DE69814874T2 - Verfahren zur abtrennung einer gruppe von 8-10-metall-phosphite-ligarden-komplexen aus einer organischen flüssigkeit - Google Patents

Verfahren zur abtrennung einer gruppe von 8-10-metall-phosphite-ligarden-komplexen aus einer organischen flüssigkeit Download PDF

Info

Publication number: DE69814874T2
Authority: DE; Germany
Prior art keywords: carrier; group; rhodium; organic; phosphite
Prior art date: 1997-08-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE69814874T

Other languages

German (de)

English (en)

Other versions

DE69814874D1 (de

Inventor

Lambertus Nicolaas BROEDERS

Jan Onko GELLING

Franciscus Hendrik MARTENS

Klaas Timmer

Anne Harmen MEINEMA

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

DSM IP Assets BV

EIDP Inc

Original Assignee

DSM IP Assets BV

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-08-08

Filing date

1998-07-29

Publication date

2004-07-29

1998-07-29 Application filed by DSM IP Assets BV, EI Du Pont de Nemours and Co filed Critical DSM IP Assets BV

2003-06-26 Publication of DE69814874D1 publication Critical patent/DE69814874D1/de

2004-07-29 Application granted granted Critical

2004-07-29 Publication of DE69814874T2 publication Critical patent/DE69814874T2/de

2018-07-30 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 58
239000007788 liquid Substances 0.000 title claims description 51
239000010948 rhodium Substances 0.000 claims description 123
239000003446 ligand Substances 0.000 claims description 92
229910052703 rhodium Inorganic materials 0.000 claims description 81
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 81
239000000203 mixture Substances 0.000 claims description 54
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 43
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 42
238000007037 hydroformylation reaction Methods 0.000 claims description 37
125000004432 carbon atom Chemical group C* 0.000 claims description 28
229910052751 metal Inorganic materials 0.000 claims description 26
239000002184 metal Substances 0.000 claims description 26
239000003054 catalyst Substances 0.000 claims description 21
150000001875 compounds Chemical class 0.000 claims description 21
238000009835 boiling Methods 0.000 claims description 16
229910052739 hydrogen Inorganic materials 0.000 claims description 13
239000003960 organic solvent Substances 0.000 claims description 11
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 10
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
238000000926 separation method Methods 0.000 claims description 10
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239000011541 reaction mixture Substances 0.000 claims description 6
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229910000073 phosphorus hydride Inorganic materials 0.000 claims description 5
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BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
UIUWNILCHFBLEQ-UHFFFAOYSA-N pent-3-enoic acid Chemical compound CC=CCC(O)=O UIUWNILCHFBLEQ-UHFFFAOYSA-N 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
125000005538 phosphinite group Chemical group 0.000 description 1
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920002717 polyvinylpyridine Polymers 0.000 description 1
238000003825 pressing Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
230000036633 rest Effects 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
239000004576 sand Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000003107 substituted aryl group Chemical group 0.000 description 1
125000006253 t-butylcarbonyl group Chemical group [H]C([H])([H])C(C(*)=O)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
OJAJJFGMKAZGRZ-UHFFFAOYSA-N trimethyl(phenoxy)silane Chemical compound C[Si](C)(C)OC1=CC=CC=C1 OJAJJFGMKAZGRZ-UHFFFAOYSA-N 0.000 description 1
GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
WXAZIUYTQHYBFW-UHFFFAOYSA-N tris(4-methylphenyl)phosphane Chemical compound C1=CC(C)=CC=C1P(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 WXAZIUYTQHYBFW-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
- B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Carbon And Carbon Compounds (AREA)

DE69814874T 1997-08-08 1998-07-29 Verfahren zur abtrennung einer gruppe von 8-10-metall-phosphite-ligarden-komplexen aus einer organischen flüssigkeit Expired - Fee Related DE69814874T2 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP97202452		1997-08-08
EP97202452A EP0895811A1 (fr)	1997-08-08	1997-08-08	Procédé de séparation d'un complexe à base d'un ligand de type phosphite d'un métal des groupes 8-10 à partir d'un liquide organique
PCT/NL1998/000433 WO1999007469A1 (fr)	1997-08-08	1998-07-29	Procede pour extraire d'un liquide organique un complexe de ligand phosphite et d'un metal des groupes 8 a 10

Publications (2)

Publication Number	Publication Date
DE69814874D1 DE69814874D1 (de)	2003-06-26
DE69814874T2 true DE69814874T2 (de)	2004-07-29

Family

ID=8228629

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE69814874T Expired - Fee Related DE69814874T2 (de)	1997-08-08	1998-07-29	Verfahren zur abtrennung einer gruppe von 8-10-metall-phosphite-ligarden-komplexen aus einer organischen flüssigkeit

Country Status (12)

Country	Link
US (1)	US6455740B1 (fr)
EP (2)	EP0895811A1 (fr)
JP (1)	JP2001513516A (fr)
KR (1)	KR20010022665A (fr)
CN (1)	CN1182917C (fr)
AU (1)	AU8650798A (fr)
CA (1)	CA2299321A1 (fr)
DE (1)	DE69814874T2 (fr)
ID (1)	ID24242A (fr)
MY (1)	MY117140A (fr)
TW (1)	TW518336B (fr)
WO (1)	WO1999007469A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1172143A1 (fr) *	2000-07-14	2002-01-16	Dsm N.V.	Procédé de récupération de rhodium
JP2007044568A (ja) *	2005-08-05	2007-02-22	Mitsubishi Chemicals Corp	遷移金属の除去方法
DE102009001230A1 (de) *	2009-02-27	2010-09-02	Evonik Oxeno Gmbh	Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
ES2624430T3 (es) *	2013-02-11	2017-07-14	Linde Ag	Método de purificación de un compuesto crudo de PNPNH
US20220143590A1 (en) *	2019-06-27	2022-05-12	Dow Technology Investments Llc	Process to prepare solution from hydroformylation process for precious metal recovery

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Publication number	Priority date	Publication date	Assignee	Title
EP0186409A3 (fr) *	1984-12-21	1988-01-20	Merck & Co. Inc.	Récupération d'un catalyseur homogène
US4748261A (en)	1985-09-05	1988-05-31	Union Carbide Corporation	Bis-phosphite compounds
US4668651A (en)	1985-09-05	1987-05-26	Union Carbide Corporation	Transition metal complex catalyzed processes
US4743572A (en) *	1986-12-05	1988-05-10	Mobil Oil Corporation	Magnesia-alumina-aluminum phosphate catalyst and catalyst product thereof
US5114473A (en)	1988-08-25	1992-05-19	Union Carbide Chemicals And Plastics Technology Corporation	Transition metal recovery
TW213465B (fr)	1991-06-11	1993-09-21	Mitsubishi Chemicals Co Ltd
DE4204808A1 (de)	1992-02-18	1993-08-19	Basf Ag	Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
US5208194A (en) *	1992-02-25	1993-05-04	Arco Chemical Technology, L.P.	Recovery of group VIII transition metals from organic solutions using acidic ion-exchange resins
BE1007944A3 (nl)	1993-12-30	1995-11-21	Dsm Nv	Werkwijze voor de bereiding van 5-formylvaleriaanzuur en -ester.
EP0712828A1 (fr)	1994-11-17	1996-05-22	Dsm N.V.	Procédé pour la préparation d'un aldéhyde
IT1286618B1 (it)	1996-05-03	1998-07-15	Lapa Services S R L	Dispositivo per il comando dell'alimentazione di acqua (od altro liquido) mediante pompa e per la protezione della stessa in caso di

1997
- 1997-08-08 EP EP97202452A patent/EP0895811A1/fr not_active Withdrawn
- 1997-11-26 TW TW086117800A patent/TW518336B/zh not_active IP Right Cessation
1998
- 1998-07-29 JP JP2000507049A patent/JP2001513516A/ja active Pending
- 1998-07-29 EP EP98937864A patent/EP1007209B1/fr not_active Expired - Lifetime
- 1998-07-29 KR KR1020007001260A patent/KR20010022665A/ko not_active Abandoned
- 1998-07-29 AU AU86507/98A patent/AU8650798A/en not_active Abandoned
- 1998-07-29 WO PCT/NL1998/000433 patent/WO1999007469A1/fr not_active Ceased
- 1998-07-29 DE DE69814874T patent/DE69814874T2/de not_active Expired - Fee Related
- 1998-07-29 CN CNB988081032A patent/CN1182917C/zh not_active Expired - Fee Related
- 1998-07-29 CA CA002299321A patent/CA2299321A1/fr not_active Abandoned
- 1998-07-29 ID IDW20000231A patent/ID24242A/id unknown
- 1998-08-06 MY MYPI98003590A patent/MY117140A/en unknown
2000
- 2000-02-08 US US09/500,083 patent/US6455740B1/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CN1182917C (zh)	2005-01-05
AU8650798A (en)	1999-03-01
TW518336B (en)	2003-01-21
DE69814874D1 (de)	2003-06-26
CN1266381A (zh)	2000-09-13
JP2001513516A (ja)	2001-09-04
WO1999007469A1 (fr)	1999-02-18
CA2299321A1 (fr)	1999-02-18
EP0895811A1 (fr)	1999-02-10
US6455740B1 (en)	2002-09-24
EP1007209B1 (fr)	2003-05-21
KR20010022665A (ko)	2001-03-26
MY117140A (en)	2004-05-31
EP1007209A1 (fr)	2000-06-14
ID24242A (id)	2000-07-13

Legal Events

Date

Code

Title

Description

2004-05-13

8327

Change in the person/name/address of the patent owner

Owner name: DSM IP ASSETS B.V., HEERLEN, NL

Owner name: E.I. DU PONT DE NEMOURS AND CO., WILMINGTON, DEL.,

2004-06-17

8364

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2007-05-16

8339

Ceased/non-payment of the annual fee

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DE69916560T2 (de)	2005-04-14	Verfahren zur Herstellung von Aldehyden
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