DK171508B1 - Syntetisk, krystallinsk aluminiumsilikat, en fremgangsmåde til dets fremstilling og dets anvendelse - Google Patents

Syntetisk, krystallinsk aluminiumsilikat, en fremgangsmåde til dets fremstilling og dets anvendelse Download PDF

Info

Publication number: DK171508B1
Authority: DK; Denmark
Prior art keywords: zeolites; weak; aluminum silicate; strong; sio
Prior art date: 1989-07-06

Application number

DK150190A

Other languages

Danish (da)

English (en)

Other versions

DK150190A (da

DK150190D0 (da

Inventor

Roland Thome

Arno Tissler

Hubertus Schmidt

Guenter Winkhaus

Klaus K Unger

Original Assignee

Alsi Penta Zeolithe Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-07-06

Filing date

1990-06-19

Publication date

1996-12-09

1990-06-19 Application filed by Alsi Penta Zeolithe Gmbh filed Critical Alsi Penta Zeolithe Gmbh

1990-06-19 Publication of DK150190D0 publication Critical patent/DK150190D0/da

1991-01-07 Publication of DK150190A publication Critical patent/DK150190A/da

1996-12-09 Application granted granted Critical

1996-12-09 Publication of DK171508B1 publication Critical patent/DK171508B1/da

Links

238000000034 method Methods 0.000 title claims abstract description 17
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 title claims description 13
238000002360 preparation method Methods 0.000 title claims description 9
239000000126 substance Substances 0.000 claims abstract description 19
239000000203 mixture Substances 0.000 claims abstract description 14
230000015572 biosynthetic process Effects 0.000 claims abstract description 9
239000003054 catalyst Substances 0.000 claims abstract description 9
238000001228 spectrum Methods 0.000 claims abstract description 9
238000003786 synthesis reaction Methods 0.000 claims abstract description 7
CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 claims abstract description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
229910004298 SiO 2 Inorganic materials 0.000 claims description 19
229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 11
229910052681 coesite Inorganic materials 0.000 claims description 11
229910052906 cristobalite Inorganic materials 0.000 claims description 11
229910052682 stishovite Inorganic materials 0.000 claims description 11
229910052905 tridymite Inorganic materials 0.000 claims description 11
239000000377 silicon dioxide Substances 0.000 claims description 10
235000012239 silicon dioxide Nutrition 0.000 claims description 10
239000011541 reaction mixture Substances 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 6
150000002500 ions Chemical class 0.000 claims description 5
238000010521 absorption reaction Methods 0.000 claims description 4
239000003463 adsorbent Substances 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 2
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
150000004645 aluminates Chemical class 0.000 claims description 2
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims 1
238000001027 hydrothermal synthesis Methods 0.000 claims 1
230000011514 reflex Effects 0.000 claims 1
239000010457 zeolite Substances 0.000 abstract description 24
229910052710 silicon Inorganic materials 0.000 abstract description 14
239000010703 silicon Substances 0.000 abstract description 10
229910052782 aluminium Inorganic materials 0.000 abstract description 7
230000003197 catalytic effect Effects 0.000 abstract description 7
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 7
239000007787 solid Substances 0.000 abstract description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 5
150000001768 cations Chemical class 0.000 abstract description 5
229910021536 Zeolite Inorganic materials 0.000 abstract description 4
-1 alkali metal cation Chemical class 0.000 abstract description 4
238000001179 sorption measurement Methods 0.000 abstract description 4
239000002253 acid Substances 0.000 abstract description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
229910052593 corundum Inorganic materials 0.000 abstract description 3
229910052500 inorganic mineral Inorganic materials 0.000 abstract description 3
239000011707 mineral Substances 0.000 abstract description 3
229910001845 yogo sapphire Inorganic materials 0.000 abstract description 3
150000003868 ammonium compounds Chemical class 0.000 abstract description 2
230000002209 hydrophobic effect Effects 0.000 abstract description 2
229910000323 aluminium silicate Inorganic materials 0.000 abstract 2
229910052783 alkali metal Inorganic materials 0.000 abstract 1
239000004411 aluminium Substances 0.000 abstract 1
150000001875 compounds Chemical class 0.000 abstract 1
238000007796 conventional method Methods 0.000 abstract 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 13
239000000047 product Substances 0.000 description 12
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
238000007323 disproportionation reaction Methods 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000012265 solid product Substances 0.000 description 3
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
230000002051 biphasic effect Effects 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000005216 hydrothermal crystallization Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
239000002994 raw material Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
238000004611 spectroscopical analysis Methods 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000005004 MAS NMR spectroscopy Methods 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000000567 combustion gas Substances 0.000 description 1
238000005388 cross polarization Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000003599 detergent Substances 0.000 description 1
BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
238000004146 energy storage Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000007789 gas Substances 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
125000005372 silanol group Chemical group 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000010189 synthetic method Methods 0.000 description 1
125000005207 tetraalkylammonium group Chemical group 0.000 description 1
BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7003—A-type
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

DK150190A 1989-07-06 1990-06-19 Syntetisk, krystallinsk aluminiumsilikat, en fremgangsmåde til dets fremstilling og dets anvendelse DK171508B1 (da)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3922181A DE3922181A1 (de)	1989-07-06	1989-07-06	Synthetisches kristallines alumosilikat und verfahren zu seiner herstellung
DE3922181		1989-07-06

Publications (3)

Publication Number	Publication Date
DK150190D0 DK150190D0 (da)	1990-06-19
DK150190A DK150190A (da)	1991-01-07
DK171508B1 true DK171508B1 (da)	1996-12-09

Family

ID=6384392

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DK150190A DK171508B1 (da)	1989-07-06	1990-06-19	Syntetisk, krystallinsk aluminiumsilikat, en fremgangsmåde til dets fremstilling og dets anvendelse

Country Status (14)

Country	Link
US (1)	US5385714A (fr)
EP (1)	EP0406474B1 (fr)
JP (1)	JP2918054B2 (fr)
AT (1)	ATE86948T1 (fr)
AU (1)	AU627902B2 (fr)
BR (1)	BR9003203A (fr)
CA (1)	CA2020580C (fr)
DD (1)	DD300507A5 (fr)
DE (2)	DE3922181A1 (fr)
DK (1)	DK171508B1 (fr)
ES (1)	ES2047626T3 (fr)
RO (1)	RO109055B1 (fr)
RU (2)	RU2066675C1 (fr)
UA (1)	UA32404C2 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4022140C2 (de) *	1990-07-11	1998-05-20	Ecolith Zeolithe Gmbh	Verwendung eines synthetischen, kristallinen Alumosilikates
UA27705C2 (uk) *	1990-07-11	2000-10-16	Еколіт-Цеоліте Гмбх	СПОСІБ КАТАЛІТИЧНОЇ ІЗОМЕРИЗАЦІЇ С<sub>8 </sub>- АРОМАТИЧНИХ ВУГЛЕВОДНІВ
DE4042655C2 (de) *	1990-07-11	1996-12-19	Ecolith Zeolithe Gmbh	Verwendung eines synthetischen, kristallinen Alumosilikats mit der chemischen Zusammensetzung 0-3M¶2¶O : Al¶2¶O¶3¶ : 15-40SiO¶2¶ : 0-40H¶2¶O zur Gewinnung und Verarbeitung von Aromaten
DE19722789A1 (de) *	1997-05-30	1998-12-03	Alsi Penta Zeolithe Gmbh	Synthetisches kristallines Zeolithpulver und Verfahren zu seiner Herstellung
US6368571B1 (en)	2000-01-28	2002-04-09	Chk Group, Inc.	ZSM-5 made from siliceous ash
JP4896110B2 (ja) *	2001-06-25	2012-03-14	三菱樹脂株式会社	ゼオライト及び吸着材
DE60143944D1 (de)	2001-09-28	2011-03-10	Sued Chemie Ag	Poröser Katalysator, Verfahren und Anordnung zur katalytischen Konversion von Abgasen
DE102007059129A1 (de)	2007-12-07	2009-06-10	Süd-Chemie AG	Katalysator mit erhöhter Olefinselektivität zur Umsetzung von Oxygenaten zu Olefinen
EP2130586A1 (fr)	2008-06-06	2009-12-09	Total Petrochemicals Research Feluy	Procédé de fabrication de métallosilicates cristallins
WO2011123337A2 (fr) *	2010-03-31	2011-10-06	Uop Llc	Zéolithe aluminosilicate uzm-37
RU2467950C1 (ru) *	2011-04-29	2012-11-27	Государственное образовательное учреждение высшего профессионального образования "Курганский государственный университет"	Способ получения алюмосиликатов и кремния из воздушной взвеси частиц песка и устройство для его осуществления

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3702886A (en) *	1969-10-10	1972-11-14	Mobil Oil Corp	Crystalline zeolite zsm-5 and method of preparing the same
US4994251A (en) *	1973-12-13	1991-02-19	Mobil Oil Corporation	Method for producing zeolites
US4341748A (en) *	1973-12-13	1982-07-27	Mobil Oil Corporation	Method for producing zeolites
US4199556A (en) *	1973-12-13	1980-04-22	Mobil Oil Corporation	Method for producing zeolites
US4175114A (en) *	1973-12-13	1979-11-20	Mobil Oil Corporation	Method for producing zeolites
US5102644A (en) *	1973-12-13	1992-04-07	Mobil Oil Corporation	Method for producing zeolites
US4257885A (en) *	1976-02-04	1981-03-24	Union Carbide Corporation	Novel zeolite compositions and processes for preparing and using same
NZ193927A (en) *	1979-06-11	1982-09-07	Mobil Oil Corp	Continuous stream method of preparing crystalline zeolite
NZ193928A (en) *	1979-06-11	1982-09-07	Mobil Oil Corp	Preparation of large crystal zeolite zsm-5
ZA803365B (en) *	1979-10-09	1981-05-27	Mobil Oil Corp	Synthesis of large crystal zeolite zsm-5
JPS56160316A (en) *	1980-05-14	1981-12-10	Toa Nenryo Kogyo Kk	Synthetic crystalline aluminosilicate composition and its manufacture
JPS577819A (en) *	1980-06-14	1982-01-16	Idemitsu Kosan Co Ltd	Manufacture of crystalline aluminosilicate zeolite
JPS58145616A (ja) *	1982-02-22	1983-08-30	Teijin Yuka Kk	新規結晶性アルミノシリケ−トゼオライト及びその製造法
DD207186B1 (de) *	1982-02-23	1988-01-06	Bitterfeld Chemie	Verfahren zur herstellung von hochkieselsaeurehaltigen zeolithen des typs zsm-5
JPS58204817A (ja) *	1982-05-19	1983-11-29	Teijin Yuka Kk	結晶性アルミノシリケ−トゼオライトの製造法
IT1152998B (it) *	1982-07-01	1987-01-14	Anic Spa	Procedimento per la preparazione di allumino-silicati cristallini porosi
JPS5939715A (ja) *	1982-08-26	1984-03-05	Toyo Soda Mfg Co Ltd	高シリカモルデナイト及びその製造法
DK164097C (da) *	1982-09-20	1992-10-05	Tosoh Corp	Fremgangsmaade til fremstilling af zeoliter
FR2552418B1 (fr) *	1983-09-28	1985-10-25	Rhone Poulenc Spec Chim	Procede de fabrication de zeolithe du type zsm-5
DE3477184D1 (en) *	1984-08-10	1989-04-20	Toa Nenryo Kogyo Kk	Novel crystalline aluminosilicate, process for the preparation thereof, and process for the conversion of organic materials using the same
US4900529A (en) *	1984-09-04	1990-02-13	W. R. Grace & Co.-Conn.	Process for making crystalline siliceous materials
NZ225813A (en) *	1987-09-02	1990-11-27	Mobil Oil Corp	Zsm-5 in crystal form having specific dimensions, and preparation thereof

1989
- 1989-07-06 DE DE3922181A patent/DE3922181A1/de not_active Withdrawn
- 1989-08-29 ES ES89115906T patent/ES2047626T3/es not_active Expired - Lifetime
- 1989-08-29 EP EP89115906A patent/EP0406474B1/fr not_active Expired - Lifetime
- 1989-08-29 AT AT89115906T patent/ATE86948T1/de not_active IP Right Cessation
- 1989-08-29 DE DE8989115906T patent/DE58903834D1/de not_active Expired - Lifetime
1990
- 1990-06-19 DK DK150190A patent/DK171508B1/da not_active IP Right Cessation
- 1990-07-02 RO RO145475A patent/RO109055B1/ro unknown
- 1990-07-05 AU AU58692/90A patent/AU627902B2/en not_active Ceased
- 1990-07-05 DD DD342537A patent/DD300507A5/de unknown
- 1990-07-05 RU SU904830485A patent/RU2066675C1/ru active
- 1990-07-05 BR BR909003203A patent/BR9003203A/pt not_active IP Right Cessation
- 1990-07-06 JP JP2177627A patent/JP2918054B2/ja not_active Expired - Lifetime
- 1990-07-06 CA CA002020580A patent/CA2020580C/fr not_active Expired - Fee Related
1991
- 1991-10-31 UA UA5001891A patent/UA32404C2/uk unknown
- 1991-10-31 RU SU915001891A patent/RU2042621C1/ru active
1992
- 1992-06-29 US US07/908,539 patent/US5385714A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP0406474A3 (en)	1991-09-18
ATE86948T1 (de)	1993-04-15
RU2042621C1 (ru)	1995-08-27
DE3922181A1 (de)	1991-01-17
DE58903834D1 (de)	1993-04-22
ES2047626T3 (es)	1994-03-01
AU5869290A (en)	1991-01-10
CA2020580A1 (fr)	1991-01-07
BR9003203A (pt)	1991-08-27
RU2066675C1 (ru)	1996-09-20
JPH03115116A (ja)	1991-05-16
AU627902B2 (en)	1992-09-03
UA32404C2 (uk)	2000-12-15
CA2020580C (fr)	2000-02-22
DK150190A (da)	1991-01-07
EP0406474A2 (fr)	1991-01-09
EP0406474B1 (fr)	1993-03-17
JP2918054B2 (ja)	1999-07-12
DK150190D0 (da)	1990-06-19
RO109055B1 (ro)	1994-11-30
DD300507A5 (de)	1992-06-17
US5385714A (en)	1995-01-31

Legal Events

Date	Code	Title
1992-05-25	PBP	Patent lapsed
1996-12-09	B1	Patent granted (law 1993)
2002-01-28	PBP	Patent lapsed

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US12606449B2 (en)	2026-04-21	Molecular sieve SSZ-117x with high acidity
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