DD298936A5 - Verfahren zur gasphasenherstellung von elastorneren kopolymeren aus propylen - Google Patents

Verfahren zur gasphasenherstellung von elastorneren kopolymeren aus propylen Download PDF

Info

Publication number: DD298936A5
Authority: DD; German Democratic Republic
Prior art keywords: catalyst; propylene; compound; carrier; prepolymer
Prior art date: 1989-08-29

Application number

DD90343664A

Other languages

German (de)

English (en)

Inventor

Jean Claude

Louis Bordere

Original Assignee

��@��@��@��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-08-29

Filing date

1990-08-27

Publication date

1992-03-19

1990-08-27 Application filed by ��@��@��@��@��k�� filed Critical ��@��@��@��@��k��

1992-03-19 Publication of DD298936A5 publication Critical patent/DD298936A5/de

Links

QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 39
238000000034 method Methods 0.000 title claims abstract description 33
230000008569 process Effects 0.000 title claims abstract description 13
238000004519 manufacturing process Methods 0.000 title claims description 4
229920001971 elastomer Polymers 0.000 title 1
239000000806 elastomer Substances 0.000 title 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 37
229920001577 copolymer Polymers 0.000 claims abstract description 28
238000002360 preparation method Methods 0.000 claims abstract description 27
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 21
239000005977 Ethylene Substances 0.000 claims abstract description 21
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 20
239000004711 α-olefin Substances 0.000 claims abstract description 13
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 10
238000006116 polymerization reaction Methods 0.000 claims abstract description 4
239000011954 Ziegler–Natta catalyst Substances 0.000 claims abstract 4
239000003054 catalyst Substances 0.000 claims description 46
239000000126 substance Substances 0.000 claims description 38
150000001875 compounds Chemical class 0.000 claims description 34
239000010936 titanium Substances 0.000 claims description 32
229910052719 titanium Inorganic materials 0.000 claims description 30
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 29
239000000725 suspension Substances 0.000 claims description 28
238000007334 copolymerization reaction Methods 0.000 claims description 27
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 26
239000007789 gas Substances 0.000 claims description 26
239000007788 liquid Substances 0.000 claims description 20
239000012071 phase Substances 0.000 claims description 19
-1 alkylaluminum halide Chemical class 0.000 claims description 17
239000004215 Carbon black (E152) Substances 0.000 claims description 15
229930195733 hydrocarbon Natural products 0.000 claims description 15
150000002430 hydrocarbons Chemical class 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 15
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 14
235000011147 magnesium chloride Nutrition 0.000 claims description 13
238000009826 distribution Methods 0.000 claims description 10
HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 claims description 10
150000001336 alkenes Chemical class 0.000 claims description 8
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 7
229910052739 hydrogen Inorganic materials 0.000 claims description 7
239000002245 particle Substances 0.000 claims description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
230000004913 activation Effects 0.000 claims description 6
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 5
239000007792 gaseous phase Substances 0.000 claims description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
239000000460 chlorine Substances 0.000 claims description 4
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 4
238000005470 impregnation Methods 0.000 claims description 4
150000002894 organic compounds Chemical class 0.000 claims description 4
229920000642 polymer Polymers 0.000 claims description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
230000003197 catalytic effect Effects 0.000 claims description 2
229910052801 chlorine Inorganic materials 0.000 claims description 2
230000000536 complexating effect Effects 0.000 claims description 2
229920005606 polypropylene copolymer Polymers 0.000 claims description 2
239000002244 precipitate Substances 0.000 claims description 2
239000000047 product Substances 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims 3
150000001412 amines Chemical class 0.000 claims 2
150000002170 ethers Chemical class 0.000 claims 2
150000003003 phosphines Chemical class 0.000 claims 2
150000003457 sulfones Chemical class 0.000 claims 2
150000003462 sulfoxides Chemical class 0.000 claims 2
150000003568 thioethers Chemical class 0.000 claims 2
150000003623 transition metal compounds Chemical class 0.000 claims 2
USSIQXCVUWKGNF-UHFFFAOYSA-N 6-(dimethylamino)-4,4-diphenylheptan-3-one Chemical compound C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 USSIQXCVUWKGNF-UHFFFAOYSA-N 0.000 claims 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
239000002879 Lewis base Substances 0.000 claims 1
240000006240 Linum usitatissimum Species 0.000 claims 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
150000001408 amides Chemical class 0.000 claims 1
XTKDAFGWCDAMPY-UHFFFAOYSA-N azaperone Chemical compound C1=CC(F)=CC=C1C(=O)CCCN1CCN(C=2N=CC=CC=2)CC1 XTKDAFGWCDAMPY-UHFFFAOYSA-N 0.000 claims 1
230000015572 biosynthetic process Effects 0.000 claims 1
WZGKIRHYWDCEKP-UHFFFAOYSA-N cadmium magnesium Chemical compound [Mg].[Cd] WZGKIRHYWDCEKP-UHFFFAOYSA-N 0.000 claims 1
238000012512 characterization method Methods 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 claims 1
125000001309 chloro group Chemical group Cl* 0.000 claims 1
238000009264 composting Methods 0.000 claims 1
150000002013 dioxins Chemical class 0.000 claims 1
229910001882 dioxygen Inorganic materials 0.000 claims 1
229910003480 inorganic solid Inorganic materials 0.000 claims 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
150000007527 lewis bases Chemical class 0.000 claims 1
229910052751 metal Inorganic materials 0.000 claims 1
239000002184 metal Substances 0.000 claims 1
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 claims 1
229930195734 saturated hydrocarbon Natural products 0.000 claims 1
238000003860 storage Methods 0.000 claims 1
238000003786 synthesis reaction Methods 0.000 claims 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
229910052723 transition metal Inorganic materials 0.000 claims 1
150000003624 transition metals Chemical class 0.000 claims 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 87
238000003756 stirring Methods 0.000 description 24
238000006243 chemical reaction Methods 0.000 description 11
239000000843 powder Substances 0.000 description 11
241001178520 Stomatepia mongo Species 0.000 description 8
229910052749 magnesium Inorganic materials 0.000 description 6
239000012299 nitrogen atmosphere Substances 0.000 description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
239000002243 precursor Substances 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
239000012530 fluid Substances 0.000 description 3
229960004279 formaldehyde Drugs 0.000 description 3
235000019256 formaldehyde Nutrition 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
239000008187 granular material Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
239000010959 steel Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 1
BWSQKOKULIALEW-UHFFFAOYSA-N 2-[2-[4-fluoro-3-(trifluoromethyl)phenyl]-3-[2-(piperidin-3-ylamino)pyrimidin-4-yl]imidazol-4-yl]acetonitrile Chemical compound FC1=C(C=C(C=C1)C=1N(C(=CN=1)CC#N)C1=NC(=NC=C1)NC1CNCCC1)C(F)(F)F BWSQKOKULIALEW-UHFFFAOYSA-N 0.000 description 1
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
BPPVUXSMLBXYGG-UHFFFAOYSA-N 4-[3-(4,5-dihydro-1,2-oxazol-3-yl)-2-methyl-4-methylsulfonylbenzoyl]-2-methyl-1h-pyrazol-3-one Chemical compound CC1=C(C(=O)C=2C(N(C)NC=2)=O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 BPPVUXSMLBXYGG-UHFFFAOYSA-N 0.000 description 1
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
238000004438 BET method Methods 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
AIPCVCLDLXEATR-UHFFFAOYSA-N Cl.Cl.Cl.Cl.CC1=CC=CC=C1 Chemical compound Cl.Cl.Cl.Cl.CC1=CC=CC=C1 AIPCVCLDLXEATR-UHFFFAOYSA-N 0.000 description 1
241001091551 Clio Species 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
241000218213 Morus <angiosperm> Species 0.000 description 1
108091034117 Oligonucleotide Proteins 0.000 description 1
241000237502 Ostreidae Species 0.000 description 1
101001012040 Pseudomonas aeruginosa (strain ATCC 15692 / DSM 22644 / CIP 104116 / JCM 14847 / LMG 12228 / 1C / PRS 101 / PAO1) Immunomodulating metalloprotease Proteins 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
240000003768 Solanum lycopersicum Species 0.000 description 1
241000894433 Turbo <genus> Species 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
239000012491 analyte Substances 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
239000001273 butane Substances 0.000 description 1
229960004424 carbon dioxide Drugs 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
241001233037 catfish Species 0.000 description 1
230000008859 change Effects 0.000 description 1
230000001055 chewing effect Effects 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
230000002538 fungal effect Effects 0.000 description 1
230000005021 gait Effects 0.000 description 1
230000005484 gravity Effects 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
RBBOWEDMXHTEPA-UHFFFAOYSA-N hexane;toluene Chemical compound CCCCCC.CC1=CC=CC=C1 RBBOWEDMXHTEPA-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000011835 investigation Methods 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
235000020636 oyster Nutrition 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920005591 polysilicon Polymers 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000012265 solid product Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
230000002477 vacuolizing effect Effects 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Materials For Medical Uses (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Polymerisation Methods In General (AREA)

DD90343664A 1989-08-29 1990-08-27 Verfahren zur gasphasenherstellung von elastorneren kopolymeren aus propylen DD298936A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR8911523A FR2651234B1 (fr)	1989-08-29	1989-08-29	Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite.

Publications (1)

Publication Number	Publication Date
DD298936A5 true DD298936A5 (de)	1992-03-19

Family

ID=9385092

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD90343664A DD298936A5 (de)	1989-08-29	1990-08-27	Verfahren zur gasphasenherstellung von elastorneren kopolymeren aus propylen

Country Status (17)

Country	Link
EP (1)	EP0415588B1 (fr)
JP (1)	JPH0393803A (fr)
KR (1)	KR910004675A (fr)
CN (1)	CN1050199A (fr)
AT (1)	ATE100475T1 (fr)
AU (1)	AU622573B2 (fr)
BR (1)	BR9004245A (fr)
CA (1)	CA2023653A1 (fr)
DD (1)	DD298936A5 (fr)
DE (1)	DE69006141T2 (fr)
ES (1)	ES2062387T3 (fr)
FI (1)	FI904255A7 (fr)
FR (1)	FR2651234B1 (fr)
HU (1)	HUT54715A (fr)
NO (1)	NO175263C (fr)
NZ (1)	NZ235060A (fr)
PL (1)	PL286655A1 (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
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1989
- 1989-08-29 FR FR8911523A patent/FR2651234B1/fr not_active Expired - Fee Related
1990
- 1990-08-10 ES ES90308836T patent/ES2062387T3/es not_active Expired - Lifetime
- 1990-08-10 EP EP90308836A patent/EP0415588B1/fr not_active Expired - Lifetime
- 1990-08-10 DE DE90308836T patent/DE69006141T2/de not_active Expired - Fee Related
- 1990-08-10 AT AT90308836T patent/ATE100475T1/de not_active IP Right Cessation
- 1990-08-20 CA CA002023653A patent/CA2023653A1/fr not_active Abandoned
- 1990-08-24 AU AU61330/90A patent/AU622573B2/en not_active Ceased
- 1990-08-27 NZ NZ235060A patent/NZ235060A/xx unknown
- 1990-08-27 DD DD90343664A patent/DD298936A5/de not_active IP Right Cessation
- 1990-08-28 JP JP2224507A patent/JPH0393803A/ja active Pending
- 1990-08-28 BR BR909004245A patent/BR9004245A/pt unknown
- 1990-08-28 PL PL28665590A patent/PL286655A1/xx unknown
- 1990-08-28 NO NO903763A patent/NO175263C/no unknown
- 1990-08-28 HU HU905509A patent/HUT54715A/hu unknown
- 1990-08-29 KR KR1019900013389A patent/KR910004675A/ko not_active Ceased
- 1990-08-29 FI FI904255A patent/FI904255A7/fi not_active IP Right Cessation
- 1990-08-29 CN CN90107047A patent/CN1050199A/zh active Pending

Also Published As

Publication number	Publication date
EP0415588A1 (fr)	1991-03-06
DE69006141D1 (de)	1994-03-03
NZ235060A (en)	1991-10-25
HUT54715A (en)	1991-03-28
FI904255A7 (fi)	1991-03-01
CN1050199A (zh)	1991-03-27
FR2651234B1 (fr)	1993-03-12
EP0415588B1 (fr)	1994-01-19
AU6133090A (en)	1991-03-07
DE69006141T2 (de)	1994-05-05
NO903763L (no)	1991-03-01
NO903763D0 (no)	1990-08-28
FR2651234A1 (fr)	1991-03-01
JPH0393803A (ja)	1991-04-18
ATE100475T1 (de)	1994-02-15
BR9004245A (pt)	1991-09-03
AU622573B2 (en)	1992-04-09
FI904255A0 (fi)	1990-08-29
ES2062387T3 (es)	1994-12-16
NO175263B (no)	1994-06-13
CA2023653A1 (fr)	1991-03-01
KR910004675A (ko)	1991-03-29
PL286655A1 (fr)	1991-06-17
NO175263C (no)	1994-09-21
HU905509D0 (en)	1991-02-28

Legal Events

Date	Code	Title	Description
1994-01-27	EP	Request for examination under paragraph 12(1) filed
1994-01-27	VZ	Disclaimer of patent (art. 11 and 12 extension act)

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