EP0121089A2 - Combustible pour moteurs - Google Patents
Combustible pour moteurs Download PDFInfo
- Publication number
- EP0121089A2 EP0121089A2 EP84102024A EP84102024A EP0121089A2 EP 0121089 A2 EP0121089 A2 EP 0121089A2 EP 84102024 A EP84102024 A EP 84102024A EP 84102024 A EP84102024 A EP 84102024A EP 0121089 A2 EP0121089 A2 EP 0121089A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- ethanol
- vol
- butanol
- methanol
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B1/00—Engines characterised by fuel-air mixture compression
- F02B1/02—Engines characterised by fuel-air mixture compression with positive ignition
- F02B1/04—Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder
Definitions
- the invention relates to an engine fuel and a method for its production, which consists of a base fuel consisting of hydrocarbons or predominantly hydrocarbons and additions of alcohols and / or ethers and / or ketones and additives and optionally water and aromatics.
- Bioethanol can be obtained in burners with relatively little expenditure on equipment and energy. Since this bioalcohol also contains organic impurities, e.g. Aldehydes, ketones, acetic acid and esters have so far not considered the use of this bioethanol in motor vehicles as an additive to conventional petrol fuels feasible, and in addition the problem of complete miscibility at particularly low outside temperatures due to the high water content of the bioalcohol was not considered economically solvable has been.
- organic impurities e.g. Aldehydes, ketones, acetic acid and esters
- a typical bioethanol has e.g. B. the following data:
- the object of the present invention was therefore to provide a fuel which avoids the specified technical problems, meets all the requirements of the fuel standards, takes into account the availability of the additional components and can be offered to the motorist in the existing gas station distribution network without any problems.
- the object was achieved according to the invention by a new motor fuel consisting of base fuel, hydrocarbons or predominantly hydrocarbons and consisting of additions of alcohols and / or ethers and / or ketones and optionally aromatics, additional water and additives and compounds of the lead, characterized thereby that it contains> 0 to 10 vol.% ethanol with more than the ethanol / water azeotrope (at normal pressure) corresponding water content,> 0 to 10 vol.% butanol (s) and;> 0 to 5 vol.% methanol and / or> 0 - 15 vol.% methyl tert-butyl ether and / or> 0 - 15 vol.% acetone.
- the fuel according to the invention is excellently suited for the usual motor vehicle engines, can be mixed as desired with fuels already on the market, conversions to the carburettors and engines and other parts that use the fuel come into contact, are not required, all requirements of the DIN standard be fulfilled and the fuel can be made available to the driver at the existing filling stations.
- the fuel according to the invention contains from> 0 to 10% by volume of ethanol with a higher water content than the ethanol / water azeotrope, but can also contain proportions of pure ethanol and / or ethanol / water azeotrope and / or ethanol or technical grade ethanol contain with less water, preferably> 0 - 5 vol.% bioethanol is used, furthermore> 0 to 5 vol.% methanol can be contained, which can be technical, undistilled methanol, or topped technical, undistilled methanol. In the latter part of the impurities contained in technical methanol is driven off overhead.
- butanol s
- tert-butanol tert-butanol
- butanol mixtures can also be used, methyl tert-butyl ether and acetone.
- Other ethers such as e.g. Dimethyl, diethyl, methyl tert-amyl ether and components such as e.g. Aromatics. Water can also be added.
- Acetone can be added as pure or technical or bioacetone.
- the basic hydrocarbons used are preferably super gasoline or normal gasoline or mixtures thereof which comply with the fuel standards.
- the basic hydrocarbons can already contain additives or even methanol additions of> 0 to 5 vol.% And / or butanols of> 0 - 10 vol.% Butanol (s), these having to be taken into account accordingly when adding bioethanol according to the invention.
- Keropur As an additive, numerous additives that are available on the market, such as Keropur from BASF, can be used. Lead can also be added in the form of its compounds commonly used in fuels.
- the components can be mixed together by mixing a high octane hydrocarbon-based super fuel component and / or a lower octane hydrocarbon-based normal fuel component with bioethanol, methanol, butanol (s), methyl tert-butyl ether, acetone and the additives, has proven to be a preferred embodiment of mixing super fuel and / or normal fuel, which may already contain> 0-5 vol.% methanol and> 0-10 vol.% butanol (s), with a premixed component containing bioethanol, butanol ( e) and / or methanol and / or methyl tert-butyl ether and / or acetone and optionally additives and lead compounds.
- a typical mixture according to the invention has, for example, the following composition:
- This mixture was added to a super fuel containing no methanol / butanol additives, so that a mixture of 7 vol% and 93 vol% super fuel was obtained.
- This mixture was added to a mixture of 80% by volume of super fuel and 10% by volume of normal fuel, so that a mixture of 90% by volume of super / normal fuel and 10% by volume of mixture of the oxygen-containing compounds was obtained.
- This mixture was added to super fuel so that a mixture of 90% by volume of super fuel and 10% by volume of the oxygen-containing compounds was obtained.
- the present invention is of great importance with regard to reducing the dependency on imported mineral oil, since it makes it possible for the first time to use fuel alcohol (bioalcohol) which can be obtained in fuels even with relatively little energy expenditure. Contrary to the prejudice of experts, the extensive investigations by the applicant have shown that the contaminants contained in this alcohol cause neither damage to motor vehicle parts nor increased environmental pollution.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Fuel-Injection Apparatus (AREA)
- Valve Device For Special Equipments (AREA)
- Lens Barrels (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT84102024T ATE43625T1 (de) | 1983-03-03 | 1984-02-27 | Motor-kraftstoff. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3307505 | 1983-03-03 | ||
| DE3307505 | 1983-03-03 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0121089A2 true EP0121089A2 (fr) | 1984-10-10 |
| EP0121089A3 EP0121089A3 (en) | 1986-05-07 |
| EP0121089B1 EP0121089B1 (fr) | 1989-05-31 |
Family
ID=6192400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84102024A Expired EP0121089B1 (fr) | 1983-03-03 | 1984-02-27 | Combustible pour moteurs |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0121089B1 (fr) |
| AT (1) | ATE43625T1 (fr) |
| DE (1) | DE3478465D1 (fr) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0227176A3 (fr) * | 1985-12-19 | 1988-03-23 | SNAMPROGETTI S.p.A. | Composition oxygénée à haut indice d'octane pour combustible et méthode pour sa préparation |
| EP0171440B1 (fr) * | 1983-08-20 | 1988-07-20 | DEA Mineraloel Aktiengesellschaft | Combustible pour moteurs |
| WO1989005339A1 (fr) * | 1987-12-03 | 1989-06-15 | Chemical Fuels Corporation | Additifs pour l'essence ameliorant l'indice d'octane |
| WO2000055610A1 (fr) * | 1999-03-18 | 2000-09-21 | Aae Holdings Plc | Tensioactifs |
| WO2001018155A1 (fr) * | 1999-09-06 | 2001-03-15 | Agrofuel Ab | Carburant pour moteurs diesel, pour turbines a gaz et pour turboreacteurs comprenant au moins quatre groupes fonctionnels differents contenant de l'oxygene choisis dans le groupe constitue par alcool, ether, aldehyde, cetone, ester, ester inorganique, acetal, epoxyde et peroxyde |
| WO2001053436A1 (fr) * | 2000-01-24 | 2001-07-26 | Angelica Golubkov | Carburant pour moteurs thermiques à étincelles |
| US6761745B2 (en) | 2000-01-24 | 2004-07-13 | Angelica Hull | Method of reducing the vapor pressure of ethanol-containing motor fuels for spark ignition combustion engines |
| US7410514B2 (en) * | 2002-12-05 | 2008-08-12 | Greg Binions | Liquid fuel composition having aliphatic organic non-hydrocarbon compounds, an aromatic hydrocarbon having an aromatic content of less than 15% by volume, an oxygenate, and water |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2117690C1 (ru) * | 1996-06-20 | 1998-08-20 | Товарищество с ограниченной ответственностью "Экология, маркетинг, инженерное дело" | Топливная композиция |
| RU2102437C1 (ru) * | 1996-06-26 | 1998-01-20 | Шапиро Арон Лейбович | Добавка к моторному топливу |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2363848A1 (de) * | 1973-12-21 | 1975-07-10 | Basf Ag | Verfahren zum betreiben von ottound rotationskolben-motoren |
| JPS5681394A (en) * | 1979-10-23 | 1981-07-03 | Quigley Leroy Jr | Liquid fuel composition |
| DK148747C (da) * | 1980-06-09 | 1986-02-24 | Inst Francais Du Petrole | Motorbraendstof |
-
1984
- 1984-02-27 EP EP84102024A patent/EP0121089B1/fr not_active Expired
- 1984-02-27 DE DE8484102024T patent/DE3478465D1/de not_active Expired
- 1984-02-27 AT AT84102024T patent/ATE43625T1/de not_active IP Right Cessation
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0171440B1 (fr) * | 1983-08-20 | 1988-07-20 | DEA Mineraloel Aktiengesellschaft | Combustible pour moteurs |
| EP0227176A3 (fr) * | 1985-12-19 | 1988-03-23 | SNAMPROGETTI S.p.A. | Composition oxygénée à haut indice d'octane pour combustible et méthode pour sa préparation |
| WO1989005339A1 (fr) * | 1987-12-03 | 1989-06-15 | Chemical Fuels Corporation | Additifs pour l'essence ameliorant l'indice d'octane |
| WO2000055610A1 (fr) * | 1999-03-18 | 2000-09-21 | Aae Holdings Plc | Tensioactifs |
| US7014668B2 (en) * | 1999-09-06 | 2006-03-21 | Agrofuel Ab | Motor fuel for diesel, gas-turbine and turbojet engines |
| WO2001018155A1 (fr) * | 1999-09-06 | 2001-03-15 | Agrofuel Ab | Carburant pour moteurs diesel, pour turbines a gaz et pour turboreacteurs comprenant au moins quatre groupes fonctionnels differents contenant de l'oxygene choisis dans le groupe constitue par alcool, ether, aldehyde, cetone, ester, ester inorganique, acetal, epoxyde et peroxyde |
| HRP20020285B1 (hr) * | 1999-09-06 | 2011-03-31 | Bio Petroleum Ltd. No. 3875505 | Motorno gorivo za dizel, plinske turbine i turbojet motore, koje obuhvaća najmanje četiri različite funkcionalne skupine, koje sadržavaju kisik, odabrane između alkohola, etera, aldehida, ketona, estera, anorganskog estera, acetala, epoksida i peroksida |
| KR100761924B1 (ko) * | 1999-09-06 | 2007-10-04 | 아그로퓨엘 에이비 | 알코올, 에테르, 알데히드, 케톤, 에스테르, 무기 에스테르, 아세탈, 에폭시드 및 과산화물 중에서 선택된 산소 함유 작용기를 4개 이상 함유하는 디젤, 가스-터빈 및 터보제트 엔진용 모터 연료 |
| AU771381B2 (en) * | 1999-09-06 | 2004-03-18 | Bio Petroleum Ltd. No. 3875505 | Motor fuel for diesel, gas-turbine and turbojet engines, comprising at least four different oxygen-containing functional groups selected from alcohol, ether, aldehyde, ketone, ester, inorganic ester, acetal, epoxide and peroxide |
| US6761745B2 (en) | 2000-01-24 | 2004-07-13 | Angelica Hull | Method of reducing the vapor pressure of ethanol-containing motor fuels for spark ignition combustion engines |
| WO2001053437A1 (fr) * | 2000-01-24 | 2001-07-26 | Golubkov Angelica | Procede permettant de reduire la pression de la vapeur des carburants a base d'ethanol dans des moteurs a combustion a allumage commande |
| US7323020B2 (en) | 2000-01-24 | 2008-01-29 | Angelica Hull | Method for making a fuel for a modified spark ignition combustion engine, a fuel for a modified spark ignition combustion engine and a fuel additive for a conventional spark ignition combustion engine |
| HRP20020670B1 (en) * | 2000-01-24 | 2010-05-31 | Hull Angelica | Method of reducing the vapour pressure of ethanol-containing motor fuels for spark ignition combustion engines |
| WO2001053436A1 (fr) * | 2000-01-24 | 2001-07-26 | Angelica Golubkov | Carburant pour moteurs thermiques à étincelles |
| CZ305710B6 (cs) * | 2000-01-24 | 2016-02-17 | Angelica Hull | Způsob snížení tlaku par na uhlovodíku založené motorové palivové směsi, kompozice motorového paliva |
| US7410514B2 (en) * | 2002-12-05 | 2008-08-12 | Greg Binions | Liquid fuel composition having aliphatic organic non-hydrocarbon compounds, an aromatic hydrocarbon having an aromatic content of less than 15% by volume, an oxygenate, and water |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0121089A3 (en) | 1986-05-07 |
| EP0121089B1 (fr) | 1989-05-31 |
| ATE43625T1 (de) | 1989-06-15 |
| DE3478465D1 (en) | 1989-07-06 |
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| 17P | Request for examination filed |
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