Lifetime
- 1990-04-03 KR KR1019900004549A patent/KR960016417B1/ko not_active Expired - Fee Related
- 1990-04-04 CA CA002013782A patent/CA2013782A1/en not_active Abandoned
- 1990-04-04 DD DD90339430A patent/DD298004A5/de not_active IP Right Cessation
- 1990-04-04 RU SU904743501A patent/RU1806221C/ru active
- 1990-04-05 ZA ZA902626A patent/ZA902626B/xx unknown
- 1990-04-05 PL PL90284642A patent/PL163448B1/pl unknown
- 1990-04-05 BR BR909001593A patent/BR9001593A/pt active Search and Examination
- 1990-04-06 AR AR90316581A patent/AR246559A1/es active
1991
- 1991-06-10 US US07/713,625 patent/US5127999A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
US5127999A (en)	1992-07-07
PL163448B1 (pl)	1994-03-31
EP0391192A2 (de)	1990-10-10
JP2904860B2 (ja)	1999-06-14
DE3911065A1 (de)	1990-10-11
EP0391192B1 (de)	1995-06-21
CA2013782A1 (en)	1990-10-06
EP0391192A3 (de)	1991-12-11
RU1806221C (ru)	1993-03-30
RO108989B1 (ro)	1994-10-31
AR246559A1 (es)	1994-08-31
JPH02285084A (ja)	1990-11-22
DE59009265D1 (de)	1995-07-27
KR960016417B1 (ko)	1996-12-11
ES2075083T3 (es)	1995-10-01
TR26262A (tr)	1995-02-15
BR9001593A (pt)	1991-05-07
KR900016501A (ko)	1990-11-13
ZA902626B (en)	1991-01-30

Legal Events

Date	Code	Title	Description
1995-05-11	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
EP0391192B1 (de)	1995-06-21	Verfahren zur Herstellung von Alkalidichromaten und Chromsäuren durch Elektrolyse
EP0124087B1 (de)	1986-10-15	Verfahren zur Anreicherung von Schwefelsäure
DE4426246A1 (de)	1995-02-23	Verfahren zur gleichzeitigen Herstellung von Alkalimetall- oder Ammoniumperoxodisulfatsalzen und Alkalimetallhydroxid
EP0433748B1 (de)	1993-12-01	Verfahren zur Herstellung von Chromsäure
EP0384194B1 (de)	1994-03-09	Formstabile Anoden und deren Verwendung bei der Herstellung von Alkalidichromaten und Chromsäure
DE2432416A1 (de)	1975-01-30	Verfahren zur gewinnung von elektrolytisch hergestellten alkalichloraten
DD262679A5 (de)	1988-12-07	Verfahren zur entfernung von chrom-vi-ionen aus waessrigen loesungen
DE2124045C3 (de)	1973-11-22	Verfahren zur elektrolytischen Her stellung von reinem Chlor, Wasserstoff und reinen konzentrierten Alkaliphosphat lösungen und Elektrolyslerzelle zur Durch führung des Verfahrens
DE3324945C2 (de)	1986-04-17	Verfahren zur Gewinnung von Wasserstoff und Sauerstoff aus Wasser
DE2845943A1 (de)	1980-04-30	Verfahren zur alkalichlorid-elektrolyse
EP0008470B1 (de)	1982-05-05	Verfahren zur Elektrolyse wässriger Alkalihalogenid-Lösungen
EP0356804B1 (de)	1992-05-20	Verfahren zur Herstellung von Alkalidichromaten und Chromsäure
DE4219758A1 (de)	1993-12-23	Verfahren zur elektrochemischen Herstellung von Dicarbonsäuren
EP0356806B1 (de)	1992-06-24	Verfahren zur Herstellung von Chromsäure
EP0356805B1 (de)	1992-05-20	Verfahren zur Herstellung von Alkalidichromaten und Chromsäure
EP0433750B1 (de)	1993-12-01	Verfahren zur Herstellung von Chromsäure
EP0356802B1 (de)	1992-07-29	Elektrochemisches Verfahren zur Herstellung von Chromsäure
EP1167579B1 (de)	2006-09-27	Chloralkalielektrolyse-Verfahren in Membranzellen unter Elektrolyse von ungereinigtem Siedesalz
EP0356807B1 (de)	1992-05-20	Verfahren zur Herstellung von Alkalidichromaten und Chromsäure
DE3529649A1 (de)	1987-02-19	Verfahren zur anreicherung von schwefelsaeure
DE2701453A1 (de)	1977-09-15	Verfahren zur elektrolytischen oxydation von dialkyldithiocarbamaten zu tetraalkylthiuramdisulfiden
DE19516304C1 (de)	1996-07-25	Verfahren zur Herstellung von Alkaliperoxid-Hydrat
DE3837266A1 (de)	1990-05-10	Verfahren zur herstellung von natriumdichromat
EP3824118A1 (de)	2021-05-26	Verfahren zur leistungsverbesserung von nickelelektroden
CH203740A (de)	1939-03-31	Verfahren zur Herstellung von Mangan auf elektrolytischem Wege.