ECSP088686A - Proceso híbrido que usa resinas de intercambio iónico en la recuperación selectiva de níquel y cobalto a partir de efluentes de lixiviación - Google Patents

Proceso híbrido que usa resinas de intercambio iónico en la recuperación selectiva de níquel y cobalto a partir de efluentes de lixiviación

Info

Publication number
ECSP088686A
ECSP088686A EC2008008686A ECSP088686A ECSP088686A EC SP088686 A ECSP088686 A EC SP088686A EC 2008008686 A EC2008008686 A EC 2008008686A EC SP088686 A ECSP088686 A EC SP088686A EC SP088686 A ECSP088686 A EC SP088686A
Authority
EC
Ecuador
Prior art keywords
ion exchange
cobalt
nickel
effluents
lixiviation
Prior art date
Application number
EC2008008686A
Other languages
English (en)
Inventor
Renato De Souza Costa
Flavia Dutra Mendes
Original Assignee
Vale Do Rio Doce Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vale Do Rio Doce Co filed Critical Vale Do Rio Doce Co
Publication of ECSP088686A publication Critical patent/ECSP088686A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0407—Leaching processes
    • C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/043—Sulfurated acids or salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/02—Column or bed processes
    • B01J47/026—Column or bed processes using columns or beds of different ion exchange materials in series
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0476—Separation of nickel from cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Analytical Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

La presente invención está dirigida a un proceso híbrido que usa resinas de intercambio iónico en la recuperación selectiva de níquel y cobalto de los efluentes de lixiviación, que está compuesto de los pasos de: procesamiento (1) del mineral de laterita (M), el cual es luego tratado mediante lixiviación (2) (ya sea a presión atmosférica o bajo presión), considerando las soluciones provenientes del paso de separación sólido-líquido de las instalaciones ya existentes en funcionamiento (2) también, de manera que el proceso corriente abajo comprende un circuito híbrido de intercambio iónico, donde el primer paso de intercambio iónico (3) con resinas (Re) muestra condiciones de selectividad específicas para la extracción de hierro, aluminio y cobre y un aumento del pH, y el segundo paso de intercambio iónico (4) permite la extracción de níquel y cobalto.
EC2008008686A 2006-02-02 2008-08-19 Proceso híbrido que usa resinas de intercambio iónico en la recuperación selectiva de níquel y cobalto a partir de efluentes de lixiviación ECSP088686A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0600901-8A BRPI0600901B1 (pt) 2006-02-02 2006-02-02 Processo híbrido de resinas de troca iônica na recuperação seletiva de níquel e cobalto de efluentes de lixiviação

Publications (1)

Publication Number Publication Date
ECSP088686A true ECSP088686A (es) 2008-09-29

Family

ID=38327097

Family Applications (1)

Application Number Title Priority Date Filing Date
EC2008008686A ECSP088686A (es) 2006-02-02 2008-08-19 Proceso híbrido que usa resinas de intercambio iónico en la recuperación selectiva de níquel y cobalto a partir de efluentes de lixiviación

Country Status (15)

Country Link
US (1) US9034283B2 (es)
EP (1) EP2038437B1 (es)
JP (1) JP5282027B2 (es)
KR (1) KR101433960B1 (es)
CN (1) CN101415848A (es)
AU (1) AU2007211854B2 (es)
BR (1) BRPI0600901B1 (es)
CA (1) CA2648095C (es)
EC (1) ECSP088686A (es)
ES (1) ES2394287T3 (es)
GT (1) GT200800150A (es)
HN (1) HN2008001211A (es)
RU (1) RU2418873C2 (es)
WO (1) WO2007087698A1 (es)
ZA (1) ZA200806650B (es)

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BRPI0612374B1 (pt) * 2006-11-10 2015-08-11 Vale Sa Processo de recuperação de níquel e cobalto a partir de minérios lateríticos empregando resina de troca iônica e produto contendo níquel ou cobalto
US7901484B2 (en) * 2007-08-28 2011-03-08 Vale Inco Limited Resin-in-leach process to recover nickel and/or cobalt in ore leaching pulps
US20090056501A1 (en) * 2007-08-29 2009-03-05 Vale Inco Limited Hydrometallurgical process using resin-neutralized-solution of a heap leaching effluent
FR2925349A1 (fr) 2007-12-20 2009-06-26 Applexion Procede de separation sequence multicolonnes d'un derive metallique ionique
WO2010037169A1 (en) * 2008-10-01 2010-04-08 The University Of Queensland Process for extraction of mined material
JP5154622B2 (ja) * 2010-03-02 2013-02-27 Ｊｘ日鉱日石金属株式会社 銅含有水溶液に含まれるコバルトの回収方法
JP2011214132A (ja) * 2010-03-17 2011-10-27 Jx Nippon Mining & Metals Corp コバルトを回収する方法
CN102010996A (zh) * 2010-11-26 2011-04-13 兰州金川新材料科技股份有限公司 一种硫化镍矿生物堆浸溶液的处理方法
RU2466101C1 (ru) * 2011-03-11 2012-11-10 Государственное образовательное учреждение высшего профессионального образования Воронежская государственная технологическая академия (ГОУ ВПО ВГТА) Способ ионообменного разделения ионов меди (ii) и никеля (ii)
RU2621504C2 (ru) 2012-05-01 2017-06-06 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Извлечение никеля и кобальта с использованием непрерывного ионного обмена
KR101389484B1 (ko) * 2012-05-16 2014-04-25 한국지질자원연구원 저농도 구리이온이 함유된 용액으로부터 구리이온 제거방법
CN102815763B (zh) * 2012-09-17 2013-11-06 工信华鑫科技有限公司 通过重金属吸附材料实现铜钴分离、富集、提纯的方法
CN103173623B (zh) * 2013-02-28 2014-11-05 江西铜业股份有限公司 一种从多金属酸性水中回收镍钴的方法
KR101654198B1 (ko) * 2014-12-30 2016-09-05 엘에스니꼬동제련 주식회사 저품위 니켈광석 제련시 발생하는 폐액으로부터 코발트 및 니켈의 회수방법
KR101662725B1 (ko) * 2015-09-14 2016-10-05 재단법인 포항산업과학연구원 니켈 및 코발트의 추출 방법
CN107304462B (zh) * 2016-04-17 2018-12-28 湖南大学 一种可重复去除镀锌电解液中的钴离子树脂的制备方法
CN111004926A (zh) * 2018-10-08 2020-04-14 金川集团股份有限公司 一种树脂提取低品位红土镍矿浸出液中镍、钴的方法
CN110194545B (zh) * 2019-06-26 2021-04-27 浙江中金格派锂电产业股份有限公司 一种废水中镍、钴重金属与镁分离、富集和回收工艺
CN111115903A (zh) * 2020-01-06 2020-05-08 湖南中伟新能源科技有限公司 一种两级离子交换除四钴废水中钴的方法
CN111809048A (zh) * 2020-07-19 2020-10-23 河南科技大学 一种去除硫酸钴电解中痕量镍的方法
CN112143888A (zh) * 2020-10-14 2020-12-29 衢州华友钴新材料有限公司 一种镍钴浸出液深度除硅的方法
CN112452308B (zh) * 2020-12-09 2022-10-25 昆明理工大学 一种含吡啶酰胺的吸附聚合物的合成方法及应用
CN113512650A (zh) * 2021-05-27 2021-10-19 金川集团股份有限公司 一种从氧化铜钴矿湿法冶炼尾矿中高效回收金属钴的方法
JP2025510170A (ja) * 2022-03-22 2025-04-14 ランクセス・ドイチュランド・ゲーエムベーハー アルミニウムイオン及び／又は亜鉛イオンを溶出させるための方法
CN115700226B (zh) * 2022-11-18 2024-06-25 金川集团镍钴有限公司 一种掺铝碳酸钴生产中工业废水的除重方法
WO2025000318A1 (zh) * 2023-06-29 2025-01-02 广东邦普循环科技有限公司 一种镍铁合金制备磷酸铁过程中的洗水的资源化处理方法
JP7758078B2 (ja) * 2024-03-08 2025-10-22 三菱マテリアル株式会社 有価金属の回収方法

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Also Published As

Publication number Publication date
US9034283B2 (en) 2015-05-19
JP5282027B2 (ja) 2013-09-04
CN101415848A (zh) 2009-04-22
RU2418873C2 (ru) 2011-05-20
RU2008135443A (ru) 2010-03-10
GT200800150A (es) 2009-07-09
AU2007211854B2 (en) 2012-07-12
CA2648095C (en) 2015-04-07
EP2038437B1 (en) 2012-08-15
WO2007087698A8 (en) 2008-08-14
KR20080093146A (ko) 2008-10-20
AU2007211854A1 (en) 2007-08-09
ES2394287T3 (es) 2013-01-30
KR101433960B1 (ko) 2014-08-25
ZA200806650B (en) 2010-02-24
EP2038437A1 (en) 2009-03-25
BRPI0600901A (pt) 2007-10-30
WO2007087698A1 (en) 2007-08-09
BRPI0600901B1 (pt) 2018-04-03
JP2009526136A (ja) 2009-07-16
HN2008001211A (es) 2010-10-01
EP2038437A4 (en) 2010-04-07
US20080289448A1 (en) 2008-11-27
CA2648095A1 (en) 2007-08-09

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