DK0712833T3 - Fremgangsmåde til fremstilling af 2-phenoxymethylbenzoesyrer - Google Patents

Fremgangsmåde til fremstilling af 2-phenoxymethylbenzoesyrer

Info

Publication number: DK0712833T3
Authority: DK; Denmark
Prior art keywords: converted; image; general formula; compound; keto
Prior art date: 1990-12-31

Application number

DK96101038.6T

Other languages

English (en)

Inventor

Hubert Dr Sauter

Horst Dr Wingert

Remy Dr Benoit

Wassilios Dr Grammenos

Bernd Dr Wolf

Michael Dr Hepp

Thomas Dr Kuekenhoehner

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-12-31

Filing date

1991-12-10

Publication date

1997-10-06

1990-12-31 Priority claimed from DE4042283A external-priority patent/DE4042283A1/de

1990-12-31 Priority claimed from DE4042282A external-priority patent/DE4042282A1/de

1990-12-31 Priority claimed from DE4042271A external-priority patent/DE4042271A1/de

1990-12-31 Priority claimed from DE4042272A external-priority patent/DE4042272A1/de

1990-12-31 Priority claimed from DE4042280A external-priority patent/DE4042280A1/de

1990-12-31 Priority claimed from DE4042273A external-priority patent/DE4042273A1/de

1991-12-10 Application filed by Basf Ag filed Critical Basf Ag

1997-10-06 Application granted granted Critical

1997-10-06 Publication of DK0712833T3 publication Critical patent/DK0712833T3/da

Links

YKNORODREYVARM-UHFFFAOYSA-N 2-(phenoxymethyl)benzoic acid Chemical class OC(=O)C1=CC=CC=C1COC1=CC=CC=C1 YKNORODREYVARM-UHFFFAOYSA-N 0.000 title abstract 2
150000001875 compounds Chemical class 0.000 abstract 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
FKLJPTJMIBLJAV-UHFFFAOYSA-N Compound IV Chemical compound O1N=C(C)C=C1CCCCCCCOC1=CC=C(C=2OCCN=2)C=C1 FKLJPTJMIBLJAV-UHFFFAOYSA-N 0.000 abstract 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
150000004716 alpha keto acids Chemical class 0.000 abstract 1
GJQBHOAJJGIPRH-UHFFFAOYSA-N benzoyl cyanide Chemical compound N#CC(=O)C1=CC=CC=C1 GJQBHOAJJGIPRH-UHFFFAOYSA-N 0.000 abstract 1
150000002148 esters Chemical class 0.000 abstract 1
229910052736 halogen Inorganic materials 0.000 abstract 1
150000002367 halogens Chemical class 0.000 abstract 1
150000002596 lactones Chemical class 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 abstract 1
229940031826 phenolate Drugs 0.000 abstract 1
FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical class OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 abstract 1
125000001424 substituent group Chemical group 0.000 abstract 1
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/24—Sulfones; Sulfoxides having sulfone or sulfoxide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
- C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C235/32—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton containing six-membered aromatic rings
- C07C235/34—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton containing six-membered aromatic rings having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/08—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reaction of hydroxylamines with carbonyl compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/14—Preparation of carboxylic acid nitriles by reaction of cyanides with halogen-containing compounds with replacement of halogen atoms by cyano groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/17—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and doubly-bound oxygen atoms bound to the same acyclic carbon skeleton
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
- C07C65/24—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups polycyclic
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Toxicology (AREA)
Health & Medical Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Saccharide Compounds (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

DK96101038.6T 1990-12-31 1991-12-10 Fremgangsmåde til fremstilling af 2-phenoxymethylbenzoesyrer DK0712833T3 (da)

Applications Claiming Priority (6)

Application Number	Priority Date	Filing Date	Title
DE4042283A DE4042283A1 (de)	1990-12-31	1990-12-31	Verfahren zur herstellung von 2-phenoxymethylbenzoesaeuren
DE4042282A DE4042282A1 (de)	1990-12-31	1990-12-31	O-substituierte benzoylcyanide
DE4042271A DE4042271A1 (de)	1990-12-31	1990-12-31	Verfahren zur herstellung von arylglyoxylsaeureestern
DE4042272A DE4042272A1 (de)	1990-12-31	1990-12-31	Verfahren zur herstellung von e-oximethern von phenylglyoxylsaeureestern
DE4042280A DE4042280A1 (de)	1990-12-31	1990-12-31	Verfahren zur herstellung von (alpha)-ketocarbonsaeureestern
DE4042273A DE4042273A1 (de)	1990-12-31	1990-12-31	Verfahren zur herstellung von (alpha)-ketocarbonsaeureestern

Publications (1)

Publication Number	Publication Date
DK0712833T3 true DK0712833T3 (da)	1997-10-06

Family

ID=27544603

Family Applications (4)

Application Number	Title	Priority Date	Filing Date
DK96101025.3T DK0712835T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af alfa-ketocarboxylsyreestere
DK96101038.6T DK0712833T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af 2-phenoxymethylbenzoesyrer
DK91121148.0T DK0493711T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af E-oximethere af phenylglyoxylsyreestere
DK96101039.4T DK0718279T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af o-substituerede benzoylcyanider

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
DK96101025.3T DK0712835T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af alfa-ketocarboxylsyreestere

Family Applications After (2)

Application Number	Title	Priority Date	Filing Date
DK91121148.0T DK0493711T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af E-oximethere af phenylglyoxylsyreestere
DK96101039.4T DK0718279T3 (da)	1990-12-31	1991-12-10	Fremgangsmåde til fremstilling af o-substituerede benzoylcyanider

Country Status (13)

Country	Link
US (1)	US5221762A (da)
EP (4)	EP0712833B1 (da)
JP (3)	JP3343263B2 (da)
KR (1)	KR100214191B1 (da)
AT (4)	ATE143356T1 (da)
AU (1)	AU641579B2 (da)
CA (2)	CA2367876C (da)
DE (4)	DE59108861D1 (da)
DK (4)	DK0712835T3 (da)
ES (4)	ES2105903T3 (da)
GR (4)	GR3021280T3 (da)
HU (1)	HU209283B (da)
IL (5)	IL116443A (da)

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US5258551A (en) *	1991-12-18	1993-11-02	Shionogi & Co., Ltd.	Process for producing α-ketoamide derivative
DE4203170A1 (de)	1992-02-05	1993-08-12	Basf Ag	Verfahren zur herstellung von e-oximethern von phenylglyoxylsaeureestern
DE4311722C1 (de) *	1993-04-08	1994-04-07	Basf Ag	Verfahren zur Herstellung von Halogenmethyl-benzoylcyaniden und neue Halogenmethyl-benzoylcyanide
DE4320499A1 (de) *	1993-05-14	1994-11-17	Bayer Ag	Verfahren zur Herstellung von 2-Oximinoessigsäurederivaten
US5510506A (en) *	1993-07-02	1996-04-23	Shionogi & Co., Ltd.	Process for producing carboxylic acid derivatives
CN1082503C (zh) *	1994-06-10	2002-04-10	巴斯福股份公司	α－甲氧基亚氨基羧酸的甲基酰胺的制备方法及其中间体
PT793642E (pt) *	1994-11-24	2000-06-30	Basf Ag	Processo para a preparacao de cianetos de halogenometil-benzoilo
DE4442560A1 (de) *	1994-11-30	1996-06-05	Basf Ag	Iminooxybenzylcrotonsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19648009A1 (de)	1996-11-20	1998-05-28	Bayer Ag	Glyoxylsäureamide
CZ184599A3 (cs) *	1996-11-26	1999-09-15	E. I. Du Pont De Nemours And Company	Methylem substituované fungicidy a artropodicidy
DE19726201A1 (de)	1997-06-20	1998-12-24	Bayer Ag	Glyoxylsäureamide
DE19848200A1 (de) *	1998-10-20	2000-04-27	Basf Ag	Verfahren zur Trocknung von Phenoxymethylbenzoesäuren
DE19958165A1 (de)	1999-12-02	2001-06-07	Bayer Ag	Glyoxylsäureamide
US7238835B2 (en) *	2003-12-22	2007-07-03	Sanofi-Aventis Deutschland Gmbh	Process for the preparation of substituted 2-(phenoxymethyl) benzoic acids
US20070054948A1 (en) *	2004-09-02	2007-03-08	Lilach Hedvati	Purification of olmesartan medoxomil
WO2006029057A1 (en) *	2004-09-02	2006-03-16	Teva Pharmaceutical Industries, Ltd.	Purification of olmesartan medoxomil
CN100443463C (zh) *	2005-06-28	2008-12-17	沈阳化工研究院	取代的对三氟甲基苯醚类化合物及其制备与应用
JP5417860B2 (ja) *	2008-08-26	2014-02-19	住友化学株式会社	α−ヒドロキシエステル類の製造方法
JP2012516868A (ja)	2009-02-05	2012-07-26	ビーエーエスエフソシエタス・ヨーロピア	２−ハロゲノメチルフェニル酢酸誘導体の製造方法
CN101664031B (zh) *	2009-09-30	2012-09-05	南宁市德丰富化工有限责任公司	一种含醚菌酯和春雷霉素的杀菌组合物
CN102391121B (zh) *	2011-08-04	2014-06-18	京博农化科技股份有限公司	2-（2-甲基苯氧基）-亚甲基苯基乙醛酸甲酯的制备方法
WO2013144924A1 (en)	2012-03-29	2013-10-03	Rallis India Ltd.	An improved process for the synthesis of strobilurin fungicides viz trifloxystrobin and kresoxim-methyl
CN103787916B (zh) *	2014-01-15	2016-07-13	京博农化科技股份有限公司	一种肟菌酯的制备方法
CN104529818A (zh) *	2014-12-16	2015-04-22	江苏耕耘化学有限公司	制备(e)-2-(2-取代苯基)-2-甲氧亚胺基乙酸衍生物的方法
CN105884651B (zh) *	2016-04-25	2019-04-12	山东理工大学	一种醚菌酯中间体的制备装置及方法
CN109651190B (zh) *	2018-12-28	2026-04-21	山东京博农化科技股份有限公司	一种醚菌酯的合成方法
CN113754527B (zh) *	2021-09-07	2024-01-12	山东京博农化科技股份有限公司	一种醚菌酯中间体的合成方法
CN114478241A (zh) *	2021-12-31	2022-05-13	山东京博生物科技有限公司	一种芳甲酰基甲酸酯的制备方法

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DE3002203A1 (de)	1980-01-22	1981-07-23	Bayer Ag, 5090 Leverkusen	Verfahren zur herstellung von (alpha)-ketocarbonsaeure-n-tert.-butylamiden
DE3009044A1 (de)	1980-03-08	1981-09-24	Bayer Ag, 5090 Leverkusen	Verfahren zur herstellung von (alpha)-ketocarbon-n-acylamiden
DE3623921A1 (de) *	1986-07-16	1988-01-21	Basf Ag	Oximether und diese enthaltende fungizide
GB8617648D0 (en)	1986-07-18	1986-08-28	Ici Plc	Fungicides
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JPH02306934A (ja) *	1989-05-19	1990-12-20	Mitsubishi Petrochem Co Ltd	４―（アルキルフェノキシ）酪酸の製造方法
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FR2647109B1 (fr) *	1989-05-19	1991-07-26	Atochem	Procede de preparation de cyanures d'acyle en milieu anhydre
DE3917352A1 (de) *	1989-05-27	1990-11-29	Basf Ag	Neue oximether und diese enthaltende fungizide

1991
- 1991-12-10 EP EP96101038A patent/EP0712833B1/de not_active Expired - Lifetime
- 1991-12-10 AT AT91121148T patent/ATE143356T1/de not_active IP Right Cessation
- 1991-12-10 AT AT96101039T patent/ATE158569T1/de not_active IP Right Cessation
- 1991-12-10 DK DK96101025.3T patent/DK0712835T3/da active
- 1991-12-10 DE DE59108861T patent/DE59108861D1/de not_active Expired - Lifetime
- 1991-12-10 EP EP91121148A patent/EP0493711B1/de not_active Expired - Lifetime
- 1991-12-10 ES ES96101025T patent/ES2105903T3/es not_active Expired - Lifetime
- 1991-12-10 EP EP96101025A patent/EP0712835B1/de not_active Expired - Lifetime
- 1991-12-10 ES ES91121148T patent/ES2091278T3/es not_active Expired - Lifetime
- 1991-12-10 EP EP96101039A patent/EP0718279B1/de not_active Expired - Lifetime
- 1991-12-10 ES ES96101039T patent/ES2107923T3/es not_active Expired - Lifetime
- 1991-12-10 AT AT96101025T patent/ATE157079T1/de not_active IP Right Cessation
- 1991-12-10 DE DE59108832T patent/DE59108832D1/de not_active Expired - Lifetime
- 1991-12-10 ES ES96101038T patent/ES2105904T3/es not_active Expired - Lifetime
- 1991-12-10 DK DK96101038.6T patent/DK0712833T3/da active
- 1991-12-10 AT AT96101038T patent/ATE157643T1/de not_active IP Right Cessation
- 1991-12-10 DK DK91121148.0T patent/DK0493711T3/da active
- 1991-12-10 DK DK96101039.4T patent/DK0718279T3/da active
- 1991-12-10 DE DE59108848T patent/DE59108848D1/de not_active Expired - Lifetime
- 1991-12-10 DE DE59108229T patent/DE59108229D1/de not_active Expired - Lifetime
- 1991-12-13 US US07/806,295 patent/US5221762A/en not_active Expired - Lifetime
- 1991-12-16 IL IL116443A patent/IL116443A/xx not_active IP Right Cessation
- 1991-12-16 IL IL116442A patent/IL116442A/xx not_active IP Right Cessation
- 1991-12-16 IL IL100387A patent/IL100387A/xx not_active IP Right Cessation
- 1991-12-20 JP JP33812791A patent/JP3343263B2/ja not_active Expired - Fee Related
- 1991-12-24 AU AU90082/91A patent/AU641579B2/en not_active Expired
- 1991-12-30 KR KR1019910025541A patent/KR100214191B1/ko not_active Expired - Lifetime
- 1991-12-30 CA CA002367876A patent/CA2367876C/en not_active Expired - Lifetime
- 1991-12-30 CA CA002058553A patent/CA2058553C/en not_active Expired - Lifetime
- 1991-12-30 HU HU914162A patent/HU209283B/hu unknown
1995
- 1995-12-19 IL IL11644395A patent/IL116443A0/xx unknown
- 1995-12-19 IL IL11644295A patent/IL116442A0/xx unknown
1996
- 1996-10-09 GR GR960402642T patent/GR3021280T3/el unknown
1997
- 1997-08-22 GR GR970402161T patent/GR3024518T3/el unknown
- 1997-10-29 GR GR970402856T patent/GR3025219T3/el unknown
- 1997-11-12 GR GR970403012T patent/GR3025370T3/el unknown
2000
- 2000-04-03 JP JP2000100964A patent/JP3378555B2/ja not_active Expired - Fee Related
2002
- 2002-04-18 JP JP2002116019A patent/JP3378576B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DK0718279T3 (da)	1997-10-27
ES2105904T3 (es)	1997-10-16
JP2002356468A (ja)	2002-12-13
GR3025370T3 (en)	1998-02-27
JP2000256273A (ja)	2000-09-19
EP0712833B1 (de)	1997-09-03
IL116443A0 (en)	1996-03-31
DE59108832D1 (de)	1997-09-25
EP0712833A2 (de)	1996-05-22
DE59108229D1 (de)	1996-10-31
JP3378555B2 (ja)	2003-02-17
US5221762A (en)	1993-06-22
DK0712835T3 (da)	1997-09-15
HU209283B (en)	1994-04-28
CA2058553A1 (en)	1992-07-01
ES2107923T3 (es)	1997-12-01
GR3025219T3 (en)	1998-02-27
EP0712835A3 (da)	1996-06-05
EP0718279B1 (de)	1997-09-24
DE59108848D1 (de)	1997-10-09
ATE143356T1 (de)	1996-10-15
GR3024518T3 (en)	1997-11-28
ATE157079T1 (de)	1997-09-15
IL116442A0 (en)	1996-03-31
CA2367876C (en)	2006-10-24
KR920012013A (ko)	1992-07-25
CA2367876A1 (en)	1992-07-01
ATE158569T1 (de)	1997-10-15
IL100387A0 (en)	1992-09-06
JP3378576B2 (ja)	2003-02-17
EP0493711B1 (de)	1996-09-25
EP0712835B1 (de)	1997-08-20
EP0712835A2 (de)	1996-05-22
EP0712833A3 (da)	1996-06-05
EP0718279A1 (de)	1996-06-26
IL100387A (en)	1997-06-10
DE59108861D1 (de)	1997-10-30
HUT61264A (en)	1992-12-28
DK0493711T3 (da)	1996-11-11
ES2091278T3 (es)	1996-11-01
GR3021280T3 (en)	1997-01-31
ES2105903T3 (es)	1997-10-16
HU914162D0 (en)	1992-03-30
EP0493711A1 (de)	1992-07-08
JPH04295454A (ja)	1992-10-20
KR100214191B1 (ko)	1999-08-02
AU9008291A (en)	1992-07-02
AU641579B2 (en)	1993-09-23
IL116443A (en)	1997-06-10
IL116442A (en)	1997-06-10
CA2058553C (en)	2005-09-13
ATE157643T1 (de)	1997-09-15
JP3343263B2 (ja)	2002-11-11

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JPS5782392A (en)	1982-05-22	Preparation of 7-aminocephem compound
DE2960733D1 (en)	1981-11-26	Process for the preparation of 3-substituted cyclo-propane-1-carboxylic acids and products obtained
JPS5392771A (en)	1978-08-15	2-(1h-tetrazole-1-yl)-3-hydroxypropionic acids and process for their preparation
JPS54125687A (en)	1979-09-29	Pirazine derivative and its preparation