EP0256443A2 - Composition à base d'acide peroxydé et son utilisation dans des compositions détergentes - Google Patents

Composition à base d'acide peroxydé et son utilisation dans des compositions détergentes Download PDF

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Publication number
EP0256443A2
EP0256443A2 EP87111425A EP87111425A EP0256443A2 EP 0256443 A2 EP0256443 A2 EP 0256443A2 EP 87111425 A EP87111425 A EP 87111425A EP 87111425 A EP87111425 A EP 87111425A EP 0256443 A2 EP0256443 A2 EP 0256443A2
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EP
European Patent Office
Prior art keywords
peroxyacid
acid
weight
bleach composition
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP87111425A
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German (de)
English (en)
Other versions
EP0256443A3 (fr
Inventor
Timothy David Finch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
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Unilever PLC
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Filing date
Publication date
Application filed by Unilever PLC filed Critical Unilever PLC
Publication of EP0256443A2 publication Critical patent/EP0256443A2/fr
Publication of EP0256443A3 publication Critical patent/EP0256443A3/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds

Definitions

  • This invention relates to a dry, granular bleaching composition comprising a peroxyacid compound, having improved stability and effectiveness.
  • the dry, granular peroxyacid bleaching composition of the invention can be used as a bleach additive to or as a bleach component in detergent compositions suitable for washing, cleaning, sanitizing and/or bleaching of substrates, particularly fabrics.
  • Organic peroxyacids as a class are quite effective bleaches and the use of organic peroxyacid compounds as the bleach system in detergent compositions has been proposed in the art (see for example GB Patent 1,456,591, US Patent 4,100,095 and EP-B- 00 37 146).
  • GB Patent 1,456,591, US Patent 4,100,095 and EP-B- 00 37 146 Although the efficiency of certain organic peroxyacid compound bleach systems has long been recognized at low to medium wash temperatures, the major problem, which has prevented their exploitation so far, has been their inherent instability in conventional alkaline fabric-­washing compositions. Their use has therefore been restricted to specialized wash additive products.
  • Solid peroxyacid particularly diperoxy dodecanedioic acid
  • highly diluted forms of granules, powder mix or aqueous suspensions having a peroxyacid content of up to 12% by weight have been manufactured on a small scale.
  • Such highly diluted organic peroxyacid forms are, however, not suitable for use as an effective bleach system in detergent bleach compositions owing to high amounts of inactive material introduced into the composition.
  • the present invention seeks to provide an improved granular organic peroxyacid bleach composition which can be suitably used as an effective bleach component of fabric-washing compositions.
  • the dry, granular peroxyacid bleach composition of the invention consists of particles of which more than 75% by weight will have a size of from 500-2000 ⁇ m, and comprises from 20 to 65% by weight of an organic peroxyacid compound, at least one inert inorganic salt in an amount of from 79.5-30% by weight, and from 0.5 to about 6.5% by weight of a non-oxidisable acidic polymeric binder.
  • the acidic polymers usable as a binder in this invention can be any non-cellulosic homo-or copolymeric mono- and polycarboxylic acids having an average molecular weight of from 500 to about 1,000,000, preferably from 2000-­250,0000, more preferably from 10,000-50,000.
  • Suitable polymers include those derived from acrylic acid, methacrylic acid, maleic acid, citraconic acid, aconitic acid, fumaric acid, mesaconic acid, phenyl maleic acid, benzyl maleic acid, itaconic acid, methylene malonic acid, alpha-C1-C4 alkyl acrylic acid, alpha-hydroxy acrylic acid and acetalcarboxylic acid monomers, or from the anhydrides of the above monomers where these exist.
  • the polymer can be homopolymers of the above mono- or polycarboxylic monomers; or copolymers of two or more of the above mono- or polycarboxyl monomers; or copolymers of one or more of the above carboxyl monomers with an unsaturated polymerizable monomer other than the specified mono- and polycarboxyl monomers; or modified homo- or copolymers of the above classes having for example a non-oxidisable phosphinic acid or sulphinic acid group.
  • Preferred acidic polymeric binders are polyacrylic acids, phosphinate-modified polyacrylic acids such as described in GB Patents 1,485,235 and 1,595,688 and EP-­A- 01 82 411; copolymers of maleic acid (anhydride) and acrylic or methacrylic acid; and acidic copolymers containing hydrophobic groups, such as copolymers based on polymethacrylic acid and polyacrylic acid esters in which the ratio of free carboxyl groups to ester groups is at least 1:1.
  • Copolymers of the latter group can be advantageously used as polymeric binder for granular peroxyacid bleach compositions for use in liquid bleaching compositions, where they could further reduce the solubility of the organic peroxyacid, and hence improve its stability.
  • molecular weights are from 2000-250,000, more preferably from 10,000-­50,000.
  • the inert inorganic salts usable in the present invention are non-alkaline salts and can be neutral or acid salts. They are used as a diluent in an amount within the range as specified above, which is adjustable at will dependent upon the levels of the organic peroxyacid compound and the acidic polymeric binder in the granule composition.
  • suitable inert inorganic salts are sodium sulphate (Na2SO4), sodium hydrogen sulphate (NaHSO4), potassium sulphate (K2SO4), potassium hydrogen sulphate (KHSO4); the alkali metal acid phosphates such as Na2HPO4, NaH2PO4, K2HPO4 and KH2PO4.
  • the organic peroxyacid compounds used in the present invention are solid at room temperature and should preferably have a melting point of at least 50°C.
  • Such peroxyacid compounds are the organic peroxyacids and water-soluble salts thereof having the general formula: HO-O- -R-Y, wherein R is an alkylene or substituted alkylene group containing 1 to 20 carbon atoms or an arylene group containing from 6 to 8 carbon atoms, and Y is hydrogen, halogen, alkyl, aryl or any group which provides an anionic moiety in aqueous solution.
  • Y groups can include, for example: wherein M is H or a water-soluble, salt-forming cation.
  • the organic peroxyacids and salts thereof usable in the present invention can contain either one, two or more peroxy groups and can be either aliphatic or aromatic.
  • the unsubstituted acid may have the general formula: HO-O- -(CH2) n -Y wherein Y can be H, -CH3, -CH2Cl, - -OM, or - -O-OM and n can be an integer from 6 to 20.
  • Peroxydodecanoic acids, peroxytetradecanoic acids and peroxyhexadecanoic acids are the most preferred compounds of this type, particularly 1, 12-­diperoxydodecanedioic acid, 1,14-­diperoxytetradecanedioic acid and 1,16-­diperoxyhexadecanedioic acid.
  • Examples of other preferred compounds of this type are diperoxyazelaic acid, diperoxyadipic acid and diperoxysebacic acid.
  • the unsubstituted acid may have the general formula: HO-O- -C6H4-Y wherein Y is, for example, hydrogen, halogen, alkyl, - -OM, or - -O-OM.
  • the percarboxy and Y groupings can be in any relative position around the aromatic ring.
  • the ring and/or Y group (if alkyl) can contain any non-interfering substituents such as halogen or sulphonate groups.
  • suitable aromatic peroxyacids and salts thereof include monoperoxyphthalic acid, diperoxyterephthalic acid, 4-chlorodiperoxyphthalic acid, diperoxyisophthalic acid, peroxy benzoic acids and ring-substituted peroxy benzoic acids, such as peroxy-alpha-naphthoic acid.
  • a preferred aromatic peroxyacid is diperoxyisophthalic acid.
  • the granular peroxyacid bleach composition of the invention will preferably have a particle size of between 500 and 1700 ⁇ m, more preferably from 500 ⁇ m to 1200 ⁇ m, and a reactive organic peroxyacid content of from 35% to about 55% by weight.
  • the level of acidic polymeric binder should preferably be kept as low as possible, e.g. from 0.5-3.0% by weight, as true encapsulation is not aimed at, in contrast with previous workers who believed in the theory of stabilization by encapsulation. Besides, high binder levels were found to reduce peroxyacid stability.
  • a heavy metal sequestrant such as ethylenediamine tetraacetic acid (EDTA), ethylenediamine tetramethylene phosphonic acid (EDTMP), dipicolinic acid or Chel® DP may further be incorporated as desired in the peroxyacid granule of the invention. They are normally incorporated in only small amounts of up to about 5% by weight of the composition, preferably from 0.05 to 2.5% by weight.
  • the granular peroxyacid bleach composition of the invention may further contain any solid organic acid, such as citric acid, succinic acid, adipic acid, glutaric acid and mixtures thereof. These may be present at a level of up to about 20% by weight of the composition.
  • Additional coating of the peroxyacid granule with a protective layer does not essentially contribute to increased peroxyacid stability, but it may be applied as desired to prevent or reduce interaction with oxidation-susceptible components of the detergent composition, such as fluorescers and perfumes.
  • Suitable coating materials are, for example, saturated long-chain fatty acids of C12-C22 chain length. These coating materials can be advantageously used at a level of 1-5% by weight. In most cases a coating level of about 2% by weight is adequate for serving the purpose and there is no need to exceed said level.
  • the dry, granular peroxyacid bleach composition can be conveniently prepared by spraying polymeric binder solutions onto a dry mixture of the organic peroxyacid and the inert inorganic salt using any type of granulating equipment, such as a pan granulator or a rotating drum-type granulator. Alternatively, the other granulation processes, such as noodling, marumerizing and the like can be used, followed by drying.
  • Optional coating can be applied by a second spray of liquefied coating material onto the dry, granular composition.
  • the dry, granular peroxyacid bleaching composition of the invention can be used as an effective bleach component in detergent compositions, which are particularly suitable for use at low to medium wash temperatures, e.g. from 20°C to 60°C.
  • a low to medium temperature bleach detergent composition comprising a surface-active compound, a detergency builder and a dry granular peroxyacid bleaching composition as defined hereinbefore.
  • Said dry, granular peroxyacid bleaching composition of the invention can be incorporated in bleach detergent compositions in amounts of from 1 to 15% by weight, preferably from 2 to 10% by weight, calculated as organic peroxyacid, without difficulty.
  • the bleach detergent compositions of the invention will contain at least one surface-active compound, which may be anionic, cationic, nonionic or amphoteric in character, the amount of which generally will be from about 3 to about 40%, preferably from 10 to 35% by weight.
  • mixtures of the above surface-active compounds are used; mixtures of anionic and nonionic surface-active compounds are commonly used.
  • Typical anionic surface-active compounds are water-­soluble or water-dispersible salts of various organic acids.
  • the cations of such salts are generally alkali metals, such as sodium and, less preferably, potassium, but other cations, such as ammonium and substituted ammonium, can be used if desired.
  • alkyl benzene sulphonic acids the alkyl chains of which contain from about 8 to about 20 carbon atoms, such as p-dodecyl benzene sulphonic acid and linear alkyl (C 10-15 ) benzene suphonic acid; the mixtures of sulphonic acids obtained by reacting linear and branched olefins, particularly linear "cracked-wax” or “Ziegler" alpha-olefins, containing from about 8 to about 22 carbon atoms, with sulphur trioxide; alkyl sulphonic acids obtained by reacting alkanes containing from about 8 to about 22 carbon atoms with sulphur dioxide/oxygen or sulphur dioxide/chlorine (followed by hydrolysis in the latter case), or by the addition of bisulphite to olefins, particularly linear "cracked-­wax” or "Ziegler alpha-olefins,
  • nonionic surface-active compounds are condensates of alkylphenols having an alkyl group (derived, for example, from polymerized propylene, diisobutylene, octene, dodecene or nonene) containing from about 6 to 12 carbon atoms in either a straight-­chain or branched-chain configuration, with about 5 to 25 moles of ethylene oxide per mole of alkylphenol; condensates containing from about 40% to about 80% polyoxyethylene by weight and having a molecular weight of from about 5,000 to about 11,000 resulting from the reaction of ethylene oxide with the reaction product of ethylenediamine and excess propylene oxide; condensates of linear or branched-chain aliphatic alcohols containing from 8 to 18 carbon atoms with ethylene oxide, e.g.
  • a coconut alcohol-ethylene oxide condensate containing about 6 to 30 moles of ethylene oxide per mole of coconut alcohol
  • long-chain tertiary amine oxides corresponding to the general formula R1R2R3N O, wherein R1 is an alkyl radical containing from about 8 to 18 carbon atoms and R2 and R3 are each methyl, ethyl or hydroxy ethyl radicals, such as dimethyldodecylamine oxide, dimethyloctylamine oxide, dimethylhexadecylamine oxide and N-bis (hydroxyethyl) dodecylamine oxide; long-chain tertiary phosphine oxides corresponding to the general formula RR ⁇ R ⁇ P ⁇ O, wherein R is an alkyl, alkenyl or monohydroxyalkyl radical containing from 10 to 18 carbon atoms and R ⁇ and R ⁇ are each alkyl or monohydroxyalkyl groups containing from one to three carbon atoms, such as dimethyldo
  • amphoteric surface-active compounds are: derivatives of aliphatic secondary and tertiary amines, in which the aliphatic radical may be straight-chain or branched and wherein one of the aliphatic substituents contains from about 8 to 18 carbon atoms and one contains an anionic water-­solubilizing group, such as sodium-3-­dodecylaminopropionate, sodium-3-docecylaminopropane­sulphonate and sodium N-2-hydroxydodecyl-N-methyl­taurate; and derivatives of aliphatic quaternary ammonium compounds, sulphonium compounds and phosphonium compounds in which the aliphatic radical may be straight-chain or branched and wherein one of the aliphatic substituents contains from about 8 to 18 carbon atoms and one contains an anionic water-­solubilizing group, such as 3-(N,N-dimethyl-N-­hexadecylammonium) propane-1
  • the bleach detergent composition of the invention also includes one or more detergency builders.
  • Usually the total amount of detergency builders in a detergent composition of the invention will be from about 5% to about 70% by weight of the detergent composition.
  • Many detergency builders are known, and those skilled in the art of formulating fabric-washing detergent compositions will be familiar with these materials.
  • detergency builders are sodium tripolyphosphate; sodium orthophosphate; sodium pyrophosphate; sodium trimetaphosphate; sodium ethane-­1-hydroxy-1,1-diphosphonate; sodium carbonate; sodium silicate; sodium citrate; sodium oxydiacetate; sodium nitrilotriacetate; sodium ethylenediaminetetraacetate; sodium salts of long-chain dicarboxylic acids, for instance straight-chain (C10 to C20) succinic acids and malonic acids; sodium salts of alpha-sulphonated long-chain monocarboxylic acids; sodium salts of polycarboxylic acids; i.e.
  • acids derived from the polymerization or copolymerization of unsaturated carboxylic acids and unsaturated carboxy acid anhydrides such as maleic acid, acrylic acid, itaconic acid, methacrylic acid, crotonic acid and aconitic acid, and the anhydrides of these acids, and also from the copolymerization of the above acids and anhydrides with minor amounts of other monomers, such as vinyl chloride, vinyl acetate, methyl methacrylate, methyl acrylate and styrene; and modified starches such as starches oxidized, for example using sodium hypochlorite, in which some anhydroglucose units have been opened to give dicarboxyl units.
  • detergency builder which can be used, either alone or in admixture with other builders, is a cation-exchange material, especially a sodium aluminosilicate such as described in GB Patent 1,429,143 or in Netherlands Patent Application 7403381.
  • Preferred materials of this type have the formula: (Na2O) 0.7-1.1 .Al2O3(SiO2) 1.3-3.3 and may be amorphous or crystalline, with some bound water usually in an amount of about 10-30% depending on the drying conditions used.
  • Such water-insoluble aluminosilicate cation-exchange materials are available as very finely divided powder, commercially known under various grades of zeolites, e.g. Zeolite A and Zeolite B.
  • any of these builders can be used to prepare the detergent base powder for admixing with the dry, granular peroxyacid bleaching composition of the invention.
  • the solution pH of the base powder measured at 5 g/l in distilled water should not exceed 9.5 and the moisture content is kept low.
  • the detergent base powder should preferably have a moisture content of not more than 6%, particularly not more than 3%.
  • the dry, granular peroxyacid bleaching composition should preferably incorporate a heavy metal sequestrant.
  • acidic copolymers containing hydrophobic groups are preferably used as the acidic polymeric binder for improved stability.
  • the zeolite-built detergent base powder composition incorporates a hydratable material to act as moisture sink.
  • the bleach detergent composition of the invention may contain any other non-­interfering ingredients normally used in detergent compositions in minor amounts, which serve to improve the bleaching and laundering characteristics of the compositions or which add aesthetic appeal to the composition.
  • minor ingredients can include buffering agents, sequestering agents and co-builders; suds-control agents; soil-suspending agents and anti-redeposition agents; enzymes, particularly proteolytic and lipolytic enzymes; corrosion inhibitors; optical brighteners; colouring agents, perfumes and filler materials.
  • such minor components comprise no more than 20% by weight of the bleach detergent composition.
  • peroxide bleaches such as sodium perborate may also be included with benefit in amounts from e.g. 2-­20% by weight, preferably from 5-15% by weight of the detergent bleach composition.
  • the granulated products were dried (over P2O5 or at 40°C) and sieved to obtain the 500-1700 ⁇ m fractions.
  • PAA Polyacrylic acid
  • DKW Phosphinate-modified polyacrylic acid.
  • Granule compositions III and IV were each dry-mixed with the following base powder composition (A) at a ratio of 82% base powder to 18% granule composition.
  • the powders were stored in open vials at 30°C and 75% relative humidity conditions and the peroxyacid decomposition rates of both compositions were monitored.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP87111425A 1986-08-15 1987-08-07 Composition à base d'acide peroxydé et son utilisation dans des compositions détergentes Withdrawn EP0256443A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB868619953A GB8619953D0 (en) 1986-08-15 1986-08-15 Peroxyacid bleach composition
GB8619953 1986-08-15

Publications (2)

Publication Number Publication Date
EP0256443A2 true EP0256443A2 (fr) 1988-02-24
EP0256443A3 EP0256443A3 (fr) 1988-12-14

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Application Number Title Priority Date Filing Date
EP87111425A Withdrawn EP0256443A3 (fr) 1986-08-15 1987-08-07 Composition à base d'acide peroxydé et son utilisation dans des compositions détergentes

Country Status (7)

Country Link
EP (1) EP0256443A3 (fr)
JP (1) JPS6348400A (fr)
AU (1) AU600503B2 (fr)
BR (1) BR8704199A (fr)
GB (1) GB8619953D0 (fr)
TR (1) TR23892A (fr)
ZA (1) ZA876041B (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4863626A (en) * 1985-08-21 1989-09-05 The Clorox Company Encapsulated enzyme in dry bleach composition
EP0340847A3 (fr) * 1988-05-05 1990-10-03 Unilever N.V. Procédé de préparation de corps contenant un composé d'un peroxyacide et compositions comprenant les dits corps
EP0360323A3 (fr) * 1988-09-20 1990-11-07 Unilever N.V. Compositions de blanchiment et procédé de préparation
EP0450587A3 (en) * 1990-04-06 1991-12-18 Hoechst Aktiengesellschaft Stable granules of peroxycarboxylic acid
EP0421664A3 (en) * 1989-10-02 1991-12-18 Rohm And Haas Company Polymer-containing granulates
US5279757A (en) * 1990-04-06 1994-01-18 Hoechst Aktiengesellschaft Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof
US5296239A (en) * 1989-10-05 1994-03-22 Interox Peracetic acid compositions and process for obtaining these compositions
US5409632A (en) * 1992-11-16 1995-04-25 The Procter & Gamble Company Cleaning and bleaching composition with amidoperoxyacid
US5536435A (en) * 1992-10-07 1996-07-16 The Procter & Gamble Company Process for making peroxyacid containing particles
US5932532A (en) * 1993-10-14 1999-08-03 Procter & Gamble Company Bleach compositions comprising protease enzyme
US7708905B2 (en) 2004-03-31 2010-05-04 Lg Household & Health Care Ltd. Method for preparing ester compounds as bleach activators

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1847590B1 (fr) * 2006-04-20 2013-06-19 The Procter & Gamble Company Procédé pour la préparation de particules de blachiment

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IE49996B1 (en) * 1979-07-06 1986-01-22 Unilever Ltd Particulate bleach compositions
DE3515712A1 (de) * 1985-05-02 1986-11-06 Henkel KGaA, 4000 Düsseldorf Bleichwirkstoff, seine herstellung und seine verwendung
DE3683882D1 (de) * 1985-08-21 1992-03-26 Clorox Co Stabiles persaeurebleichmittel.

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4863626A (en) * 1985-08-21 1989-09-05 The Clorox Company Encapsulated enzyme in dry bleach composition
EP0340847A3 (fr) * 1988-05-05 1990-10-03 Unilever N.V. Procédé de préparation de corps contenant un composé d'un peroxyacide et compositions comprenant les dits corps
EP0360323A3 (fr) * 1988-09-20 1990-11-07 Unilever N.V. Compositions de blanchiment et procédé de préparation
EP0421664A3 (en) * 1989-10-02 1991-12-18 Rohm And Haas Company Polymer-containing granulates
US5296239A (en) * 1989-10-05 1994-03-22 Interox Peracetic acid compositions and process for obtaining these compositions
EP0450587A3 (en) * 1990-04-06 1991-12-18 Hoechst Aktiengesellschaft Stable granules of peroxycarboxylic acid
US5279757A (en) * 1990-04-06 1994-01-18 Hoechst Aktiengesellschaft Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof
US5536435A (en) * 1992-10-07 1996-07-16 The Procter & Gamble Company Process for making peroxyacid containing particles
US5409632A (en) * 1992-11-16 1995-04-25 The Procter & Gamble Company Cleaning and bleaching composition with amidoperoxyacid
US5932532A (en) * 1993-10-14 1999-08-03 Procter & Gamble Company Bleach compositions comprising protease enzyme
US7708905B2 (en) 2004-03-31 2010-05-04 Lg Household & Health Care Ltd. Method for preparing ester compounds as bleach activators

Also Published As

Publication number Publication date
AU7674587A (en) 1988-02-18
TR23892A (tr) 1990-10-17
EP0256443A3 (fr) 1988-12-14
GB8619953D0 (en) 1986-09-24
JPS6348400A (ja) 1988-03-01
ZA876041B (en) 1989-04-26
BR8704199A (pt) 1988-04-12
AU600503B2 (en) 1990-08-16

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