DK0804380T3 - Fremgangsmåde og katalysator til katalytisk oxidation til svovl af H2S indeholdt i lav koncentration i en gas - Google Patents
Fremgangsmåde og katalysator til katalytisk oxidation til svovl af H2S indeholdt i lav koncentration i en gasInfo
- Publication number
- DK0804380T3 DK0804380T3 DK95940334T DK95940334T DK0804380T3 DK 0804380 T3 DK0804380 T3 DK 0804380T3 DK 95940334 T DK95940334 T DK 95940334T DK 95940334 T DK95940334 T DK 95940334T DK 0804380 T3 DK0804380 T3 DK 0804380T3
- Authority
- DK
- Denmark
- Prior art keywords
- catalyst
- sulphur
- gas
- pct
- oxidation
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 6
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- 239000005864 Sulphur Substances 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 4
- 230000001590 oxidative effect Effects 0.000 abstract 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 2
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical group 0.000 abstract 2
- 230000004913 activation Effects 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
- B01J27/224—Silicon carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
- C01B17/0465—Catalyst compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/515—Specific contaminant removal
- Y10S502/517—Sulfur or sulfur compound removal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9413752A FR2727101B1 (fr) | 1994-11-17 | 1994-11-17 | Procede pour oxyder directement en soufre par voie catalytique l'h2s contenu en faible concentration dans un gaz et catalyseur pour la mise en oeuvre de ce procede |
| PCT/FR1995/001524 WO1997019019A1 (fr) | 1994-11-17 | 1995-11-20 | Procede et catalyseur pour oxyder en soufre par voie catalytique l'h2s contenu en faible concentration dans un gaz |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0804380T3 true DK0804380T3 (da) | 2003-06-02 |
Family
ID=26231540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK95940334T DK0804380T3 (da) | 1994-11-17 | 1995-11-20 | Fremgangsmåde og katalysator til katalytisk oxidation til svovl af H2S indeholdt i lav koncentration i en gas |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6083471A (da) |
| EP (1) | EP0804380B1 (da) |
| JP (1) | JP3519740B2 (da) |
| AT (1) | ATE232507T1 (da) |
| CA (1) | CA2211800C (da) |
| DE (1) | DE69529625T2 (da) |
| DK (1) | DK0804380T3 (da) |
| ES (1) | ES2188678T3 (da) |
| FR (1) | FR2727101B1 (da) |
| NO (1) | NO973278D0 (da) |
| PT (1) | PT804380E (da) |
| RU (1) | RU2142405C1 (da) |
| WO (1) | WO1997019019A1 (da) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2773085B1 (fr) * | 1997-12-29 | 2000-02-18 | Elf Exploration Prod | Procede catalytique pour oxyder directement en soufre, a basse temperature, l'h2s contenu en faible concentration dans un gaz et catalyseur pour sa mise en oeuvre |
| FR2783818B1 (fr) * | 1998-09-24 | 2000-11-10 | Elf Exploration Prod | Procede pour oxyder directement en soufre, par voie catalytique et en phase vapeur, l'h2s contenu a faible teneur dans un gaz |
| US6946111B2 (en) | 1999-07-30 | 2005-09-20 | Conocophilips Company | Short contact time catalytic partial oxidation process for recovering sulfur from an H2S containing gas stream |
| US6579510B2 (en) | 1999-07-30 | 2003-06-17 | Alfred E. Keller | SPOX-enhanced process for production of synthesis gas |
| US6403051B1 (en) * | 1999-07-30 | 2002-06-11 | Conoco Inc. | Recovery of sulfur from H2S and concurrent production of H2 using short contact time CPOX |
| US6800269B2 (en) * | 1999-07-30 | 2004-10-05 | Conocophillips Company | Short contact time catalytic sulfur recovery system for removing H2S from a waste gas stream |
| US7122170B2 (en) * | 2000-07-25 | 2006-10-17 | Conocophillips Company | Catalysts for SPOC™ enhanced synthesis gas production |
| WO2002058822A1 (en) | 2000-12-18 | 2002-08-01 | Conoco Inc. | Short contact time catalytic sulfur recovery system for removing h2s from a waste gas stream |
| US7326397B2 (en) | 2000-12-18 | 2008-02-05 | Conocophillips Company | Catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream |
| WO2002057002A1 (en) * | 2000-12-18 | 2002-07-25 | Conoco Inc. | Sulfur recovery process |
| US7357908B2 (en) | 2000-12-18 | 2008-04-15 | Conocophillips Company | Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream |
| US8158843B2 (en) * | 2002-02-12 | 2012-04-17 | The Penn State Research Foundation | Deep desulfurization of hydrocarbon fuels |
| EP1447124A1 (en) * | 2003-02-04 | 2004-08-18 | Gastec N.V. | Supported catalyst system for removing sulfur compounds from gases |
| US7108842B2 (en) * | 2004-01-15 | 2006-09-19 | Conocophillips Company | Process for the catalytic partial oxidation of H2S using staged addition of oxygen |
| RU2288888C1 (ru) * | 2005-03-05 | 2006-12-10 | Открытое акционерное общество "Катализатор" | Катализатор для селективного окисления сероводорода, способ его получения и способ селективного окисления сероводорода до элементарной серы |
| DE102005022164B4 (de) * | 2005-05-13 | 2009-08-06 | Lurgi Gmbh | Vorrichtung und Verfahren zum Betrieb der Vorrichtung zur kontinuierlichen Rückgewinnung von Schwefel aus H2S enthaltendem Gas |
| US7226572B1 (en) | 2006-03-03 | 2007-06-05 | Conocophillips Company | Compact sulfur recovery plant and process |
| TW200800387A (en) * | 2006-06-01 | 2008-01-01 | Ritek Corp | Catalyst for catalyzing carbon nanotubes growth |
| US7501111B2 (en) | 2006-08-25 | 2009-03-10 | Conoco Phillips Company | Increased capacity sulfur recovery plant and process for recovering elemental sulfur |
| RU2414298C2 (ru) * | 2008-07-11 | 2011-03-20 | Учреждение Российской Академии Наук Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В. Топчиева Ран (Инхс Ран) | Катализатор и способ глубокой очистки газовых смесей от сероводорода в его присутствии |
| RU2405738C2 (ru) * | 2008-10-16 | 2010-12-10 | Общество с ограниченной ответственностью "Старт-Катализатор" | Способ получения серы и способ приготовления катализатора для получения серы |
| US20100240135A1 (en) * | 2009-03-19 | 2010-09-23 | Seeger David M | System and method for sour gas well testing |
| RU2398735C1 (ru) * | 2009-05-29 | 2010-09-10 | Ирина Геннадиевна Тарханова | Способ очистки газовых потоков от сероводорода |
| CN117985836A (zh) * | 2022-10-28 | 2024-05-07 | 中国石油化工股份有限公司 | 一种用于含硫污水的脱硫系统及方法 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US42898A (en) * | 1864-05-24 | William cleland | ||
| DE129037C (da) * | ||||
| US2386390A (en) * | 1941-12-01 | 1945-10-09 | Willis C Fernelius | Apparatus for extracting sulphur from gases |
| US4054642A (en) * | 1973-08-30 | 1977-10-18 | Rhone-Poulenc Industries | Process for the treatment of gases containing various derivatives of sulphur |
| FR2277877A1 (fr) * | 1974-07-11 | 1976-02-06 | Aquitaine Petrole | Procede de desulfuration des gaz contenant de l'hydrogene sulfure |
| US4311683A (en) * | 1976-06-28 | 1982-01-19 | Union Oil Company Of California | Process for removal of hydrogen sulfide from gas streams |
| DD129037B1 (de) * | 1976-11-18 | 1980-05-28 | Rudolf Haase | Verfahren zur herstellung von vanadinkatalysatoren |
| FR2511663A1 (fr) * | 1981-08-19 | 1983-02-25 | Elf Aquitaine | Procede catalytique de production de soufre a partir d'un gaz renfermant h2s |
| DE3143400A1 (de) * | 1981-11-02 | 1983-06-01 | Mobil Oil Corp., 10017 New York, N.Y. | Verfahren zur verringerung des schwefelgehaltes in gasstroemen unter gewinnung von elementarem schwefel |
| FR2518424B1 (fr) * | 1981-12-17 | 1988-03-11 | Elf Aquitaine | Procede de desulfuration catalytique d'un gaz acide renfermant h2s, et eventuellement une quantite globale d'au plus 3 % en volume de cs2 et/ou cos |
| JPS58150438A (ja) * | 1982-03-02 | 1983-09-07 | Ube Ind Ltd | インド−ル類製造用触媒の再生法 |
| FR2540092B1 (fr) * | 1983-01-31 | 1986-02-21 | Elf Aquitaine | Procede catalytique de production de soufre a partir d'un gaz renfermant h2s |
| GB8318098D0 (en) * | 1983-07-04 | 1983-08-03 | Shell Int Research | Oxidation of hydrogen sulphide to elemental sulphur |
| DE3332563A1 (de) * | 1983-09-09 | 1985-03-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur entschwefelung von h(pfeil abwaerts)2(pfeil abwaerts)s-haltigen gasen |
| FR2589141B1 (fr) * | 1985-10-25 | 1987-12-11 | Elf Aquitaine | Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre |
| FR2589140B1 (fr) * | 1985-10-25 | 1991-02-22 | Elf Aquitaine | Procede catalytique de production de soufre a partir d'un gaz acide renfermant de l'h2s |
| FR2589082B1 (fr) * | 1985-10-25 | 1989-12-01 | Elf Aquitaine | Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre |
| US4914070A (en) * | 1987-10-19 | 1990-04-03 | Pechiney Electrometallurgie | Process for the production of silicon carbide with a large specific surface area and use for high-temperature catalytic reactions |
| FR2652759B1 (fr) * | 1989-10-09 | 1994-02-25 | Rhone Poulenc Chimie | Catalyseurs pour le traitement des effluents gazeux et procede de traitement de ces effluents. |
| FR2657603B1 (fr) * | 1990-01-29 | 1993-07-09 | Pechiney Electrometallurgie | Procede d'obtention de corps solides poreux a base de carbure refractaire a l'aide de composes organiques et de metal ou metallouide. |
| FR2675713B1 (fr) * | 1991-04-29 | 1993-07-02 | Pechiney Electrometallurgie | Systeme catalytique, notamment pour la postcombustion de gaz d'echappement et procede pour le fabriquer. |
| FR2684091B1 (fr) * | 1991-11-21 | 1994-02-25 | Pechiney Recherche | Procede de fabrication de carbures metalliques a grande surface specifique sous balayage de gaz inerte a pression atmospherique. |
| FR2684092B1 (fr) * | 1991-11-21 | 1994-03-04 | Pechiney Recherche | Procede de preparation de carbures metalliques a grande surface specifique a partir de mousses de carbone activees. |
| FR2702673B1 (fr) * | 1993-03-16 | 1995-04-28 | Elf Aquitaine | Procédé d'élimination de l'H2S contenu dans un gaz en concentration inférieure à 5 % en volume avec récupération de cet H2S sous la forme de soufre. |
| FR2702674B1 (fr) * | 1993-03-16 | 1995-04-28 | Elf Aquitaine | Procédé d'élimination des composés soufrés contenus dans un gaz résiduaire du type gaz résiduaire d'usine à soufre Claus, avec récupération desdits composés sous la forme de soufre. |
| FR2702675B1 (fr) * | 1993-03-16 | 1995-04-28 | Elf Aquitaine | Procédé pour oxyder directement en soufre par voie catalytique, avec une sélectivité élevée, l'H2S contenu en faible concentration dans un gaz et catalyseur pour la mise en Óoeuvre de ce procédé. |
-
1994
- 1994-11-17 FR FR9413752A patent/FR2727101B1/fr not_active Expired - Fee Related
-
1995
- 1995-11-20 DK DK95940334T patent/DK0804380T3/da active
- 1995-11-20 EP EP95940334A patent/EP0804380B1/fr not_active Expired - Lifetime
- 1995-11-20 AT AT95940334T patent/ATE232507T1/de not_active IP Right Cessation
- 1995-11-20 RU RU97113720A patent/RU2142405C1/ru active
- 1995-11-20 CA CA002211800A patent/CA2211800C/fr not_active Expired - Lifetime
- 1995-11-20 PT PT95940334T patent/PT804380E/pt unknown
- 1995-11-20 ES ES95940334T patent/ES2188678T3/es not_active Expired - Lifetime
- 1995-11-20 US US08/875,703 patent/US6083471A/en not_active Expired - Lifetime
- 1995-11-20 DE DE69529625T patent/DE69529625T2/de not_active Expired - Lifetime
- 1995-11-20 WO PCT/FR1995/001524 patent/WO1997019019A1/fr not_active Ceased
- 1995-11-20 JP JP51942597A patent/JP3519740B2/ja not_active Expired - Fee Related
-
1997
- 1997-07-15 NO NO973278A patent/NO973278D0/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2142405C1 (ru) | 1999-12-10 |
| JPH11500403A (ja) | 1999-01-12 |
| US6083471A (en) | 2000-07-04 |
| CA2211800C (fr) | 2005-10-25 |
| FR2727101B1 (fr) | 1996-12-20 |
| PT804380E (pt) | 2003-06-30 |
| WO1997019019A1 (fr) | 1997-05-29 |
| ATE232507T1 (de) | 2003-02-15 |
| ES2188678T3 (es) | 2003-07-01 |
| DE69529625T2 (de) | 2003-12-18 |
| NO973278L (no) | 1997-07-15 |
| FR2727101A1 (fr) | 1996-05-24 |
| DE69529625D1 (de) | 2003-03-20 |
| EP0804380A1 (fr) | 1997-11-05 |
| JP3519740B2 (ja) | 2004-04-19 |
| NO973278D0 (no) | 1997-07-15 |
| CA2211800A1 (fr) | 1997-05-29 |
| EP0804380B1 (fr) | 2003-02-12 |
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