EP0160873B1 - Weichmachendes Waschmittel - Google Patents

Weichmachendes Waschmittel Download PDF

Info

Publication number: EP0160873B1
Authority: EP; European Patent Office
Prior art keywords: acid; softening; crystalline; line; alkali metal
Prior art date: 1984-05-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

EP85104833A

Other languages

German (de)

English (en)

French (fr)

Other versions

EP0160873A3 (en

EP0160873A2 (de

Inventor

Hans-Peter Dr. Rieck

Jürgen Dr. Grosse

Werner Gohla

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Clariant Produkte Deutschland GmbH

Original Assignee

Hoechst AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-05-05

Filing date

1985-04-20

Publication date

1991-06-26

1985-04-20 Application filed by Hoechst AG filed Critical Hoechst AG

1985-11-13 Publication of EP0160873A2 publication Critical patent/EP0160873A2/de

1990-01-10 Publication of EP0160873A3 publication Critical patent/EP0160873A3/de

1991-06-26 Application granted granted Critical

1991-06-26 Publication of EP0160873B1 publication Critical patent/EP0160873B1/de

2005-04-20 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000005406 washing Methods 0.000 title description 11
239000003599 detergent Substances 0.000 claims description 26
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
-1 alkali metal salt Chemical class 0.000 claims description 15
239000002253 acid Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 10
238000002441 X-ray diffraction Methods 0.000 claims description 9
229910052708 sodium Inorganic materials 0.000 claims description 9
229910052700 potassium Inorganic materials 0.000 claims description 7
238000010586 diagram Methods 0.000 claims description 6
239000004094 surface-active agent Substances 0.000 claims description 6
229910052783 alkali metal Inorganic materials 0.000 claims description 5
229910052906 cristobalite Inorganic materials 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000010453 quartz Substances 0.000 claims description 5
229910052905 tridymite Inorganic materials 0.000 claims description 5
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 3
239000004753 textile Substances 0.000 claims description 2
238000005341 cation exchange Methods 0.000 claims 1
150000001447 alkali salts Chemical class 0.000 description 11
239000011734 sodium Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
239000003513 alkali Substances 0.000 description 8
239000008139 complexing agent Substances 0.000 description 8
125000004432 carbon atom Chemical group C* 0.000 description 7
230000000694 effects Effects 0.000 description 7
150000004760 silicates Chemical class 0.000 description 7
239000003093 cationic surfactant Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000003945 anionic surfactant Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
235000012239 silicon dioxide Nutrition 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical class CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
239000007844 bleaching agent Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000002734 clay mineral Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
238000000034 method Methods 0.000 description 3
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000004480 active ingredient Substances 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
235000012216 bentonite Nutrition 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000004744 fabric Substances 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
125000005341 metaphosphate group Chemical group 0.000 description 2
239000011707 mineral Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
239000011591 potassium Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical class COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 1
URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
ZMPRRFPMMJQXPP-UHFFFAOYSA-N 2-sulfobenzoic acid Chemical class OC(=O)C1=CC=CC=C1S(O)(=O)=O ZMPRRFPMMJQXPP-UHFFFAOYSA-N 0.000 description 1
LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
235000011293 Brassica napus Nutrition 0.000 description 1
240000008100 Brassica rapa Species 0.000 description 1
235000000540 Brassica rapa subsp rapa Nutrition 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical class OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
229920002125 Sokalan® Chemical class 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000002947 alkylene group Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
230000003712 anti-aging effect Effects 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Chemical class 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
235000015165 citric acid Nutrition 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
WOSVXXBNNCUXMT-UHFFFAOYSA-N cyclopentane-1,2,3,4-tetracarboxylic acid Chemical class OC(=O)C1CC(C(O)=O)C(C(O)=O)C1C(O)=O WOSVXXBNNCUXMT-UHFFFAOYSA-N 0.000 description 1
239000000645 desinfectant Substances 0.000 description 1
FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
229940043264 dodecyl sulfate Drugs 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
239000008187 granular material Substances 0.000 description 1
159000000011 group IA salts Chemical class 0.000 description 1
229910000271 hectorite Inorganic materials 0.000 description 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
LPTIRUACFKQDHZ-UHFFFAOYSA-N hexadecyl sulfate;hydron Chemical compound CCCCCCCCCCCCCCCCOS(O)(=O)=O LPTIRUACFKQDHZ-UHFFFAOYSA-N 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical class OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
239000000391 magnesium silicate Substances 0.000 description 1
229910052919 magnesium silicate Inorganic materials 0.000 description 1
235000019792 magnesium silicate Nutrition 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
MBKDYNNUVRNNRF-UHFFFAOYSA-N medronic acid Chemical class OP(O)(=O)CP(O)(O)=O MBKDYNNUVRNNRF-UHFFFAOYSA-N 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
NUGJFLYPGQISPX-UHFFFAOYSA-N peroxydiphosphoric acid Chemical compound OP(O)(=O)OOP(O)(O)=O NUGJFLYPGQISPX-UHFFFAOYSA-N 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229910052615 phyllosilicate Inorganic materials 0.000 description 1
239000004584 polyacrylic acid Chemical class 0.000 description 1
229920001444 polymaleic acid Chemical class 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
239000011347 resin Chemical class 0.000 description 1
229920005989 resin Chemical class 0.000 description 1
229910000275 saponite Inorganic materials 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
229910000269 smectite group Inorganic materials 0.000 description 1
239000000344 soap Substances 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
IWMMSZLFZZPTJY-UHFFFAOYSA-M sodium;3-(dodecylamino)propane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCNCCCS([O-])(=O)=O IWMMSZLFZZPTJY-UHFFFAOYSA-M 0.000 description 1
HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
AGGIJOLULBJGTQ-UHFFFAOYSA-N sulfoacetic acid Chemical class OC(=O)CS(O)(=O)=O AGGIJOLULBJGTQ-UHFFFAOYSA-N 0.000 description 1
DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical class OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads

Definitions

softening means this softening effect on the textiles and not, for example, softening of the water by complexing the calcium and magnesium ions causing the water hardness.
the cationic surfactants are incompatible with the anionic surfactants usually used in detergents, since poorly soluble precipitates result which lead to a partial loss of softening cationic surfactants and detergent-active anionic surfactants in the wash liquor and thus to a reduced effectiveness of the detergent. It is therefore known to use cationic reagents in a separate rinse cycle.
softening detergents are already known, which have a cleaning and softening effect in one operation.
DE-PS 23 34 899 describes the use of clay minerals, namely saponites, hectorites or montmorrillonites as softening agents Active ingredients in detergent formulations.
DE-OS 33 12 774 bentonites are added to detergents.
smectites into softening detergents in the presence of softening ammonium compounds (cationic surfactants) and / or amines (for example EP 00 76 572, US Pat. No. 4,375,416). This is intended to achieve a softening and antistatic effect, especially in laundry tumblers.
cationic surfactants are embedded in the smectites (crystalline alkali layer silicates), they are also effective in the presence of anionic surfactants.
Smectites are clay minerals that carry a grid charge and expand when solvated with water and alcohol.
Montmorillonite belongs to the Smectite group ⁇ (Al1, 67Mg0, 33) (OH) 2 [Si4O10] ⁇ Na0, 33, the hectorite ⁇ (Mg2, 67Li0, 33) (OH, F) 2 [Si4O10] ⁇ Na0, 33 and possibly the saponite ⁇ (Mg3 -x Al x ) (OH) 2 [Si4 -y Al y O10] ⁇ Na z .
Bentonites are certain clay minerals containing montmorrillonite.
Clays are usually natural minerals that are more or less colored due to the inclusion of impurities; this is disadvantageous for use in detergents. Although synthetic clays can be produced, they cannot be used economically for cost reasons.
the task was to find softening active ingredients that overcome the disadvantages mentioned.
the compounds are colorless, economically producible and free from alkaline earth and aluminum ions. Their molecular structure differs fundamentally from that of the above-mentioned clays;
the layered silicates to be used according to the invention can be assigned to the group of phyllosilicates and contain adhesive and / or water of crystallization.
M is preferably sodium, but depending on the respective pH, it can also be partially replaced by protons.
the ion exchange capacity of the crystalline layered silicates is 130 - 400 mmol M + / 100 g anhydrous substance.
the silicates have one or more reflections in the range of the d values of 3.0 - 4.0 x 10 ⁇ 8 cm, which cannot be assigned to quartz, tridymite and cristobalite.
Natural alkali silicates are e.g. Magadiite Na2Si14O29. 11 H2O and Kenyait Na2Si22O45. 10 H2O (H.P. Eugster, Science, 157, pp. 1177-1180 (1967)).
Synthetic products have, for example, the composition Na2Si8O17, K2Si8O17 or Na2Si14O29 (RK Iler, J. Colloid Sci. 19, pp. 648-657 (1964); DE-PS 27 42 912; G. Lagaly et al., Am. Mineral. 60, pp. 642-649 (1975)).
Crystalline layered silicas and their alkali metal salts which can be used according to the invention and processes for their preparation are also described in the older German DE-A-34 00 130 and 34 00 132.
the crystalline layered silicas or alkali layer silicates to be used in accordance with the invention can be incorporated into detergents by means of customary processes for the production of detergents, such as mixing, spray mixing processes and spray drying. However, they can also be used separately.
the softening detergent of the invention preferably contains 5-30% by weight of surfactants, 10-40% by weight of builders and 1-15% by weight of crystalline layered silicas or their alkali salts, the rest of the washing aids, provided that it is marketed in granules. If it is sold in liquid form, it preferably contains 10-55% by weight of surfactants, 0.5-25% by weight of builders and 1-15% by weight of crystalline layered silicas or their alkali salts, the rest of the washing aids. Very good washing results are achieved with the softening detergent of the invention.
the softening detergent of the invention preferably contains such anionic, zwitterionic (ampholytic) or nonionic in nature as surfactants.
Nonionic surfactants are understood to mean those compounds which have an organic, hydrophobic group and a hydrophilic radical, for example the condensation products of alkylphenols or higher fatty alcohols with ethylene oxide, the condensation products of polypropylene glycol with ethylene oxide or propylene oxide, the condensation products of ethylene oxide with the reaction product from ethylenediamine and propylene oxide, as well as long-chain tertiary amine oxides
surfactants with a zwitterionic (ampholytic) character include the following compounds: Derivatives of aliphatic, secondary and tertiary amines or quaternary ammonium compounds with 8 to 18 carbon atoms and a hydrophilic group in the aliphatic radical, such as sodium 3-dodecylaminopropionate, sodium 3-dodecylaminopropanesulfonate, 3- (N, N-dimethyl -N-hexadecyl-amino) -propane-1-sulf
Suitable builders for the detergents according to the invention are weakly acidic, neutral or alkaline inorganic or organic salts, in particular inorganic or organic complexing agents.
Useful, weakly acidic, neutral or alkaline salts are, for example, the bicarbonates, carbonates or silicates of the alkalis, and also mono-, di- or trialkali orthophosphates.
the weakly acidic metaphosphates and the alkaline polyphosphates, in particular tripolyphosphate, are also suitable as complex-forming framework substances. They can be replaced in whole or in part by organic complexing agents.
the organic complexing agents include, for example, nitrilotriacetic acid, ethylenediaminetetraacetic acid, N-hydroxyethylethylenediaminetriacetic acid, polyalkylene-polyamine-N-polycarboxylic acids and other known organic complexing agents, it also being possible to use combinations of different complexing agents.
Washing aids include products such as the alkali or ammonium salts of sulfuric acid, silica, carbonic acid, boric acid, alkylene, hydroxyalkylene or aminoalkylenephosphonic acid as well as bleaching agents, stabilizers for peroxide compounds (bleaching agents) and water-soluble organic complexing agents.
the bleaching agents include sodium perborate mono- or tetrahydrate, the alkali salts of peroxomono- or peroxodisulfuric acid, the alkali salts of peroxodiphosphoric acid (H4P2O8).
a stabilizer for these bleaches is e.g. water-soluble, precipitated magnesium silicate.
Organic complexing agents are the alkali salts of iminodiacetic acid, nitrilotriacetic acid, ethylenediaminetetraacetic acid, methylenediphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid and nitrilotrismethylenephosphonic acid.
Washing aids that increase the dirt-carrying capacity of washing liquors, such as carboxymethyl cellulose, carboxymethyl starch, methyl cellulose or copolymers of maleic anhydride with methyl vinyl ether, foam regulators, such as mono- and dialkyl phosphoric acid esters with 16 to 20 carbon atoms in the alkyl radical, as well as optical brighteners, disinfectants and / or proteolytic enzymes additional components of the softening detergent.
Detergent A is a commercially available detergent that had been mixed in the mixer according to the invention with the layered crystalline sodium silicate of the formula Na2Si22O45 (loss on ignition 4% (5 h / 360 ° C));
Detergent B is a commercially available detergent that contains crystalline, layered alkali aluminum silicates and cationic surfactants and whose grip-improving effect is highlighted in advertising.

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Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Detergent Compositions (AREA)

EP85104833A 1984-05-05 1985-04-20 Weichmachendes Waschmittel Expired - Lifetime EP0160873B1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3416669		1984-05-05
DE3416669A DE3416669A1 (de)	1984-05-05	1984-05-05	Weichmachendes waschmittel

Publications (3)

Publication Number	Publication Date
EP0160873A2 EP0160873A2 (de)	1985-11-13
EP0160873A3 EP0160873A3 (en)	1990-01-10
EP0160873B1 true EP0160873B1 (de)	1991-06-26

Family

ID=6235037

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP85104833A Expired - Lifetime EP0160873B1 (de)	1984-05-05	1985-04-20	Weichmachendes Waschmittel

Country Status (6)

Country	Link
US (1)	US4728443A (da)
EP (1)	EP0160873B1 (da)
JP (1)	JPH0633407B2 (da)
CA (1)	CA1228205A (da)
DE (2)	DE3416669A1 (da)
DK (1)	DK166288C (da)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3627773A1 (de) *	1986-08-16	1988-02-18	Hoechst Ag	Phosphatfreies geschirrspuelmittel
DE3632107A1 (de) *	1986-09-22	1988-03-31	Henkel Kgaa	Phosphatreduziertes waschmittel enthaltend n-alkoxylierte fettsaeureamide
JPH01153800A (ja) *	1987-12-11	1989-06-15	Lion Corp	濃縮柔軟付与粒状洗剤組成物
DE3812556A1 (de) *	1988-04-15	1989-10-26	Hoechst Ag	Waschmittel mit lagerstabilisiertem bleichsystem
JPH02178399A (ja) *	1988-12-29	1990-07-11	Lion Corp	粒状洗剤組成物
JPH02178398A (ja) *	1988-12-29	1990-07-11	Lion Corp	高嵩密度洗剤組成物
TW240243B (da) *	1992-03-12	1995-02-11	Kao Corp
US5814289A (en) *	1992-03-28	1998-09-29	Hoechst Aktiengesellschaft	Process for the peparation of cogranulates comprising aluminosilicates and sodium silicates
DE4308063A1 (de) *	1993-03-13	1994-09-15	Hoechst Ag	Verfahren zur Herstellung von Gemischen aus synthetischem, kristallinem Magadiit und sauerstoffabspaltenden Salzen sowie deren Verwendung
DE4308062A1 (de) *	1993-03-13	1994-09-15	Hoechst Ag	Verfahren zur Herstellung von Gemischen aus synthetischem, kristallinem Kenyait und sauerstoffabspaltenden Salzen sowie deren Verwendung
GB9307493D0 (en) *	1993-04-08	1993-06-02	Procter & Gamble	Detergent compositions
DE4328509A1 (de) *	1993-08-25	1995-03-02	Hoechst Ag	Inhibitor für die chemische Textilfaserschädigung
DE69327654T2 (de) *	1993-11-11	2000-08-31	The Procter & Gamble Company, Cincinnati	Beim Waschen weichmachende Zusammensetzungen
FI963633A7 (fi) *	1994-03-14	1996-09-13	Procter & Gamble	Rakeisia valkaisukoostumuksia
ZA952081B (en) *	1994-03-14	1996-12-12	Procter & Gamble	Granular bleaching composition
GB9605534D0 (en) *	1996-03-15	1996-05-15	Unilever Plc	Detergent compositions

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ZA734721B (en) *	1972-07-14	1974-03-27	Procter & Gamble	Detergent compositions
DD161180A3 (de) *	1981-02-23	1985-05-02	Univ Halle Wittenberg	Wasch- und reinigungsmittel fuer feste oberflaechen
US4526702A (en) *	1982-08-25	1985-07-02	Colgate Palmolive Co.	Process for manufacturing bentonite-containing particulate fabric softening detergent composition
US4469605A (en) *	1982-12-13	1984-09-04	Colgate-Palmolive Company	Fabric softening heavy duty liquid detergent and process for manufacture thereof
US4436637A (en) *	1982-12-13	1984-03-13	Colgate-Palmolive Company	Fabric softening heavy duty liquid detergent containing a mixture of water insoluble soap and clay
US4536316A (en) *	1983-06-01	1985-08-20	Colgate-Palmolive Co.	Fabric softening composition containing surface modified clay
US4524012A (en) *	1983-06-08	1985-06-18	Colgate-Palmolive Company	Fabric softening and fluffing detergent composition
DD220325A1 (de) *	1983-09-05	1985-03-27	Bitterfeld Chemie	Waschhilfsmittel
DE3400132A1 (de) *	1984-01-04	1985-07-11	Hoechst Ag, 6230 Frankfurt	Verfahren zur herstellung von kristallinen alkalischichtsilikaten
DE3400130A1 (de) *	1984-01-04	1985-07-11	Hoechst Ag, 6230 Frankfurt	Kristalline kieselsaeure, ihre salze und verfahren zu ihrer herstellung

1984
- 1984-05-05 DE DE3416669A patent/DE3416669A1/de not_active Withdrawn
1985
- 1985-04-17 CA CA000479325A patent/CA1228205A/en not_active Expired
- 1985-04-20 EP EP85104833A patent/EP0160873B1/de not_active Expired - Lifetime
- 1985-04-20 DE DE8585104833T patent/DE3583306D1/de not_active Expired - Lifetime
- 1985-04-22 US US06/725,376 patent/US4728443A/en not_active Expired - Fee Related
- 1985-05-02 DK DK199685A patent/DK166288C/da active
- 1985-05-07 JP JP60095704A patent/JPH0633407B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE3416669A1 (de)	1985-11-07
EP0160873A3 (en)	1990-01-10
EP0160873A2 (de)	1985-11-13
DK199685D0 (da)	1985-05-02
DK166288B (da)	1993-03-29
DE3583306D1 (de)	1991-08-01
CA1228205A (en)	1987-10-20
US4728443A (en)	1988-03-01
JPH0633407B2 (ja)	1994-05-02
JPS60240799A (ja)	1985-11-29
DK166288C (da)	1993-08-23
DK199685A (da)	1985-11-06

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Publication	Publication Date	Title
EP0163910B1 (de)	1987-10-14	Weichmacher enthaltende Waschmittel
DE2412837C3 (de)	1989-10-12	Mittel zum Waschen bzw. Bleichen von Textilien unter Einsatz kristalliner wasserunlöslicher Silikate, ihre Herstellung und ihre Verwendung
DE2334899C2 (de)	1983-12-22	Körniges, gerüststoffhaltiges Waschmittel zum gleichzeitigen Waschen und Weichmachen von Textilien
DE2406553C2 (de)	1985-07-18	Gewebeweichmachende Mittel und diese enthaltende Detergensgemische
EP0160873A2 (de)	1985-11-13	Weichmachendes Waschmittel
EP0444415B1 (de)	1995-05-03	Teilentwässertes Disilikat enthaltendes Waschmittel
DE4034131C2 (de)	1999-08-26	Gerüststoff für Waschmittel
DE3717227A1 (de)	1988-12-01	Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
DE2550900A1 (de)	1976-05-20	Mittel zum weichmachen von textilien, das mit detergentien vertraeglich ist oder gleichzeitig als waschmittel dient
EP0276705A2 (de)	1988-08-03	Poröses Schichtsilikat/Natriumsulfat-Agglomerat
DE2544035A1 (de)	1976-04-08	Verfahren zum waschen von textilien, sowie mittel zur durchfuehrung des verfahrens
DE2820554A1 (de)	1979-11-22	Wasch- und reinigungsmittel
US5209857A (en)	1993-05-11	Fabric softening detergent compositions containing smectite clays having a lattice charge deficiency
DE3874806T2 (de)	1993-04-08	Detergenszusammensetzung.
EP0263520A2 (de)	1988-04-13	Weichmacher enthaltende Waschmittel
EP0622448B1 (de)	1999-07-21	Waschmittel
DE2607508C2 (da)	1988-03-31
CA2017671C (en)	1996-12-10	Detergent composition
DE2548233A1 (de)	1976-05-06	Phosphatfreies waschmittel
EP0668344B1 (de)	2000-05-17	Polyepoxy-Bernsteinsäure enthaltende Waschmittel
EP0640683A2 (de)	1995-03-01	Inhibitor für die chemische Textilfaserschädigung
DE2539270A1 (de)	1977-03-24	Textil-weichmacher enthaltende waschmittel
DE2544949A1 (de)	1977-04-14	Verfahren zum waschen von textilien
DE19521291A1 (de)	1996-02-08	Waschmittel
EP0695800A2 (de)	1996-02-07	Waschmittel