EP0121089A2 - Combustible pour moteurs - Google Patents

Combustible pour moteurs Download PDF

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Publication number
EP0121089A2
EP0121089A2 EP84102024A EP84102024A EP0121089A2 EP 0121089 A2 EP0121089 A2 EP 0121089A2 EP 84102024 A EP84102024 A EP 84102024A EP 84102024 A EP84102024 A EP 84102024A EP 0121089 A2 EP0121089 A2 EP 0121089A2
Authority
EP
European Patent Office
Prior art keywords
ethanol
vol
butanol
methanol
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84102024A
Other languages
German (de)
English (en)
Other versions
EP0121089A3 (en
EP0121089B1 (fr
Inventor
Hans-Joachim Majunke
Heinrich Dr. Müller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DEA Mineraloel AG
Original Assignee
DEA Mineraloel AG
Union Rheinische Braunkohlen Kraftstoff AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6192400&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0121089(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by DEA Mineraloel AG, Union Rheinische Braunkohlen Kraftstoff AG filed Critical DEA Mineraloel AG
Priority to AT84102024T priority Critical patent/ATE43625T1/de
Publication of EP0121089A2 publication Critical patent/EP0121089A2/fr
Publication of EP0121089A3 publication Critical patent/EP0121089A3/de
Application granted granted Critical
Publication of EP0121089B1 publication Critical patent/EP0121089B1/fr
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B1/00Engines characterised by fuel-air mixture compression
    • F02B1/02Engines characterised by fuel-air mixture compression with positive ignition
    • F02B1/04Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder

Definitions

  • the invention relates to an engine fuel and a method for its production, which consists of a base fuel consisting of hydrocarbons or predominantly hydrocarbons and additions of alcohols and / or ethers and / or ketones and additives and optionally water and aromatics.
  • Bioethanol can be obtained in burners with relatively little expenditure on equipment and energy. Since this bioalcohol also contains organic impurities, e.g. Aldehydes, ketones, acetic acid and esters have so far not considered the use of this bioethanol in motor vehicles as an additive to conventional petrol fuels feasible, and in addition the problem of complete miscibility at particularly low outside temperatures due to the high water content of the bioalcohol was not considered economically solvable has been.
  • organic impurities e.g. Aldehydes, ketones, acetic acid and esters
  • a typical bioethanol has e.g. B. the following data:
  • the object of the present invention was therefore to provide a fuel which avoids the specified technical problems, meets all the requirements of the fuel standards, takes into account the availability of the additional components and can be offered to the motorist in the existing gas station distribution network without any problems.
  • the object was achieved according to the invention by a new motor fuel consisting of base fuel, hydrocarbons or predominantly hydrocarbons and consisting of additions of alcohols and / or ethers and / or ketones and optionally aromatics, additional water and additives and compounds of the lead, characterized thereby that it contains> 0 to 10 vol.% ethanol with more than the ethanol / water azeotrope (at normal pressure) corresponding water content,> 0 to 10 vol.% butanol (s) and;> 0 to 5 vol.% methanol and / or> 0 - 15 vol.% methyl tert-butyl ether and / or> 0 - 15 vol.% acetone.
  • the fuel according to the invention is excellently suited for the usual motor vehicle engines, can be mixed as desired with fuels already on the market, conversions to the carburettors and engines and other parts that use the fuel come into contact, are not required, all requirements of the DIN standard be fulfilled and the fuel can be made available to the driver at the existing filling stations.
  • the fuel according to the invention contains from> 0 to 10% by volume of ethanol with a higher water content than the ethanol / water azeotrope, but can also contain proportions of pure ethanol and / or ethanol / water azeotrope and / or ethanol or technical grade ethanol contain with less water, preferably> 0 - 5 vol.% bioethanol is used, furthermore> 0 to 5 vol.% methanol can be contained, which can be technical, undistilled methanol, or topped technical, undistilled methanol. In the latter part of the impurities contained in technical methanol is driven off overhead.
  • butanol s
  • tert-butanol tert-butanol
  • butanol mixtures can also be used, methyl tert-butyl ether and acetone.
  • Other ethers such as e.g. Dimethyl, diethyl, methyl tert-amyl ether and components such as e.g. Aromatics. Water can also be added.
  • Acetone can be added as pure or technical or bioacetone.
  • the basic hydrocarbons used are preferably super gasoline or normal gasoline or mixtures thereof which comply with the fuel standards.
  • the basic hydrocarbons can already contain additives or even methanol additions of> 0 to 5 vol.% And / or butanols of> 0 - 10 vol.% Butanol (s), these having to be taken into account accordingly when adding bioethanol according to the invention.
  • Keropur As an additive, numerous additives that are available on the market, such as Keropur from BASF, can be used. Lead can also be added in the form of its compounds commonly used in fuels.
  • the components can be mixed together by mixing a high octane hydrocarbon-based super fuel component and / or a lower octane hydrocarbon-based normal fuel component with bioethanol, methanol, butanol (s), methyl tert-butyl ether, acetone and the additives, has proven to be a preferred embodiment of mixing super fuel and / or normal fuel, which may already contain> 0-5 vol.% methanol and> 0-10 vol.% butanol (s), with a premixed component containing bioethanol, butanol ( e) and / or methanol and / or methyl tert-butyl ether and / or acetone and optionally additives and lead compounds.
  • a typical mixture according to the invention has, for example, the following composition:
  • This mixture was added to a super fuel containing no methanol / butanol additives, so that a mixture of 7 vol% and 93 vol% super fuel was obtained.
  • This mixture was added to a mixture of 80% by volume of super fuel and 10% by volume of normal fuel, so that a mixture of 90% by volume of super / normal fuel and 10% by volume of mixture of the oxygen-containing compounds was obtained.
  • This mixture was added to super fuel so that a mixture of 90% by volume of super fuel and 10% by volume of the oxygen-containing compounds was obtained.
  • the present invention is of great importance with regard to reducing the dependency on imported mineral oil, since it makes it possible for the first time to use fuel alcohol (bioalcohol) which can be obtained in fuels even with relatively little energy expenditure. Contrary to the prejudice of experts, the extensive investigations by the applicant have shown that the contaminants contained in this alcohol cause neither damage to motor vehicle parts nor increased environmental pollution.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Fuel-Injection Apparatus (AREA)
  • Valve Device For Special Equipments (AREA)
  • Lens Barrels (AREA)
EP84102024A 1983-03-03 1984-02-27 Combustible pour moteurs Expired EP0121089B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84102024T ATE43625T1 (de) 1983-03-03 1984-02-27 Motor-kraftstoff.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3307505 1983-03-03
DE3307505 1983-03-03

Publications (3)

Publication Number Publication Date
EP0121089A2 true EP0121089A2 (fr) 1984-10-10
EP0121089A3 EP0121089A3 (en) 1986-05-07
EP0121089B1 EP0121089B1 (fr) 1989-05-31

Family

ID=6192400

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84102024A Expired EP0121089B1 (fr) 1983-03-03 1984-02-27 Combustible pour moteurs

Country Status (3)

Country Link
EP (1) EP0121089B1 (fr)
AT (1) ATE43625T1 (fr)
DE (1) DE3478465D1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0227176A3 (fr) * 1985-12-19 1988-03-23 SNAMPROGETTI S.p.A. Composition oxygénée à haut indice d'octane pour combustible et méthode pour sa préparation
EP0171440B1 (fr) * 1983-08-20 1988-07-20 DEA Mineraloel Aktiengesellschaft Combustible pour moteurs
WO1989005339A1 (fr) * 1987-12-03 1989-06-15 Chemical Fuels Corporation Additifs pour l'essence ameliorant l'indice d'octane
WO2000055610A1 (fr) * 1999-03-18 2000-09-21 Aae Holdings Plc Tensioactifs
WO2001018155A1 (fr) * 1999-09-06 2001-03-15 Agrofuel Ab Carburant pour moteurs diesel, pour turbines a gaz et pour turboreacteurs comprenant au moins quatre groupes fonctionnels differents contenant de l'oxygene choisis dans le groupe constitue par alcool, ether, aldehyde, cetone, ester, ester inorganique, acetal, epoxyde et peroxyde
WO2001053436A1 (fr) * 2000-01-24 2001-07-26 Angelica Golubkov Carburant pour moteurs thermiques à étincelles
US6761745B2 (en) 2000-01-24 2004-07-13 Angelica Hull Method of reducing the vapor pressure of ethanol-containing motor fuels for spark ignition combustion engines
US7410514B2 (en) * 2002-12-05 2008-08-12 Greg Binions Liquid fuel composition having aliphatic organic non-hydrocarbon compounds, an aromatic hydrocarbon having an aromatic content of less than 15% by volume, an oxygenate, and water

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2117690C1 (ru) * 1996-06-20 1998-08-20 Товарищество с ограниченной ответственностью "Экология, маркетинг, инженерное дело" Топливная композиция
RU2102437C1 (ru) * 1996-06-26 1998-01-20 Шапиро Арон Лейбович Добавка к моторному топливу

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2363848A1 (de) * 1973-12-21 1975-07-10 Basf Ag Verfahren zum betreiben von ottound rotationskolben-motoren
JPS5681394A (en) * 1979-10-23 1981-07-03 Quigley Leroy Jr Liquid fuel composition
DK148747C (da) * 1980-06-09 1986-02-24 Inst Francais Du Petrole Motorbraendstof

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0171440B1 (fr) * 1983-08-20 1988-07-20 DEA Mineraloel Aktiengesellschaft Combustible pour moteurs
EP0227176A3 (fr) * 1985-12-19 1988-03-23 SNAMPROGETTI S.p.A. Composition oxygénée à haut indice d'octane pour combustible et méthode pour sa préparation
WO1989005339A1 (fr) * 1987-12-03 1989-06-15 Chemical Fuels Corporation Additifs pour l'essence ameliorant l'indice d'octane
WO2000055610A1 (fr) * 1999-03-18 2000-09-21 Aae Holdings Plc Tensioactifs
US7014668B2 (en) * 1999-09-06 2006-03-21 Agrofuel Ab Motor fuel for diesel, gas-turbine and turbojet engines
WO2001018155A1 (fr) * 1999-09-06 2001-03-15 Agrofuel Ab Carburant pour moteurs diesel, pour turbines a gaz et pour turboreacteurs comprenant au moins quatre groupes fonctionnels differents contenant de l'oxygene choisis dans le groupe constitue par alcool, ether, aldehyde, cetone, ester, ester inorganique, acetal, epoxyde et peroxyde
HRP20020285B1 (hr) * 1999-09-06 2011-03-31 Bio Petroleum Ltd. No. 3875505 Motorno gorivo za dizel, plinske turbine i turbojet motore, koje obuhvaća najmanje četiri različite funkcionalne skupine, koje sadržavaju kisik, odabrane između alkohola, etera, aldehida, ketona, estera, anorganskog estera, acetala, epoksida i peroksida
KR100761924B1 (ko) * 1999-09-06 2007-10-04 아그로퓨엘 에이비 알코올, 에테르, 알데히드, 케톤, 에스테르, 무기 에스테르, 아세탈, 에폭시드 및 과산화물 중에서 선택된 산소 함유 작용기를 4개 이상 함유하는 디젤, 가스-터빈 및 터보제트 엔진용 모터 연료
AU771381B2 (en) * 1999-09-06 2004-03-18 Bio Petroleum Ltd. No. 3875505 Motor fuel for diesel, gas-turbine and turbojet engines, comprising at least four different oxygen-containing functional groups selected from alcohol, ether, aldehyde, ketone, ester, inorganic ester, acetal, epoxide and peroxide
US6761745B2 (en) 2000-01-24 2004-07-13 Angelica Hull Method of reducing the vapor pressure of ethanol-containing motor fuels for spark ignition combustion engines
WO2001053437A1 (fr) * 2000-01-24 2001-07-26 Golubkov Angelica Procede permettant de reduire la pression de la vapeur des carburants a base d'ethanol dans des moteurs a combustion a allumage commande
US7323020B2 (en) 2000-01-24 2008-01-29 Angelica Hull Method for making a fuel for a modified spark ignition combustion engine, a fuel for a modified spark ignition combustion engine and a fuel additive for a conventional spark ignition combustion engine
HRP20020670B1 (en) * 2000-01-24 2010-05-31 Hull Angelica Method of reducing the vapour pressure of ethanol-containing motor fuels for spark ignition combustion engines
WO2001053436A1 (fr) * 2000-01-24 2001-07-26 Angelica Golubkov Carburant pour moteurs thermiques à étincelles
CZ305710B6 (cs) * 2000-01-24 2016-02-17 Angelica Hull Způsob snížení tlaku par na uhlovodíku založené motorové palivové směsi, kompozice motorového paliva
US7410514B2 (en) * 2002-12-05 2008-08-12 Greg Binions Liquid fuel composition having aliphatic organic non-hydrocarbon compounds, an aromatic hydrocarbon having an aromatic content of less than 15% by volume, an oxygenate, and water

Also Published As

Publication number Publication date
EP0121089A3 (en) 1986-05-07
EP0121089B1 (fr) 1989-05-31
ATE43625T1 (de) 1989-06-15
DE3478465D1 (en) 1989-07-06

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