EP0054861A1 - Procédé pour fabriquer une structure composite caoutchouc-métal - Google Patents

Procédé pour fabriquer une structure composite caoutchouc-métal Download PDF

Info

Publication number: EP0054861A1
Authority: EP; European Patent Office
Prior art keywords: coating; baked; lacquer; rubber; metal part
Prior art date: 1980-12-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP81110336A

Other languages

German (de)

English (en)

Other versions

EP0054861B1 (fr

Inventor

Volker Dr. Härtel

Fritz Schreiber

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Metzeler Gimetall AG

Original Assignee

Metzeler Kautschuk GmbH

Metzeler Kautschuk AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-12-19

Filing date

1981-12-11

Publication date

1982-06-30

1981-12-11 Application filed by Metzeler Kautschuk GmbH, Metzeler Kautschuk AG filed Critical Metzeler Kautschuk GmbH

1982-06-30 Publication of EP0054861A1 publication Critical patent/EP0054861A1/fr

1986-08-20 Application granted granted Critical

1986-08-20 Publication of EP0054861B1 publication Critical patent/EP0054861B1/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 21
239000002184 metal Substances 0.000 title claims abstract description 20
229910052751 metal Inorganic materials 0.000 title claims abstract description 20
239000002131 composite material Substances 0.000 title 1
239000004922 lacquer Substances 0.000 claims abstract description 22
229920005989 resin Polymers 0.000 claims abstract description 8
239000011347 resin Substances 0.000 claims abstract description 8
238000004519 manufacturing process Methods 0.000 claims abstract description 7
238000000576 coating method Methods 0.000 claims description 25
239000011248 coating agent Substances 0.000 claims description 23
238000003618 dip coating Methods 0.000 claims description 12
239000003973 paint Substances 0.000 claims description 12
239000002905 metal composite material Substances 0.000 claims description 8
230000007797 corrosion Effects 0.000 claims description 6
238000005260 corrosion Methods 0.000 claims description 6
239000004593 Epoxy Substances 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
229920000877 Melamine resin Polymers 0.000 claims description 4
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
239000004202 carbamide Substances 0.000 claims description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
238000004070 electrodeposition Methods 0.000 claims description 3
125000004185 ester group Chemical group 0.000 claims description 3
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
239000011701 zinc Substances 0.000 claims description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 6
239000011230 binding agent Substances 0.000 claims 2
229920001807 Urea-formaldehyde Polymers 0.000 claims 1
239000003822 epoxy resin Substances 0.000 claims 1
229920000647 polyepoxide Polymers 0.000 claims 1
239000004848 polyfunctional curative Substances 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 4
239000000945 filler Substances 0.000 abstract description 3
239000003431 cross linking reagent Substances 0.000 abstract description 2
238000007598 dipping method Methods 0.000 abstract 1
239000000853 adhesive Substances 0.000 description 5
230000001070 adhesive effect Effects 0.000 description 5
238000010422 painting Methods 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000010439 graphite Substances 0.000 description 2
229910002804 graphite Inorganic materials 0.000 description 2
238000007654 immersion Methods 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000004073 vulcanization Methods 0.000 description 2
239000004971 Cross linker Substances 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000006735 deficit Effects 0.000 description 1
238000000151 deposition Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000000502 dialysis Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008595 infiltration Effects 0.000 description 1
238000001764 infiltration Methods 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000004636 vulcanized rubber Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process

Definitions

the invention relates to a method for producing a corrosion protection; paint coating to be burned on the metal part of a rubber / metal composite part.
a rubber part is then applied to this adhesive system, which is converted into rubber by vulcanization and firmly connected to the metal.
the baked paint layer provides the same adhesive strength as the usual metal / rubber connection; however, the adhesion to the burned-on lacquer layer is more resistant to rusting and infiltration by aqueous media, salt solutions, etc., as is particularly important for the use of such rubber / metal composite bodies in motor vehicles.
the lacquer layer baked at high temperatures is also sufficiently resistant to mechanical stress, such as occurs when cleaning rubber overflows with rotating brushes.
a disadvantage of the known method is that a uniform coating of paint cannot be achieved by spraying on the paint system; this applies in particular to the hard-to-reach areas of a metal part, as they occur in particular in the case of more complicated rubber / metal composite parts.
the invention is therefore based on the object of providing a method for producing a lacquer coating of the type specified, in which the disadvantages mentioned above are avoided.
lacquer coatings applied by electrocoating in particular cataphoretic immersion coating, have a very uniform layer thickness over the entire surface of the metal part.
the high grip of the cataphoretic dip coating ensures that the layer of the coating is so thin and uniform, even in hard-to-reach areas of the metal part, that even threads can be coated with the appropriate design and still retain the teaching.
water-soluble, precondensed epoxy ester systems are used for the cataphoretic dip coating, the ester groups being formaldehyde-reactive resin groups based on phenol, melamine or urea.
the dispenser systems are blocked; the reactions, i.e. the polyaddition and polycondensation, take place at about 250 ° C.
the workpiece to be coated forms the cathode, that is to say the negative pole, while additional anodes made of a special material, for example graphite, which are usually hung in dialysis boxes, serve as the positive pole; the pool itself is grounded and isolated.
additional anodes made of a special material for example graphite, which are usually hung in dialysis boxes, serve as the positive pole; the pool itself is grounded and isolated.
cataphoretic dip painting a water-insoluble lye is released in the boundary layer of the cathode, i.e. the workpiece.
the coagulated paint adheres to the cathode, i.e. to the workpiece.
the polarity reversed compared to the anaphoretic dip coating brings about a major advantage of the cataphoretic dip coating: Since the workpiece to be coated forms the cathode, in contrast to the anaphoretic dip coating, no metal ions can be released on the workpiece. Furthermore, no acidic area arises in the boundary layer, so that the generally in the pretreatment brought phosphate layer is protected against destruction; this is an essential factor for the higher corrosion resistance.
the metal part to be coated is first degreased and then provided with zinc phosphating with a passive rinse. This rinsing can be carried out with a solution containing Cr VI, which leads to a solidification of the phosphate layer.
the metal part pretreated in this way is then hung in a basin for cataphoretic dip coating and connected to the negative pole of a power source (see FIG. 2), so that the metal part serves as a cathode.
the anode is formed by a graphite plate arranged in the lacquer solution, which is connected to the positive pole of the power source.
the pool itself is grounded and isolated, as can be seen in Figure 2.
a water-soluble, precondensed epoxy ester system is used as the paint system, the ester groups being formaldehyde-reactive resin groups based on phenol, melamine or urea.
the dispenser systems are blocked.
a coating of sufficient thickness is deposited within 30 to 60 seconds, which is then baked at about 250 ° C.
the lacquer layer finally obtained has a thickness of about 20 / u m.
a commercially available adhesive system is then applied to this baked lacquer layer, which essentially consists of halogenated polymers mixed with fillers, resins and crosslinking agents. Details of the structure of such adhesive systems can be found in the above-mentioned patents.
a rubber part is then applied to this business system, which is firmly connected to the metal part by vulcanization.
the paint system with the specified structure leads to a tough, elastic, impact and abrasion-resistant coating, so that there is a substantial improvement in the corrosion resistance and the mechanical strength without any impairment of the adhesiveness.

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Paints Or Removers (AREA)
Application Of Or Painting With Fluid Materials (AREA)
Laminated Bodies (AREA)

EP81110336A 1980-12-19 1981-12-11 Procédé pour fabriquer une structure composite caoutchouc-métal Expired EP0054861B1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19803047992 DE3047992A1 (de)	1980-12-19	1980-12-19	Verfahren zur herstellung eines lackueberzuges auf dem metallteil eines gummi/metall-verbundteils
DE3047992		1980-12-19

Publications (2)

Publication Number	Publication Date
EP0054861A1 true EP0054861A1 (fr)	1982-06-30
EP0054861B1 EP0054861B1 (fr)	1986-08-20

Family

ID=6119670

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP81110336A Expired EP0054861B1 (fr)	1980-12-19	1981-12-11	Procédé pour fabriquer une structure composite caoutchouc-métal

Country Status (4)

Country	Link
EP (1)	EP0054861B1 (fr)
CA (1)	CA1148896A (fr)
DE (2)	DE3047992A1 (fr)
ES (1)	ES508091A0 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19515234A1 (de) *	1995-04-28	1996-10-31	Henkel Kgaa	Metallteile mit einer Korrosionsschutz-Schicht
DE19640180A1 (de) *	1996-09-30	1998-04-09	Freudenberg Carl Fa	Verfahren zur Herstellung eines Gummi-Metall-Teils
EP0786336A3 (fr) *	1996-01-29	1998-09-02	Firma Carl Freudenberg	Procédé pour fabriquer un article en caoutchouc et métal
CN110565149A (zh) *	2019-08-12	2019-12-13	东风商用车有限公司	一种带橡胶金属件的防腐方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4135188A1 (de) *	1991-10-24	1993-04-29	Lucas Ind Plc	Verbundkoerper und verfahren zum herstellen eines solchen
DE19755421A1 (de)	1997-12-13	1999-06-17	Henkel Kgaa	Gummi-Metall-Verbund
DE102005016607B3 (de) *	2005-04-11	2006-10-19	Trelleborg Automotive Technical Centre Gmbh	Vorrichtung zur Dämpfung von Schwingungen an einer Kurbelwelle sowie Verfahren zur Herstellung einer derartigen Vorrichtung

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1526244A (fr) *	1967-04-13	1968-05-24	Vernis Bouvet Soc D	Procédé de revêtement sélectif par électrophorèse d'un support conducteur de l'électricité
US4049168A (en) *	1975-09-24	1977-09-20	Milliken Research Corporation	Tension equalizer
DE2748686A1 (de) *	1976-11-01	1978-05-11	Lord Corp	Gummi-metallstruktur mit erhoehter korrosionsfestigkeit

1980
- 1980-12-19 DE DE19803047992 patent/DE3047992A1/de not_active Withdrawn
1981
- 1981-03-27 CA CA000374075A patent/CA1148896A/fr not_active Expired
- 1981-12-11 EP EP81110336A patent/EP0054861B1/fr not_active Expired
- 1981-12-11 DE DE8181110336T patent/DE3175180D1/de not_active Expired
- 1981-12-17 ES ES508091A patent/ES508091A0/es active Granted

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1526244A (fr) *	1967-04-13	1968-05-24	Vernis Bouvet Soc D	Procédé de revêtement sélectif par électrophorèse d'un support conducteur de l'électricité
US4049168A (en) *	1975-09-24	1977-09-20	Milliken Research Corporation	Tension equalizer
DE2748686A1 (de) *	1976-11-01	1978-05-11	Lord Corp	Gummi-metallstruktur mit erhoehter korrosionsfestigkeit

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Chemical Engineering, Band 78, Nr. 13, 14. Juni 1971, seiten 114-118 M. WISMER et al.: "Make the Part the Cathode: Key to Resistant Coatings" *
WILLIBALD MACHU: "Elektrotauchlackierung", 1974, seiten 3, 4, 101, 172 Verlag Chemie *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19515234A1 (de) *	1995-04-28	1996-10-31	Henkel Kgaa	Metallteile mit einer Korrosionsschutz-Schicht
EP0786336A3 (fr) *	1996-01-29	1998-09-02	Firma Carl Freudenberg	Procédé pour fabriquer un article en caoutchouc et métal
DE19640180A1 (de) *	1996-09-30	1998-04-09	Freudenberg Carl Fa	Verfahren zur Herstellung eines Gummi-Metall-Teils
EP0832915A3 (fr) *	1996-09-30	1998-08-12	Firma Carl Freudenberg	Procédé de fabrication de pièces en caoutchouc et métal
DE19640180C2 (de) *	1996-09-30	1999-07-01	Freudenberg Carl Fa	Verfahren zur Herstellung eines Gummi-Metall-Teils und Verwendung des Verfahrens
CN110565149A (zh) *	2019-08-12	2019-12-13	东风商用车有限公司	一种带橡胶金属件的防腐方法
CN110565149B (zh) *	2019-08-12	2021-02-09	东风商用车有限公司	一种带橡胶金属件的防腐方法

Also Published As

Publication number	Publication date
DE3175180D1 (en)	1986-09-25
EP0054861B1 (fr)	1986-08-20
ES8301288A1 (es)	1982-12-01
DE3047992A1 (de)	1982-07-15
CA1148896A (fr)	1983-06-28
ES508091A0 (es)	1982-12-01

Legal Events

Date	Code	Title	Description
1982-04-30	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
1982-06-30	AK	Designated contracting states	Designated state(s): CH DE FR GB IT LI SE
1983-03-09	17P	Request for examination filed	Effective date: 19821222
1983-03-09	RAP1	Party data changed (applicant data changed or rights of an application transferred)	Owner name: METZELER KAUTSCHUK GMBH
1986-07-05	GRAA	(expected) grant	Free format text: ORIGINAL CODE: 0009210
1986-08-20	AK	Designated contracting states	Kind code of ref document: B1 Designated state(s): CH DE FR GB IT LI SE
1986-08-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: SE Effective date: 19860831
1986-09-25	REF	Corresponds to:	Ref document number: 3175180 Country of ref document: DE Date of ref document: 19860925
1986-10-10	ET	Fr: translation filed
1986-11-06	ITF	It: translation for a ep patent filed
1987-06-22	PLBE	No opposition filed within time limit	Free format text: ORIGINAL CODE: 0009261
1987-06-22	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT
1987-08-12	26N	No opposition filed
1987-12-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: LI Effective date: 19871231 Ref country code: CH Effective date: 19871231
1988-08-31	REG	Reference to a national code	Ref country code: CH Ref legal event code: PL
1988-11-18	REG	Reference to a national code	Ref country code: FR Ref legal event code: CN
1990-12-31	ITTA	It: last paid annual fee
1993-02-08	ITPR	It: changes in ownership of a european patent	Owner name: CAMBIO RAGIONE SOCIALE;METZELER AUTOMOTIVE PROFILE
1993-02-09	ITPR	It: changes in ownership of a european patent	Owner name: CESSIONE;METZELER GIMETALL AG
1993-02-24	REG	Reference to a national code	Ref country code: GB Ref legal event code: 732E
1993-07-09	REG	Reference to a national code	Ref country code: FR Ref legal event code: TP Ref country code: FR Ref legal event code: CD Ref country code: FR Ref legal event code: CA
1994-12-01	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: GB Payment date: 19941201 Year of fee payment: 14
1994-12-08	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: DE Payment date: 19941208 Year of fee payment: 14
1994-12-09	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: FR Payment date: 19941209 Year of fee payment: 14
1995-12-11	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: GB Effective date: 19951211
1996-07-31	GBPC	Gb: european patent ceased through non-payment of renewal fee	Effective date: 19951211
1996-08-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: FR Effective date: 19960830
1996-10-01	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: DE Effective date: 19961001
1996-10-31	REG	Reference to a national code	Ref country code: FR Ref legal event code: ST

Publication	Publication Date	Title
DE60021763T2 (de)	2006-04-20	Beschichtete metallische substrate und verfahren zur herstellung und verfahren zur verhinderung der korrosion
DE102013201388A1 (de)	2014-07-31	Verfahren zur Herstellung eines Metall-Kunststoff-Hybridbauteils
EP0783548B2 (fr)	2001-11-28	Procede de production d'un revetement anticorrosion, a forte adherence, et pieces ainsi revetues
DE3640662A1 (de)	1987-10-15	Hoch korrosionsbestaendiges, oberflaechenbehandeltes stahlblech
DE10022075A1 (de)	2001-11-08	Leitfähige, organische Beschichtungen
DE3412234A1 (de)	1985-10-10	Gleitfaehiger und schweissbarer korrosionsschutzprimer fuer elektrolytisch duennverzinktes, verformbares, phosphatiertes oder chromatisiertes stahlblech
DE69111189T2 (de)	1995-12-07	Verfahren zur Erzeugung eines organisch verbundbeschichteten Stahlbleches.
DE102011004801B4 (de)	2013-11-07	Selektiv beschichtete CFK-Bauteile und Verfahren zu deren Herstellung
EP0054861A1 (fr)	1982-06-30	Procédé pour fabriquer une structure composite caoutchouc-métal
WO1995033083A1 (fr)	1995-12-07	Procede de revetement de substrats metalliques phosphates
CA2013089A1 (fr)	1990-09-30	Tole d'acier avec revetement organique, presentant une resistance amelioree a la corrosion, a l'etat final
DE3833119C2 (fr)	1990-09-27
DE2611046A1 (de)	1976-10-07	Grundiermittel fuer die kunststoffbeschichtung von metallen
EP0044917B1 (fr)	1986-09-10	Agent d'adhérence pour un matériau de support
DE68927072T2 (de)	1997-02-27	Organische Beschichtungsmasse für Metalle
DE4303787C1 (de)	1994-03-24	Verfahren zur Herstellung von Elektrotauchlacküberzügen, die frei von Oberflächenstörungen sind und Verwendung von wäßrigen Polyvinylalkohollösungen zur Nachbehandlung von elektrophoretisch abgeschiedenen Überzügen
DE69614606T2 (de)	2002-07-04	Organisch beschichtetes Verbundstahlblech
EP0033465B1 (fr)	1983-09-21	Procédé de fabrication d'un produit composé d'un substrat électroconducteur et d'un revêtement d'apparence métallique adhérant solidement au substrat
DE19640180C2 (de)	1999-07-01	Verfahren zur Herstellung eines Gummi-Metall-Teils und Verwendung des Verfahrens
DE60219714T2 (de)	2007-12-27	Elektrobeschichtungsverfahren
DE69002481T2 (de)	1993-12-16	Verfahren zur Beschichtung von Werkstücken mit Aluminium.
DE3116404A1 (de)	1982-05-19	Beschichtungs-zusammensetzung und verfahren fuer die kathodische elektrolytische abscheidung
DE68906651T2 (de)	1993-09-02	Zusammensetzung und verfahren zur behandlung von metalloberflaechen.
DE1496753A1 (de)	1969-08-07	Verbundmaterial
DE19534898A1 (de)	1996-08-29	Verfahren zur Elektrotauchlackierung von Kunststoffsubstraten