DK3252128T3 - Termisk ekstraktionsfremgangsmåde til fremstilling af et taxanekstrakt - Google Patents
Termisk ekstraktionsfremgangsmåde til fremstilling af et taxanekstrakt Download PDFInfo
- Publication number
- DK3252128T3 DK3252128T3 DK17165988.1T DK17165988T DK3252128T3 DK 3252128 T3 DK3252128 T3 DK 3252128T3 DK 17165988 T DK17165988 T DK 17165988T DK 3252128 T3 DK3252128 T3 DK 3252128T3
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- DK
- Denmark
- Prior art keywords
- thermal
- extract
- starting material
- thermal extraction
- extraction
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C07D305/14—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms condensed with carbocyclic rings or ring systems
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/13—Coniferophyta (gymnosperms)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
- C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
- C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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Claims (10)
1. Termisk ekstraktionsfremgangsmåde, omfattende: i) at forberede et diterpenoid-indeholdende biomasse-udgangsmateriale omfattende en art af slægten Taxus eller Austrotaxus, hvor biomassen er reduceret i størrelse til en gennemsnitsdiameter på mindre end 2 cm i sin mindste dimension; ii) at indføre biomasse-udgangsmaterialet med reduceret størrelse i et termisk ekstraktionssystem omfattende en lukket beholder, en varmekilde, og mindst en genvindingsenhed; iii) at opvarme biomasse-udgangsmaterialet med reduceret størrelse til en temperatur på fra 250 °C til 650 °C for at danne en taxan-indeholdende damp; iv) at bratkøle den taxan-indeholdende damp med en bratkølingsvæske i en kondensator med direkte væskekontakt; og v) at opsamle et termisk ekstrakt omfattende: a) paclitaxel; og b) 7-epi-taxol, hvor: a) forholdet mellem koncentrationen af 7-epi-taxol og koncentrationen af paclitaxel i det kondenserede termiske ekstrakt er omkring 10; b) forholdet mellem koncentrationen af 7-epi-taxol i det kondenserede termiske ekstrakt og koncentrationen af 7-epi-taxol i udgangsmaterialet er mindst 10; c) den totale opholdstid af biomasse-udgangsmaterialet i det termiske ekstraktionssystem er i området fra 0,2 til 5 sekunder, hvor den totale opholdstid af materialet i det termiske ekstraktionssystem er målt som tidsintervallet fra opvarmningen af udgangsmaterialet i det termiske ekstraktionssystem til bratkøling.
2. Fremgangsmåde ifølge krav 1, hvor opvarmningen er til en temperatur på fra 300 °C til 550 °C for en total opholdstid på mindre end 2 sekunder.
3. Fremgangsmåde ifølge krav 1, hvor den mindst ene genvindingsenhed omfatter en indretning til at opsamle en væskefraktion fra dampfraktionen, og hvor indretningen er valgt fra gruppen bestående af en kondensator, et dråbefang, et fiber-leje filter og kombinationer deraf.
4. Termisk ekstraktionsfremgangsmåde ifølge krav 1, hvor det indledende volumen af kondenseret termisk ekstrakt påkrævet for at opnå et givet udbytte af 7-epi-taxol er lavere end volumenet af solventekstrakt påkrævet for at opnå det samme givne udbytte.
5. Termisk ekstraktionsfremgangsmåde ifølge krav 1, hvor opsamling af det termiske ekstrakt omfatter opsamling afen kondenseret dampfraktion og en væskefraktion.
6. Fremgangsmåde ifølge krav 1, endvidere omfattende: behandling af det termiske ekstrakt med et separations-solvent for selektivt at fjerne en eller flere taxaner.
7. Fremgangsmåde ifølge krav 1, hvor det termiske ekstrakt omfatter mindre end 10 vægtprocent af en eller flere forbindelser uden paclitaxel og 7-epi-taxol.
8. Fremgangsmåde ifølge krav 1, hvor forholdet mellem volumenet af udgangsmaterialet og volumenet af det kondenserede termiske ekstrakt er mindst 10.
9. Fremgangsmåde ifølge krav 1, hvor opvarmningen er til en temperatur på fra 320°C til 400 °C for en total opholdstid på mindre end 2 sekunder.
10. Fremgangsmåde ifølge krav 1, hvor den termiske ekstraktionsfremgangsmåde er uden en solvent-ekstration.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78804506P | 2006-04-03 | 2006-04-03 | |
| EP07719465.2A EP2007744B1 (en) | 2006-04-03 | 2007-04-02 | Thermal extraction method for producing a taxane extract |
Publications (1)
| Publication Number | Publication Date |
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| DK3252128T3 true DK3252128T3 (da) | 2019-04-01 |
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK17165988.1T DK3252128T3 (da) | 2006-04-03 | 2007-04-02 | Termisk ekstraktionsfremgangsmåde til fremstilling af et taxanekstrakt |
| DK07719465.2T DK2007744T3 (da) | 2006-04-03 | 2007-04-02 | Termisk ekstraktionsfremgangsmåde til fremstilling af et taxan-ekstrakt |
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| Application Number | Title | Priority Date | Filing Date |
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| DK07719465.2T DK2007744T3 (da) | 2006-04-03 | 2007-04-02 | Termisk ekstraktionsfremgangsmåde til fremstilling af et taxan-ekstrakt |
Country Status (6)
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| US (2) | US9127208B2 (da) |
| EP (2) | EP3252128B1 (da) |
| CN (2) | CN102702139B (da) |
| CA (1) | CA2647564C (da) |
| DK (2) | DK3252128T3 (da) |
| WO (1) | WO2007112570A1 (da) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702139B (zh) | 2006-04-03 | 2016-01-20 | 药物热化学品公司 | 热提取方法和产物 |
| US20110284359A1 (en) | 2010-05-20 | 2011-11-24 | Uop Llc | Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas |
| US8499702B2 (en) | 2010-07-15 | 2013-08-06 | Ensyn Renewables, Inc. | Char-handling processes in a pyrolysis system |
| BR112013002003A2 (pt) | 2010-07-26 | 2019-09-24 | Sapphire Energy Inc | processo para recuperação de compostos oleaginosos de biomassa |
| US8906236B2 (en) | 2010-07-26 | 2014-12-09 | Sapphire Energy, Inc. | Process for the recovery of oleaginous compounds and nutrients from biomass |
| US9028696B2 (en) | 2010-07-26 | 2015-05-12 | Sapphire Energy, Inc. | Process for the recovery of oleaginous compounds from biomass |
| US9441887B2 (en) | 2011-02-22 | 2016-09-13 | Ensyn Renewables, Inc. | Heat removal and recovery in biomass pyrolysis |
| US9347005B2 (en) | 2011-09-13 | 2016-05-24 | Ensyn Renewables, Inc. | Methods and apparatuses for rapid thermal processing of carbonaceous material |
| US9109177B2 (en) | 2011-12-12 | 2015-08-18 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
| US9670413B2 (en) | 2012-06-28 | 2017-06-06 | Ensyn Renewables, Inc. | Methods and apparatuses for thermally converting biomass |
| CN103808851A (zh) * | 2012-11-15 | 2014-05-21 | 刘胜远 | 一种红豆杉中10-去乙酰基紫杉醇的薄层色谱检测方法 |
| EP3013922A4 (en) | 2013-06-26 | 2017-02-08 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
| EP3307850B1 (en) * | 2015-06-12 | 2019-05-15 | Nettenergy B.V. | System and method for the conversion of biomass |
| EP3337966B1 (en) | 2015-08-21 | 2021-12-15 | Ensyn Renewables, Inc. | Liquid biomass heating system |
| BR112019013387B1 (pt) | 2016-12-29 | 2023-03-28 | Ensyn Renewables, Inc | Desmetalização de biomassa |
| WO2021130679A1 (en) | 2019-12-23 | 2021-07-01 | Kerry Luxembourg S.a.r.l. | Methods for formaldehyde control |
| CN114773158A (zh) * | 2022-04-26 | 2022-07-22 | 云南七丹药业股份有限公司 | 一种新鲜三七花的有效成分提取工艺及其生产方法 |
Family Cites Families (416)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2318555A (en) | 1943-05-04 | Cleansing agent and the | ||
| US1252072A (en) | 1916-09-13 | 1918-01-01 | William George Abbott Jr | Apparatus for cleaning the interior of tubular members. |
| US2205757A (en) | 1937-09-18 | 1940-06-25 | Standard Oil Dev Co | Coke cleaning apparatus |
| US2326525A (en) | 1940-08-28 | 1943-08-10 | Standard Oil Co | Method of preventing deleterious coke deposits |
| US2328202A (en) | 1940-12-30 | 1943-08-31 | Henry A Doerner | Process for producing magnesium metal |
| FR879606A (fr) | 1941-10-27 | 1943-03-01 | Procédé et appareil de traitement des gaz de gazogènes | |
| US2380098A (en) | 1943-01-23 | 1945-07-10 | Henry A Doerner | Automatic reamer |
| US2492948A (en) | 1945-10-05 | 1950-01-03 | Universal Oil Prod Co | Controlling catalyst regeneration temperature |
| US2566353A (en) | 1948-08-04 | 1951-09-04 | Houdry Process Corp | Purification of oils |
| US2696979A (en) | 1951-04-16 | 1954-12-14 | Kennecott Copper Corp | Automatic tuyere punching apparatus |
| US2884303A (en) | 1956-03-06 | 1959-04-28 | Exxon Research Engineering Co | High temperature burning of particulate carbonaceous solids |
| US3130007A (en) | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
| GB1019133A (en) | 1962-09-12 | 1966-02-02 | Exxon Research Engineering Co | Hydrocarbon separation process for removal of impurities |
| US3313726A (en) | 1963-06-24 | 1967-04-11 | Monsanto Co | Process for regenerating ion exchange resins |
| US3309356A (en) | 1965-07-06 | 1967-03-14 | Weyerhaeuser Co | Separating levoglucosan and carbohydrate acids from aqueous mixtures containing the same-by solvent extraction |
| FI46091C (fi) | 1966-06-15 | 1972-12-11 | Ahlstroem Oy | Tapa lämpökäsitellä meesaa tai sentapaista ainetta. |
| US3467502A (en) | 1966-10-12 | 1969-09-16 | Continental Carbon Co | Feedstock control system for carbon black reactors |
| BE759016A (fr) | 1969-12-18 | 1971-04-30 | Deggendorfer Werft Eisenbau | Refroidisseur pour le passage d'une partie reglable d'un vehicule de chaleur maintenu en circulation dans un reacteur |
| US3776533A (en) | 1970-01-28 | 1973-12-04 | Dravo Corp | Apparatus for continuous heat processing of ore pellets |
| GB1300966A (en) * | 1970-03-10 | 1972-12-29 | Yoshizo Sakamoto | Methods for processing medicinal plants and herbs |
| US3696022A (en) | 1970-07-27 | 1972-10-03 | Universal Oil Prod Co | Swing-bed guard chamber in hydrogenerating and hydrorefining coke-forming hydrocarbon charge stock |
| US3694346A (en) | 1971-05-06 | 1972-09-26 | Exxon Research Engineering Co | Integrated fluid coking/steam gasification process |
| US3925024A (en) | 1971-09-10 | 1975-12-09 | Borden Inc | Grid burner system |
| US4039290A (en) | 1972-05-15 | 1977-08-02 | Kureha Kagaku Kogyo Kabushiki Kaisha | Spent activated carbon regenerator |
| US3959420A (en) | 1972-05-23 | 1976-05-25 | Stone & Webster Engineering Corporation | Direct quench apparatus |
| US3853498A (en) | 1972-06-28 | 1974-12-10 | R Bailie | Production of high energy fuel gas from municipal wastes |
| US3814176A (en) | 1973-01-22 | 1974-06-04 | R Seth | Fixed-fluidized bed dry cooling tower |
| US3907661A (en) | 1973-01-29 | 1975-09-23 | Shell Oil Co | Process and apparatus for quenching unstable gas |
| US3876533A (en) | 1974-02-07 | 1975-04-08 | Atlantic Richfield Co | Guard bed system for removing contaminant from synthetic oil |
| US3890111A (en) | 1974-02-21 | 1975-06-17 | Exxon Research Engineering Co | Transfer line burner system using low oxygen content gas |
| US3927996A (en) | 1974-02-21 | 1975-12-23 | Exxon Research Engineering Co | Coal injection system |
| US4052265A (en) | 1974-07-26 | 1977-10-04 | Kemp Klaus M | Process for the pyrolytic treatment of organic, pseudo-organic and inorganic material |
| US4032305A (en) | 1974-10-07 | 1977-06-28 | Squires Arthur M | Treating carbonaceous matter with hot steam |
| US4003829A (en) | 1975-02-10 | 1977-01-18 | Atlantic Richfield Company | Method of removing contaminant from a hydrocarbonaceous fluid |
| US4064043A (en) | 1975-02-18 | 1977-12-20 | Rohm And Haas Company | Liquid phase adsorption using partially pyrolyzed polymer particles |
| US4153514A (en) | 1975-02-27 | 1979-05-08 | Occidental Petroleum Corporation | Pyrolysis process for solid wastes |
| US4101414A (en) | 1975-09-02 | 1978-07-18 | Unitech Chemical Inc. | Rerefining of used motor oils |
| US4165717A (en) | 1975-09-05 | 1979-08-28 | Metallgesellschaft Aktiengesellschaft | Process for burning carbonaceous materials |
| CA1081466A (en) | 1976-03-26 | 1980-07-15 | David S. Mitchell | Countercurrent plug-like flow of two solids |
| US4145274A (en) | 1976-06-25 | 1979-03-20 | Occidental Petroleum Corporation | Pyrolysis with staged recovery |
| US4102773A (en) | 1976-06-25 | 1978-07-25 | Occidental Petroleum Corporation | Pyrolysis with cyclone burner |
| US4085030A (en) | 1976-06-25 | 1978-04-18 | Occidental Petroleum Corporation | Pyrolysis of carbonaceous materials with solvent quench recovery |
| US4064018A (en) | 1976-06-25 | 1977-12-20 | Occidental Petroleum Corporation | Internally circulating fast fluidized bed flash pyrolysis reactor |
| GB1561237A (en) | 1976-09-22 | 1980-02-13 | Ahlstroem Oy | Method of treating materials in a fluidized bed reactor |
| US4210492A (en) | 1977-03-14 | 1980-07-01 | Shell Oil Company | Process for the pyrolysis of coal in dilute- and dense-phase fluidized beds |
| JPS53116314A (en) | 1977-03-19 | 1978-10-11 | Mitsui Petrochem Ind Ltd | Separation of acetic acid and water |
| US4138020A (en) | 1977-05-13 | 1979-02-06 | Foster Wheeler Energy Corporation | Regeneration flow distribution device |
| US4103902A (en) | 1977-08-16 | 1978-08-01 | Foster Wheeler Energy Corporation | Water seal for regenerator |
| US4344770A (en) | 1977-11-04 | 1982-08-17 | Wilwardco, Inc. | Method and apparatus for converting solid organic material to fuel oil and gas |
| US4298453A (en) | 1977-12-27 | 1981-11-03 | Mobil Oil Corporation | Coal conversion |
| US4284616A (en) | 1978-02-15 | 1981-08-18 | Intenco, Inc. | Process for recovering carbon black and hydrocarbons from used tires |
| US4245693A (en) | 1978-10-11 | 1981-01-20 | Phillips Petroleum Company | Waste heat recovery |
| US4219537A (en) | 1978-10-31 | 1980-08-26 | Foster Wheeler Energy Corporation | Desulfurization and low temperature regeneration of carbonaceous adsorbent |
| US4300009A (en) | 1978-12-28 | 1981-11-10 | Mobil Oil Corporation | Conversion of biological material to liquid fuels |
| US4233119A (en) | 1979-01-23 | 1980-11-11 | Louis A. Grant, Inc. | Ascension pipe and elbow cleaning apparatus |
| IT1112472B (it) | 1979-04-09 | 1986-01-13 | Trojani Ing Benito Luigi | Tubo con alettatura interna ed alettatura o piolinatura esterna,particolarmente per apparecchi scambiatori di calore,e suo metodo di fabbricazione |
| US4334893A (en) | 1979-06-25 | 1982-06-15 | Exxon Research & Engineering Co. | Recovery of alkali metal catalyst constituents with sulfurous acid |
| US4272402A (en) | 1979-07-16 | 1981-06-09 | Cosden Technology, Inc. | Process for regenerating fluidizable particulate cracking catalysts |
| US4225415A (en) | 1979-08-10 | 1980-09-30 | Occidental Petroleum Corporation | Recovering hydrocarbons from hydrocarbon-containing vapors |
| US4341598A (en) | 1979-08-14 | 1982-07-27 | Occidental Research Corporation | Fluidized coal pyrolysis apparatus |
| ZA807805B (en) | 1979-12-14 | 1982-01-27 | Energy Resources Co Inc | Fluidized-bed process to convert solid wastes to clean energy |
| JPS591758B2 (ja) | 1980-01-18 | 1984-01-13 | 工業技術院長 | 熱分解装置のガス処理方法 |
| US4456504A (en) | 1980-04-30 | 1984-06-26 | Chevron Research Company | Reactor vessel and process for thermally treating a granular solid |
| US4301771A (en) | 1980-07-02 | 1981-11-24 | Dorr-Oliver Incorporated | Fluidized bed heat exchanger with water cooled air distributor and dust hopper |
| US4324637A (en) | 1980-08-26 | 1982-04-13 | Occidental Research Corporation | Pyrolysis process with feed pretreatment utilizing a beneficially reactive gas |
| US4324642A (en) | 1980-08-26 | 1982-04-13 | Occidental Research Corporation | Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas |
| US4324641A (en) | 1980-08-26 | 1982-04-13 | Occidental Research Corporation | Pyrolysis process utilizing a beneficially reactive gas |
| US4324644A (en) | 1980-08-26 | 1982-04-13 | Occidental Research Corporation | Pyrolysis process for stabilizing volatile hydrocarbons utilizing a beneficially reactive gas |
| US4308411A (en) | 1980-08-28 | 1981-12-29 | Occidental Research Corporation | Process for converting oxygenated hydrocarbons into hydrocarbons |
| US4317703A (en) | 1980-12-03 | 1982-03-02 | American Can Company | Pyrolysis process utilizing pyrolytic oil recycle |
| US4321096A (en) | 1980-12-16 | 1982-03-23 | John B. Pike & Son, Inc. | Apparatus and method for cleaning an explosion sensing port |
| US4325327A (en) | 1981-02-23 | 1982-04-20 | Combustion Engineering, Inc. | Hybrid fluidized bed combuster |
| US4336128A (en) | 1981-06-01 | 1982-06-22 | Chevron Research Company | Combustion of pyrolyzed carbon containing solids in staged turbulent bed |
| US4415434A (en) | 1981-07-21 | 1983-11-15 | Standard Oil Company (Ind.) | Multiple stage desalting and dedusting process |
| US4373994A (en) | 1981-09-28 | 1983-02-15 | Occidental Research Corporation | Pyrolysis process and apparatus |
| US4422927A (en) | 1982-01-25 | 1983-12-27 | The Pittsburg & Midway Coal Mining Co. | Process for removing polymer-forming impurities from naphtha fraction |
| JPS58150793U (ja) | 1982-04-02 | 1983-10-08 | 日本鋼管株式会社 | 焼結原料サンプラ− |
| US4495056A (en) | 1982-04-16 | 1985-01-22 | Standard Oil Company (Indiana) | Oil shale retorting and retort water purification process |
| FR2526182B1 (fr) | 1982-04-28 | 1985-11-29 | Creusot Loire | Procede et dispositif de controle de la temperature d'un lit fluidise |
| US4931171A (en) | 1982-08-03 | 1990-06-05 | Phillips Petroleum Company | Pyrolysis of carbonaceous materials |
| DE3230656A1 (de) | 1982-08-18 | 1984-02-23 | Uhde Gmbh, 4600 Dortmund | Verfahren zur wiederaufheizung und foerderung eines koernigen waermetraegers sowie vorrichtung insbesondere zu dessen durchfuehrung |
| US4482451A (en) | 1982-09-16 | 1984-11-13 | Uop Inc. | Process for the separation of particulate solids from vapors using a discharge having a helical twist |
| EP0105980B1 (en) | 1982-10-06 | 1986-01-29 | Uop Inc. | Fluid particle backmixed cooling process and apparatus |
| US4434726A (en) | 1982-12-27 | 1984-03-06 | Combustion Engineering, Inc. | Fine particulate feed system for fluidized bed furnace |
| JPS58150793A (ja) | 1983-01-17 | 1983-09-07 | Hitachi Ltd | 熱回収装置 |
| US4443229A (en) | 1983-01-31 | 1984-04-17 | Chevron Research Company | Gasification process for carbonaceous materials |
| FR2540739A1 (fr) | 1983-02-11 | 1984-08-17 | Elf France | Dispositif et installations pour la distillation par evaporation en couches minces, en particulier pour hydrocarbures, et procede de mise en oeuvre de ce dispositif |
| FR2541435B1 (fr) | 1983-02-21 | 1986-10-17 | Elf France | Generateur thermique pour la realisation du chauffage de fluide par echange thermique au moyen d'un lit fluidise et le procede pour sa mise en oeuvre |
| US4897178A (en) | 1983-05-02 | 1990-01-30 | Uop | Hydrocracking catalyst and hydrocracking process |
| FR2548208B1 (fr) | 1983-06-30 | 1987-01-09 | Inst Francais Du Petrole | Procede de fabrication de combustibles solides a partir d'huiles lourdes d'hydrocarbures et de matieres vegetales |
| BR8304158A (pt) | 1983-07-26 | 1984-07-31 | Cia Agricolas E Florestal Sant | Processo de recuperacao de alcatrao leve,volatizado na pirolise de biomassa em fornos de carbonizacao descontinuos e respectivas instalacao |
| US4504379A (en) | 1983-08-23 | 1985-03-12 | Exxon Research And Engineering Co. | Passivation of metal contaminants in cat cracking |
| BR8304794A (pt) | 1983-09-02 | 1985-04-09 | Petroleo Brasileiro Sa | Processo para a producao de gasolina de lata octanagem |
| FR2563118B1 (fr) | 1984-04-20 | 1987-04-30 | Creusot Loire | Procede et installation de traitement de matiere en lit fluidise circulant |
| DE3426080C2 (de) | 1984-07-14 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung konzentrierter, stabiler Wasser-in-Öl-Polymeremulsionen von wasserlöslichen oder wasserquellbaren Polymerisaten |
| US4617693A (en) | 1984-08-06 | 1986-10-21 | Meyer Marjorie A | Drain pipe cleaning tool |
| FI75504C (fi) | 1984-08-28 | 1988-07-11 | Ahlstroem Oy | Anordning i virvelbaeddsreaktor. |
| US4595567A (en) | 1984-12-28 | 1986-06-17 | Uop Inc. | Cooling fluidized catalytic cracking regeneration zones with heat pipe apparatus |
| US4710357A (en) | 1984-12-28 | 1987-12-01 | Uop Inc. | FCC combustion zone catalyst cooling apparatus |
| US4615870A (en) | 1985-03-11 | 1986-10-07 | The M. W. Kellogg Company | Back-mixed hydrotreating reactor |
| US4584947A (en) | 1985-07-01 | 1986-04-29 | Chittick Donald E | Fuel gas-producing pyrolysis reactors |
| US4828581A (en) | 1985-09-20 | 1989-05-09 | Battelle Development Corporation | Low inlet gas velocity high throughput biomass gasifier |
| US4732091A (en) | 1985-09-30 | 1988-03-22 | G.G.C., Inc. | Pyrolysis and combustion process and system |
| US4678860A (en) | 1985-10-04 | 1987-07-07 | Arizona Board Of Regents | Process of producing liquid hydrocarbon fuels from biomass |
| US4668243A (en) | 1985-10-23 | 1987-05-26 | Schulz Johann G | Novel fuel |
| US4823712A (en) | 1985-12-18 | 1989-04-25 | Wormser Engineering, Inc. | Multifuel bubbling bed fluidized bed combustor system |
| US4891459A (en) | 1986-01-17 | 1990-01-02 | Georgia Tech Research Corporation | Oil production by entrained pyrolysis of biomass and processing of oil and char |
| SE460146B (sv) | 1986-08-14 | 1989-09-11 | Goetaverken Energy Syst Ab | Anordning vid foerbraenningsanlaeggning med cirkulerande fluidbaedd |
| US4849091A (en) | 1986-09-17 | 1989-07-18 | Uop | Partial CO combustion with staged regeneration of catalyst |
| US4714109A (en) | 1986-10-03 | 1987-12-22 | Utah Tsao | Gas cooling with heat recovery |
| EP0282000B1 (en) | 1987-03-11 | 1993-06-09 | Kansai Paint Co., Ltd. | Cationically electrodepositable finely divided gelled polymer and cationically electrodepositable coating composition containing same |
| US4968325A (en) | 1987-08-24 | 1990-11-06 | Centre Quebecois De Valorisation De La Biomasse | Fluidized bed gasifier |
| US4983278A (en) | 1987-11-03 | 1991-01-08 | Western Research Institute & Ilr Services Inc. | Pyrolysis methods with product oil recycling |
| US4876108A (en) | 1987-11-12 | 1989-10-24 | Ensyn Engineering Associates Inc. | Method of using fast pyrolysis liquids as liquid smoke |
| US5236688A (en) | 1987-11-13 | 1993-08-17 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for activating infusibilized pitch beads |
| US4881592A (en) | 1988-02-01 | 1989-11-21 | Uop | Heat exchanger with backmix and flow through particle cooling |
| US4992605A (en) | 1988-02-16 | 1991-02-12 | Craig Wayne K | Production of hydrocarbons with a relatively high cetane rating |
| US4942269A (en) | 1988-03-17 | 1990-07-17 | Midwest Research Institute | Process for fractionating fast-pyrolysis oils, and products derived therefrom |
| US4880473A (en) | 1988-04-01 | 1989-11-14 | Canadian Patents & Development Ltd. | Process for the production of fermentable sugars from biomass |
| JPH01277196A (ja) | 1988-04-27 | 1989-11-07 | Daikin Ind Ltd | 流動層を用いた熱交換器 |
| US4940007A (en) | 1988-08-16 | 1990-07-10 | A. Ahlstrom Corporation | Fast fluidized bed reactor |
| US5009770A (en) | 1988-08-31 | 1991-04-23 | Amoco Corporation | Simultaneous upgrading and dedusting of liquid hydrocarbon feedstocks |
| US5059404A (en) | 1989-02-14 | 1991-10-22 | Manufacturing And Technology Conversion International, Inc. | Indirectly heated thermochemical reactor apparatus and processes |
| US5879650A (en) | 1989-04-06 | 1999-03-09 | Cabot Corporation | Tandem quench |
| US5041209A (en) | 1989-07-12 | 1991-08-20 | Western Research Institute | Process for removing heavy metal compounds from heavy crude oil |
| US4988430A (en) | 1989-12-27 | 1991-01-29 | Uop | Supplying FCC lift gas directly from product vapors |
| US5792340A (en) | 1990-01-31 | 1998-08-11 | Ensyn Technologies, Inc. | Method and apparatus for a circulating bed transport fast pyrolysis reactor system |
| US5961786A (en) | 1990-01-31 | 1999-10-05 | Ensyn Technologies Inc. | Apparatus for a circulating bed transport fast pyrolysis reactor system |
| CA2009021C (en) | 1990-01-31 | 2001-09-11 | Barry A. Freel | Method and apparatus for a circulating bed transport fast pyrolysis reactor system |
| US5225044A (en) | 1990-03-14 | 1993-07-06 | Wayne Technology, Inc. | Pyrolytic conversion system |
| US5011592A (en) | 1990-07-17 | 1991-04-30 | Mobil Oil Corporation | Process for control of multistage catalyst regeneration with full then partial CO combustion |
| US5077252A (en) | 1990-07-17 | 1991-12-31 | Mobil Oil Corporation | Process for control of multistage catalyst regeneration with partial co combustion |
| US5136117A (en) | 1990-08-23 | 1992-08-04 | Battelle Memorial Institute | Monomeric recovery from polymeric materials |
| US5018458A (en) | 1990-09-12 | 1991-05-28 | Zimpro Passavant Environmental Systems, Inc. | Furnace combustion zone temperature control method |
| US5380916A (en) | 1990-11-02 | 1995-01-10 | University Of Florida | Method for the isolation and purification of taxane derivatives |
| EP0580759B1 (en) | 1991-04-19 | 1999-05-26 | The University Of Mississippi | Methods and compositions for isolating taxanes |
| US5536488A (en) | 1991-07-01 | 1996-07-16 | Manufacturing And Technology Conversion | Indirectly heated thermochemical reactor processes |
| FR2683743B1 (fr) | 1991-11-14 | 1994-02-11 | Institut Francais Petrole | Procede et dispositif d'echange thermique de particules solides pour double regeneration en craquage catalytique. |
| US5212129A (en) | 1991-12-17 | 1993-05-18 | Uop | Inverted backmix coolers for FCC units |
| IT1258838B (it) | 1992-01-31 | 1996-02-29 | Indena Spa | Processo per l'estrazione di tassolo e derivati da cultivar del genere taxus |
| US5395455A (en) * | 1992-03-10 | 1995-03-07 | Energy, Mines And Resources - Canada | Process for the production of anhydrosugars from lignin and cellulose containing biomass by pyrolysis |
| SE470213B (sv) | 1992-03-30 | 1993-12-06 | Nonox Eng Ab | Sätt och anordning för framställning av bränslen ur fasta kolhaltiga naturbränslen |
| US5239946A (en) | 1992-06-08 | 1993-08-31 | Foster Wheeler Energy Corporation | Fluidized bed reactor system and method having a heat exchanger |
| JPH06184560A (ja) | 1992-07-10 | 1994-07-05 | Hiroshi Shimizu | 有機廃棄物の熱分解装置 |
| US5243922A (en) | 1992-07-31 | 1993-09-14 | Institute Of Gas Technology | Advanced staged combustion system for power generation from coal |
| US5371212A (en) | 1992-09-04 | 1994-12-06 | Midwest Research Institute | Isolation of levoglucosan from pyrolysis oil derived from cellulose |
| GB9224783D0 (en) | 1992-11-26 | 1993-01-13 | Univ Waterloo | An improved process for the thermal conversion of biomass to liquids |
| US5281727A (en) | 1992-11-27 | 1994-01-25 | Napro Biotherapeutics, Inc. | Method of using ion exchange media to increase taxane yields |
| WO1994013827A1 (en) | 1992-12-07 | 1994-06-23 | Michigan State University | PROCESS FOR THE ISOLATION AND PURIFICATION OF TAXOL AND TAXANES FROM TAXUS spp |
| US5343939A (en) | 1992-12-14 | 1994-09-06 | Uop | Offset FCC coolers with improved catalyst circulation |
| NO176455B1 (no) | 1992-12-28 | 1995-04-24 | Energos As | Ristovn |
| US5426807A (en) | 1993-02-16 | 1995-06-27 | Goodway Tools Corporation | Tube cleaning apparatus |
| US5402548A (en) | 1993-03-31 | 1995-04-04 | Adair; Michael A. | Duct cleaning apparatus |
| US5376340A (en) | 1993-04-15 | 1994-12-27 | Abb Air Preheater, Inc. | Regenerative thermal oxidizer |
| US5423891A (en) | 1993-05-06 | 1995-06-13 | Taylor; Robert A. | Method for direct gasification of solid waste materials |
| IT1261667B (it) | 1993-05-20 | 1996-05-29 | Tassano ad attivita' antitumorale. | |
| US5494653A (en) | 1993-08-27 | 1996-02-27 | Battelle Memorial Institute | Method for hot gas conditioning |
| US5713977A (en) | 1994-09-12 | 1998-02-03 | Praxair Technology, Inc. | Fixed bed filtering preheater process for high temperature process furnaces |
| GB9426066D0 (en) | 1994-12-22 | 1995-02-22 | Radlein Desmond S G | Method of upgrading biomass pyrolysis liquids for use as fuels and as a source of chemicals by reaction with alcohols |
| US5584985A (en) | 1994-12-27 | 1996-12-17 | Uop | FCC separation method and apparatus with improved stripping |
| CH690790A5 (de) | 1995-01-10 | 2001-01-15 | Von Roll Umwelttechnik Ag | Verfahren zur thermischen Behandlung von Abfallmaterial. |
| US5520722A (en) | 1995-01-18 | 1996-05-28 | Exxon Research And Engineering Company | Multiunsaturates removal process |
| US6398921B1 (en) | 1995-03-15 | 2002-06-04 | Microgas Corporation | Process and system for wastewater solids gasification and vitrification |
| US5662050A (en) | 1995-05-05 | 1997-09-02 | Angelo, Ii; James F. | Process for chemical/thermal treatment without toxic emissions |
| DE19524176C1 (de) | 1995-07-03 | 1996-09-26 | Daimler Benz Ag | Verfahren zum Zwischenabschrecken von aus einem Lösungs-Glühofen kommenden Leichtmetall-Gußstücken |
| US5654448A (en) | 1995-10-02 | 1997-08-05 | Xechem International, Inc. | Isolation and purification of paclitaxel from organic matter containing paclitaxel, cephalomannine and other related taxanes |
| IT1276116B1 (it) | 1995-11-10 | 1997-10-24 | O E T Calusco S R L | Procedimento ed impianto per la produzione di carbone vegetale mediante pirolisi di prodotti legnosi o biomasse vegetali in genere |
| FR2744037B1 (fr) | 1996-01-31 | 1998-02-27 | Gec Alsthom Stein Ind | Lit fluidise externe destine a equiper un foyer a lit fluidise circulant |
| US6190542B1 (en) | 1996-02-23 | 2001-02-20 | Hydrocarbon Technologies, Inc. | Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds |
| US6011187A (en) | 1996-02-27 | 2000-01-04 | Mitsubishi Heavy Industries, Ltd. | Method and apparatus for reclaiming oil from waste plastic |
| DE69732394T2 (de) | 1996-02-29 | 2006-03-30 | Mitsubishi Heavy Industries, Ltd. | Verfahren und vorrichtung zur erzeugung von überhitztem dampf mittels wärme von abfallverbrennung |
| US5879642A (en) | 1996-04-24 | 1999-03-09 | Chevron U.S.A. Inc. | Fixed bed reactor assembly having a guard catalyst bed |
| BR9709327A (pt) | 1996-05-20 | 2000-05-02 | Rti Resource Transforms Intern | Liquefação de biomaterias por meio de termólise eficiente com relação à energia |
| US5728271A (en) | 1996-05-20 | 1998-03-17 | Rti Resource Transforms International Ltd. | Energy efficient liquefaction of biomaterials by thermolysis |
| US5703299A (en) | 1996-06-21 | 1997-12-30 | Corona Energy Partners, Ltd. | Exhaust stack sensor probe |
| US6113862A (en) | 1997-04-23 | 2000-09-05 | Union Carbide Chemicals & Plastics Technology Corporation | Fluidized bed polymerization reactor with multiple fluidization grids |
| CA2299049C (en) * | 1997-05-02 | 2008-07-15 | Baxter Biotech Technology S.A.R.L. | Hemoglobin mutants with increased soluble expression and/or reduced nitric oxide scavenging |
| US6033555A (en) | 1997-06-10 | 2000-03-07 | Exxon Chemical Patents Inc. | Sequential catalytic and thermal cracking for enhanced ethylene yield |
| US5879079A (en) | 1997-08-20 | 1999-03-09 | The United States Of America As Represented By The Administrator, Of The National Aeronautics And Space Administration | Automated propellant blending |
| US6193837B1 (en) | 1997-09-19 | 2001-02-27 | Midwest Research Institute | Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils |
| DE69816326T2 (de) | 1997-10-16 | 2004-04-22 | Toyota Jidosha K.K., Toyota | Katalytischer verbrennungsheizer |
| JPH11148625A (ja) | 1997-11-20 | 1999-06-02 | Hitachi Ltd | 廃棄物燃焼熱回収装置および方法 |
| US6326461B1 (en) * | 1998-01-30 | 2001-12-04 | Ensyn Group, Inc. | Natural resin formulations |
| FI104561B (fi) | 1998-02-27 | 2000-02-29 | Fortum Oil And Gas Oy Fortum O | Menetelmä hiilipitoisten lähtöaineiden pyrolysoimiseksi |
| US5904838A (en) | 1998-04-17 | 1999-05-18 | Uop Llc | Process for the simultaneous conversion of waste lubricating oil and pyrolysis oil derived from organic waste to produce a synthetic crude oil |
| UA45442C2 (uk) | 1998-09-11 | 2002-04-15 | Емануїл Вольфович Прилуцький | Каталізатор низькотемпературного піролізу полімерних матеріалів, що містять вуглеводні |
| FI110205B (fi) | 1998-10-02 | 2002-12-13 | Foster Wheeler Energia Oy | Menetelmä ja laite leijupetilämmönsiirtimessä |
| FI117512B (fi) | 1998-10-14 | 2006-11-15 | Valtion Teknillinen | Menetelmä ja laite pyrolyysiöljyn valmistamiseksi |
| FI116902B (fi) | 1998-10-14 | 2006-03-31 | Valtion Teknillinen | Menetelmä ja laite pyrolyysinesteen laadun parantamiseksi |
| US6485841B1 (en) | 1998-10-30 | 2002-11-26 | Ensyn Technologies, Inc. | Bio-oil preservatives |
| US6106702A (en) | 1998-12-29 | 2000-08-22 | Uop Llc | Olefinic hydrocarbon separation process |
| US5969165A (en) | 1999-01-07 | 1999-10-19 | 508037 (Nb) Inc. | Isolation and purification of paclitaxel and other related taxanes by industrial preparative low pressure chromatography on a polymeric resin column |
| US6002025A (en) * | 1999-02-24 | 1999-12-14 | Bcm Developement Inc. | Method for the purification of taxanes |
| MXPA01010120A (es) | 1999-04-07 | 2002-08-12 | Ensyn Group Inc | Procesamiento termico rapido de materias primas de hidrocarburos pesados. |
| JP2002543268A (ja) | 1999-05-04 | 2002-12-17 | コモンウェルス サイエンティフィック アンド インダストリアル リサーチ オーガニゼーション | 木材残渣を炭化して活性炭を製造する方法 |
| US6875341B1 (en) | 1999-05-24 | 2005-04-05 | James W. Bunger And Associates, Inc. | Process for enhancing the value of hydrocabonaceous natural recources |
| CA2299149C (fr) | 1999-06-22 | 2010-09-21 | Chaichem Pharmaceuticals International | Procede d'isolation et de purification du paclitaxel a partir de sources naturelles |
| DE19930071C2 (de) | 1999-06-30 | 2001-09-27 | Wolfgang Krumm | Verfahren und Vorrichtung zur Pyrolyse und Vergasung von organischen Stoffen und Stoffgemischen |
| US6530964B2 (en) | 1999-07-07 | 2003-03-11 | The Lubrizol Corporation | Continuous process for making an aqueous hydrocarbon fuel |
| JP2001083645A (ja) | 1999-07-13 | 2001-03-30 | Fuji Photo Film Co Ltd | ハロゲン化銀写真感光材料 |
| US7047894B2 (en) | 1999-11-02 | 2006-05-23 | Consolidated Engineering Company, Inc. | Method and apparatus for combustion of residual carbon in fly ash |
| JP2001131560A (ja) | 1999-11-09 | 2001-05-15 | Hitachi Ltd | 炭化水素原料の熱分解方法及び熱分解装置 |
| ATE257170T1 (de) | 1999-11-11 | 2004-01-15 | Tno | Flash-pyrolyse in einem zyklon |
| US6596737B2 (en) * | 2000-02-02 | 2003-07-22 | Fsu Research Foundation, Inc. | C10 carbamoyloxy substituted taxanes |
| US6455015B1 (en) | 2000-02-16 | 2002-09-24 | Uop Llc | Fluid-solid contacting chambers having multi-conduit, multi-nozzle fluid distribution |
| US6452024B1 (en) | 2000-02-22 | 2002-09-17 | Chaichem Pharmaceuticals International | Process for extraction and purification of paclitaxel from natural sources |
| US6237541B1 (en) | 2000-04-19 | 2001-05-29 | Kvaerner Pulping Oy | Process chamber in connection with a circulating fluidized bed reactor |
| WO2001083645A1 (en) | 2000-05-01 | 2001-11-08 | Danmarks Tekniske Universitet | A method and an installation for thermal gasification of solid fuel |
| US6339182B1 (en) | 2000-06-20 | 2002-01-15 | Chevron U.S.A. Inc. | Separation of olefins from paraffins using ionic liquid solutions |
| US6776607B2 (en) | 2000-06-26 | 2004-08-17 | Exxonmobil Research And Engineering Company | Process for minimizing afterburn in a FCC regenerator |
| US6676828B1 (en) | 2000-07-26 | 2004-01-13 | Intevep, S.A. | Process scheme for sequentially treating diesel and vacuum gas oil |
| EP1184443A1 (en) | 2000-09-04 | 2002-03-06 | Biofuel B.V. | Process for the production of liquid fuels from biomass |
| ATE532842T1 (de) | 2000-09-18 | 2011-11-15 | Ensyn Petroleum Internat Ltd | Durch schnelle thermische behandlung von schweren kohlenwassterstoffeinsätzen hergestelltes produkt |
| US6547957B1 (en) | 2000-10-17 | 2003-04-15 | Texaco, Inc. | Process for upgrading a hydrocarbon oil |
| CN1098337C (zh) | 2000-11-02 | 2003-01-08 | 中国石油天然气股份有限公司 | 一种采用多金属液体催化剂的常压重油悬浮床加氢新工艺 |
| US6680137B2 (en) | 2000-11-17 | 2004-01-20 | Future Energy Resources Corporation | Integrated biomass gasification and fuel cell system |
| AUPR221700A0 (en) | 2000-12-20 | 2001-01-25 | Gosfern Pty Limited | Crude oil conditioning apparatus and method |
| CN1240810C (zh) | 2001-03-30 | 2006-02-08 | 中国科学院化工冶金研究所 | 循环流态化碳氢固体燃料的四联产工艺及装置 |
| US6656342B2 (en) | 2001-04-04 | 2003-12-02 | Chevron U.S.A. Inc. | Graded catalyst bed for split-feed hydrocracking/hydrotreating |
| US7241323B2 (en) | 2001-07-10 | 2007-07-10 | Advanced Fuel Research, Inc. | Pyrolysis process for producing fuel gas |
| ES2235087T3 (es) | 2001-08-10 | 2005-07-01 | Shell Internationale Research Maatschappij B.V. | Proceso para recuperar energia de gas caliente. |
| US6830730B2 (en) | 2001-09-11 | 2004-12-14 | Spectrolanalytical Instruments | Method and apparatus for the on-stream analysis of total sulfur and/or nitrogen in petroleum products |
| US6768036B2 (en) | 2001-12-31 | 2004-07-27 | Exxonmobil Chemical Patents Inc. | Method for adding heat to a reactor system used to convert oxygenates to olefins |
| US7244399B2 (en) | 2002-04-26 | 2007-07-17 | Foster Wheeler Energia Oy | Grid construction for a fluidized bed reactor |
| US7648544B2 (en) | 2002-07-19 | 2010-01-19 | Shell Oil Company | Swirl tube separator |
| US6759562B2 (en) | 2002-07-24 | 2004-07-06 | Abb Lummus Global Inc. | Olefin plant recovery system employing a combination of catalytic distillation and fixed bed catalytic steps |
| US6960325B2 (en) | 2002-08-22 | 2005-11-01 | Hydrocarbon Technologies | Apparatus for hydrocracking and/or hydrogenating fossil fuels |
| US7026262B1 (en) | 2002-09-17 | 2006-04-11 | Uop Llc | Apparatus and process for regenerating catalyst |
| US7572362B2 (en) | 2002-10-11 | 2009-08-11 | Ivanhoe Energy, Inc. | Modified thermal processing of heavy hydrocarbon feedstocks |
| US7572365B2 (en) | 2002-10-11 | 2009-08-11 | Ivanhoe Energy, Inc. | Modified thermal processing of heavy hydrocarbon feedstocks |
| FR2851570B1 (fr) | 2003-02-24 | 2007-07-27 | Inst Francais Du Petrole | Installation et procede de gazeification multi-etapes d'une charge comprenant de la matiere organique |
| US7263934B2 (en) | 2003-02-24 | 2007-09-04 | Harris Contracting Company | Methods for generating energy using agricultural biofuel |
| US7022741B2 (en) | 2003-03-28 | 2006-04-04 | Conocophillips Company | Gas agitated multiphase catalytic reactor with reduced backmixing |
| FI114115B (fi) | 2003-04-15 | 2004-08-13 | Foster Wheeler Energia Oy | Menetelmä ja laite lämmön talteenottamiseksi leijupetireaktorissa |
| JP4050184B2 (ja) | 2003-05-13 | 2008-02-20 | 株式会社日本触媒 | 脂肪族カルボン酸の製造方法 |
| US7247233B1 (en) | 2003-06-13 | 2007-07-24 | Uop Llc | Apparatus and process for minimizing catalyst residence time in a reactor vessel |
| FI20031113L (fi) | 2003-07-29 | 2005-01-30 | Outokumpu Oy | Menetelmä ja laitteisto leijupetiuunin arinalta poistettavan materiaalin jäähdyttämiseksi |
| US7004999B2 (en) | 2003-08-18 | 2006-02-28 | Dynamotive Energy Systems Corporation | Apparatus for separating fouling contaminants from non-condensable gases at the end of a pyrolysis/thermolysis of biomass process |
| JP4286864B2 (ja) | 2003-08-21 | 2009-07-01 | インターナシヨナル・エンバイロンメンタル・ソリユーシヨンズ・コーポレイシヨン | 熱分解廃棄物処理システムのための室支持体 |
| TW200519073A (en) | 2003-08-21 | 2005-06-16 | Pearson Technologies Inc | Process and apparatus for the production of useful products from carbonaceous feedstock |
| US7285186B2 (en) | 2003-12-11 | 2007-10-23 | Zbigniew Tokarz | Transverse-flow catalytic reactor for conversion of waste plastic material and scrap rubber |
| US20050209328A1 (en) | 2004-03-19 | 2005-09-22 | Allgood Charles C | Alphahydroxyacids with ultra-low metal concentration |
| KR101354740B1 (ko) | 2004-04-28 | 2014-01-22 | 헤드워터스 헤비 오일, 엘엘씨 | 에뷸레이트 베드 하이드로프로세싱 방법 및 시스템 및기존의 에뷸레이트 베드 시스템을 개량하는 방법 |
| JP2008504409A (ja) | 2004-07-07 | 2008-02-14 | カリフォルニア インスティテュート オブ テクノロジー | 金属酸化物を使用して油を改良するプロセス |
| US7685737B2 (en) | 2004-07-19 | 2010-03-30 | Earthrenew, Inc. | Process and system for drying and heat treating materials |
| US7024800B2 (en) | 2004-07-19 | 2006-04-11 | Earthrenew, Inc. | Process and system for drying and heat treating materials |
| CA2521829A1 (en) * | 2004-09-30 | 2006-03-30 | University Of Ottawa | Process for extracting taxanes |
| EP1642878B1 (en) | 2004-10-01 | 2007-12-26 | Research Institute of Petroleum Industry | An integrated process and apparatus for producing liquid fuels |
| FR2879213B1 (fr) | 2004-12-15 | 2007-11-09 | Inst Francais Du Petrole | Enchainement de procedes d'hydroconversion et de reformage a la vapeur en vue d'optimiser la production d'hydrogene sur sur des champs de production |
| US7473349B2 (en) | 2004-12-30 | 2009-01-06 | Bp Corporation North America Inc. | Process for removal of sulfur from components for blending of transportation fuels |
| US7829030B2 (en) | 2004-12-30 | 2010-11-09 | Exxonmobil Chemical Patents Inc. | Fluidizing a population of catalyst particles having a low catalyst fines content |
| NL1027932C2 (nl) | 2004-12-31 | 2006-07-03 | Btg Biomass Technology Group B | Dipleg, werkwijze voor het gebruik ervan en toepassingen van de dipleg. |
| US20060163053A1 (en) | 2005-01-21 | 2006-07-27 | Bengt-Sture Ershag | Batch pyrolysis system |
| US7476774B2 (en) | 2005-02-28 | 2009-01-13 | Exxonmobil Research And Engineering Company | Liquid phase aromatics alkylation process |
| US7964761B2 (en) | 2005-05-02 | 2011-06-21 | University Of Utah Research Foundation | Processes for catalytic conversion of lignin to liquid bio-fuels and novel bio-fuels |
| WO2006117005A1 (en) | 2005-05-03 | 2006-11-09 | Danmarks Tekniske Universitet | Pyrolysis method and apparatus |
| US20060264684A1 (en) | 2005-05-19 | 2006-11-23 | Petri John A | Production of diesel fuel from biorenewable feedstocks |
| US7868214B2 (en) | 2005-05-19 | 2011-01-11 | Uop Llc | Production of olefins from biorenewable feedstocks |
| WO2007093225A1 (en) | 2005-05-23 | 2007-08-23 | Shell Internationale Research Maatschappij B.V. | Process for the removal of contaminants |
| US7491317B2 (en) | 2005-06-07 | 2009-02-17 | China Petroleum & Chemical Corporation | Desulfurization in turbulent fluid bed reactor |
| US7943014B2 (en) | 2005-06-08 | 2011-05-17 | Agri-Therm Inc. | Apparatus and process for the pyrolysis of agricultural biomass |
| US7727383B2 (en) | 2005-06-30 | 2010-06-01 | Amt International, Inc. | Process for producing petroleum oils with ultra-low nitrogen content |
| CN100360248C (zh) | 2005-08-10 | 2008-01-09 | 重庆大学 | 生物质热解液化的工艺方法及其双塔式装置系统 |
| DE102005037917A1 (de) | 2005-08-11 | 2007-02-15 | Forschungszentrum Karlsruhe Gmbh | Verfahren zur Schnellpyrolyse von Lignocellulose |
| US20070051238A1 (en) | 2005-09-07 | 2007-03-08 | Ravi Jain | Process for gas purification |
| DE102005049375A1 (de) | 2005-10-15 | 2007-04-26 | Forschungszentrum Karlsruhe Gmbh | Verfahren zur Herstellung und Vorbereitung von Schnellpyrolyseprodukten aus Biomasse für eine Flugstrom Druckvergasung |
| WO2007045093A1 (en) * | 2005-10-21 | 2007-04-26 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Canada, Canadian Forest Service | Preparation of taxanes |
| US20090217573A1 (en) | 2005-10-26 | 2009-09-03 | Kiram Ab | Automotive fuels and fine chemicals from crude tall oil |
| US7867538B2 (en) | 2005-12-20 | 2011-01-11 | Archer Daniels Midland Company | Processes of improving the quality of oil and products produced therefrom |
| JP2007229548A (ja) | 2006-02-27 | 2007-09-13 | Nippon Steel Engineering Co Ltd | バイオマス熱分解ガス化過程で使用する改質用触媒とその製造方法、及びその改質用触媒を用いた改質方法とバイオマス熱分解ガス化装置、並びに触媒再生方法 |
| US20070205139A1 (en) | 2006-03-01 | 2007-09-06 | Sathit Kulprathipanja | Fcc dual elevation riser feed distributors for gasoline and light olefin modes of operation |
| CN102702139B (zh) * | 2006-04-03 | 2016-01-20 | 药物热化学品公司 | 热提取方法和产物 |
| CA2651463C (en) | 2006-05-05 | 2014-12-02 | Bioecon International Holding N.V. | Improved process for converting carbon-based energy carrier material |
| EP1852493A1 (en) | 2006-05-05 | 2007-11-07 | BIOeCON International Holding N.V. | Hydrothermal treatment of carbon-based energy carrier material |
| US20070272538A1 (en) | 2006-05-26 | 2007-11-29 | Satchell Donald P | Flash pyrolosis method for carbonaceous materials |
| US20080006520A1 (en) | 2006-07-06 | 2008-01-10 | Badger Phillip C | Method and system for accomplishing flash or fast pyrolysis with carbonaceous materials |
| US20080006519A1 (en) | 2006-07-06 | 2008-01-10 | Badger Phillip C | Method and system for accomplishing flash or fast pyrolysis with carbonaceous materials |
| US20100209965A1 (en) | 2006-07-17 | 2010-08-19 | Bioecon International Holding N.V. | Catalytic pyrolysis of fine particulate biomass, and method for reducing the particle size of solid biomass particles |
| US20080029437A1 (en) | 2006-08-02 | 2008-02-07 | Exxonmobil Research And Engineering Company | Olefin upgrading process with guard bed regeneration |
| US7758817B2 (en) | 2006-08-09 | 2010-07-20 | Uop Llc | Device for contacting high contaminated feedstocks with catalyst in an FCC unit |
| GB0616298D0 (en) | 2006-08-16 | 2006-09-27 | Univ Aston | Biomass pyrolysis |
| EP1892280A1 (en) | 2006-08-16 | 2008-02-27 | BIOeCON International Holding N.V. | Fluid catalytic cracking of oxygenated compounds |
| CN101506332B (zh) | 2006-08-18 | 2012-10-24 | 新日本石油株式会社 | 生物质的处理方法、燃料电池用燃料、汽油、柴油机燃料、液化石油气和合成树脂 |
| US20080051619A1 (en) | 2006-08-25 | 2008-02-28 | Santi Kulprathipanja | Olefin-Separation Process |
| US7578927B2 (en) | 2006-08-31 | 2009-08-25 | Uop Llc | Gasoline and diesel production from pyrolytic lignin produced from pyrolysis of cellulosic waste |
| US20080081006A1 (en) | 2006-09-29 | 2008-04-03 | Myers Daniel N | Advanced elevated feed distribution system for very large diameter RCC reactor risers |
| US7687261B2 (en) | 2006-10-13 | 2010-03-30 | General Atomics | Photosynthetic oil production in a two-stage reactor |
| WO2008063485A2 (en) | 2006-11-16 | 2008-05-29 | Archer-Daniels-Midland Company | Process for hydrogen gas production from carbohydrate feedstocks |
| FR2910483B1 (fr) | 2006-12-21 | 2010-07-30 | Inst Francais Du Petrole | Procede de conversion de charges issues de sources renouvelables en bases carburants gazoles de bonne qualite. |
| US20080171649A1 (en) | 2007-01-12 | 2008-07-17 | Deng-Yang Jan | Modified Y-85 and LZ-210 Zeolites |
| DE102007005835A1 (de) | 2007-02-01 | 2008-08-14 | Forschungszentrum Karlsruhe Gmbh | Verfahren und Vorrichtung zur Umwandlung von Biomasse in Kraftstoff |
| WO2008098036A1 (en) | 2007-02-06 | 2008-08-14 | North Carolina State University | Product preparation and recovery from thermolysis of lignocellulosics in ionic liquids |
| US7737314B2 (en) | 2007-02-12 | 2010-06-15 | Exxonmobil Chemical Patents Inc. | Production of high purity ethylbenzene from non-extracted feed and non-extracted reformate useful therein |
| ES2303792B1 (es) | 2007-02-15 | 2009-06-12 | Industrias Mecanicas Alcudia S.A. | Un procedimiento para la revalorizacion energetica de la fraccion organica de residuos solidos urbanos, e instalacion. |
| GB2446820B (en) | 2007-02-23 | 2011-09-21 | Mark Collins | A Method of Generating Heat |
| CA2624746C (en) | 2007-03-12 | 2015-02-24 | Robert Graham | Methods and systems for producing reduced resid and bottomless products from heavy hydrocarbon feedstocks |
| GB2447684B (en) | 2007-03-21 | 2011-11-23 | Statoil Asa | Biogasoline |
| US20080282606A1 (en) | 2007-04-16 | 2008-11-20 | Plaza John P | System and process for producing biodiesel |
| US20080274017A1 (en) | 2007-05-04 | 2008-11-06 | Boykin Jack W | System for the production of synthetic fuels |
| CN101045524B (zh) | 2007-05-04 | 2010-05-19 | 大连理工大学 | 固体燃料催化气化制富氢气体的方法 |
| US8153850B2 (en) | 2007-05-11 | 2012-04-10 | The Texas A&M University System | Integrated biofuel production system |
| US7914667B2 (en) | 2007-06-04 | 2011-03-29 | Exxonmobil Chemical Patents Inc. | Pyrolysis reactor conversion of hydrocarbon feedstocks into higher value hydrocarbons |
| US7425657B1 (en) | 2007-06-06 | 2008-09-16 | Battelle Memorial Institute | Palladium catalyzed hydrogenation of bio-oils and organic compounds |
| US8158842B2 (en) | 2007-06-15 | 2012-04-17 | Uop Llc | Production of chemicals from pyrolysis oil |
| WO2009002878A1 (en) | 2007-06-22 | 2008-12-31 | Biofuelbox Corporation | System for production and purification of biofuel |
| DE102007031461A1 (de) | 2007-07-05 | 2009-01-08 | Sappok, Manfred, Dipl.-Phys. Dr. | Verfahren zum Stabilisieren von Heizöl oder Dieselöl, insbesondere aus der Depolimerisation von kohlenwasserstoffhaltigen Rückständen |
| CN101353582B (zh) | 2007-07-25 | 2010-12-01 | 中国科学院工程热物理研究所 | 固体热载体快速热解方法及装置 |
| WO2009017958A1 (en) | 2007-07-31 | 2009-02-05 | Endicott Biofuels Ii, Llc | Production of renewable diesel by pyrolysis and esterification |
| WO2009018531A1 (en) | 2007-08-01 | 2009-02-05 | Virginia Tech Intellectual Properties, Inc. | Fractional catalytic pyrolysis of biomass |
| HUP0700508A2 (en) | 2007-08-03 | 2010-12-28 | 3R Carbon Capture And Storage Pty Ltd | Appliance for carbon catena development and process for neutralisation of dangerous wastes |
| US8217211B2 (en) | 2007-08-27 | 2012-07-10 | Purdue Research Foundation | Process for producing liquid hydrocarbon by pyrolysis of biomass in presence of hydrogen from a carbon-free energy source |
| US8217210B2 (en) | 2007-08-27 | 2012-07-10 | Purdue Research Foundation | Integrated gasification—pyrolysis process |
| US7982075B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with lower hydrogen consumption |
| US7999142B2 (en) | 2007-09-20 | 2011-08-16 | Uop Llc | Production of diesel fuel from biorenewable feedstocks |
| US7999143B2 (en) | 2007-09-20 | 2011-08-16 | Uop Llc | Production of diesel fuel from renewable feedstocks with reduced hydrogen consumption |
| US7982077B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen |
| US7982078B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen |
| US8003834B2 (en) | 2007-09-20 | 2011-08-23 | Uop Llc | Integrated process for oil extraction and production of diesel fuel from biorenewable feedstocks |
| FI123455B (fi) | 2007-10-11 | 2013-05-15 | Valtion Teknillinen | Menetelmä pyrolysoinnin toteuttamiseksi |
| FI123180B (fi) | 2007-10-11 | 2012-12-14 | Valtion Teknillinen | Laitteisto pyrolyysituotteen valmistamiseksi |
| US7905990B2 (en) | 2007-11-20 | 2011-03-15 | Ensyn Renewables, Inc. | Rapid thermal conversion of biomass |
| US8241605B2 (en) | 2008-01-31 | 2012-08-14 | Battelle Memorial Institute | Methods and apparatus for catalytic hydrothermal gasification of biomass |
| US20090208402A1 (en) | 2008-02-20 | 2009-08-20 | Rossi Robert A | Process and system for producing commercial quality carbon dioxide from fine particle limestone |
| BRPI0910281B1 (pt) | 2008-03-04 | 2017-10-24 | University Of Massachusetts | Catalytic pyrolysis of solid biomass and related biofuels, aromatic and olefinic compounds |
| US8039682B2 (en) | 2008-03-17 | 2011-10-18 | Uop Llc | Production of aviation fuel from renewable feedstocks |
| US8058492B2 (en) | 2008-03-17 | 2011-11-15 | Uop Llc | Controlling production of transportation fuels from renewable feedstocks |
| EP2105486A1 (en) | 2008-03-25 | 2009-09-30 | KiOR Inc. | Low total acid number bio-crude |
| EP2105456A1 (en) | 2008-03-25 | 2009-09-30 | KiOR Inc. | Composition comprising solid biomass coated onto a solid catalyst |
| FI122778B (fi) | 2008-03-31 | 2012-06-29 | Metso Power Oy | Pyrolyysimenetelmä kattilan yhteydessä ja pyrolyysilaitteisto |
| CN101550347B (zh) | 2008-04-02 | 2013-01-09 | 朱复东 | 生物质浆态雾化热裂解工艺 |
| US8329967B2 (en) | 2008-04-06 | 2012-12-11 | Uop Llc | Production of blended fuel from renewable feedstocks |
| US20090253947A1 (en) | 2008-04-06 | 2009-10-08 | Brandvold Timothy A | Production of Blended Fuel from Renewable Feedstocks |
| US8329968B2 (en) | 2008-04-06 | 2012-12-11 | Uop Llc | Production of blended gasoline aviation and diesel fuels from renewable feedstocks |
| WO2009126508A2 (en) | 2008-04-06 | 2009-10-15 | Uop Llc | Fuel and fuel blending components from biomass derived pyrolysis oil |
| US8324438B2 (en) | 2008-04-06 | 2012-12-04 | Uop Llc | Production of blended gasoline and blended aviation fuel from renewable feedstocks |
| CN101294085A (zh) | 2008-04-07 | 2008-10-29 | 赵靖敏 | 一种生物质燃气的制备方法及其装置 |
| US7897124B2 (en) | 2008-09-18 | 2011-03-01 | Gunnerman Rudolf W | Continuous process and plant design for conversion of biogas to liquid fuel |
| WO2009126765A2 (en) | 2008-04-09 | 2009-10-15 | Velocys Inc. | Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology |
| US8100996B2 (en) | 2008-04-09 | 2012-01-24 | Velocys, Inc. | Process for upgrading a carbonaceous material using microchannel process technology |
| US7888540B2 (en) | 2008-04-11 | 2011-02-15 | General Electric Company | Integrated system and method for producing fuel composition from biomass |
| US8097090B2 (en) | 2008-04-25 | 2012-01-17 | Ensyn Renewables Inc. | Mitigation of deposits and secondary reactions in thermal conversion processes |
| US20090293344A1 (en) | 2008-05-30 | 2009-12-03 | Baker Hughes Incorporated | Process for Removing Water and Water Soluble Contaminants From Biofuels |
| US8304592B2 (en) | 2008-06-24 | 2012-11-06 | Uop Llc | Production of paraffinic fuel from renewable feedstocks |
| US20090321311A1 (en) | 2008-06-27 | 2009-12-31 | Uop Llc | Production of diesel fuel from renewable feedstocks containing phosphorus |
| US8288599B2 (en) | 2008-06-30 | 2012-10-16 | Kior, Inc. | Co-processing solid biomass in a conventional petroleum refining process unit |
| CN101318622A (zh) | 2008-07-18 | 2008-12-10 | 华东理工大学 | 生物质快速裂解油水蒸气催化重整制氢的方法 |
| US8092578B2 (en) | 2008-08-25 | 2012-01-10 | Eisenmann Corporation | Method and apparatus for eliminating or reducing waste effluent from a wet electrostatic precipitator |
| CN101381611B (zh) | 2008-10-15 | 2012-04-11 | 中国林业科学研究院林产化学工业研究所 | 生物质裂解油酯化醚化提质改性为改质生物油的方法 |
| US7960598B2 (en) | 2008-12-08 | 2011-06-14 | Chevron U.S.A. Inc. | Selective, integrated processing of bio-derived ester species to yield low molecular weight hydrocarbons and hydrogen for the production of biofuels |
| CN102245170A (zh) | 2008-12-08 | 2011-11-16 | 格雷斯公司 | 使用沸石与基体表面积的比率高的催化剂使生物原料裂化的方法 |
| CN101745349B (zh) | 2008-12-12 | 2013-04-17 | 李群柱 | 一种催化剂取热方法及其装置 |
| US8252169B2 (en) | 2008-12-16 | 2012-08-28 | Macarthur James B | Process for upgrading coal pyrolysis oils |
| TWI558807B (zh) | 2008-12-17 | 2016-11-21 | 祿幕斯科技公司 | 包含分段漿料添加之氣化系統及方法 |
| US8283506B2 (en) | 2008-12-17 | 2012-10-09 | Uop Llc | Production of fuel from renewable feedstocks using a finishing reactor |
| US8246914B2 (en) | 2008-12-22 | 2012-08-21 | Uop Llc | Fluid catalytic cracking system |
| US20100162625A1 (en) | 2008-12-31 | 2010-07-01 | Innovative Energy Global Limited | Biomass fast pyrolysis system utilizing non-circulating riser reactor |
| CN101544901B (zh) | 2009-05-05 | 2012-05-23 | 江苏大学 | 生物质热裂解制取生物油的方法及装置 |
| CN102438969A (zh) | 2009-05-22 | 2012-05-02 | 科伊奥股份有限公司 | 利用氢源处理生物质 |
| US20100325954A1 (en) | 2009-06-30 | 2010-12-30 | General Electric Company | Quench chamber assembly for a gasifier |
| CN101993712B (zh) | 2009-08-17 | 2013-03-06 | 中国石油大学(北京) | 一种灵活调整催化裂化反应-再生系统热量平衡的方法 |
| US20110068585A1 (en) | 2009-09-24 | 2011-03-24 | Alstom Technology Ltd | Method and system for capturing and utilizing energy generated in a flue gas stream processing system |
| ITMI20091630A1 (it) | 2009-09-24 | 2011-03-24 | Mec Srl | Impianto e procedimento per produrre pellet di anidride carbonica ghiacciata |
| EP2499224B1 (en) | 2009-11-09 | 2018-01-10 | Rohit Joshi | Method for processing of spent lubricating oil |
| DE102009052282B4 (de) | 2009-11-09 | 2012-11-29 | Thyssenkrupp Uhde Gmbh | Verfahren zur Kompensation von Abgasenthalpieverlusten von Heat-Recovery-Koksöfen |
| US8314275B2 (en) | 2009-11-23 | 2012-11-20 | Uop Llc | Methods for producing biomass-derived pyrolysis oils having increased phase stability |
| EP2325281A1 (en) | 2009-11-24 | 2011-05-25 | Shell Internationale Research Maatschappij B.V. | Process for the catalytic cracking of pyrolysis oils |
| US8404909B2 (en) | 2009-12-09 | 2013-03-26 | Chevron U.S.A. Inc. | Method for capturing carbon dioxide from biomass pyrolysis process |
| US8715490B2 (en) | 2009-12-23 | 2014-05-06 | Uop Llc | Low metal biomass-derived pyrolysis oils and processes for producing the same |
| US8864999B2 (en) | 2009-12-23 | 2014-10-21 | Uop Llc | Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods |
| US8524087B2 (en) | 2009-12-23 | 2013-09-03 | Uop Llc | Low metal, low water biomass-derived pyrolysis oils and methods for producing the same |
| US20110146140A1 (en) | 2009-12-23 | 2011-06-23 | Brandvold Timothy A | Low water biomass-derived pyrolysis oil and processes for preparing the same |
| US8471081B2 (en) | 2009-12-28 | 2013-06-25 | Uop Llc | Production of diesel fuel from crude tall oil |
| US8404910B2 (en) | 2010-02-17 | 2013-03-26 | Uop Llc | Low oxygen biomass-derived pyrolysis oils and methods for producing the same |
| US8519203B2 (en) | 2010-02-17 | 2013-08-27 | Uop Llc | Low oxygen biomass-derived pyrolysis oils and methods for producing the same |
| US8575408B2 (en) | 2010-03-30 | 2013-11-05 | Uop Llc | Use of a guard bed reactor to improve conversion of biofeedstocks to fuel |
| US20110239530A1 (en) | 2010-03-30 | 2011-10-06 | Uop Llc | Use of well mixed, backmixed reactors for processing of unstable bio feedstocks |
| US8251227B2 (en) | 2010-04-16 | 2012-08-28 | Kellogg Brown & Root Llc | Methods and apparatus for separating particulates from a particulate-fluid mixture |
| US20110284359A1 (en) | 2010-05-20 | 2011-11-24 | Uop Llc | Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas |
| EP2404983A1 (en) | 2010-07-06 | 2012-01-11 | Total Raffinage Marketing | Hydroconversion process for heavy hydrocarbonaceous feedstock |
| US8499702B2 (en) | 2010-07-15 | 2013-08-06 | Ensyn Renewables, Inc. | Char-handling processes in a pyrolysis system |
| US8057641B2 (en) | 2010-07-19 | 2011-11-15 | Kior Inc. | Method and apparatus for pyrolysis of a biomass |
| US8519205B2 (en) | 2010-07-23 | 2013-08-27 | Ensyn Renewables, Inc. | Low water biomass-derived pyrolysis oils and processes for producing the same |
| US9222044B2 (en) | 2010-07-26 | 2015-12-29 | Uop Llc | Methods for producing low oxygen biomass-derived pyrolysis oils |
| US20120023809A1 (en) | 2010-07-28 | 2012-02-02 | Uop Llc | Methods for producing phase stable, reduced acid biomass-derived pyrolysis oils |
| US8083900B2 (en) | 2010-08-09 | 2011-12-27 | Kior Inc. | Removal of water from bio-oil |
| EP2638127A1 (en) | 2010-11-12 | 2013-09-18 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of a biofuel and/or biochemical |
| US20120137939A1 (en) | 2010-12-06 | 2012-06-07 | Uop Llc | Processes and systems for producing heat for rapid thermal processing of carbonaceous material |
| CA2819172A1 (en) | 2010-12-24 | 2012-06-28 | Sapphire Energy, Inc. | Production of aromatics from renewable resources |
| US8829258B2 (en) | 2010-12-27 | 2014-09-09 | Phillips 66 Company | Integrated FCC biomass pyrolysis/upgrading |
| US20120167454A1 (en) | 2010-12-30 | 2012-07-05 | Uop Llc | Pretreatment of fats and oils in the production of biofuels |
| US8716522B2 (en) | 2010-12-30 | 2014-05-06 | Uop Llc | Acetic acid production from biomass pyrolysis |
| MX2013007131A (es) | 2010-12-30 | 2013-11-04 | Kior Inc | Produccion de biocombustibles renovables. |
| US9441887B2 (en) | 2011-02-22 | 2016-09-13 | Ensyn Renewables, Inc. | Heat removal and recovery in biomass pyrolysis |
| US8236173B2 (en) | 2011-03-10 | 2012-08-07 | Kior, Inc. | Biomass pretreatment for fast pyrolysis to liquids |
| US8100990B2 (en) | 2011-05-15 | 2012-01-24 | Avello Bioenery, Inc. | Methods for integrated fast pyrolysis processing of biomass |
| US9193924B2 (en) | 2011-06-16 | 2015-11-24 | Uop Llc | Methods and apparatuses for forming low-metal biomass-derived pyrolysis oil |
| US9475960B2 (en) | 2011-07-29 | 2016-10-25 | Inaeris Technologies, Llc | Coating composition |
| US9347005B2 (en) | 2011-09-13 | 2016-05-24 | Ensyn Renewables, Inc. | Methods and apparatuses for rapid thermal processing of carbonaceous material |
| US9109174B2 (en) | 2011-09-20 | 2015-08-18 | Phillips 66 Company | Advanced cellulosic renewable fuels |
| US9044727B2 (en) | 2011-09-22 | 2015-06-02 | Ensyn Renewables, Inc. | Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material |
| US10041667B2 (en) | 2011-09-22 | 2018-08-07 | Ensyn Renewables, Inc. | Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same |
| WO2013049665A2 (en) | 2011-09-30 | 2013-04-04 | Chevron U.S.A., Inc. | Process for producing a refinery stream-compatible bio-oil from a lignocellulosic feedstock |
| US9168500B2 (en) | 2011-10-26 | 2015-10-27 | Res Usa, Llc | Gasifier fluidization |
| US20130105356A1 (en) | 2011-10-31 | 2013-05-02 | Shell Oil Company | Method for upgrading an oil, a fuel product and a hydrocarbon product fraction |
| AU2012338868A1 (en) | 2011-11-14 | 2014-05-01 | Shell Internationale Research Maatschappij B.V. | Process for conversion of a cellulosic material |
| US9109177B2 (en) | 2011-12-12 | 2015-08-18 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
| US9068126B2 (en) | 2011-12-14 | 2015-06-30 | Uop Llc | Methods for deoxygenating biomass-derived pyrolysis oil |
| US8940060B2 (en) | 2011-12-15 | 2015-01-27 | Uop Llc | Methods and apparatuses for forming low-metal biomass-derived pyrolysis oil |
| US8877995B2 (en) | 2011-12-16 | 2014-11-04 | Uop Llc | Pyrolysis fuels and methods for processing pyrolysis fuels |
| US9242219B2 (en) | 2012-01-30 | 2016-01-26 | PHG Energy, LLC | Fluidized bed biogasifier and method for gasifying biosolids |
| US8546635B1 (en) | 2012-04-04 | 2013-10-01 | Uop Llc | Methods and apparatuses for preparing upgraded pyrolysis oil |
| US9670413B2 (en) | 2012-06-28 | 2017-06-06 | Ensyn Renewables, Inc. | Methods and apparatuses for thermally converting biomass |
| CN104718010B (zh) | 2012-08-24 | 2017-08-15 | 安辛可再生能源有限公司 | 用于热制液体的脱挥发的系统和方法 |
| US9150466B2 (en) | 2012-11-20 | 2015-10-06 | Uop Llc | Counter-current fluidized bed reactor for the dehydrogenation of olefins |
| US9023285B2 (en) | 2012-11-20 | 2015-05-05 | Uop Llc | Counter-current fluidized bed reactor for the dehydrogenation of olefins |
| EP3013922A4 (en) | 2013-06-26 | 2017-02-08 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN102702139B (zh) | 2016-01-20 |
| CN102702139A (zh) | 2012-10-03 |
| EP3252128A3 (en) | 2018-03-28 |
| EP2007744A4 (en) | 2014-03-26 |
| CA2647564C (en) | 2016-08-30 |
| EP3252128A1 (en) | 2017-12-06 |
| US9809564B2 (en) | 2017-11-07 |
| US9127208B2 (en) | 2015-09-08 |
| WO2007112570A1 (en) | 2007-10-11 |
| EP2007744A1 (en) | 2008-12-31 |
| EP3252128B1 (en) | 2019-01-02 |
| CN101460473A (zh) | 2009-06-17 |
| DK2007744T3 (da) | 2017-08-28 |
| US20090298927A1 (en) | 2009-12-03 |
| CA2647564A1 (en) | 2007-10-11 |
| EP2007744B1 (en) | 2017-05-17 |
| US20160024037A1 (en) | 2016-01-28 |
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