EP0184342B1 - Destruction de composés organiques halogénés - Google Patents
Destruction de composés organiques halogénés Download PDFInfo
- Publication number
- EP0184342B1 EP0184342B1 EP85308218A EP85308218A EP0184342B1 EP 0184342 B1 EP0184342 B1 EP 0184342B1 EP 85308218 A EP85308218 A EP 85308218A EP 85308218 A EP85308218 A EP 85308218A EP 0184342 B1 EP0184342 B1 EP 0184342B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal
- compounds
- destroyed
- aluminium
- containing organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002894 organic compounds Chemical class 0.000 title claims abstract description 17
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 15
- 150000002367 halogens Chemical class 0.000 title claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 47
- 239000002184 metal Substances 0.000 claims abstract description 47
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000012159 carrier gas Substances 0.000 claims abstract description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 238000011282 treatment Methods 0.000 claims abstract description 7
- 229910052790 beryllium Inorganic materials 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 7
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 4
- 230000001172 regenerating effect Effects 0.000 claims description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 4
- 150000003071 polychlorinated biphenyls Chemical class 0.000 abstract description 3
- 239000004411 aluminium Substances 0.000 description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 27
- 230000006378 damage Effects 0.000 description 23
- 239000000376 reactant Substances 0.000 description 21
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- 239000007789 gas Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- ONXPZLFXDMAPRO-UHFFFAOYSA-N decachlorobiphenyl Chemical group ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl ONXPZLFXDMAPRO-UHFFFAOYSA-N 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 229910052786 argon Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- GSSXLFACIJSBOM-UHFFFAOYSA-N 2h-pyran-2-ol Chemical compound OC1OC=CC=C1 GSSXLFACIJSBOM-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000010407 anodic oxide Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 150000002013 dioxins Chemical class 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002240 furans Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000011005 laboratory method Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- GGMPTLAAIUQMIE-UHFFFAOYSA-N 2,3,4,5,6-pentachlorobiphenyl Chemical group ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=CC=CC=C1 GGMPTLAAIUQMIE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- -1 aluminium chloride) Chemical class 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 239000000274 aluminium melt Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- YCOXTKKNXUZSKD-UHFFFAOYSA-N as-o-xylenol Natural products CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/37—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by reduction, e.g. hydrogenation
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/22—Organic substances containing halogen
Definitions
- PCB's Polychlorinated biphenyls
- PCB's are non- conductors of electricity and have good resistance to high temperatures, so they are widely used as working fluids in heat exchangers and hydraulic systems and by the electrical industry in transformers and capacitors.
- PCB's are extremely toxic, but are difficult to destroy on account of their thermal stability and chemical inertness.
- the standard destruction method involves incineration at temperatures around 1500°C, but suffers from several disadvantages. Operation at these very high temperatures is expensive; and incomplete combustion can give rise to chlorinated dioxins or furans which are even more toxic than PCB's.
- the present invention provides a method for the destruction of PCB's and related compounds which involves reaction with metal rather than combustion, and operates at much lower temperatures.
- Shultz discloses as a non preferred embodiment, but does not claim, a process which involves contacting PCB's with a solid aluminium surface.
- his experiments involved heating transformer oils containing PCB's in the presence of aluminium foil at various temperatures, but did not result in complete destruction of the PCB's even over periods as long as 30 minutes.
- Japanese Kokai 51-25471 describes a method of decomposing PCB's by heating them to effect partial dissociation to HCI OR CI 2 , and passing the mixture over a suitable metal and recovering a chloride salt of the metal by sublimation from the decomposition system. There is no indication that air is excluded; and no evidence that complete decomposition of PCB's is achieved even after several hours reaction.
- the invention is based on the discovery that PCB's can be rapidly destroyed by heating in the presence of solid aluminium, but only provided certain critical parameters are observed.
- the invention thus provides a method of destroying halogen-containing organic compounds by reaction with a metal in the solid state at elevated temperature, characterized by contacting the compounds in gaseous form in the absence of oxygen with a metal selected from AI, Mg, Si, Ti and Be, an alloys thereof having a specific surface area in the range of from 0.1 to 65 m 2 of active metal surface per gram of compound to be destroyed and at a temperature of at least 450°C and for a contact time of up to 50 seconds, whereby the halogen-containing organic compounds are destroyed and a deactivating carbonaceous deposit is formed on the surface of the metal.
- the compounds are preferably entrained in an inert carrier gas, for example argon or other gas in group 0 of the periodic table.
- an inert carrier gas for example argon or other gas in group 0 of the periodic table.
- High purity nitrogen may also be used, and is regarded for this purpose as an inert gas.
- nitrogen is known to form highly toxic compounds with PCB's but the concetra- tions so far observed of these are insignificant.
- concentration of the compounds in carrier gas is preferably from 10 ppm up to 10%.
- metals that can be used for reaction with the compounds are specified Al, Mg, Si, Ti and Be, and alloys of these metals with each other or with minor proportions of other metals.
- the five named metals have two characteristics in common: they form oxides having electically insulating properties; and the oxides have high thermal and chemical stability.
- Berylium presents a toxicity problem in itself, and is on that account the least preferred.
- the most preferred metals are magensium and, particularly, aluminium.
- the metals can be used in the natural state, i.e. without the need to remove any oxide film that may be present.
- Aluminium can be used having an anodic oxide film which may contain minor proportions of oxides of other metals such as Co, Ni, Sn, Cu etc., in the pores. It is not known with certainty whether any oxide film remains during operation of the method, or whether it is removed by reaction with halogen-containing organic compounds.
- the metal can be used in any physical form in which is has a high specific surface area. Suitable forms include a packed bed of spheres, chips or granules, a fluidized bed of powder, honeycomb, wire mesh or wire wool. Our presently preferred material is scrap aluminium and alloys thereof in granulated form, because this is cheap and readily obtainable. Sufficient metal surface area should be provided to ensure rapid and complete destruction of the halogen-containing organic compounds. This is generally 0.1 to 65 m 2 , preferably from 1 to 20 m 2 , of active metal surface (not necessarily bare metal surface, but surface not coated with e.g. inactivating carbonaceous deposits) per gram, of compound to be destroyed.
- reaction temperature needs to be at least 450°C.
- An upper limit on temperature is set by the melting point of the metal being used.
- One of the advantages of the method of this invention is the low temperature required, and it is preferred not to use higher temperatures than are necessary in orderto achieve reaction at the desired rate. Depending on other conditions, preferred reaction temperatures are likely to lie in the range 550°C to 650°C.
- Reaction products resulting from the method appear to be metal halide (e.g. aluminium chloride), low-boiling hydrocarbons, halogen, (e.g. chlorine) and carbon deposited on the metal substrate.
- metal halide e.g. aluminium chloride
- low-boiling hydrocarbons e.g. carbon
- halogen e.g. chlorine
- carbon deposited on the metal substrate As a result of this deposition, the substrate gradually becomes inactive. When this happens, the substrate can be regenerated. With aluminium, this can be achieved by subjecting the metal to sodium hydroxide solution, or less preferably, by heating the metal in air to burn off the carbon deposits.
- Other treatments for regenerating aluminium involve exposing the carbonised surface:
- Hydrogen and chlorine may be diluted with flowing argon.
- treatment (a) is preferred. It seems possible that the regenerated surface is in some way "re-activated" by the chlorine. Using this treatment, a 79.7% recovery of usable surface was obtained.
- Treatment (b) is more preferred than (c).
- Other metal substrates can similarly be regenerated by removing the carbon deposits under conditions in which the substrate is not effected.
- the metal used was 1100 aluminium alloy chips (0.5 x 0.5 x 0.1 cm). A bed about 27 cm long of these chips was positioned in a vertical quartz tube 1.8 cm outside diameter, and maintained at a nominal temperature of 580°C. A vessel containing the reactant was positioned in the quartz tube below the bed, and was surrounded by a separate tube furnace whose temperature was raised from ambient to 600°C over a period of 60 minutes. The lower end of the quartz tube was closed except for an inlet port through which argon carrier gas was passed at a flow rate of 87.7 ml/min (NTP). As the reactant heated up it vapourized and became entrained in the carrier gas.
- NTP argon carrier gas
- the flow rate was such that the residence time of the gas in the bed of aluminium chips was about 15 seconds.
- the temperature profile of the bed of chips was measured as 366°C at 0 cm up from the bottom; 473°C at 5 cm; 563°C at 9 cm; 601°C at 16 cm and 600°C at 27 cm.
- the top end of the quartz tube was closed except for a gas outlet, and the reaction products were condensed. After the experiment, any remaining reactant, the material in the bed of aluminium chips and the reaction products were all analysed for halogen-containing organic compounds.
- the reactant was 0.0078 g of decachlorobiphenyl.
- the destruction efficiency was 99.9999%.
- the section from 14 to 24 cm (measured from the bottom) of the aluminium bed became black.
- the rate of heating of the reactant sample was varied so that the concentration of decachlorobiphenyl in carrier argon gas ranged from 166 ppm to 3048 ppm. In all cases, the destruction efficiency was at least 99.999%.
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fire-Extinguishing Compositions (AREA)
- Treating Waste Gases (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Claims (9)
1. Procédé de destruction de composés organiques halogénés par réaction avec un métal à l'état solide à température élevée, caractérisé par le contact des composés sous forme gazeuse en l'absence d'oxygène avec un métal choisi parmi AI, Mg, Si, Ti et Be et leurs alliages ayant une surface spécifique dans la gamme de 0,1 à 65 m2 de surface de métal actif par gramme de composé à détruire et à une température d'au moins 450°C pendant un temps de contact pouvant atteindre 50 secondes, pour que les composés organiques halogénés soient détruits et qu'il se forme un dépôt carboné désactivateur sur la surface du métal.
2. Procédé selon la revendication 1, dans lequel les composés organiques sont des hydrocarbures chlorés.
3. Procédé selon la revendication 2, dans lequel les hydrocarbures chlorés sont mis au contact du métal à une température de 450°C pendant un temps de contact de 0,1 à 50 secondes, si bien que les hydrocarbures chlorés sont détruits et qu'un dépôt carboné désactivateur se forme sur la surface du métal, le procédé comprenant de plus les stades de:
i) régénération de la surface métallique par élimination du dépôt carboné de celle-ci, et
ii) réutilisation du métal ayant une surface régenérée pour détruire une quantité complémentaire d'hydrocarbures chlorés.
4. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel les composés sont entraînés sous une forme gazeuse dans un gaz porteur inerte.
5. Procédé selon l'une quelconque des revendications 1 à 4, dans lequel le métal avec lequel les composés à détruire sont mis au contact est constitué de fragments d'alliages d'aluminium.
6. Procédé selon l'une quelconque des revendications 1 à 5, dans lequel la température de contact est de 550°C à 650°C.
7. Procédé selon l'une quelconque des revendications 1 à 6, dans lequel il existe de 1 à 20 m2 de surface de métal actif par gramme de composé à détruire.
8. Procédé selon la revendication 3, dans lequet le métal est régénéré par traitement avec une solution d'hydroxyde de sodium.
9. Procédé selon la revendication 3, dans lequel le métal est régénéré par exposition à une température élevée à l'action de l'oxygène puis du chlore.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT85308218T ATE40528T1 (de) | 1984-11-23 | 1985-11-12 | Vernichtung halogen enthaltender organischer verbindungen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB848429709A GB8429709D0 (en) | 1984-11-23 | 1984-11-23 | Halogen-containing organic compounds |
| GB8429709 | 1984-11-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0184342A1 EP0184342A1 (fr) | 1986-06-11 |
| EP0184342B1 true EP0184342B1 (fr) | 1989-02-01 |
Family
ID=10570205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP85308218A Expired EP0184342B1 (fr) | 1984-11-23 | 1985-11-12 | Destruction de composés organiques halogénés |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0184342B1 (fr) |
| JP (1) | JPS61137831A (fr) |
| AT (1) | ATE40528T1 (fr) |
| AU (1) | AU586840B2 (fr) |
| BR (1) | BR8505887A (fr) |
| CA (1) | CA1258682A (fr) |
| DE (1) | DE3568009D1 (fr) |
| ES (1) | ES8704867A1 (fr) |
| GB (1) | GB8429709D0 (fr) |
| IN (1) | IN165170B (fr) |
| NO (1) | NO163265C (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3623492A1 (de) * | 1986-07-11 | 1988-01-21 | Hagenmaier Hans Paul | Verfahren zum abbau von halogenierten aromaten |
| US5276250A (en) * | 1986-07-11 | 1994-01-04 | Hagenmaier Hans Paul | Process for decomposing polyhalogenated compounds |
| GB8813270D0 (en) * | 1988-06-04 | 1988-07-06 | Plasma Products Ltd | Dry exhaust gas conditioning |
| DE3820317A1 (de) * | 1988-06-15 | 1989-12-21 | Christian O Schoen | Verfahren zum zerlegen schaedliche oder umweltbelastende bestandteile enthaltender fliessfaehiger organischer medien |
| DE3932927A1 (de) * | 1989-10-03 | 1991-04-18 | Hansjoerg Prof Dr Sinn | Verfahren zur entfernung von organohalogenverbindungen aus kohlenwasserstoffgemischen, insbesondere aus pyrolyseprodukten in gasphase |
| US5141629A (en) * | 1990-05-15 | 1992-08-25 | State Of Israel, Atomic Energy Commission | Process for the dehalogenation of organic compounds |
| US5490919A (en) * | 1990-08-14 | 1996-02-13 | State Of Isreal, Atomic Energy Commission | Process for the dehalogenation of organic compounds |
| LU90191A7 (de) * | 1997-07-23 | 1999-06-24 | Pac Holdings S A | Verfahren zur entsorgung von halogenierten und nicht halogenierten abfallstoffen |
| EP0937483B1 (fr) * | 1998-02-10 | 2003-09-24 | Miyoshi Yushi Kabushiki Kaisha | Procédé de traitement de déchets solides |
| RU2200602C1 (ru) * | 2001-10-22 | 2003-03-20 | Федеральное государственное унитарное предприятие "Государственный научно-исследовательский институт органической химии и технологии" | СПОСОБ УНИЧТОЖЕНИЯ ЛЮИЗИТА (β-ХЛОРВИНИЛДИХЛОРАРСИН) |
| JP4954133B2 (ja) * | 2008-03-31 | 2012-06-13 | 本田技研工業株式会社 | オイル通路構造 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2346562A (en) * | 1940-11-07 | 1944-04-11 | Dow Chemical Co | Method of removing carbonized oil residue from magnesium articles |
| FR1190669A (fr) * | 1957-12-03 | 1959-10-14 | Pechiney | Fabrication de dérivés organiques de l'aluminium |
| US2977323A (en) * | 1958-07-14 | 1961-03-28 | Phillips Petroleum Co | Process for reactivating used cracking catalysts |
| US3343911A (en) * | 1964-02-20 | 1967-09-26 | Pittsburgh Plate Glass Co | Production of aluminum trichloride |
| US3481877A (en) * | 1967-02-27 | 1969-12-02 | Amchem Prod | Cleaning solution concentrate and method of preparing same |
| JPS5125471A (en) * | 1974-08-28 | 1976-03-02 | Arita Kenkyusho Kk | Horienkabifueniiru no bunkaiho |
| JPS5729313A (en) * | 1980-07-28 | 1982-02-17 | Hideo Koga | Suprort for bedding |
| US4469661A (en) * | 1982-04-06 | 1984-09-04 | Shultz Clifford G | Destruction of polychlorinated biphenyls and other hazardous halogenated hydrocarbons |
| US4447262A (en) * | 1983-05-16 | 1984-05-08 | Rockwell International Corporation | Destruction of halogen-containing materials |
-
1984
- 1984-11-23 GB GB848429709A patent/GB8429709D0/en active Pending
-
1985
- 1985-11-12 AT AT85308218T patent/ATE40528T1/de not_active IP Right Cessation
- 1985-11-12 DE DE8585308218T patent/DE3568009D1/de not_active Expired
- 1985-11-12 EP EP85308218A patent/EP0184342B1/fr not_active Expired
- 1985-11-21 CA CA000495858A patent/CA1258682A/fr not_active Expired
- 1985-11-22 AU AU50353/85A patent/AU586840B2/en not_active Ceased
- 1985-11-22 ES ES549182A patent/ES8704867A1/es not_active Expired
- 1985-11-22 IN IN984/DEL/85A patent/IN165170B/en unknown
- 1985-11-22 NO NO854693A patent/NO163265C/no unknown
- 1985-11-22 JP JP60263640A patent/JPS61137831A/ja active Pending
- 1985-11-22 BR BR8505887A patent/BR8505887A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN165170B (fr) | 1989-08-19 |
| JPS61137831A (ja) | 1986-06-25 |
| ES8704867A1 (es) | 1987-04-16 |
| NO163265B (no) | 1990-01-22 |
| EP0184342A1 (fr) | 1986-06-11 |
| ATE40528T1 (de) | 1989-02-15 |
| NO163265C (no) | 1990-05-02 |
| DE3568009D1 (en) | 1989-03-09 |
| CA1258682A (fr) | 1989-08-22 |
| AU586840B2 (en) | 1989-07-27 |
| BR8505887A (pt) | 1986-08-12 |
| ES549182A0 (es) | 1987-04-16 |
| GB8429709D0 (en) | 1985-01-03 |
| AU5035385A (en) | 1986-05-29 |
| NO854693L (no) | 1986-05-26 |
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