DK2289957T3 - Elastiske methacrylatsammensætninger - Google Patents
Elastiske methacrylatsammensætninger Download PDFInfo
- Publication number
- DK2289957T3 DK2289957T3 DK10191458.8T DK10191458T DK2289957T3 DK 2289957 T3 DK2289957 T3 DK 2289957T3 DK 10191458 T DK10191458 T DK 10191458T DK 2289957 T3 DK2289957 T3 DK 2289957T3
- Authority
- DK
- Denmark
- Prior art keywords
- component
- styrene
- block copolymer
- methacrylate
- mixtures
- Prior art date
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- 239000000203 mixture Substances 0.000 claims description 78
- 239000000853 adhesive Substances 0.000 claims description 44
- 230000001070 adhesive effect Effects 0.000 claims description 44
- 239000000178 monomer Substances 0.000 claims description 32
- 229920000642 polymer Polymers 0.000 claims description 28
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 20
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 18
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 18
- 229920001400 block copolymer Polymers 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 13
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 claims description 13
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 12
- YNGDWRXWKFWCJY-UHFFFAOYSA-N 1,4-Dihydropyridine Chemical compound C1C=CNC=C1 YNGDWRXWKFWCJY-UHFFFAOYSA-N 0.000 claims description 11
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 11
- 229920001169 thermoplastic Polymers 0.000 claims description 11
- 239000004416 thermosoftening plastic Substances 0.000 claims description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 239000011593 sulfur Substances 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 239000012190 activator Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 150000002978 peroxides Chemical class 0.000 claims description 9
- 239000004014 plasticizer Substances 0.000 claims description 8
- 239000004609 Impact Modifier Substances 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- -1 methacrylate ester Chemical class 0.000 claims description 7
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 6
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 229920002681 hypalon Polymers 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- GJKZSOHUVOQISW-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 GJKZSOHUVOQISW-UHFFFAOYSA-N 0.000 claims description 5
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 5
- 150000002430 hydrocarbons Chemical group 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 5
- 230000001737 promoting effect Effects 0.000 claims description 5
- 229920006132 styrene block copolymer Polymers 0.000 claims description 5
- 239000002318 adhesion promoter Substances 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 239000011258 core-shell material Substances 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 3
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 2
- 150000001558 benzoic acid derivatives Chemical class 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 2
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 claims 1
- MEUKEBNAABNAEX-UHFFFAOYSA-N hydroperoxymethane Chemical group COO MEUKEBNAABNAEX-UHFFFAOYSA-N 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
- 238000009472 formulation Methods 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 230000000977 initiatory effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000032683 aging Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 2
- 239000005041 Mylar™ Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
- 235000019204 saccharin Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003513 tertiary aromatic amines Chemical class 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- VNZQQAVATKSIBR-UHFFFAOYSA-L copper;octanoate Chemical compound [Cu+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O VNZQQAVATKSIBR-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000013038 hand mixing Methods 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/04—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerization Catalysts (AREA)
Claims (8)
1. Tokomponent-klæbesammensætning, der kan blandes i et 1:1 forhold til dannelse af elastiske eller strækbare klæbemidler, omfattende komponent A omfattende én eller flere acrylat- eller methacrylatester-monomerer, fortrinsvis valgt fra gruppen bestående af methylmethacrylat-monomerer, og acrylat- og methacrylatmonomerer med højere molekylvægt, hvor alkoholdelen af monomeren er baseret på en C6- eller højere carbonhydridenhed, og blandinger deraf, og mere foretrukket laurylmethacrylat; en svovlbærende forbindelse, fortrinsvis sulfonylchlorid; komponent B omfattende én eller flere acrylat- eller methacrylatester-monomerer, fortrinsvis valgt fra gruppen bestående af methylmethacrylatmonomerer og acrylat- og methacrylatmonomerer med højere molekylvægt, hvor alkoholdelen af monomeren er baseret på en C6-eller højere carbonhydridenhed, og blandinger deraf, og mere foretrukket laurylmethacrylat; en aminpromotor, fortrinsvis et aminaldehyd- reakti o nsprodukt eller dihydropyridin; hvor enten komponent A eller komponent B eller begge endvidere omfatter en termoplastisk blokcopolymerkomponent, der er valgt fra gruppen bestående af a. en lineær styren-butadien-styren-blokcopolymer, b. en radial styren-butadien-styren-blokcopolymer med et plastificerings-middel, c. en lineær eller radial styren-isopren-styren-blokcopolymer, d. en lineær eller radial styren-butadien-isopren-styren-blokcopolymer, og blandinger deraf.
2. Klæbemiddel ifølge krav 1, endvidere omfattende en adhæsionsfremmende polymer, fortrinsvis en chlorineret polymer, og mere foretrukket en chlorineret polymer, der er valgt fra gruppen bestående af chlorsulfoneret polyethylen, chlorineret polyethylen, polychlorprenpolymerer, og blandinger deraf.
3. Klæbemiddel ifølge krav 1, endvidere omfattende en slagmodifikator, fortrinsvis en kerne-skal-slag-modifikator.
4. Klæbesammensætning ifølge krav 1, endvidere omfattende en initiator, der er valgt fra gruppen bestående af svovlbærende forbindelser, peroxider og blandinger deraf, hvor peroxiderne fortrinsvis er valgt fra gruppen bestående af cumolhydroperoxid, methylethylketonperoxid, benzoatestere, herunder t-butylperbenzoat, og blandinger deraf, og mere foretrukket hvor initiatoren ikke indbefatter benzoylchlorid.
5. Klæbesammensætning ifølge krav 1, endvidere omfattende en aktivator, der omfatter addukter af butyraldhyd og anilin.
6. Tokomponent-klæbesammensætning, der kan blandes i et 1:1 forhold til dannelse af elastiske eller strækbare klæbemidler, omfattende komponent A omfattende fra 20 til 90 vægt-% af én eller flere acrylat- eller methacrylatestermonomerer, fortrinsvis valgt fra gruppen bestående af methylmethacrylatmonomerer og acrylat- og methacrylatmonomerer med højere molekylvægt, hvor alkoholdelen af monomeren er baseret på en C6-eller højere carbonhydridenhed og blandinger deraf, og mere fortrinsvis laurylmethacrylat; fra 0,02 til 30 vægt-% af en svovlbærende forbindelse, fortrinsvis sulfonylchlorid; komponent B omfattende én eller flere acrylat- eller methacrylatestermonomerer, fortrinsvis valgt fra gruppen bestående af methylmethacrylatmonomerer og acrylat- og methacrylatmonomerer med højere molekylvægt, hvor alkoholdelen af monomeren er baseret på en C6- eller højere carbonhydridenhed og blandinger deraf, og mere foretrukket laurylmethacrylat; fra 0,05 til 10 vægt-% af en aminpromotor, fortrinsvis et aminaldehydreaktionsprodukt eller dihydropyridin; en adhæsionspromotor; hvor enten komponent A eller komponent B eller begge endvidere omfatter fra 5 til 50 vægt-% af en termoplastisk blokcopolymerkomponent, der er valgt fra gruppen bestående af a. en lineær styren-butadien-styren-blokcopolymer, b. en radial styren-butadien-styren-blokcopolymer med et plastificerings-middel, c. en lineær eller radial styren-isopren-styren-blokcopolymer, d. en lineær eller radial styren-butadien-isopren-styren-blokcopolymer, og blandinger deraf, men uden anvendelse af benzoylperoxid.
7. Fremgangsmåde til dannelse af et klæbemiddel med et 1:1 forhold, omfattende fremstilling af komponent A omfattende én eller flere methacrylat- eller acrylatestermonomerer og en svovlbærende forbindelse, fremstilling af komponent B omfattende én eller flere acrylat- eller methacrylatestermonomerer og en aminpromotor eller -aktivator, hvor enten komponent A eller komponent B eller begge endvidere omfatter en termoplastisk blokcopolymerkomponent, der er valgt fra gruppen bestående af a. en lineær styren-butadien-styren-blokcopolymer, b. en radial styren-butadien-styren-blokcopolymer med et plastificerings-middel, c. en lineær eller radial styren-isopren-styren-blokcopolymer, d. en lineær eller radial styren-butadien-isopren-styren-blokcopolymer, og blandinger deraf, hvor forholdet mellem komponent A og komponent B er 1:1, blanding af komponent A med komponent B til dannelse af en klæbesammensætning; og hvor benzoylperoxid fortrinsvis ikke anvendes med hverken komponent A eller komponent B.
8. Fremgangsmåde ifølge krav 7, endvidere omfattende tilsætning af en adhæsionspromotor til komponent A eller B eller begge.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75271305P | 2005-12-21 | 2005-12-21 | |
| US11/642,489 US20070155899A1 (en) | 2005-12-21 | 2006-12-20 | Elastic methacrylate compositions |
| EP06847929A EP1979388B1 (en) | 2005-12-21 | 2006-12-21 | Elastic methacrylate compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2289957T3 true DK2289957T3 (da) | 2015-01-19 |
Family
ID=37944885
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
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| DK06847929.4T DK1979388T3 (da) | 2005-12-21 | 2006-12-21 | Elastiske methacrylatsammensætninger |
| DK10191458.8T DK2289957T3 (da) | 2005-12-21 | 2006-12-21 | Elastiske methacrylatsammensætninger |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK06847929.4T DK1979388T3 (da) | 2005-12-21 | 2006-12-21 | Elastiske methacrylatsammensætninger |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US20070155899A1 (da) |
| EP (2) | EP1979388B1 (da) |
| JP (1) | JP5343563B2 (da) |
| CN (1) | CN101365731B (da) |
| AU (1) | AU2006331622B2 (da) |
| CA (1) | CA2633719C (da) |
| DK (2) | DK1979388T3 (da) |
| ES (2) | ES2471465T3 (da) |
| WO (1) | WO2007075909A1 (da) |
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| FR2910908B1 (fr) * | 2006-12-27 | 2010-08-20 | Jacret | Composition pour adhesif structural |
| EP2102298B1 (fr) | 2006-12-27 | 2017-09-06 | Jacret | Composition pour adhesif structural |
| FR2928931B1 (fr) * | 2008-03-21 | 2011-03-25 | Jacret | Composition pour adhesif structural |
| WO2012134735A1 (en) * | 2011-03-25 | 2012-10-04 | Huntsman Advanced Materials Americas Llc | Peroxide-free methacrylate structural adhesives |
| EP2705064A1 (en) | 2011-05-03 | 2014-03-12 | Dow Global Technologies LLC | Accelerated cure composition containing an isocyanate functional prepolymer |
| KR101597888B1 (ko) | 2011-05-03 | 2016-02-25 | 다우 글로벌 테크놀로지스 엘엘씨 | 유리에의 결합에 유용한 이중 경화 접착제 |
| US9416301B2 (en) | 2012-11-08 | 2016-08-16 | Dow Global Technologies Llc | Ultrafast dual cure adhesive useful for bonding to glass |
| US9676922B2 (en) * | 2014-06-11 | 2017-06-13 | IPS, Corporation—Weld-On Division | Heat and moisture resistant acrylic adhesive composition |
| US10487969B2 (en) | 2014-09-26 | 2019-11-26 | Ips, Corporation-Weld-On Division | Pipe fitting apparatus and methods |
| US10392532B2 (en) * | 2015-10-07 | 2019-08-27 | Illinois Tool Works, Inc. | Adhesive compositions with repair-rework ability |
| TW201816024A (zh) * | 2016-05-09 | 2018-05-01 | 漢高智慧財產控股公司 | 含有反應性倍半矽氧烷的黏著組合物 |
| US10913876B2 (en) | 2016-05-27 | 2021-02-09 | Ips Corporation | Polyurea-poly(meth)acrylate interpenetrating polymer network adhesive compositions and methods of using the same |
| CN112703234B (zh) * | 2018-09-17 | 2023-07-14 | 汉高股份有限及两合公司 | 两部分粘合剂组合物 |
| KR102176356B1 (ko) * | 2018-12-20 | 2020-11-09 | 주식회사 오아시스 | 실링테이프 조성물 및 이를 포함하는 성형품 |
| CA3128005A1 (en) * | 2019-02-07 | 2020-08-13 | Ips Corporation | Gasketed pipe joint formed in place and method of making same |
| CN114213778B (zh) * | 2021-11-30 | 2024-03-19 | 上海金发科技发展有限公司 | 一种高抗冲高光泽hips材料及其制备方法与应用 |
| US12422064B2 (en) | 2022-10-27 | 2025-09-23 | IPS, Corporation—Weld-On Division | Pipe fittings and assemblies |
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| DE1127347B (de) * | 1961-06-26 | 1962-04-12 | Air Reduction | Verfahren zur Herstellung von Alkinol-AEthylenoxyd-Addukten |
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-
2006
- 2006-12-20 US US11/642,489 patent/US20070155899A1/en not_active Abandoned
- 2006-12-21 DK DK06847929.4T patent/DK1979388T3/da active
- 2006-12-21 CN CN200680052563.9A patent/CN101365731B/zh not_active Expired - Fee Related
- 2006-12-21 EP EP06847929A patent/EP1979388B1/en not_active Not-in-force
- 2006-12-21 EP EP10191458.8A patent/EP2289957B1/en not_active Not-in-force
- 2006-12-21 AU AU2006331622A patent/AU2006331622B2/en not_active Ceased
- 2006-12-21 WO PCT/US2006/048825 patent/WO2007075909A1/en not_active Ceased
- 2006-12-21 DK DK10191458.8T patent/DK2289957T3/da active
- 2006-12-21 ES ES10191458.8T patent/ES2471465T3/es active Active
- 2006-12-21 CA CA2633719A patent/CA2633719C/en not_active Expired - Fee Related
- 2006-12-21 JP JP2008547555A patent/JP5343563B2/ja not_active Expired - Fee Related
- 2006-12-21 ES ES06847929T patent/ES2389090T3/es active Active
-
2013
- 2013-05-29 US US13/904,161 patent/US9133373B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP5343563B2 (ja) | 2013-11-13 |
| CA2633719A1 (en) | 2007-07-05 |
| EP1979388B1 (en) | 2012-08-01 |
| AU2006331622B2 (en) | 2013-03-07 |
| ES2389090T3 (es) | 2012-10-23 |
| CN101365731B (zh) | 2015-06-17 |
| CN101365731A (zh) | 2009-02-11 |
| US20130261247A1 (en) | 2013-10-03 |
| AU2006331622A1 (en) | 2007-07-05 |
| US9133373B2 (en) | 2015-09-15 |
| DK1979388T3 (da) | 2012-08-27 |
| ES2471465T3 (es) | 2014-06-26 |
| CA2633719C (en) | 2013-09-10 |
| EP1979388A1 (en) | 2008-10-15 |
| WO2007075909A1 (en) | 2007-07-05 |
| JP2009521573A (ja) | 2009-06-04 |
| EP2289957A1 (en) | 2011-03-02 |
| EP2289957B1 (en) | 2014-05-14 |
| US20070155899A1 (en) | 2007-07-05 |
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